3M™ Scotch-Weld™ Structural Void Filling Compound EC-3524 Black Accelerator 07/27/22

Safety Data Sheet

Copyright,2022, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 35-9740-8 Version Number: 7.00

Issue Date: 07/27/22 Supercedes Date: 08/19/21

SECTION 1: Identification
1.1. Product identifier
3M™ Scotch-Weld™ Structural Void Filling Compound EC-3524 Black Accelerator

Product Identification Numbers

41-3588-1637-3

1.2. Recommended use and restrictions on use

Recommended use
Adhesive Accelerator

This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(5)) or processed (as
defined in TSCA section 3(13)) for consumer paint or coating removal.

1.3. Supplier’s details

MANUFACTURER: 3M
DIVISION: Automotive and Aerospace Solutions Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification
Serious Eye Damage/Irritation: Category 1.
Skin Corrosion/Irritation: Category 2.
Skin Sensitizer: Category 1A.
Reproductive Toxicity: Category 1B.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 2.

2.2. Label elements

Signal word
Danger

Symbols

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Corrosion | Exclamation mark | Health Hazard |

Pictograms

Hazard Statements
Causes serious eye damage.
Causes skin irritation.
May cause an allergic skin reaction.
May cause drowsiness or dizziness.
May damage fertility or the unborn child.

May cause damage to organs through prolonged or repeated exposure:

nervous system |

Precautionary Statements

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF ON SKIN: Wash with plenty of soap and water.
Immediately call a POISON CENTER or doctor/physician.
If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
IF exposed or concerned: Get medical advice/attention.

Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

Supplemental Information:
Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt
Aliphatic Polymer Diamine 68911-25-1 30 - 60 Trade Secret *
Flame Retardant 13560-89-9 10 - 30
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Oxide Glass Chemicals 65997-17-3 10 - 30

2,4,6-tris(Dimethylamino)Methyl Phenol 90-72-2 5 - 10 Trade Secret *
BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE 4246-51-9 < 5 Trade Secret *
GLYCOL
Triphenyl Phosphite 101-02-0 < 2 Trade Secret *
Toluene 108-88-3 < 0.5 Trade Secret *
DCM 75-09-2 < 0.01

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.

Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing.
Immediately get medical attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Allergic skin reaction (redness, swelling, blistering, and itching). Serious damage to the eyes (corneal cloudiness, severe pain, tearing,
ulcerations, and significantly impaired or loss of vision). Central nervous system depression (headache, dizziness, drowsiness,
incoordination, nausea, slurred speech, giddiness, and unconsciousness). Target organ effects following prolonged or repeated exposure.
See Section 11 for additional details.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.

Hazardous Decomposition or By-Products

Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Chloride During Combustion

5.3. Special protective actions for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. When fire fighting conditions are severe and total thermal decomposition of the product is
possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing
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apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of
the head.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic
absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not
remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed
container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by
a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label
and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable
local/regional/national/international regulations.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
For industrial/occupational use only. Not for consumer sale or use. Do not handle until all safety precautions have been
read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not
be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid
contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.)
as required.

7.2. Conditions for safe storage including any incompatibilities

Store in a well-ventilated place. Keep container tightly closed. Store away from acids. Store away from strong bases.
Store away from oxidizing agents. Store away from amines.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human
carcin, Ototoxicant
Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm
Oxide Glass Chemicals 65997-17-3 Manufacturer TWA(as non-fibrous,
determined respirable)(8 hours):3
mg/m3;TWA(as non-fibrous,
inhalable fraction)(8 hours):10
mg/m3
DCM 75-09-2 ACGIH TWA:50 ppm A3: Confirmed animal
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carcin.
DCM 75-09-2 OSHA TWA:25 ppm;STEL:125 ppm 29 CFR 1910.1052,
SKIN
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Full Face Shield
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

When only incidental contact is anticipated, alternative glove material(s) may be used. If contact with the glove does occur,
remove immediately and replace with a set of new gloves. For incidental contact, gloves made of the following material(s)
may be used:Nitrile Rubber

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

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Appearance
Physical state Liquid
Color White

Specific Physical Form: Paste

Odor Characteristic Amine
Odor threshold No Data Available
pH Not Applicable
Melting point No Data Available
Boiling Point > 100 ºC
Flash Point >=200 ºF [Test Method:Closed Cup]
Evaporation rate Not Applicable
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data Available
Flammable Limits(UEL) No Data Available
Vapor Pressure No Data Available
Vapor Density No Data Available
Density 0.50 g/ml
Specific Gravity 0.50 [Ref Std:WATER=1]
Solubility in Water Nil
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity > 100,000 centipoise
Molecular weight Not Applicable
Volatile Organic Compounds Not Applicable
Percent volatile 0.00 % weight
VOC Less H2O & Exempt Solvents Not Applicable

SECTION 10: Stability and reactivity

10.1. Reactivity
This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

None known.

10.6. Hazardous decomposition products

Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

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The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may
include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

May cause additional health effects (see below).

Skin Contact:
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.

Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.

Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May cause additional health effects (see below).

Additional Health Effects:

Single exposure may cause target organ effects:

Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

Prolonged or repeated exposure may cause target organ effects:

Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or
numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.

Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Carcinogenicity:

Ingredient CAS No. Class Description Regulation

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Dichloromethane (methylene chloride) 75-09-2 Grp. 2A: Probable human carc. International Agency for Research on Cancer
Dichloromethane (Methylene Chloride) 75-09-2 Anticipated human carcinogen National Toxicology Program Carcinogens
METHYLENE CHLORIDE 75-09-2 Cancer hazard OSHA Carcinogens

Additional Information:
Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg
Overall product Ingestion No data available; calculated ATE >2,000 - =5,000
mg/kg
Aliphatic Polymer Diamine Dermal Rat LD50 > 2,000 mg/kg
Aliphatic Polymer Diamine Ingestion Rat LD50 > 2,000 mg/kg
Oxide Glass Chemicals Dermal LD50 estimated to be > 5,000 mg/kg
Oxide Glass Chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Flame Retardant Dermal Rabbit LD50 > 8,000 mg/kg
Flame Retardant Inhalation- Rat LC50 > 2.25 mg/l
Dust/Mist
(4 hours)
Flame Retardant Ingestion Rat LD50 > 25,000 mg/kg
2,4,6-tris(Dimethylamino)Methyl Phenol Dermal Rat LD50 1,280 mg/kg
2,4,6-tris(Dimethylamino)Methyl Phenol Ingestion Rat LD50 1,000 mg/kg
BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL Dermal Rabbit LD50 2,525 mg/kg
BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL Ingestion Rat LD50 2,850 mg/kg
Triphenyl Phosphite Dermal Rabbit LD50 > 2,000 mg/kg
Triphenyl Phosphite Inhalation- Rat LC50 > 1.7 mg/l
Dust/Mist
(4 hours)
Triphenyl Phosphite Ingestion Rat LD50 1,590 mg/kg
Toluene Dermal Rat LD50 12,000 mg/kg
Toluene Inhalation- Rat LC50 30 mg/l
Vapor (4
hours)
Toluene Ingestion Rat LD50 5,550 mg/kg
DCM Dermal Rat LD50 > 2,000 mg/kg
DCM Inhalation- Rat LC50 63.7 mg/l
Vapor (4
hours)
DCM Ingestion Rat LD50 1,410 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Overall product In vitro Irritant

data
Aliphatic Polymer Diamine Rat Irritant
Oxide Glass Chemicals Professio No significant irritation
nal
judgeme
nt
2,4,6-tris(Dimethylamino)Methyl Phenol Rabbit Corrosive
BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL Rabbit Corrosive
Triphenyl Phosphite Rabbit Irritant
Toluene Rabbit Irritant
DCM Rabbit Irritant

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Serious Eye Damage/Irritation

Name Species Value

Aliphatic Polymer Diamine In vitro Severe irritant

data
Oxide Glass Chemicals Professio No significant irritation
nal
judgeme
nt
2,4,6-tris(Dimethylamino)Methyl Phenol Rabbit Corrosive
BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL Rabbit Corrosive
Triphenyl Phosphite Rabbit Moderate irritant
Toluene Rabbit Moderate irritant
DCM Rabbit Severe irritant

Skin Sensitization
Name Species Value
Aliphatic Polymer Diamine Guinea Sensitizing
pig
2,4,6-tris(Dimethylamino)Methyl Phenol Guinea Not classified
pig
BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL Professio Sensitizing
nal
judgeme
nt
Triphenyl Phosphite Mouse Sensitizing
Toluene Guinea Not classified
pig

Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity

Name Route Value

Aliphatic Polymer Diamine In Vitro Not mutagenic

Oxide Glass Chemicals In Vitro Some positive data exist, but the data are not
sufficient for classification
2,4,6-tris(Dimethylamino)Methyl Phenol In Vitro Not mutagenic
BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL In Vitro Not mutagenic
Toluene In Vitro Not mutagenic
Toluene In vivo Not mutagenic
DCM In vivo Not mutagenic
DCM In Vitro Some positive data exist, but the data are not
sufficient for classification

Carcinogenicity
Name Route Species Value
Oxide Glass Chemicals Inhalation Multiple Some positive data exist, but the data are not
animal sufficient for classification
species
Toluene Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Toluene Ingestion Rat Some positive data exist, but the data are not
sufficient for classification
Toluene Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification
DCM Inhalation Multiple Carcinogenic
animal
species

Reproductive Toxicity

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Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure
Duration
Aliphatic Polymer Diamine Ingestion Not classified for female reproduction Rat NOAEL 1,000 premating
mg/kg/day into lactation
Aliphatic Polymer Diamine Ingestion Not classified for male reproduction Rat NOAEL 1,000 29 days
mg/kg/day
Aliphatic Polymer Diamine Ingestion Not classified for development Rat NOAEL 1,000 premating
mg/kg/day into lactation
BIS(3-AMINOPROPYL) ETHER OF Ingestion Not classified for female reproduction Rat NOAEL 600 premating
DIETHYLENE GLYCOL mg/kg/day into lactation
BIS(3-AMINOPROPYL) ETHER OF Ingestion Not classified for male reproduction Rat NOAEL 600 59 days
DIETHYLENE GLYCOL mg/kg/day
BIS(3-AMINOPROPYL) ETHER OF Ingestion Not classified for development Rat NOAEL 600 premating
DIETHYLENE GLYCOL mg/kg/day into lactation
Toluene Inhalation Not classified for female reproduction Human NOAEL Not occupational
available exposure
Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 1 generation
mg/l
Toluene Ingestion Toxic to development Rat LOAEL 520 during
mg/kg/day gestation
Toluene Inhalation Toxic to development Human NOAEL Not poisoning
available and/or abuse
DCM Inhalation Not classified for female reproduction Rat NOAEL 5.2 2 generation
mg/l
DCM Inhalation Not classified for male reproduction Rat NOAEL 5.2 2 generation
mg/l
DCM Inhalation Not classified for development Multiple NOAEL 4.3 during
animal mg/l gestation
species

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Aliphatic Polymer Diamine Inhalation respiratory irritation Some positive data exist, but the similar Irritation
data are not sufficient for health Positive
classification hazards
Aliphatic Polymer Diamine Ingestion central nervous May cause drowsiness or Rat NOAEL Not
system depression dizziness available
2,4,6- Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
tris(Dimethylamino)Methyl data are not sufficient for available
Phenol classification
BIS(3-AMINOPROPYL) Inhalation respiratory irritation Some positive data exist, but the similar NOAEL Not
ETHER OF data are not sufficient for health available
DIETHYLENE GLYCOL classification hazards
Toluene Inhalation central nervous May cause drowsiness or Human NOAEL Not
system depression dizziness available
Toluene Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not
data are not sufficient for available
classification
Toluene Inhalation immune system Not classified Mouse NOAEL 3 hours
0.004 mg/l
Toluene Ingestion central nervous May cause drowsiness or Human NOAEL Not poisoning
system depression dizziness available and/or abuse
DCM Dermal blood Some positive data exist, but the Rat NOAEL Not 4 hours
data are not sufficient for available
classification
DCM Inhalation central nervous May cause drowsiness or Human NOAEL Not occupational
system depression dizziness available exposure
DCM Inhalation blood Some positive data exist, but the Human NOAEL Not
data are not sufficient for available
classification
DCM Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
data are not sufficient for available
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classification

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Aliphatic Polymer Diamine Ingestion heart | skin | Not classified Rat NOAEL 29 days
endocrine system | 1,000
gastrointestinal tract mg/kg/day
| bone, teeth, nails,
and/or hair |
hematopoietic
system | liver |
immune system |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system | vascular
system
Oxide Glass Chemicals Inhalation respiratory system Not classified Human NOAEL not occupational
available exposure
2,4,6- Dermal skin | liver | nervous Not classified Rat NOAEL 125 28 days
tris(Dimethylamino)Methy system | auditory mg/kg/day
l Phenol system |
hematopoietic
system | eyes
BIS(3-AMINOPROPYL) Ingestion gastrointestinal tract Not classified Rat NOAEL 600 59 days
ETHER OF | heart | endocrine mg/kg/day
DIETHYLENE GLYCOL system | bone, teeth,
nails, and/or hair |
hematopoietic
system | liver |
immune system |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system | vascular
system
Triphenyl Phosphite Ingestion nervous system May cause damage to organs Rat NOAEL 15 28 days
though prolonged or repeated mg/kg/day
exposure
Toluene Inhalation auditory system | Causes damage to organs through Human NOAEL Not poisoning
eyes | olfactory prolonged or repeated exposure available and/or abuse
system
Toluene Inhalation nervous system May cause damage to organs Human NOAEL Not poisoning
though prolonged or repeated available and/or abuse
exposure
Toluene Inhalation respiratory system Some positive data exist, but the Rat LOAEL 2.3 15 months
data are not sufficient for mg/l
classification
Toluene Inhalation heart | liver | kidney Not classified Rat NOAEL 11.3 15 weeks
and/or bladder mg/l
Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 4 weeks
mg/l
Toluene Inhalation immune system Not classified Mouse NOAEL Not 20 days
available
Toluene Inhalation bone, teeth, nails, Not classified Mouse NOAEL 1.1 8 weeks
and/or hair mg/l
Toluene Inhalation hematopoietic Not classified Human NOAEL Not occupational
system | vascular available exposure
system
Toluene Inhalation gastrointestinal tract Not classified Multiple NOAEL 11.3 15 weeks
animal mg/l
species
Toluene Ingestion nervous system Some positive data exist, but the Rat NOAEL 625 13 weeks
data are not sufficient for mg/kg/day

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classification
Toluene Ingestion heart Not classified Rat NOAEL 13 weeks
2,500
mg/kg/day
Toluene Ingestion liver | kidney and/or Not classified Multiple NOAEL 13 weeks
bladder animal 2,500
species mg/kg/day
Toluene Ingestion hematopoietic Not classified Mouse NOAEL 600 14 days
system mg/kg/day
Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 28 days
mg/kg/day
Toluene Ingestion immune system Not classified Mouse NOAEL 105 4 weeks
mg/kg/day
DCM Inhalation kidney and/or Some positive data exist, but the Rat LOAEL 6.95 2 years
bladder data are not sufficient for mg/l
classification
DCM Inhalation liver Some positive data exist, but the Rat NOAEL 0.17 2 years
data are not sufficient for mg/l
classification
DCM Inhalation respiratory system Some positive data exist, but the Multiple LOAEL 35 8 weeks
data are not sufficient for animal mg/l
classification species
DCM Inhalation heart Not classified Human NOAEL Not
available
DCM Inhalation immune system Not classified Rat NOAEL 18 28 days
mg/l
DCM Ingestion liver Some positive data exist, but the Rat LOAEL 3 months
data are not sufficient for 1,200
classification mg/kg/day
DCM Ingestion blood Not classified Rat NOAEL 249 2 years
mg/kg/day
DCM Ingestion kidney and/or Not classified Rat NOAEL 3 months
bladder 1,469
mg/kg/day
DCM Ingestion eyes Not classified Rat NOAEL 249 104 weeks
mg/kg/day

Aspiration Hazard
Name Value
Toluene Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and

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3M™ Scotch-Weld™ Structural Void Filling Compound EC-3524 Black Accelerator 07/27/22

handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable

regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable
waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal
facilities.

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information.

EPCRA 311/312 Hazard Classifications:

Physical Hazards
Not applicable

Health Hazards
Reproductive toxicity
Respiratory or Skin Sensitization
Serious eye damage or eye irritation
Skin Corrosion or Irritation
Specific target organ toxicity (single or repeated exposure)

This material contains a chemical which requires export notification under TSCA Section 12[b]:

Ingredient (Category if applicable) C.A.S. No Regulation Status

DCM 75-09-2 Toxic Substances Control Act (TSCA) 6 Applicable
Banned or Restricted Use Chemicals

Additional TSCA Information

This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(5)) or processed (as
defined in TSCA section 3(13)) for consumer paint or coating removal.

15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.

Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

__________________________________________________________________________________________

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3M™ Scotch-Weld™ Structural Void Filling Compound EC-3524 Black Accelerator 07/27/22

NFPA Hazard Classification

Health: 3 Flammability: 1 Instability: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 35-9740-8 Version Number: 7.00

Issue Date: 07/27/22 Supercedes Date: 08/19/21

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.

3M USA SDSs are available at www.3M.com

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3M™ Scotch-Weld™ Structural Void Filling Compound EC-3524 B/A Black Part B 03/22/22

Safety Data Sheet

Copyright,2022, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 35-9861-2 Version Number: 4.02

Issue Date: 03/22/22 Supercedes Date: 08/25/21

SECTION 1: Identification
1.1. Product identifier
3M™ Scotch-Weld™ Structural Void Filling Compound EC-3524 B/A Black Part B

Product Identification Numbers

41-3588-1638-1

1.2. Recommended use and restrictions on use

Recommended use
Adhesive

1.3. Supplier’s details

MANUFACTURER: 3M
DIVISION: Automotive and Aerospace Solutions Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2B.
Skin Sensitizer: Category 1.
Carcinogenicity: Category 2.
Specific Target Organ Toxicity (repeated exposure): Category 1.

2.2. Label elements

Signal word
Danger

Symbols
Exclamation mark | Health Hazard |

Pictograms

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Hazard Statements
Causes eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.

Causes damage to organs through prolonged or repeated exposure:

skin |

May cause damage to organs through prolonged or repeated exposure:

respiratory system |

Precautionary Statements

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.

Storage:
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt
2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether 25085-99-8 40 - 70 Trade Secret *
polymer
BROMINATED ALIPHATIC POLYOL POLYEPOXY 31452-80-9 10 - 30 Trade Secret *
RESIN
Oxide glass chemicals 65997-17-3 10 - 30
Antimony Trioxide 1309-64-4 3 - 7 Trade Secret *
Carbon Black 1333-86-4 0.5 - 1.5 Trade Secret *

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*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.

Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical
attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Allergic skin reaction (redness, swelling, blistering, and itching). Target organ effects following prolonged or repeated exposure. See
Section 11 for additional details.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Bromide During Combustion
Hydrogen Chloride During Combustion
Irritant Vapors or Gases During Combustion
Oxides of Antimony During Combustion

5.3. Special protective actions for fire-fighters

When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective
clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants,
bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for

__________________________________________________________________________________________

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information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions
on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with
applicable local/regional/national/international regulations.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray.
Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after
handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment.
Wash contaminated clothing before reuse. Use personal protective equipment (gloves, respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilities

No special storage requirements.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
ANTIMONY COMPOUNDS 1309-64-4 OSHA TWA(as Sb):0.5 mg/m3
Antimony Trioxide 1309-64-4 ACGIH TWA(inhalable fraction):0.02 A2: Suspected human
mg/m3 carcin.
Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 A3: Confirmed animal
mg/m3 carcin.
Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3
Oxide glass chemicals 65997-17-3 Manufacturer TWA(as non-fibrous,
determined respirable)(8 hours):3
mg/m3;TWA(as non-fibrous,
inhalable fraction)(8 hours):10
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

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Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Physical state Liquid
Color Black

Specific Physical Form: Viscous

Odor Epoxy
Odor threshold No Data Available
pH No Data Available
Melting point No Data Available
Boiling Point No Data Available
Flash Point Flash point > 93 °C (200 °F)
Evaporation rate No Data Available
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data Available
Flammable Limits(UEL) No Data Available
Vapor Pressure No Data Available
Vapor Density No Data Available
Density No Data Available
Specific Gravity 1.08 [Ref Std:WATER=1]
Solubility In Water No Data Available
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Solubility- non-water No Data Available

Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity No Data Available
Molecular weight Not Applicable

SECTION 10: Stability and reactivity

10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

Not determined

10.5. Incompatible materials

None known.

10.6. Hazardous decomposition products

Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may
include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

May cause additional health effects (see below).

Skin Contact:
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Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

May cause additional health effects (see below).

Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Additional Health Effects:

Prolonged or repeated exposure may cause target organ effects:

Fibrosis: Signs/symptoms may include breathlessness, chronic dry cough, phlegm production, wheezing, and changes in
lung function tests.

Dermal Effects: Signs/symptoms may include redness, itching, acne, or bumps on the skin.

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.

Ingredient CAS No. Class Description Regulation

Antimony trioxide 1309-64-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer
Carbon black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether polymer Dermal Rat LD50 > 1,600 mg/kg
2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether polymer Ingestion Rat LD50 > 1,000 mg/kg
BROMINATED ALIPHATIC POLYOL POLYEPOXY RESIN Dermal LD50 estimated to be > 5,000 mg/kg
BROMINATED ALIPHATIC POLYOL POLYEPOXY RESIN Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Oxide glass chemicals Dermal LD50 estimated to be > 5,000 mg/kg
Oxide glass chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Antimony Trioxide Dermal Rabbit LD50 > 6,685 mg/kg
Antimony Trioxide Inhalation- Rat LC50 > 2.76 mg/l
Dust/Mist
(4 hours)
Antimony Trioxide Ingestion Rat LD50 > 34,600 mg/kg
Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg
Carbon Black Ingestion Rat LD50 > 8,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether polymer Rabbit Mild irritant

BROMINATED ALIPHATIC POLYOL POLYEPOXY RESIN Professio Mild irritant
nal
judgeme
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nt
Oxide glass chemicals Professio No significant irritation
nal
judgeme
nt
Antimony Trioxide Human Minimal irritation
and
animal
Carbon Black Rabbit No significant irritation

Serious Eye Damage/Irritation

Name Species Value

2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether polymer Rabbit Moderate irritant

BROMINATED ALIPHATIC POLYOL POLYEPOXY RESIN Professio Moderate irritant
nal
judgeme
nt
Oxide glass chemicals Professio No significant irritation
nal
judgeme
nt
Antimony Trioxide Rabbit Mild irritant
Carbon Black Rabbit No significant irritation

Skin Sensitization
Name Species Value
2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether polymer Human Sensitizing
and
animal
BROMINATED ALIPHATIC POLYOL POLYEPOXY RESIN similar Sensitizing
compoun
ds
Antimony Trioxide Human Not classified

Respiratory Sensitization
Name Species Value

2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether polymer Human Not classified

Germ Cell Mutagenicity

Name Route Value

2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether polymer In vivo Not mutagenic

2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether polymer In Vitro Some positive data exist, but the data are not
sufficient for classification
Oxide glass chemicals In Vitro Some positive data exist, but the data are not
sufficient for classification
Antimony Trioxide In Vitro Some positive data exist, but the data are not
sufficient for classification
Antimony Trioxide In vivo Some positive data exist, but the data are not
sufficient for classification
Carbon Black In Vitro Not mutagenic
Carbon Black In vivo Some positive data exist, but the data are not
sufficient for classification

Carcinogenicity
Name Route Species Value
2,2-Bis(p-hydroxyphenyl)propane diglycidyl ether polymer Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Oxide glass chemicals Inhalation Multiple Some positive data exist, but the data are not
animal sufficient for classification
species

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Antimony Trioxide Inhalation Multiple Carcinogenic

animal
species
Carbon Black Dermal Mouse Not carcinogenic
Carbon Black Ingestion Mouse Not carcinogenic
Carbon Black Inhalation Rat Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure
Duration
2,2-Bis(p-hydroxyphenyl)propane Ingestion Not classified for female reproduction Rat NOAEL 750 2 generation
diglycidyl ether polymer mg/kg/day
2,2-Bis(p-hydroxyphenyl)propane Ingestion Not classified for male reproduction Rat NOAEL 750 2 generation
diglycidyl ether polymer mg/kg/day
2,2-Bis(p-hydroxyphenyl)propane Dermal Not classified for development Rabbit NOAEL 300 during
diglycidyl ether polymer mg/kg/day organogenesi
s
2,2-Bis(p-hydroxyphenyl)propane Ingestion Not classified for development Rat NOAEL 750 2 generation
diglycidyl ether polymer mg/kg/day
Antimony Trioxide Inhalation Not classified for female reproduction Rat LOAEL 0.25 premating &
mg/l during
gestation

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Antimony Trioxide Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
data are not sufficient for available
classification

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
2,2-Bis(p- Dermal liver Not classified Rat NOAEL 2 years
hydroxyphenyl)propane 1,000
diglycidyl ether polymer mg/kg/day
2,2-Bis(p- Dermal nervous system Not classified Rat NOAEL 13 weeks
hydroxyphenyl)propane 1,000
diglycidyl ether polymer mg/kg/day
2,2-Bis(p- Ingestion auditory system | Not classified Rat NOAEL 28 days
hydroxyphenyl)propane heart | endocrine 1,000
diglycidyl ether polymer system | mg/kg/day
hematopoietic
system | liver | eyes |
kidney and/or
bladder
Oxide glass chemicals Inhalation respiratory system Not classified Human NOAEL not occupational
available exposure
Antimony Trioxide Dermal skin Causes damage to organs through Human NOAEL Not occupational
prolonged or repeated exposure available exposure
Antimony Trioxide Inhalation pulmonary fibrosis May cause damage to organs Rat NOAEL 1 years
though prolonged or repeated 0.002 mg/l
exposure
Antimony Trioxide Inhalation liver Not classified Rat NOAEL 1 years
0.043 mg/l
Antimony Trioxide Inhalation blood Not classified Rat NOAEL not available
0.004 mg/l
Antimony Trioxide Inhalation pneumoconiosis Not classified Human LOAEL 0.01 occupational
mg/l exposure
Antimony Trioxide Inhalation heart Not classified Rat NOAEL 0.02 1 years
mg/l
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Antimony Trioxide Ingestion blood | liver Not classified Rat NOAEL 418 not available
mg/kg/day
Antimony Trioxide Ingestion heart Not classified Rat NOAEL Not not available
available
Carbon Black Inhalation pneumoconiosis Not classified Human NOAEL Not occupational
available exposure

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. Combustion products will include halogen acid
(HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for
transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per
applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by
applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and
disposal facilities.

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information.

EPCRA 311/312 Hazard Classifications:

Physical Hazards
Not applicable

Health Hazards
Carcinogenicity
Respiratory or Skin Sensitization
Serious eye damage or eye irritation
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Specific target organ toxicity (single or repeated exposure)

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Antimony Trioxide (ANTIMONY COMPOUNDS) 1309-64-4 Trade Secret 3- 7

15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.

Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 35-9861-2 Version Number: 4.02

Issue Date: 03/22/22 Supercedes Date: 08/25/21

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.

3M USA SDSs are available at www.3M.com

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