Hempel's Thinner 08230

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Safety Data Sheet

Hempel's Thinner 08230

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878 - Europe

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Product name : Hempel's Thinner 08230
Product identity : 0823000000
Product type : thinner

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : buildings and metal industry. yacht, ships and shipyards.
Identified uses : Consumer applications, Industrial applications, Professional applications.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
[email protected]
Date of issue : 18 November 2022
Date of previous issue : 12 November 2021.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects)
STOT RE 1, H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
Asp. Tox. 1, H304 ASPIRATION HAZARD
Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM)
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements


Hazard pictograms :

Signal word : Danger


Hazard statements : H226 - Flammable liquid and vapor.
H304 - May be fatal if swallowed and enters airways.
H336 - May cause drowsiness or dizziness.
H372 - Causes damage to organs through prolonged or repeated exposure.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements :
General : Keep out of reach of children. If medical advice is needed, have product container or label at hand.
Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use
only outdoors or in a well-ventilated area. Avoid release to the environment. Do not breathe vapor,
mist or spray. Do not eat, drink or smoke when using this product.
Response : Collect spillage. IF INHALED: Call a POISON CENTER or doctor if you feel unwell. IF SWALLOWED:
Immediately call a POISON CENTER or doctor. Do NOT induce vomiting.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed.
Disposal : Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Hazardous ingredients : hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
Supplemental label elements : Repeated exposure may cause skin dryness or cracking.
Special packaging requirements

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SECTION 2: Hazards identification


Containers to be fitted with child- Yes, applicable.
resistant fastenings :
Tactile warning of danger : Yes, applicable.

2.3 Other hazards


This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
Other hazards which do not result None known.
in classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

hydrocarbons, C9-C12, n- REACH #: 01-2119458049-33 ≥90 Flam. Liq. 3, H226 - [1] [2]
alkanes, isoalkanes, cyclics, EC: 265-185-4 STOT SE 3, H336
aromatics (2-25%) CAS: 64742-82-1 STOT RE 1, H372
Index: 649-405-00-X (central nervous system
(CNS)) (inhalation)
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
EUH066
solvent naphtha (petroleum), REACH #: 01-2119455851-35 ≥1 - ≤3 Flam. Liq. 3, H226 - [1] [2]
light arom. EC: 918-668-5 STOT SE 3, H335
CAS: 64742-95-6 STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
EUH066
naphthalene REACH #: 01-2119561346-37 <1 Acute Tox. 4, H302 ATE [Oral] = 490 mg/kg [1] [2]
EC: 202-049-5 Carc. 2, H351 M [Acute] = 1
M [Chronic] = 1
CAS: 91-20-3 Aquatic Acute 1, H400
Aquatic Chronic 1, H410
See Section 16 for the full text of the H statements declared
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures


General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 5
minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and seek medical advice.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects

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SECTION 4: First aid measures


Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Skin contact : Defatting to the skin. May cause skin dryness and irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
dryness
cracking
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media


Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.

5.2 Special hazards arising from the substance or mixture


Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides

5.3 Advice for firefighters


Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapor or mist. Refer to protective
measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training. If the product
contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

6.2 Environmental precautions


Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.

6.3 Methods and materials for containment and cleaning up

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SECTION 6: Accidental release measures


Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.

6.4 Reference to other sections


See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling


Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities


Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)


See separate Product Data Sheet for recommendations or industrial sector specific solutions.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters


Product/ingredient name Exposure limit values

hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, EU OEL (Europe, 2000).


aromatics (2-25%) TWA: 25 ppm 8 hours.
TWA: 145 mg/m³ 8 hours.
solvent naphtha (petroleum), light arom. EU OEL (Europe).
TWA: 120 mg/m³ 8 hours. Form: Tentativ
TWA: 25 ppm 8 hours. Form: Tentativ
naphthalene EU OEL (Europe, 1/2022).
TWA: 50 mg/m³ 8 hours.
TWA: 10 ppm 8 hours.

Recommended monitoring procedures


If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels
Not applicable.
Predicted effect concentrations
Not applicable.

8.2 Exposure controls


Appropriate engineering controls

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SECTION 8: Exposure controls/personal protection


Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: safety glasses with side-shields.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:

Recommended: Silver Shield / Barrier / 4H gloves, nitrile rubber, polyvinyl alcohol (PVA), Viton®
Short term exposure: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)

Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator. If working areas have insufficient
ventilation: When the product is applied by means that will not generate an aerosol such as, brush or
roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle
filter of type P. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Physical state : Liquid.
Color : Transparent
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : -66°C This is based on data for the following ingredient: hydrocarbons, C9-C12, n-alkanes, isoalkanes,
cyclics, aromatics (2-25%)
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 38°C (100.4°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Not available.
Lower and upper explosive 1.4 - 7.6 vol %
(flammable) limits :
Vapor pressure : 0.147 kPa This is based on data for the following ingredient: hydrocarbons, C9-C12, n-alkanes,
isoalkanes, cyclics, aromatics (2-25%)
Vapor density : Testing not relevant or not possible due to nature of the product.
Specific gravity : 0.781 g/cm³
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.

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SECTION 9: Physical and chemical properties


Auto-ignition temperature : Lowest known value: 280 - 470°C (536 - 878°F) (hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics,
aromatics (2-25%)).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Kinematic (40°C): <7 mm2/s
Explosive properties : Testing not relevant or not possible due to nature of the product.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information


Solvent(s) % by weight : Weighted average: 100 %
Water % by weight : Weighted average: 0 %
VOC content : 781 g/l
TOC Content : Weighted average: 702 g/l
Solvent Gas : Weighted average: 0.156 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability


The product is stable.

10.3 Possibility of hazardous reactions


Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid


Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.

10.5 Incompatible materials

10.6 Hazardous decomposition products


When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008


Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
solvent naphtha (petroleum), light LC50 Inhalation Vapor Rat 6193 mg/m³ 4 hours
arom.
LD50 Dermal Rabbit 3160 mg/kg -
LD50 Oral Rat 8400 mg/kg -
naphthalene LD50 Dermal Rabbit >20 g/kg -
LD50 Oral Rat 490 mg/kg -
Acute toxicity estimates

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SECTION 11: Toxicological information

Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation


mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
solvent naphtha (petroleum), light arom. 8400 3160
naphthalene 490

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
solvent naphtha (petroleum), light Eyes - Mild irritant Rabbit - 24 hours 100 microliters
arom.
naphthalene Skin - Severe irritant Rabbit - 24 hours 0.05 Mililiters
Mutagenic effects
No known significant effects or critical hazards.

Carcinogenicity
No known significant effects or critical hazards.

Reproductive toxicity
No known significant effects or critical hazards.

Teratogenic effects
No known significant effects or critical hazards.

Specific target organ toxicity (single exposure)


Product/ingredient name Category Route of exposure Target organs
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, Category 3 Narcotic effects
aromatics (2-25%)
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, Category 1 inhalation central nervous system (CNS)
aromatics (2-25%)
Aspiration hazard
Product/ingredient name Result
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, ASPIRATION HAZARD - Category 1
aromatics (2-25%)
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
11.2 Information on other hazards
Endocrine disrupting properties : See Section 15 for details.
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
hydrocarbons, C9-C12, n-alkanes, Chronic EC50 4.6 - 10 mg/l Algae 72 hours
isoalkanes, cyclics, aromatics
(2-25%)
Chronic EC50 10 - 20 mg/l Daphnia 48 hours
Chronic EC50 10 - 30 mg/l Fish 96 hours
solvent naphtha (petroleum), light Acute EC50 19 mg/l Algae - Pseudokirchneriella subcapitata 96 hours
arom. (green algae)
Acute EC50 6.14 mg/l Daphnia - Daphnia magna 48 hours
Acute LC50 9.22 mg/l Fish - Oncorhynchus mykiss (rainbow 96 hours
trout)
naphthalene Acute EC50 1600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours
Acute LC50 2350 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours

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SECTION 12: Ecological information


Acute LC50 213 µg/l Fresh water Fish - Melanotaenia fluviatilis - Larvae 96 hours

12.2 Persistence and degradability


Product/ingredient name Test Result Dose Inoculum
hydrocarbons, C9-C12, n-alkanes, OECD 301F Ready 74.7 % - Readily - 28 days - -
isoalkanes, cyclics, aromatics Biodegradability - Manometric
(2-25%) Respirometry Test
solvent naphtha (petroleum), light - >70 % - Readily - 28 days - -
arom.

Product/ingredient name Aquatic half-life Photolysis Biodegradability


hydrocarbons, C9-C12, n-alkanes, - - Readily
isoalkanes, cyclics, aromatics
(2-25%)
solvent naphtha (petroleum), light - - Readily
arom.

12.3 Bioaccumulative potential


Product/ingredient name LogPow BCF Potential
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics - 10 - 2500 high
(2-25%)
solvent naphtha (petroleum), light arom. - 10 - 2500 high
naphthalene 3.4 36.5 - 168 low

12.4 Mobility in soil


Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.

12.5 Results of PBT and vPvB assessment


Product/ingredient name PBT P B T vPvB vP vB
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties


See Section 15 for details.
12.7 Other adverse effects
No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods


The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

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SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN1263 PAINT RELATED MATERIAL 3 III Yes. The environmentally


Class hazardous substance mark
is not required when
transported in sizes of ≤5 L
or ≤5 kg.
Tunnel code (D/E)

IMDG UN1263 PAINT RELATED MATERIAL. 3 III Yes. The marine pollutant
Class (hydrocarbons, C9-C12, n-alkanes, mark is not required
isoalkanes, cyclics, aromatics when transported in
(2-25%)) sizes of ≤5 L or ≤5 kg.
Emergency schedules
F-E, S-E

IATA UN1263 PAINT RELATED MATERIAL 3 III Yes. The environmentally


Class hazardous substance mark
may appear if required by
other transportation
regulations.
PG* : Packing group
Env.* : Environmental hazards

14.6 Special precautions for user


Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Not applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
E2: Hazardous to the aquatic environment - Chronic 2

15.2 Chemical Safety Assessment


Consumer use: Chemical Safety Assessments for this product are either complete or not applicable.
Not applicable.

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SECTION 16: Other information


Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H226 Flammable liquid and vapor.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.
Full text of classifications [CLP/GHS] : Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Acute 1 AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 1 AQUATIC HAZARD (LONG-TERM) - Category 1
Aquatic Chronic 2 AQUATIC HAZARD (LONG-TERM) - Category 2
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Carc. 2 CARCINOGENICITY - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
STOT RE 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification
FLAMMABLE LIQUIDS On basis of test data
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) Calculation method
ASPIRATION HAZARD Calculation method
AQUATIC HAZARD (LONG-TERM) Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

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Safe Use of Mixture Information
Hempel's Thinner 08230

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor painting by professionals by dipping or with brush, roller, putty knife etc. with enhanced ventilation or local exhaust ventilation (LEV)
This safe use information is : Professional low-energy painting, near-industrial setting - Level I
linked to HMP I/PW 02a
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
application hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Loading of application PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
equipment and handling hours (mechanical) room according to EN 166. tested to EN374.
of coated parts before ventilation
curing

Industrial application of PROC10 More than 4 Local exhaust Refer to Wear a respirator Use eye protection Wear suitable gloves
coatings by other than hours ventilation relevant conforming to EN140 with according to EN 166. tested to EN374.
spraying technical an assigned protection
standards factor of at least 10.

Film formation - force PROC04 More than 4 Enhanced 5 - 10 None None None
drying, stoving and other hours (mechanical) room
technologies ventilation

Cleaning PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Waste management PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 11/14
Safe Use of Mixture Information
Hempel's Thinner 08230

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor painting by professionals with brush or roller, with good general room ventilation (open doors/windows)
This safe use information is : Professional painting, indoor brush/roller - Level I
linked to CEPE / HMP PW 04a
Sector(s) of use : Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
application hours ventilation according to EN 166. tested to EN374.

Loading of application PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours ventilation according to EN 166. tested to EN374.
of coated parts before
curing

Professional application of PROC10 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
coatings by brush or roller hours ventilation according to EN 166. tested to EN374.

Film formation - force PROC04 More than 4 Good general room 3-5 None None None
drying, stoving and other hours ventilation
technologies

Cleaning PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
hours ventilation according to EN 166. tested to EN374.

Waste management PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
hours ventilation according to EN 166. tested to EN374.
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 12/14
Safe Use of Mixture Information
Hempel's Thinner 08230

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor painting by professionals by dipping or with brush, roller, putty knife etc.
This safe use information is : Professional painting, outdoor brush/roller - Level I
linked to CEPE / HMP PW 06a
Sector(s) of use : Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
application hours according to EN 166. tested to EN374.

Loading of application PROC08a More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours according to EN 166. tested to EN374.
of coated parts before
curing

Professional application of PROC10 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
coatings by brush or roller hours according to EN 166. tested to EN374.

Film formation - force PROC04 More than 4 Outdoors 3-5 None None None
drying, stoving and other hours
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.

Waste management PROC08a More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 13/14
Safe Use of Mixture Information
Hempel's Thinner 08230

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor painting by professionals by dipping or with brush, roller, putty knife etc.
This safe use information is : Professional low-energy painting, near-industrial setting - Level I
linked to HMP I/PW 06a
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
application hours according to EN 166. tested to EN374.

Loading of application PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours according to EN 166. tested to EN374.
of coated parts before
curing

Industrial application of PROC10 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
coatings by other than hours according to EN 166. tested to EN374.
spraying

Film formation - force PROC04 More than 4 Outdoors 3-5 None None None
drying, stoving and other hours
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.

Waste management PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 14/14

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