SHS Physical Science Q1 SLM - 3
SHS Physical Science Q1 SLM - 3
SHS Physical Science Q1 SLM - 3
PHYSICAL SCIENCE
FIRST QUARTER MODULE 3
POLARITY OF MOLECULES
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Physical Science – Senior High School
Quarter 1 – Module 3: Polarity of Molecules
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Determine if a molecule is polar or
non-polar given its structure
(S11/12PS-IIIc-15)
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Supplementary Learning Module for Senior High School Learners
LESSON
Polarity of Molecules
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At the end of this module, you should be able to:
1. Define electronegativity
2. Recognize the electronegativity of elements in the periodic
table
3. Explain the VSEPR theory
4. Draw the geometry of molecules using the VSEPR theory
5. Distinguish between polar and non-polar molecules
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Directions: Identify what is asked or described in each
item then write the letter of the correct answer. You may
refer to the periodic table on the previous page.
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Hi! How did you find the test?
Please check your answers at the answer key section and
see how you did. Don’t worry if you got a low score, this just
means that there are more things that you can learn from
this module. So, hop on!
Lesson 1: Electronegativity
In Grade 9, you were able to learn that elements in the periodic table combine with
other elements to form substances and compounds through chemical bonding. You have
already been acquainted with the different properties of elements like boiling point, melting,
point, oxidation number etc. In this module you are going to explore another property of
elements found in the periodic table. Are you ready? Let’s do this.
NC T ENAG YVT
Unlock the mystery word by combining the two words in A and B to form a single word. What
is the mystery word? Write your answer below.
___________________________________________________
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How did you find the activity? I hope that you were able to unlock the mystery word
that we are looking for. What’s the word again? Yes, you’re right the word is
ELECTRONEGATIVITY. Do you have any idea what is this all about? Well don’t worry if you
haven’t because this module will help you discover its meaning and importance. Unlike the
pictures showing negativity I just hope that you’re an optimist (positive thinker) and would try
your best to accomplish this module no matter how difficult it is. Let’s try the following activity.
Source: www.mrteverett.com/Chemistry/pdictable/electronegativity%20table.jpg
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Electronegativity Electronegativity Molecular
Molecule Bond Type
Values Difference Polarity
Example:H2O H = 2.1, O = 3.5 3.5 – 2.1 = 1.4 Polar bond Polar molecule
N2 N = 3.0, N = 3.0 3.0 – 3.0 = 0 Nonpolar bond Nonpolar molecule
SO2
HCl
HF
H2
F2
CO
NF3
Cl2
O2
I2
Based on the given activity, describe a polar covalent bond and a nonpolar covalent bond.
Write your answer on the space below.
_________________________________________________________________________
_________________________________________________________________________
_________________________________________________________________________
How does the electronegativity difference of the atoms in a covalent bond affect the polarity
of the bond? Write your answer on the space below.
_________________________________________________________________________
_________________________________________________________________________
_________________________________________________________________________
How does molecular polarity related to the type of bond of a compound? Write your answer
on the space below.
_________________________________________________________________________
_________________________________________________________________________
_________________________________________________________________________
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Bond polarity based on the electronegativity (EN) difference between the atoms present in a
molecule is one good way to determine the polarity of a molecule, whether a molecule is polar
or nonpolar. Please take note of the following:
• Polar bonds occur when electron pairs are unequally shared due to the difference in
electronegativity of the atoms. The greater the difference in electronegativity between
two atoms, the more polar their bond is. Unequal sharing of electrons between atoms
creates a dipole (two poles) ( ). This means that one end of a polar bond is more
negative while the other end is more positive. The atom with higher electronegativity
value increases in electron density and thus, develops a slight negative charge or
partial negative charge (δ-). On the other side, electron density is less on the side of
the atom with lower electronegativity, and that atom gains a slight positive charge (δ+).
• Non polar bond develops if both atoms equally share a pair of electron between them.
This happens when the bonding atoms have approximately equal ability to attract
electron on each side (equal electronegativity value). The electron density is spread
evenly (or essentially evenly) between the two atoms in the bond. Since a pair of
electrons is shared equally between atoms, there is no partial charge created, hence,
no dipole moment.
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Good job in finishing the activity! Now, take time to process the information you acquired by
accomplishing the next task.
A. Identify the kind of bond (polar or nonpolar) between the atoms of the
following compound
___________________________________________________________________
___________________________________________________________________
__________________________________________________________________
Congratulations!
You have completed the task in the first part of this module!
How did you find the activities? I hope that you were able to
learn the importance of knowing the electronegativity
difference of the atoms in predicting the polarity of molecules.
In Self Test 1 you are correct to have identified bromine gas
as a nonpolar molecule because of the nonpolar bond that
exist between bromine atoms (Br-Br) having an
electronegativity difference of zero (0). Actually, aside from
bromine gas, carbon tetrafluoride (CF4) and carbon dioxide
(CO2) is also a nonpolar molecule though the type of bond is
polar bond having an electronegativity difference of 1.5 and
1.0 respectively.
Maybe you’re now wondering how it happened. As what I have
said earlier, you will realize that the polarity of molecules do
not depend solely on the type of bond present but also on the
shape of the molecules.
So, here it is. You are about to explore another factor that
determines the polarity of molecule which is the molecular
structure. Hop on and keep learning!
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Lesson 2: Molecular Geometry: VSEPR (Valence Shell Electron Pair
Repulsion) Theory
The shape of molecules plays an important role in complex biochemical reactions such
as those between protein and DNA molecules. In Lesson 1, we discussed electronegativity as
one of the factors to determine the polarity of molecules. Here we will study another factor
which is the shape, or geometry, of molecules. Geometry has an important influence on the
physical and chemical properties of molecules, such as density, melting point, boiling point,
and reactivity. We will see that we can predict the shapes of molecules with considerable
accuracy using a simple method based on Lewis structures.
To help you become familiar on the different geometrical shape of the molecules, let’s do an
activity.
A B
A. Tetrahedral
. B. Linear
C. Bent
D. Trigonal planar
1. ________________ 2. ________________ E. Octahedral
F. Distorted octahedron
or (seesaw)
G. Trigonal bipyramidal
H. Trigonal pyramidal
3. ________________ 4. ________________
5. ________________ 6. ________________
7. ________________ 8. ________________
You have just encountered some of the geometrical shape that a molecule should be
oriented. We use a ball and stick model to represent a molecule in which there is a central
atom where the surrounding atoms are bonded at specific angle to minimize the repulsion as
suggested in the VSEPR Theory.
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Molecular geometry pertains to the three-dimensional
arrangement of atoms in a molecule. Geometry affects the
physical and chemical properties of molecules and their
reactivity towards other molecules. Molecular geometry can be
determined by experiment such as x-ray diffraction. The
approach in predicting molecular geometry is called the
Valence Shell Electron Pair Repulsion Theory (VSEPR).
The key ideas of the VSEPR theory are:
1. Electron pairs stay as far apart from each other as possible to minimize repulsions.
2. Molecular shape is determined by the number of bond pairs and lone pairs around
the central atom.
3. Treat multiple bonds as if they were single bonds (in making the prediction).
4. Lone pairs occupy more volume than bond pairs. Lone pair – lone pair repulsions
are greater than lone pair – bond pair repulsions which in turn are greater than
bond pair – bond pair repulsions
To describe the difference between lone pairs and bonding pairs, please refer to the
illustrations below.
o bond pairs
pair while oxygen bonded to it has 2 lone pairs
each having a total of 4 lone pairs. Carbon and
both oxygen are bonded through double bond
which count as 2 bond pairs thus, the molecule
has 2 bond pairs.
lone pair
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To minimize the repulsion, electron pairs (bond pair and lone pair) should be oriented
accordingly. Table 2, shows the arrangement of a specific number of electron pairs and its
corresponding VSEPR Shape.
Table 2: Arrangement of Electron Pairs and its Corresponding VSEPR Shape
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Trigonal planar Trigonal planar
(with no lone pair)
3
Bent
(with 2 bond pair and 1 lone Trigonal planar
pair)
Tetrahedral
4
Tetrahedral
(with no lone pair)
Trigonal
4 Pyramidal
(with 3 bond pair and 1 lone Tetrahedral
pair)
Bent
4
(with 2 bond pair and 2 lone Tetrahedral
pair)
Trigonal
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Trigonal bipyramidal bipyramidal
(with no lone pair)
Octahedral
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Octahedral
(with no lone pair)
Note that the arrangement of electron pair does not necessarily mean the same to its
molecular geometry. The molecular geometry is determined by the position of the nuclei of
the atoms. We do not “see” lone pairs.
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Guidelines for Applying the VSEPR Model
1. Write the Lewis structure of the molecule, considering only the electron pairs around
the central atom (that is, the atom that is bonded to more than one other atom). For a
molecule in which the atom is bonded to another single atom like O 2 and HCl,
the geometrical shape is obviously linear.
2. Count the number of electron pairs around the central atom (bonding pairs and lone
pairs). Treat double and triple bonds as though they were single bonds. Refer to Table
2 to predict the overall arrangement of the electron pairs.
3. Use Tables 2 to predict the geometry of the molecule.
4. In predicting bond angles, note that a lone pair repels another lone pair or a bonding
pair more strongly than a bonding pair repels another bonding pair. Remember that in
general there is no easy way to predict bond angles accurately when the central atom
possesses one or more lone pairs.
Solution We follow the preceding procedure for constructing the VSEPR Model.
Step 1: Draw the Lewis structure of water.
Step 2 Count the number of electron pairs around the central atom. There are four electron
pairs around the central atom: two bond pairs and two lone pairs.
Step 3: Use Tables 2 to predict the geometry of the molecule. The arrangement of
electron pairs are tetrahedral
Step 4: Determine the molecular geometry. Since the two lone pair is not considered since
this cannot be “seen”, therefore, the molecular geometry is bent.
You’re now familiar with the molecular geometry as described in the VSEPR theory. Let’s now
use the information in Table 2 to connect its relationship with some molecules used in the
previous activities.
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Activity 4: Molecular Architecture (Part 1)
Given the Lewis structure of the following molecules, predict
the VSEPR Shape that corresponds to the structure of
molecule. Draw the molecular geometry. Use the information
in Table 2 for your answer.
o pair)
4
(2 bond pairs bent
Ex. 2. H2O tetrahedral
and 2 lone
pairs)
4
Ex. 3. CF4 (no lone tetrahedral tetrahedral
pair)
HCl
H
NH3
CF2Cl2
SO2 o o
BF3
CH4
How did you find the activity? I hope that you were able to determine the geometry of
molecules from the Lewis structure. Knowing the geometrical shape of simple molecules
applying the VSEPR theory, you are now ready to perform the next activity.
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The VSEPR model generates reliable predictions of the
geometries of a variety of molecular structures. Chemists use
the VSEPR approach because of its simplicity. As mentioned
earlier, aside from electronegativity as factor to determine the
polarity of molecule, molecular geometry applying the VSEPR
theory is one good way to determine whether a molecule is
polar or nonpolar. Looking at the geometry and arrangement of
molecule we can easily determine the polarity of a molecule.
Here are some points to remember to determine the polarity of molecules base on the
geometrical arrangement of molecules.
Nonpolar molecule
• A molecule is nonpolar if the shape of the molecule is symmetrical. This is due to the
equal sharing of electrons hence, no dipole moment is produced thus, the valence
electrons are shared equally on both sides of an atom. Example: O 2 , F2, Cl2 and other
diatomic molecules containing atoms of the same element.
• The central atom does not have lone pairs, thus all its electrons were equally shared
to another atom of the same element. Example: CF 4 and CO2
Polar Molecules
• A molecule is polar, if the shape of the molecule is asymmetrical. This is due to the
unequal sharing of electrons between atoms creating a dipole moment. Example: HCl,
HF where Cl and F atoms are more electronegative than H atom
H H
• The central atom or one of the central atoms has lone pair. Example: H 2O and NCl3
• The central atom does not have lone pair but bonded to atoms of different kind. This
will affect the polarity of molecule due to the differences on electronegativity. Example:
CH2F2 and OCS
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I hope that the discussion above helps you differentiate polar molecule from nonpolar
molecule. To check your understanding about molecular polarity, let’s identify the molecules
in Activities 4 and 5 if the molecule is polar or nonpolar.
Now, let’s combine the concepts discussed in Lesson 1 and 2 by performing the next activity.
Electro-
Bond Molecular Geometric Polarity of
Molecule negativity Reason
Polarity Geometry Sketch Molecules
Difference
No lone pair at the
Ex. 1
4.0 – 2.5 = Polar Nonpolar central atom and the
CF4 Tetra-
1.5 bond molecule bonding atom are of the
hedral
same kinds of element
HCl
NF3
CCl4
O2
BF3
CH4
SO2
Cl2
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Answer the following questions.
Good job in finishing the activity! Now, take time to process the information you acquired by
accomplishing the next task.
For questions 1 to 4: Choose the letter that corresponds to the best answer.
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Complete the Concept Map below using the words written
inside the box.
Molecular Polarity
having electronegativity
having electronegativity difference of 0.5—2.0
difference of 0—0.4 uses a model to determine
the geometric arrangement
of electron pair
has positive and negative
poles referred to as
will always form
Arrangement of electron
pairs could be
will form
Equally shared electron
will form pair will produce
Unequally shared
electron pair will produce
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Congratulations on finishing the supplementary learning
module! You have just an amazing learning journey and for sure,
you will have the same in the succeeding modules. Please take
note that on the next module you will learn how the understanding
of the polarity of molecules can be used to explain several
properties like how soap can able to kill viruses and bacteria and
how chemist develop vaccines and medicines to cure several
diseases. Good luck on your next learning journey!
This time, share to the class your final insights by
completing the following sentence prompts.
,
To strengthen what you have learned in this module, perform the following additional tasks:
Studying the molecular structure of a substance is a difficult thing to understand
because of its particle nature that even our naked eye cannot see. That is why scientist uses
a model to understand their properties and behavior.
Your task is to create a 3D (three dimensional) VSEPR Model of a molecule of your
choice using any recyclable materials. Choose a molecule of at least 3 atoms. You can
choose from among of the molecules presented in this module. Create at least one 3D
molecule. Build your model with the correct number of bonds in the correct places and different
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colors or sizes representing the different elements. Be creative and resourceful in constructing
your 3D VSEPR Model. Refer to the rubric below for you to be guided in making your 3D
VSEPR Model.
Molecular Model Rubric
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The following terms used in this module are defined as
follows:
Bond pair – these are the valence electrons that take part in
the bonding during the molecule formation
Chemical bond – is the electrostatic force holding two or more atoms in a molecule
Covalent bond – the electrostatic attraction between atoms of the same nonmetallic elements
in which are equally sharing the same number of electron pairs
Dipole – are polar molecules with atoms arranged in such a way that they have permanent
positive and negative poles.
Lewis structure – is a representation of covalent bonding in which shared electron pairs are
shown either as lines or as pairs of dots between two atoms, and lone pairs are shown as
pairs of dots on individual atoms
Lone pair – these are valence electrons which do not take part in the bonding during the
molecule formation.
Nonpolar covalent bond – it is the electrostatic attraction between atoms of the same
nonmetallic elements which are equally sharing the same number of electron pairs.
Polar covalent bond – it is the electrostatic attraction between atoms of different nonmetallic
elements which are not equally sharing the same number of electron pairs. The electron pair
is nearer the stronger atom.
Valence electrons – the electrons found in the valence shell of an atom in which can but may
not take part in the bonding during the molecule formation.
Valence shell – is the outermost electron-occupied shell of an atom; it holds the electrons
that are usually involved in bonding
Valence Shell Electron Pair Repulsion Model – it accounts for the geometric arrangements
of electron pairs around a central atom in terms of the electrostatic repulsion between electron
pairs.
Valence Shell Electron Pair Repulsion Theory – it predicts that all electron pairs in the
valence shell around a central atom repel one another. They want to be as far apart from one
another as possible.
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Directions: Identify what is asked or described in each item
then write the letter of the correct answer.
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