Dulux Gloss Enamel Msds
Dulux Gloss Enamel Msds
Dulux Gloss Enamel Msds
1.2. Relevant identified uses of the substance or mixture and uses advised against
Product use : Solvent borne coating for interior and exterior use.
Version : 8
Date of previous issue : 23-12-2018
4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Contains butanone oxime, neodecanoic acid, cobalt salt. May produce an allergic reaction.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
6.2 Environmental : Do not allow to enter drains or watercourses. If the product contaminates lakes,
precautions rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.
6.3 Methods and material : Contain and collect spillage with non-combustible, absorbent material e.g. sand,
for containment and earth, vermiculite or diatomaceous earth and place in container for disposal
cleaning up according to local regulations (see Section 13). Preferably clean with a detergent.
Avoid using solvents.
PNECs
No PNECs available
NOTICE: The selection of a specific glove for a particular application and duration of
use in a workplace should also take into account all relevant workplace factors such
as, but not limited to: Other chemicals which may be handled, physical requirements
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.
Always ensure that the gloves are free from defects and that they are stored and
used correctly.
Body protection : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators.
When surfaces are to be prepared for painting, account should be taken of the age
of the property and the possibility that lead-pigmented paint might be present. There
is a possibility that ingestion or inhalation of scrapings or dust arising from the
preparation work could cause health effects. As a working rule you should assume
that this will be the case if the age of the property is pre 1960.
Where possible wet sanding or chemical stripping methods should be used with
surfaces of this type to avoid the creation of dust. When dry sanding cannot be
avoided, and effective local exhaust ventilation is not available, it is recommended
that a dust respirator is worn, that is approved for use with lead dusts, and its type
selected on the basis of the COSHH assessment, taking into account the
Workplace Exposure Limit for lead in air. Furthermore, steps should be taken to
ensure containment of the dusts created, and that all practicable measures are
taken to clean up thoroughly all deposits of dusts in and around the affected area.
Respiratory protection in case of dust or spray mist formation. (particle filter EN143
type P2) Respiratory protection in case of vapour formation. (half mask with
combination filter A2-P2 til concentrations of 0,5 Vol%.)
The current Control of Lead at Work Regulations approved code of practice should
be consulted for advice on protective clothing and personal hygiene precautions.
Care should also be taken to exclude visitors, members of the household and
especially children from the affected area, during the actual work and the
subsequent clean up operations. All scrapings, dust, etc. should be disposed of by
the professional painting contractor as Hazardous Waste.
Extra precautions will also need to be taken when burning off old lead-based paints
because fumes containing lead will be produced. It is recommended that a
respirator, approved for use with particulate fumes of lead is selected on the basis
of the COSHH assessment, taking into account the Workplace Exposure Limit for
lead in air. Similar precautions to those given above about sanding should be taken
with reference to protective clothing, disposal of scrapings and dusts, and exclusion
of other personnel and especially children from the building during actual work and
the subsequent clean up operations.
Avoid the inhalation of dust. Wear suitable face mask if dry sanding. Special
precautions should be taken during surface preparation of pre-1960s paint surfaces
over wood and metal as they may contain harmful lead.
Environmental exposure : Do not allow to enter drains or watercourses.
controls
10.2 Chemical stability : Stable under recommended storage and handling conditions (see Section 7).
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.
10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
10.6 Hazardous : Decomposition products may include the following materials: carbon monoxide,
decomposition products carbon dioxide, smoke, oxides of nitrogen.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Contains butanone oxime, neodecanoic acid, cobalt salt. May produce an allergic reaction.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Solvent naphtha LC50 Inhalation Vapour Rat >5500 ppm 4 hours
(petroleum), medium aliph.
LD50 Dermal Rabbit >3000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Solvent naphtha LDLo Oral Rat 5 mL/kg -
(petroleum), heavy arom.
Conclusion/Summary : Not available.
Acute toxicity estimates
Not available.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Solvent naphtha (petroleum), Skin - Mild irritant Rabbit - 24 hours 500 -
heavy arom. microliters
Methyl ethyl ketoxime Eyes - Severe irritant Rabbit - 100 -
microliters
Conclusion/Summary : Not available.
Sensitisation
Conclusion/Summary : Not available.
Mutagenicity
Conclusion/Summary : Not available.
Carcinogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
Teratogenicity
Conclusion/Summary : Not available.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
Naphtha (petroleum), hydrodesulfurized heavy Category 3 Not applicable. Narcotic effects
Specific target organ toxicity (repeated exposure)
The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is
classified for eco-toxicological properties accordingly. See Sections 2 and 3 for details.
Product/ingredient name Result Species Exposure
2-butoxyethanol Acute EC50 >1000 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Conclusion/Summary : Not available.
Subsidiary class - -
Information pertaining to IATA and ADN is considered not relevant since the
material is not packaged in the correct approved packaging required of these
methods of transport.
14.5
Environmental
hazards
Marine pollutant No. No.
Additional Viscous substance exemption In pack sizes Viscous substance exemption In pack sizes
information less than 450 litres, under the terms of 2.2.3.1. up to and including 30 litres, under the terms of
5, 2.3.2.5, this product is not subject to the
this product is not subject to the provisions of packaging,
ADR. labelling and marking requirements of the
Tunnel code (D/E) IMDG Code, but both full documentation and
placarding of cargo transport units is still
required.
Seveso Directive
This product may add to the calculation for determining whether a site is within the scope of the Seveso Directive on
major accident hazards.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
15.2 Chemical safety : No Chemical Safety Assessment has been carried out.
assessment
Brand names mentioned in this data sheet are trademarks of or are licensed to AkzoNobel.
Head Office
AkzoNobel Decorative Coatings BV, Christian Neefestraat 2, 1077 WW Amsterdam, The Netherlands