JEE Main 30-01-2024 (Morning Shift) : Questions
JEE Main 30-01-2024 (Morning Shift) : Questions
JEE Main 30-01-2024 (Morning Shift) : Questions
Questions
(a) 2 mV
(b) 12 mV
(c) 4V
(d) 0.5 V
(c) B⃗ = E0
C
cos(ωt + kz) j
^
(d)
E0
^
B⃗ = cos(ωt − kz) j
C
3. A particle is placed at the point A of a frictionless track ABC as shown in figure. IT is gently pushed towards
right. The speed of the particle when it reaches the point B is: (Take g = 10m/s ). 2
(a) √− −
10 m/s
(b) 10 m/s
(c) 20 m/s
(d) 2√− −
10 m/s
4. A Zener diode of breakdown voltage 10V is used as a voltage regulator as shown in the figure. The current
through the Zener diode is:
(a) 30 mA
(b) 20 mA
(c) 50 mA
(d) 0
5. Two insulated circular loop A and B of radius ‘a’ carrying a current of ‘I’ in the anti clockwise direction as shown
in the figure. The magnitude of the magnetic induction at the centre will be:
2μ I
(a) a
0
μ
(b) 2
0 I
√ 2 μ0 I
(c) a
μ0 I
(d) √ 2a
List – I List – II
A Coefficient of viscosity (I) 2
[M L T
−2
]
7. All surfaces shown in figure are assumed to be frictionless and the pulleys and the string are light.
The acceleration of the block of mass 2 kg is:
g
(a) 3
g
(b) 4
(c) g
g
(d) 2
8. The gravitational potential at a point above the surface of earth is −5.12 × 10 J /kg and the acceleration due to
7
gravity at that point is 6.4m/s . Assume that the mean radius of earth to be 6400 km. The height of this point
2
9. A particle of mass m is projected with a velocity ‘u’ making an angle of 30 with the horizontal. The magnitude
∘
of angular momentum of the projectile about the point of projection when the particle is at its maximum height h
is:
3
(a) √3
16
mu
(b) √3
2
mu
(c) Zero
3
mu
(d) √ 2g
10. Two thermodynamical processes shown in the figure. The molar heat capacity for process A and B are C and A
C . The molar heat capacity at constant pressure and constant volume are represented by C
B and C ,
P V
(a) C B = ∞, C A = 0
(c) CA = 0 and C B = ∞
11. Primary coil of a transformer is connected to 220V ac. Primary and secondary coil turns of the transforms are
100 and 10 respectively. Secondary coil of transformer is connected to two series resistances shown in figure.
The output voltage (V ) is: 0
(a) 7V
(b) 15V
(c) 22V
(d) 44V
12. An electric toaster has resistance of 60Ω at room temperature (27 C ) . The toaster is connected to a 220V
∘
supply. If the current flowing through it reaches 2.75 A, the temperature attained by toaster is around: (If
/ C)
−4 ∘
α = 2 × 10
(a) 1694 C ∘
(b) 694 C ∘
(c) 1235 C ∘
(d) 1667 C ∘
13. At which temperature the r.m.s. velocity of a hydrogen molecule equal to that of an oxygen molecule at 47 ∘
C?
(a) 80 K
(b) 20 K
(c) -73 K
(d) 4 K
14. A spherical body of mass 100g is dropped from a height of 10m from the ground. After hitting the ground, the
body rebounds to a height of 5m. The impulse of force imparted by the ground to the body is given by: (given,
g = 9.8m/s )
2
(a) 2.39kg ms −1
(b) 43.2 kg ms −1
(c) 4.32kg ms −1
(d) 23.9kg ms −1
15. A series LR circuit connected with an ac source E = (25 sin 100t) V has a power factor of 1
. If the source of
√2
emf is changed to E = (20 sin 2000t) V , the new power factor fo the circuit will be:
1
(a) √2
1
(b) √7
1
(c) √5
1
(d) √3
16. The electrostatic potential due to an electric dipole at a distance ‘r’ varies as:
1
(a) 2
r
(b) r
(c) 1
r
1
(d) r
3
17. Young’s modules of material of a wire of length ‘L’ and cross-sectional area A is Y. If the length of the wire is
doubled and cross-sectional area is halved then Young’s modules will be:
(a) Y
(b)
Y
(c) 4Y
(d) 2Y
18. The work function of a substance is 3.0 eV. The longest wavelength of light that can cause the emission of
photoelectrons from this substance is approximately.
(a) 200 nm
(b) 215 nm
(c) 400 nm
(d) 414 nm
19. The ratio of the magnitude of the kinetic energy to the potential energy of an electron in the 5th excited state of
a hydrogen atom is:
1
(a) 4
(b) 4
1
(c) 2
(d) 1
20. The diffraction pattern of a light of wavelength 400 nm diffracting from a slit of width 0.2 mm is focused on the
focal plane of a convex lens of focal length 100cm. The width of the 1st secondary maxima will be:
(a) 2 cm
(b) 0.2 mm
(c) 2 mm
(d) 0.02 mm
21. Each of three blocks P, Q and R shown in figure has a mass of 3 kg. Each of the wires A and B has cross-
sectional area 0.005cm and Young’s modulus 2 × 10 N m . Neglecting friction, the longitudinal strain on
2 11 −2
22. A capacitor of capacitance C and potential V has energy E. It is connected to another capacitor of capacitance
2C and potential 2V. Then the loss of energy is E, where x is ____.
x
23. The horizontal component of earth’s magnetic field at a place is 3.5 × 10 T . A very long straight conductor
−5
–
carrying current of √2A in the direction from South east to North West is placed. The force per unit length
experienced by the conductor is ______ ×10 N /m −6
24. In a closed organ pipe, the frequency of fundamental note is 30Hz. A certain amount of water is now poured in
the organ pipe so that the fundamental frequency is increased to 110Hz. If the organ pipe has a cross-sectional
area of 2cm , the amount of water poured in the organ tube is _____ g. (Take speed of sound in air is 330m/s).
2
25. The distance between object and its two times magnified real image as produced by a convex lens is 45 cm. The
focal length of the lens used is ____ cm.
26. A electron of hydrogen atom on an excited state is having energy E n = −0.85eV . The maximum number of
allowed transitions to lower energy level is _____.
27.
Consider a disc of mass 5 kg, radius 2 m, rotating with angular velocity of 10 rad/s about an axis perpendicular
to the plane of rotation. An identical disc is kept gently over the rotating disc along the same axis. The energy
dissipated so that both the discs continue to rotate together without slipping is _____ J.
28. The displacement and the increase in the velocity of a moving particle in the time interval of t to (t + 1) s are
125m and 50 m/s, respectively. The distance travelled by the particle in (t + 2) s is _____m.
th
29. Two cells are connected in opposition as shown. Cell E is of 8V emf and 2Ω internal resistance; the cell E is
1 2
of 2V emf and 4Ω internal resistance. The terminal potential difference of cell E is _____ V.
2
30. A ceiling fan having 3 blades of length 80cm each is rotating with an angular velocity of 1200 rpm. The
magnetic field of earth in that region is 0.5 G and angle of dip is 30 . The emf induced across the blades is
∘
(a)
(b)
(c)
(d)
33. What happens to freezing point of benzene when small quantity of napthalene is added to benzene?
(a) Remains unchanged
(b) First decreases and then increases
(c) Decreases
(d) Increases
36. The Lassiagne's extract is boiled with dil HNO3 before testing for halogens because,
(a) AgCN is soluble in HNO3.
(b) Silver halides are soluble in HNO3.
(c) Ag2S is soluble in HNO3.
(d) Na2S and NaCN are decomposed by HNO3
37. Following is a confirmatory test for aromatic primary amines. Identify reagent (A) and (B).
(a)
(b)
(c)
(d)
A = HNO3 / H2SO4; B =
38. Which of the following molecule/ species is most stable?
(a)
(b)
(c)
(d)
(a)
(b)
(c)
(d)
41. Compound A formed in the following reaction reacts with B gives the product C. Find out A and B.
+
(a) A = CH3 – C ≡ C
¯
Na , B = CH3 – CH2 – CH2 – Br
(b) A = CH3 – CH2 – CH3, B = CH3 – C ≡ CH
+
(c) A = CH3 – C ≡ C
¯ N , B = CH – CH – CH
a 3 2 3
(d) A = CH3 – CH = CH2, B = CH3 – CH2 – CH2 – Br
42. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): CH2 = CH – CH2 – Cl is an example of allyl halide.
Reason (R): Allyl halides are the compounds in which the halogen atom is attached to sp2 hybridised carbon
atom.
In the light of the above statements, choose the most appropriate answer from the options given below:
(a) Both (A) and (R) are true but (R) is not the correct explanation of (A)
(b) (A) is false but (R) is true
(c) Both (A) and (R) are true and (R) is the correct explanation of (A)
(d) (A) is true but (R) is false
43. Match List - I with List - II.
44.
(a)
(b)
(c)
(d)
49. Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): There is a considerable increase in covalent radius from N to P. However from As to Bi only a
small increase in covalent radius is observed.
Reason (R): Covalent and ionic radii in a particular oxidation state increases down the group.
In the light of the above statements, choose the most appropriate answer from the options given below:
(a) (A) is true but (R) is false
(b) Both (A) and (R) are true and (R) is the correct explanation of (A)
(c) (A) is false but (R) is true
(d) Both (A) and (R) are true but (R) is not the correct explanation oi (A)
50. Sugar which does not give reddish brown precipitate with Fehling’s reagent, is:
(a) Sucrose
(b) Glucose
(c) Maltose
(d) Lactose
51. The pH at which Mg(OH) [K = 1 × 10–11] begins to precipitate from a solution containing 0.10 M Mg2+ ions
2 sp
is ____
52. The total number of molecular orbitals formed from 2s and 2p atomic orbitals of a diatomic molecule is _____
53. The rate of First order reaction is 0.04 mol L–1 s–1 at 10 minutes and 0.03 mol L–1 s–1 at 20 minutes after
initiation. Half life of the reaction is _______ minutes. (Given log2 = 0.3010,
log3 = 0.4771)
54. The compound formed by the reaction of ethanal with semicarbazide contains ________ number of nitrogen
atoms.
55. If IUPAC name of an element is "Unununnium'' then the element belongs to nth group of Periodic table. The
value of n is _____
57. 0.05 cm thick coating of silver is deposited on a plate of 0.05 m2 area. The number of silver atoms deposited on
plate are _______ × 1023.
(At mass Ag = 108, d = 7.9 g cm–3)
58. The mass of sodium acetate (CH3COONa) required to prepare 250 mL of 0.35 M aqueous solution is _______
g. (Molar mass of CH3COONa is 82.02 g mol–1)
59. On a thin layer chromatographic plate, an organic compound moved by 3.5 cm, while the solvent moved by 5
cm. The retardation factor of the organic compound is ______ × 10–1.
60.
An ideal gas undergoes a cyclic transformation starting from the point A and coming back to the same point by
tracing the path A → B → C → A as shown in the diagram above. The total work done in the process is
________ J.
61. The area (in square units) of the region bounded by the parabola y 2
= 4 (x − 2) and the line y = 2x − 8, is:
(a) 6
(b) 7
(c) 8
(d) 9
2
3 1
(a) f
′
(
2
) + f
′
(
2
) = 1
(b) f
′′
(x) = 0 for no x in (0, 1)
(c) (x) = 0 for atleast two x in (0, 2)
′′
f
63. If 2sin x + sin 2x cos x + 4 sin x − 4 = 0 has exactly 3 solutions in the interval [0,
3 nπ
],n ∈ N , then the
2
√ 17 √ 17
(a) (−
2
,
2
)
(b) (0, ∞)
(c) Z
(d) (−∞, 0)
64. Let a⃗ ^ ^ ^
= a1 i + a2 j + a3 k and b ⃗ = ^ ^ ^
b1 i + b2 j + b3 k be two vectors such that |a|⃗ ⃗
= 1, a ⃗ ⋅ b = 2 and ∣∣b∣∣⃗ = 4 .
If c ⃗ = ⃗ ⃗
2 (a ⃗ × b) − 3b, then the angle between b ⃗ and c ⃗ is equal to:
(a) cos
−1
(
√3
2
)
(b) cos
−1
(
2
3
)
(c) cos
−1
(−
1
√3
)
√3
(d) cos
−1
(−
2
)
65. Let y = y (x) be the solution of the differential equation sec x dy + {2 (1 − x) tan x + x (2 − x)} dx = 0
66. A line passing through the point A (9, 0) makes an angle of 30 with the positive direction of x-axis. If this line
∘
is rotated about A through an angle of 15 in the clockwise direction, then its equation in the new position is:
∘
x
(a) + y = 9
√ 3 +2
y
(b) √ 3 +2
+ x = 9
x
(c) √ 3 −2
+ y = 9
y
(d) √ 3 −2
+ x = 9
67. If the length of the minor axis of an ellipse is equal to half of the distance between the foci, then the eccentricity
of the ellipse is:
2
(a) √5
(b)
√5
(c) √3
2
1
(d) √3
68. Two integers x and y are chosen with replacement from the set {0, 1, 2, 3, . . . , 10}. Then the probability that
|x − y| > 5, is:
(a) 60
121
(b)
30
121
(c) 31
121
(d) 62
121
70. The maximum area of a triangle whose one vertex is at (0, 0) and the other two vertices lie on the curve
y = −2x + 54 at points (x, y) and (−x, y) , where y > 0, is:
2
(a) 92
(b) 108
(c) 88
(d) 122
71. Consider the system of linear equations x + y + z = 4μ, z + 2y + 2λz = 10μ, x + 3y + 4λ z = μ
2 2
+ 15,
72. ∣ 4
2cos x 2sin x
4 2
3 + sin 2x ∣
∣ ∣
If f (x) = ∣ 3 + 2cos4 x 2sin x
4 2
sin 2x ∣ , then 1
5
f
′
(0) = is equal to:
∣ ∣
4 4 2
∣ 2cos x 3 + 2sin x sin 2x ∣
(a) 1
(b) 2
(c) 0
(d) 6
73. n
13π
(a) 8(4√ 3 +3)
24
π
(c) 8(2√ 3 +3)
74. Let (α, β, γ) be the foot of perpendicular from the point (1, 2, 3) on the line x+3
=
y−1
=
z+4
. Then
5 2 3
19 (α + β + γ) is equal to:
(a) 102
(b) 101
(c) 99
(d) 100
75. Let A (2, 3, 5) and C (−3, 4, −2) be opposite vertices of a parallelogram ABC D. If the diagonal
−→
−
^ ^ ^
BD = i + 2 j + 3k , then the area of the parallelogram is equal to:
− −−
(a)1
√ 586
2
− −−
(b) 1
2
√ 410
− −−
(c) 1
2
√ 306
− −−
(d) 1
2
√ 474
76. Let M denote the median of the following frequency distribution
(a) 410
(b) 395
(c) 405
(d) 390
is equal to:
(a) 11
(b) 8
(c) 12
(d) 9
(b) 1
(c) 9
(d) 4
80. x
x ∫ f (t)dt
Let f : [−
π
2
,
π
2
] → R be a differentiable function such that f (0) =
1
2
. If the lim
0
x2
= α, then 8α is
2
x→0 e −1
equal to:
(a) 16
(b) 2
(c) 1
(d) 4
81. 1 1
824
−
y
2
= 1 subtend an angle of π
at the centre of the hyperbola. If b is 2
9
2 3
b
equal to m
l −−
(1 + √ n ) , where l and m are co-prime numbers, then l 2
+ m
2
+ n
2
is equal to _____.
83. 10
Let α = 1
2
+ 4
2
+ 8
2
+ 13
2
+ 19
2
+ 26 +. . .
2
upto 10 terms and β = ∑ n
4
. If 4α − β = 55k + 40 , then k
n=1
is equal to _____.
(√ α−1+√ β−1)(λ+35)
possible value, then |α−β|
is equal to:
85. A group of 40 students appeared in an examination of 3 subjects - Mathematics, Physics and Chemistry. It was
found that all students passed atleast one of the subjects, 20 students passes in Mathematics, 25 students passed
in Physics, 16 students passes in Chemistry, atmost 11 students passed in both Mathematics and Physics, atmost
15 students passed in both Physics and Chemistry, atmost 15 students passed in both Mathematics and
Chemistry. The maximum number of students passed in all the three subjects is ______.
86. 9
−−−
The value of 9 ∫ [√
10x
x+1
] dx, where [t] denotes the greatest integer less than or equal to t, is _____.
0
87. Let A = {1, 2, 3, . . . . , 7} and let P (A) denote the power set of A. If the number of functions f : A → P (A)
−−−−−−−−
88. Let y = y (x) be the solution of the differential equation (1 − x ) dy = [xy + (x + 2) √3 (1 − x ) ] dx,
2 3 2
90. 1
, |x| ⩾ 2
If the function f (x) = {
|x|
is differentiable on R, then 48 (a + b) is equal to ____.
2
ax + 2b, |x| < 2
Answer Key
1. D 2. D 3. A 4. A 5. D 6. A
7. A 8. C 9. A 10. C 11. A 12. A
13. B 14. A 15. C 16. A 17. A 18. D
19. C 20. C 21. 2 22. 2 23. 35 24. 400
25. 10 26. 6 27. 250 28. 175 29. 6 30. 32
31. A 32. B 33. C 34. D 35. D 36. D
37. B 38. A 39. D 40. D 41. A 42. D
43. D 44. D 45. B 46. A 47. D 48. B
49. D 50. A 51. 9 52. 8 53. 24 54. 3
55. 11 56. 8 57. 11 58. 7 59. 7 60. 200
61. D 62. C 63. D 64. D 65. B 66. D
67. A 68. B 69. B 70. B 71. C 72. C
73. B 74. B 75. B 76. B 77. B 78. A
79. B 80. B 81. 138.00 82. 182.00 83. 353.00 84. 60.00
85. 10.00 86. 155.00 87. 44.00 88. 97.00 89. 16.00 90. 15.00
Solutions
1. (D)
R eq = 4000Ω
4 1
i = = A
4000 1000
1
V 0 = i. R = × 500 = 0.5V
1000
2. (D)
Given E ⃗ ^
= E0 cos(ωt − kz) i
E0
⃗ ^
B = cos(ωt − kz) j
C
^ ^ ^
C = E × B
3. (A)
By COME
K EA + UA = K EB + UB
1 2
0 + mg (1) = mv + mg × 0.5
2
− −
v = √ g = √ 10 m/s
4. (A)
I2 = I1 − I3
1 1 3
I2 = ( − ) = ( ) = 30mA
20 50 100
5. (D)
√ 2μ I
0
∴ B net =
2a
6. (A)
dA
F = ηA
dy
−2 2 −1
[M LT ] = η [L ] [T ]
−1 −1
η = [M L T ]
−2
[M LT ]
F 0 −2
S. T = = = [M L T ]
ℓ [L]
2 −1
L = mvr = [M L T ]
1 2 2 −2
K. E = Iω = [M L T ]
2
7. (A)
40 − 2T = 4a
T − 14a ⇒ 20 = 12a
5 g
⇒ a = ⇒ 2a =
3 3
8. (C)
GME
−7
− = −5.12 × 10 . . . (i)
R E +h
GME
2
= 6.4 . . . . . (ii)
(R E +h)
9. (A)
L = mu cos θH
2 2
u sin θ
= mu cos θ ×
2g
3
3 √3 2 √ 3 mu
mu 1
= × × ( ) =
2g 2 2 16g
10. (C)
For process A
γ
log P = γ log V ⇒ P = V , (γ > 1)
PV
−γ
= Constant
R
CA = CV + . . . . . (i)
1+γ
C P = C v + R . . . . . (iii)
11. (A)
ε1 N1 100
= = ⇒ ε 2 = 22V
ε2 N2 10
22
I = 3
= 1mA, V 0 = 7V
22×10
12. (A)
220
R T =27 = 60Ω, R T = = 80Ω
2.75
R = R 0 (1 + αΔT )
−4
80 = 60 [1 + 2 × 10 (T − 27)]
∘
T ≈ 1694 C
13. (B)
−
−−− −−−−−−
3R(320)
3RT
√ = √
2 32
320
T = = 20K
16
14. (A)
⃗ ⃗ ⃗ − ⃗
I = ΔP = P f Pi
M = 0.1 kg
− −−−−−−− − − −−−−− −−−−
I = ΔP = 0.1 (√ 2 × 9.8 × 5 − (−√ 2 × 9.8 × 10 ))
– −1
= 0.1 (14 + 7√ 2) ≈ 2.39kg ms
15. (C)
E = 25 sin(1000t)
1
cos θ =
√2
LR circuit
Initially ω1 L
R
=
1
tan θ
=
1
tan 45
∘
= 1
X L = ω1 L
ω2 = 2θ 1 , given
ω2 L 2ω1 L
′
tan θ = =
R R
′
tan θ = 2
′ 1
cos θ =
√5
16. (A)
V =
kP cos θ
2
r
& can also checked dimensionally.
17. (A)
Young’s modulus depends on the material not length and cross sectional area. So young’s modulus remains same.
18. (D)
For P.E.E.: λ ⩽
hc
We
1240nm−eV
λ ⩽
3eV
λ ⩽ 413.33nm
19. (C)
1
2
|P E| = K E for each value of n (orbit)
KE 1
∴ =
|P E| 2
20. (C)
Width of 1st secondary maxima = λ
a
.D
Here
−3
a = 0.2 × 10 m
−9
λ = 400 × 10 m
−2
D = 100 × 10
= 2mm
21. (2)
10 2
a = m/s
3
30 − T 1 = 3 × a
T 1 = 20N
Strain = Stress
22. (2)
C1 C2
Energy loss = 1 2
(V 1 − V 2 )
2 C1 +C2
2
= .E
3
∴ x = 2
23. (35)
−5
B H = 3.5 × 10 T
–
F = iℓB sin θ, i = √ 2A
F – −5 1
= iB sin θ = √ 2 × 3.5 × 10 ×
ℓ √2
−6
= 35 × 10 N /m
24. (400)
V 11
= 30 ⇒ ℓ1 = m
4ℓ1 4
V 3
= 110 ⇒ ℓ2 = m
4ℓ2 4
Δℓ = 2m,
3
M = 400g; (∵ ρ = 1g/cm )
25. (10)
v
= −2
u
v = −2u . . . . (i)
v − u = 45 . . . . (ii)
⇒ u = −15cm
v = 30cm
1 1 1
= −
f v u
f = +10cm
26. (6)
13.6
En = − = −0.85
2
n
⇒ n = 4
No of transition
n(n−1) 4(4−1)
= = = 6
2 2
27. (250)
→ 2
MR 2
Li = I ωi = . ω = 100kgm /s
2
2
1 MR 2
Ei = . .ω = 500J
2 2
→ −
→
Li = Lf ⇒ 100 = 2I ωf
ωf = 5 rad/ sec
2
5(2) 2
1
Ef = 2 × . . (5) = 250J
2 2
ΔE = 250J
28. (175)
Considering acceleration is constant
v = u + at
2
u + 50 = u + a ⇒ a = 50m/s
1 2
125 = ut + at
2
a
125 = u +
2
⇒ u = 100m/s
a
∴ Snth = u + [2n − 1]
2
= 175m
29. (6)
8−2 6
I = = = 1A
2+4 6
V C − V B = 6V
30. (32)
1 −4
B v = B sin 30 = × 10
4
2π
ω = 2π × f = × 1200 rad/s
60
1 2
ε = B V ωℓ
2
−5
= 32π × 10 V
31. (A)
32. (B)
33. (C)
On addition of naphthalene to benzene there is depression in freezing point of benzene.
34. (D)
Ce : [Xe] 4f15d16s2 ; Ce4+ diamagnetic
La : [Xe] 4f05d16s2 ; La3+ diamagnetic
35. (D)
For single electron species the energy depends upon principal quantum number ‘n’ only. So, statement II is false.
Statement I is correct definition of degenerate orbitals.
36. (D)
If nitrogen or sulphur is also present in the compound, the sodium fusion extract is first boiled with concentrated
nitric acid to decompose cyanide or sulphide of sodium during Lassaigne's test
37. (B)
38. (A)
it is aromatic species.
39. (D)
Na2S + H2SO4 → Na2SO4 + H2S
(CH3COO)2Pb + H2S → PbS + 2CH3COOH
Black lead sulphide
40. (D)
41. (A)
42. (D)
43. (D)
H2O Bent
ClF3 T-shape
It is known as rosenmund reduction that is the partial reduction of acid chloride to aldehyde.
45. (B)
5 1 2+ 4
24Cr → [Ar] 3d 4s ; Cr → [Ar] 3d
46. (A)
AlCl3 in acidified aqueous solution forms octahedral geometry [Al(H2O)6]3+
47. (D)
Bidentate, chelating
Based on Hall-Heroults process
[Rh(PPh3)3CI] Wilkinson's catalyst
Air
is vinyl halide
49. (D)
According to NCERT,
Statement-I : Factual data,
Statement-II is true.
But correct explanation is presence of completely filled d and f-orbitals of heavier members.
50. (A)
Sucrose do not contain hemiacetal group.
Hence it does not give test with Fehling solution.
While all other give positive test with Fehling solution
51. (9)
Precipitation when Qsp = Ksp
[Mg2+][OH–]2 = 10–11
0.1 × [OH–]2 = 10–11 ⇒ [OH–] = 10–5
⇒ pOH = 5
⇒ pH = 9
52. (8)
Two molecular orbitals σ 2s and σ*2s.
Six molecular orbitals σ 2pz and σ*2pz.
π2px, π2py and π*2px, π*2py
53. (24)
0.04 = k[A]0e–k × 10 × 60 ….. (1)
0.03 = k[A]0e–k × 20 × 60 ….. (2)
(1)/(2)
4 600 k(2−1)
= e
3
4 600 k
= e
3
4
ln = 600 k
3
4 ln 2
ln = 600 ×
3 t 1/2
ln 2
t1/2 = 600 4
sec
ln
3
log 2 0.3010
t1/2 = 600 × sec. = 10 × min
log 4−log 3 0.6020−0.477
54. (3)
55. (11)
111 belongs to 11th group
56. (8)
Reduction Half
2MnO → 2MnO2
−
Oxidation Half
2I– → I2 + 2e–
6I– → 3I2 + 6e–
Adding oxidation half and reduction half, net reaction is
2MnO + 6I– + 4H2O → 3I2 + 2MnO2 + 8OH–
−
⇒z=8
⇒ Ans 8
57. (11)
Volume of silver coating = 0.05 × 0.05 × 10000 = 25 cm3
Mass of silver deposited = 25 × 7.9 g
Moles of silver atoms = 25×7.9
108
108
23
= 11.01 × 1023
Ans. 11
58. (7)
Moles = Molarity × Volume in litres
= 0.35 × 0.25
Mass = moles × molar mass
= 0.35 × 0.25 × 82.02 = 7.18 g
Ans. 7
59. (7)
Distance travelled by sample/organiccompound
Retardation factor =
Distance travelled by solvent
3.5 −1
= = 7 × 10
5
60. (200)
Work done is given by area enclosed in the P vs V cyclic graph or V vs P cyclic graph.
Sign of work is positive for clockwise cyclic process for V vs P graph.
W = × (30 – 10) × (30 – 10) = 200 kPa – dm3
1
61. (D)
Let X = x − 2
2
y = 4x, y = 2 (x + 2) − 8
2
y = 4x, y = 2x − 4
4
2
y y+4
A = ∫ −
4 2
−2
= 9
62. (C)
′ 3 ′ 1
′ ′ g ( )−g ( )
g (x)−g (2−x) 2 2
′ ′ 3
f (x) = ,f ( ) = = 0
2 2 2
′ 1 ′ 3
g ( )−g ( )
Also f
2 2
′ 1 ′ 1
( ) = = 0, f ( ) = 0
2 2 2
′ 3 ′ 1
⇒ f ( ) = f ( ) = 0
2 2
2
3
6 sin x − 4 = 0
2
sin x =
3
64. (D)
Given |a|⃗ ∣ ∣⃗ ⃗ b⃗ = 2
= 1, b = 4, a .
∣ ∣
⃗ ⃗
c ⃗ = 2 (a ⃗ × b) − 3b
2 2
|c |⃗ = 4 [(1) (4) − (4)] + 9 (16)
2
|c |⃗ = 4 [12] + 144
2
|c |⃗ = 48 + 144
2
|c |⃗ = 192
⃗
b. c ⃗
∴ cos θ =
⃗
∣ ∣
b ∣ ⃗
∣c ∣
∣
∣ ∣
−48
∴ cos θ =
√ 192.4
−48
∴ cos θ =
8√ 3 .4
−3
∴ cos θ =
2√ 3
−√ 3 −√ 3
−1
∴ cos θ = ⇒ θ = cos ( )
2 2
65. (B)
dy
2
= 2 (x − 1) sin x + (x − 2x) cos x
dx
2
y (x) = (x − 2x) sin x + λ
y (0) = 0 + λ ⇒ 2 = λ
2
y (x) = (x − 2x) sin x + 2
y (2) = 2
66. (D)
–
Eqn: y − 0 = tan 15
∘
(x − 9) ⇒ y = (2 − √ 3) (x − 9)
67. (A)
2b = ae
b e
=
a 2
−−−−−
2
e
e = √1 −
4
2
e =
√5
68. (B)
If x = 0, y = 6, 7, 8, 9, 10
If x = 1, y = 7, 8, 9, 10
If x = 2, y = 8, 9, 10
If x = 3, y = 9, 10
If x = 4, y = 10
If x = 5, y = no possible value
Total possible ways = (5 + 4 + 3 + 2 + 1) × 2
= 30
Required probability = 30
11×11
=
30
121
69. (B)
If two circles intersect at two distinct points
⇒ |r1 − r2 | < C 1 C 2 < r1 + r2
−−−−−
|r − 2| < √ 9 + 16 < r + 2
−5 < r − 2 < 5
r > 3 . . . . (2)
∣ 0 0 1 ∣
∣ ∣
Area of Δ =
1
2 ∣
x y 1
∣
∣ −x y 1 ∣
1
⇒ ∣
∣ (xy + xy)∣
∣ = |xy|
2
dx
= ∣
2
∣ (−6x + 54)∣
∣ ⇒
dΔ
dx
= 0 at x = 3
71. (C)
x + y + z = 4μ, x + 2y + 2λz = 10μ, x + 3y + 4λ z = μ
2 2
+ 15 ,
∣ 1 1 1 ∣
∣ ∣ 2
Δ = 1 2 2λ = (2λ − 1)
∣ ∣
2
∣ 1 3 4λ ∣
2
)
Let Δ = 0, λ = 1
∣ 4μ 1 1∣
∣ ∣
Δ y = 0, Δx = Δz = 10μ 2 1
∣ ∣
2
∣ μ + 15 3 1∣
= (μ − 15) (μ − 1)
2
,μ = 1 or 15
72. (C)
4 4 2
∣ 2cos x 2sin x 3 + sin 2x ∣
∣ ∣
4 4 2
∣ 3 + 2cos x 2sin x sin 2x ∣
∣ ∣
4 4 2
∣ 2cos x 3 + 2sin x sin 2x ∣
R2 → R2 − R1 , R3 → R3 − R1
4 2
∣ 2cos4 x 2sin x 3 + sin 2x ∣
∣ ∣
3 0 −3
∣ ∣
∣ 0 3 −3 ∣
f (x) = 45
′
f (x) = 0
73. (B)
n
3
n
lim ∑ 2 2
k 3k
n→∞ 4
k=1 n (1+ )(1+ )
n2 n2
n
3
1 n
= lim ∑
n k
2 3k2
n→∞
k=1 (1+ )(1+ )
n2 n2
1
dx
= ∫
1
2 2
3(1+x )( +x )
0 3
1
1 2
(x +1)−(x +
2
)
1 3 3
= ∫ × dx
3 2 1
(1+x 2 )(x 2 + )
0 3
1
1 1 1
= ∫ [ − ] dx
2 2 2
1 1+x
2
0 x +( )
√3
1 – −1
– 1
1 −1
1
= [√ 3tan (√ 3x)] − (tan x)
2 0 2 0
√3 π 1 π π π
= ( ) − ( ) = −
2 3 2 4 2√ 3 8
13π
=
8.(4√ 3 +3)
74. (B)
Then k = 43
38
Then 19 (α + β + γ) = 101
75. (B)
∣−−→ −→
− ∣
Area = ∣ AC × BD∣
∣ ∣
∣ ^
i
^
j
^
k∣
∣ ∣
= ∣ 5 −1 7∣
∣ ∣
∣ 1 2 3∣
1 ∣ ^ ^ ^∣ 1 − −−
= √ 474
2
∣ −17 i + 8 j + 11k ∣ = 2
76. (B)
N
−C
2
M = 1 + ( )h
f
18−12
M = 8 + × 4
10
M = 10.4
20M = 208
77. (B)
20
S20 = [2a + 19d] = 790
2
2a + 19d = 79 . . . . (1)
10
S10 = [2a + 9d] = 145
2
2a + 9d = 29 . . . . (2)
= 405 − 10
= 395
78. (A)
2−|x|
∣ ∣
−1 ⩽ ⩽ 1
∣ 4 ∣
∣ 2−|x| ∣
⇒ ⩽ 1
∣ 4 ∣
−4 ⩽ 2 − |x| ⩽ 4
−6 ⩽ − |x| ⩽ 2
−2 ⩽ |x| ⩽ 6
|x| ⩽ 6
⇒ x ∈ [−6, 6] . . . . (1)
Now, 3 − x ≠ 1
And x ≠ 2
and 3 − x > 0
x < 3
α = 6
β = 3
γ = 2
α + β + γ = 11
79. (B)
2
z = −i z̄
2
∣
∣z ∣∣ = |i z̄ |
2
|z| = |z|
2
|z| − |z| = 0
|z| (|z| − 1) = 0
80. (B)
x
x ∫ f (t)dt
0
lim
2
x→0 e x −1 2
( )×x
x2
∫ f (t)dt
2
x
0 e −1
lim ( lim = 1)
x 2
x→0 x→0 x
f (x)
= lim
1
(using L Hospital)
x→0
1
f (0) =
2
1
α =
2
2
8α = 2
81. (138.00)
1 1 824
82. (182.00)
LR subtends 60° at centre
2
b
2
∘ a b 1
⇒ tan 30 = = =
ae a e
2
√3
2
√ 3b
⇒ e =
9
2 2 4
Also, e 2
= 1 +
b
9
⇒ 1 +
b
9
=
3b
81
4 2
⇒ b = 3b + 27
4 2
⇒ b − 3b − 27 = 0
2 3 −−
⇒ b = (1 + √ 13 )
2
⇒ l = 3, m = 2, n = 13
2 2 2
⇒ l + m + n = 182
83. (353.00)
2 2 2
α = 1 + 4 + 8 ....
2
t n = an + bn + c
1 = a + b + c
4 = 4a + 2b + c
8 = 9a + 3b + c
On solving we get, a =
1
2
,b =
3
2
, c = −1
10 2
2
n 3n
α = ∑ ( + − 1)
2 2
n=1
10 10
2
2 4
4α = ∑ (n + 3n − 2) , β = ∑ n
n=1 n=1
10
3 2
4α − β = ∑ (6n + 5n + 12n + 4) = 55 (353) + 40
n=1
84. (60.00)
2
x − 70x + λ = 0
α + β = 70
αβ = λ
∴ α (70 − α) = λ
Hence maximum number of students passed in all the three subjects is 10.
86. (155.00)
10x 1
= 1 ⇒ x =
x+1 9
10x 2
= 4 ⇒ x =
x+1 3
10x
= 9 ⇒ x = 9
x+1
1 2
⎛ 9 3 9 ⎞
I = 9 ⎜∫ 0 dx + ∫ 1. dx + ∫ 2 dx⎟
⎝0 1 2 ⎠
9 3
= 155
87. (44.00)
f : A → P (A)
a ∈ f (a)
Ans. 2 + 42 = 44
88. (97.00)
3 2
(x +2)√ 3(1−x )
dy xy
− =
dx 2 2
1−x 1−x
x
− ∫ 2 −
dx−−−− 1
IF =e 1−x 2 = e 2
ln(1−x )
= √1 − x
2 +
−−−−− –
2 3
y√1 − x = √ 3 ∫ (x + 2) dx
−−−−− – x
4
y√1 − x2 = √ 3 ( + 2x) + c
4
⇒ y (0) = 0
∴ c = 0
1 65 m
y( ) = =
2 32 n
m + n = 97
89. (16.00)
x+1 y z x y+2 z−1
L1 : = = , L2 : = =
1 1 1 1 1 1
−
2 12 6
d1 = 2
x−1 y+8 z−4 x−1 y−2 z−6
L3 : = = , L4 : = =
2 −7 5 2 1 −3
Hence =
32√ 3 d1 32√ 3 ×2
= 12
= 16
d2
√3
90. (15.00)
1
⎧
⎪ ; x ⩾ 2
⎪ x
2
f (x) = ⎨ ax + 2b; −2 < x < 2
⎪
⎩
⎪ 1
− ; x ⩽ −2
x
Continuous at x = 2 ⇒ = 1
2
a
4
+ 2b
Continuous at x = −2 ⇒ = 1
2
a
4
+ 2b
Since, it is differentiable at x = 2
1
− = 2ax
2
x
Differentiable at x
−1 −1 3
= 2 ⇒ = 4a ⇒ a = ,b =
4 16 8