SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

SECTION 1. IDENTIFICATION

Product name : Eastman(TM) Propionic Acid, Food Grade, Kosher

Product code : 19703-00, P1970300, P1970301, P1970302, P1970307,

E1970301, E1970302

Manufacturer or supplier's details

Company name of supplier : Eastman Chemical Company

Address : 200 South Wilcox Drive

Kingsport TN 37660-5280

Telephone : (423) 229-2000

Emergency telephone : CHEMTREC: +1-800-424-9300, +1-703-527-3887 CCN7321

Recommended use of the chemical and restrictions on use

Recommended use : Industrial chemical
Feed additive.
Food additive.

Restrictions on use : None known.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with 29 CFR 1910.1200

Flammable liquids : Category 3

Skin corrosion : Category 1B

Serious eye damage : Category 1

GHS label elements

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H226 Flammable liquid and vapor.

H314 Causes severe skin burns and eye damage.

Precautionary Statements :
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equip-
ment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam to extinguish.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients
Chemical name CAS-No. Concentration (% w/w)
propionic acid 79-09-4 100

SECTION 4. FIRST AID MEASURES

If inhaled : Move to fresh air.

If breathing is irregular or stopped, administer artificial
respiration.

In case of skin contact : Wash off immediately with soap and plenty of water while

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

removing all contaminated clothes and shoes.

Wash contaminated clothing before re-use.
Call a physician or poison control center immediately.
Thoroughly clean shoes before reuse.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Call a physician or poison control center immediately.

If swallowed : Seek medical advice.

Do not induce vomiting without medical advice.
Never give anything by mouth to an unconscious person.

Most important symptoms : Causes serious eye damage.

and effects, both acute and Causes severe burns.
delayed

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray

Dry chemical
Carbon dioxide (CO2)
Alcohol-resistant foam

Unsuitable extinguishing : None known.

media

Specific hazards during fire : Water may be ineffective.

fighting The product will float on water and can be reignited on surface
water.

Further information : Flammable liquid and vapor.

Use water spray to cool unopened containers.

Special protective equipment : Wear an approved positive pressure self-contained breathing

for fire-fighters apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Local authorities should be advised if significant spillages
gency procedures cannot be contained.

Environmental precautions : Avoid release to the environment.

Methods and materials for : Contain spillage, soak up with non-combustible absorbent
containment and cleaning up material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

national regulations (see section 13).

After cleaning, flush away traces with water.
Eliminate all ignition sources if safe to do so.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Keep away from heat and sources of ignition.
fire and explosion

Advice on safe handling : Do not breathe vapors or spray mist.

Do not get on skin or clothing.
Do not get in eyes.
Do not swallow.
Ensure adequate ventilation.
Wash thoroughly after handling.
Keep away from fire (No Smoking).
Keep away from fire, sparks and heated surfaces.
Do not use sparking tools.

Conditions for safe storage : Keep container closed when not in use.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Ingredients CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
propionic acid 79-09-4 TWA 10 ppm ACGIH
TWA 10 ppm NIOSH REL
30 mg/m3
ST 15 ppm NIOSH REL
45 mg/m3
TWA 10 ppm OSHA P0
30 mg/m3
Engineering measures : Ensure adequate ventilation.

Personal protective equipment

Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Hand protection

Remarks : Wear chemical-resistant gloves, boots, and protective

clothing appropriate for the risk of exposure. Contact glove
manufacturer for specific information. Wash hands after
handling.

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Eye protection : Safety glasses with side-shields

Face-shield

Protective measures : Remove respiratory and skin/eye protection only after vapors
have been cleared from the area.
Ensure that eye flushing systems and safety showers are
located close to the working place.
Use personal protective equipment as required.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : colorless

Odor : unpleasant

Odor Threshold : 0.16 ppm

pH : not determined

Melting point/range : -8 °F / -22 °C

Boiling point/boiling range : 286 °F / 141 °C

Flash point : 120 °F / 49 °C

Method: Seta closed cup

Evaporation rate : not determined

Vapor pressure : not determined

Relative vapor density : 2.6

Relative density : 1 (68 °F / 20 °C)

Solubility(ies)
Water solubility : completely soluble

Partition coefficient: n- : Pow: 2.1

octanol/water log Pow: 0.33

Autoignition temperature : 955.0 °F / 512.8 °C

Method: ASTM D2155

Decomposition temperature : Thermal stability not tested. Low stability hazard expected at
normal operating temperatures.

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Viscosity
Viscosity, dynamic : not determined

Viscosity, kinematic : not determined

Explosive properties : No data available

Oxidizing properties : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Stable

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : Stable

tions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Carbon dioxide (CO2)

products Carbon monoxide

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity : LD50 Oral (Rat): 3,455.1 mg/kg

Acute inhalation toxicity : Remarks: No data available

Acute dermal toxicity : Remarks: No data available

Skin corrosion/irritation
Causes severe burns.
Product:
Species : Rabbit
Exposure time : 24 h
Result : strong

Serious eye damage/eye irritation

Causes serious eye damage.

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Product:
Species : Rabbit
Result : strong
Exposure time : 1 min

Respiratory or skin sensitization

Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Product:
Test Type : OECD 406: Guinea pig sensitization
Species : Guinea pig
Result : Not a skin sensitizer.

Germ cell mutagenicity

Not classified based on available information.
Product:
Genotoxicity in vitro : Test Type: Salmonella typhimurium assay (Ames test)
Metabolic activation: +/- activation
Method: Bacterial Reverse Mutation Assay
Result: negative

Genotoxicity in vivo : Test Type: Micronucleus test

Species: Hamster (Male and Female)
Method: Mammalian Erythrocyte Micronucleus Test
Result: negative

Carcinogenicity
Not classified based on available information.
IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Aspiration toxicity
Not classified based on available information.
Product:
No aspiration toxicity classification

Information on likely routes of exposure

Product:
Inhalation : Remarks: None known.

Skin contact : Remarks: Causes severe skin burns.

Eye contact : Remarks: Causes serious eye damage.

Ingestion : Remarks: None known.

Further information

Product:
Remarks : None known.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:
Toxicity to fish : LC50 (golden orfe): > 1,000 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 500 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : EC50 (Scenedesmus subspicatus): > 500 mg/l

Exposure time: 72 h

Persistence and degradability

Product:
Biodegradability : Test Type: Ozone depletion
Result: Readily biodegradable
Biodegradation: 60 %
Exposure time: 2 d

Bioaccumulative potential
No data available
Mobility in soil
No data available

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.

SECTION 14. TRANSPORT INFORMATION

International Regulations

IATA-DGR
UN/ID No. : UN 3463
Proper shipping name : Propionic acid
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : Corrosive, Flammable Liquids
Packing instruction (cargo : 855
aircraft)
Packing instruction (passen- : 851
ger aircraft)
IMDG-Code
UN number : UN 3463
Proper shipping name : PROPIONIC ACID

Class : 8
Subsidiary risk : 3
Packing group : II
Labels : 8 (3)
EmS Code : F-E, S-C
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
UN/ID/NA number : UN 3463
Proper shipping name : Propionic acid

Class : 8
Subsidiary risk : 3
Packing group : II
Labels : Class 8 - Corrosive, Class 3 - Flammable Liquid
ERG Code : 132
Marine pollutant : no

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Special precautions for user

The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : Fire Hazard
Acute Health Hazard

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer,
birth, or any other reproductive defects.
The ingredients of this product are reported in the following inventories:
DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

ENCS : On the inventory, or in compliance with the inventory

ISHL : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

TCSI : On the inventory, or in compliance with the inventory

TSCA : On the inventory, or in compliance with the inventory

TSCA list
No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification requirements.

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

SECTION 16. OTHER INFORMATION

Further information

NFPA 704: HMIS® IV:

Flammability
HEALTH / 3
2 FLAMMABILITY
Instability

2
Health

3 0
PHYSICAL HAZARD
0

HMIS® ratings are based on a 0-4 rating

scale, with 0 representing minimal haz-
ards or risks, and 4 representing signifi-
Special hazard. cant hazards or risks. The "*" represents
a chronic hazard, while the "/" represents
the absence of a chronic hazard.

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA P0 : USA. OSHA - TABLE Z-1 Limits for Air Contaminants -
1910.1000
ACGIH / TWA : 8-hour, time-weighted average
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
OSHA P0 / TWA : 8-hour time weighted average

AICS - Australian Inventory of Chemical S ubstances; AS TM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concent ration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Canc er; IA TA - International Air Transport Association; IB C
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICA O - International Civil A viation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Let hal Concentration to 50 % of a test population; LD50 - Let hal Dose to
50% of a test population (Median Lethal Dose); MARPOL - Int ernational Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-

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SAFETY DATA SHEET

Eastman(TM) Propionic Acid, Food Grade,

Kosher

Version Revision Date: SDS Number: Date of last issue: -

22.1 07/09/2018 150000014309 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

erwis e Specified; NFPA - National Fire P rotection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A )EL - No Observed (A dverse) Effect Level; NOE LR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution P revention; PB T - P ersistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Invent ory of Chemicals and Chemical Substances; (Q)SA R - (Quanti-
tative) Structure Activity Relationship; RCRA - Resourc e Conservation and Recovery Act;
REACH - Regulation (E C) No 1907/2006 of the E uropean Parliament and of the Council concern-
ing the Registration, E valuation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TS CA - Toxic Substanc es Cont rol Act (United States); UN - Unit ed Nations; UNRTDG -
United Nations Recommendations on the Trans port of Dangerous Goods; vP vB - Very Persistent
and Very Bioaccumulative

Revision Date : 07/09/2018

The information provided in this Material S afety Data S heet is correct to the best of our
knowledge, information and belief at the dat e of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transp ortation, disposal and re-
lease and is not to be considered a warranty or quality specification. The information relates only
to the specific material designat ed and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.

US / Z8

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