Hoja de Seguridad Acido Propionico
Hoja de Seguridad Acido Propionico
Hoja de Seguridad Acido Propionico
SECTION 1. IDENTIFICATION
Precautionary Statements :
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
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SAFETY DATA SHEET
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equip-
ment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam to extinguish.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Other hazards
None known.
Ingredients
Chemical name CAS-No. Concentration (% w/w)
propionic acid 79-09-4 100
In case of skin contact : Wash off immediately with soap and plenty of water while
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In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Call a physician or poison control center immediately.
Methods and materials for : Contain spillage, soak up with non-combustible absorbent
containment and cleaning up material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
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Advice on protection against : Keep away from heat and sources of ignition.
fire and explosion
Conditions for safe storage : Keep container closed when not in use.
Hand protection
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SAFETY DATA SHEET
Protective measures : Remove respiratory and skin/eye protection only after vapors
have been cleared from the area.
Ensure that eye flushing systems and safety showers are
located close to the working place.
Use personal protective equipment as required.
Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
Appearance : liquid
Color : colorless
Odor : unpleasant
pH : not determined
Solubility(ies)
Water solubility : completely soluble
Decomposition temperature : Thermal stability not tested. Low stability hazard expected at
normal operating temperatures.
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SAFETY DATA SHEET
Viscosity
Viscosity, dynamic : not determined
Reactivity : Stable
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity : LD50 Oral (Rat): 3,455.1 mg/kg
Skin corrosion/irritation
Causes severe burns.
Product:
Species : Rabbit
Exposure time : 24 h
Result : strong
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SAFETY DATA SHEET
Product:
Species : Rabbit
Result : strong
Exposure time : 1 min
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Product:
Test Type : OECD 406: Guinea pig sensitization
Species : Guinea pig
Result : Not a skin sensitizer.
Carcinogenicity
Not classified based on available information.
IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
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SAFETY DATA SHEET
Aspiration toxicity
Not classified based on available information.
Product:
No aspiration toxicity classification
Product:
Inhalation : Remarks: None known.
Further information
Product:
Remarks : None known.
Ecotoxicity
Product:
Toxicity to fish : LC50 (golden orfe): > 1,000 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 500 mg/l
aquatic invertebrates Exposure time: 48 h
Product:
Biodegradability : Test Type: Ozone depletion
Result: Readily biodegradable
Biodegradation: 60 %
Exposure time: 2 d
Bioaccumulative potential
No data available
Mobility in soil
No data available
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SAFETY DATA SHEET
Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
International Regulations
IATA-DGR
UN/ID No. : UN 3463
Proper shipping name : Propionic acid
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : Corrosive, Flammable Liquids
Packing instruction (cargo : 855
aircraft)
Packing instruction (passen- : 851
ger aircraft)
IMDG-Code
UN number : UN 3463
Proper shipping name : PROPIONIC ACID
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : 8 (3)
EmS Code : F-E, S-C
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 3463
Proper shipping name : Propionic acid
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : Class 8 - Corrosive, Class 3 - Flammable Liquid
ERG Code : 132
Marine pollutant : no
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SAFETY DATA SHEET
SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer,
birth, or any other reproductive defects.
The ingredients of this product are reported in the following inventories:
DSL : All components of this product are on the Canadian DSL
TSCA list
No substances are subject to a Significant New Use Rule.
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SAFETY DATA SHEET
Further information
2
Health
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PHYSICAL HAZARD
0
AICS - Australian Inventory of Chemical S ubstances; AS TM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concent ration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Canc er; IA TA - International Air Transport Association; IB C
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICA O - International Civil A viation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Let hal Concentration to 50 % of a test population; LD50 - Let hal Dose to
50% of a test population (Median Lethal Dose); MARPOL - Int ernational Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
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SAFETY DATA SHEET
erwis e Specified; NFPA - National Fire P rotection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A )EL - No Observed (A dverse) Effect Level; NOE LR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution P revention; PB T - P ersistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Invent ory of Chemicals and Chemical Substances; (Q)SA R - (Quanti-
tative) Structure Activity Relationship; RCRA - Resourc e Conservation and Recovery Act;
REACH - Regulation (E C) No 1907/2006 of the E uropean Parliament and of the Council concern-
ing the Registration, E valuation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TS CA - Toxic Substanc es Cont rol Act (United States); UN - Unit ed Nations; UNRTDG -
United Nations Recommendations on the Trans port of Dangerous Goods; vP vB - Very Persistent
and Very Bioaccumulative
The information provided in this Material S afety Data S heet is correct to the best of our
knowledge, information and belief at the dat e of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transp ortation, disposal and re-
lease and is not to be considered a warranty or quality specification. The information relates only
to the specific material designat ed and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
US / Z8
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