D-Block in One Page
D-Block in One Page
D-Block in One Page
Oxidation states of the lanthanoids? +3 is the common oxidation lso +3, oxidation states +2 and +4
Transition metals are paramagnetic For having unpaired electrons
Enthalpies of atomisation of the transition Due to strong metallic bonding
metals are high.
Transition metal form coloured Due to incompletely filled d-orbital there is d-d electron
compounds transition
Transition metals and their many Because they can adopt variable oxidation states to form
compounds act as good catalyst. different intermediate
How is the variability in oxidation states In transition elements the oxidation states vary by one
of transition metals different from For example, for Mn it may vary as +2, +3, +4, +5, +6, +7.
that of the non transition metals? Illustrate In the nontransition elements the variation is selective, always
with examples. differing by 2, e.g. +2, +4, or +3, +5 or +4, +6 etc.
Which of the following will be coloured Except Sc3+, all others will be coloured due to incompletely
Ti3+,V3+,Cu+,Sc3+,Mn2+, Fe3+ & Co2+. filled 3d-orbitals, will give rise to d-d transitions.
Of the d4 species, Cr2+ is reducing while Cr2+ is reducing as it change from d4 to d3, the latter is more
Mn(III) is strongly oxidising. stable Mn(III) to Mn(II) is from 3d4 to 3d5 again 3d5 is stable
Co(II) is stable in aq sol but in the Due to CFSE, which more than compensates the 3rd IE.
presence of complexing reagents it easily
oxidised.
The d1 configuration is unstable in ions. The hydration or lattice energy more than compensates the
ionisation enthalpy involved in removing electron from d1.
Which transition metal has +1 oxidation Cu, because with +1 oxidation state an stable configuration, 3d10
state most frequently and why?
Calculate the number of unpaired electrons Unpaired electrons Mn3+ = 4, Cr3+ = 3, V3+ = 2, Ti3+ = 1. Most
in the following gaseous ions: Mn3+, stable Cr3+
Cr3+, V3+ and Ti3+. Which one of these is
the most stable in aqueous solution?
The lowest oxide of transition metal is In lowest oxidation state ionic bond is formed but in highest
basic, the highest is oxidation state covalent bond is formed
amphoteric/acidic.
A transition metal exhibits highest O and F are strong oxidizing agents and can excite electrons
oxidation state in oxides
and fluorides.