Acetic Acid, 3% v/v (3+97)

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Issue date: 12/09/2013 Revision date: 02/02/2021 Supersedes: 09/06/2016 Version: 1.2

SECTION 1: Identification
1.1. Identification
Product form : Mixtures
Product name : Acetic Acid, 3% v/v (3+97)
Product code : LC10160
1.2. Recommended use and restrictions on use
Use of the substance/mixture : For laboratory and manufacturing use only.
Recommended use : Laboratory chemicals
Restrictions on use : Not for food, drug or household use
1.3. Supplier
LabChem, Inc.
1010 Jackson's Pointe Ct.
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
[email protected] - www.labchem.com

1.4. Emergency telephone number

Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS US classification
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2A H319 Causes serious eye irritation
Full text of H statements : see section 16

2.2. GHS Label elements, including precautionary statements

GHS US labeling
Hazard pictograms (GHS US) :

Signal word (GHS US) : Warning

Hazard statements (GHS US) : H315 - Causes skin irritation
H319 - Causes serious eye irritation
Precautionary statements (GHS US) : P264 - Wash exposed skin thoroughly after handling.
P280 - Wear protective gloves, eye protection.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.

2.3. Other hazards which do not result in classification

Other hazards not contributing to the : None.
classification
2.4. Unknown acute toxicity (GHS US)
Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
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Acetic Acid, 3% v/v (3+97)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

3.2. Mixtures
Name Product identifier % GHS US classification
Water (CAS-No.) 7732-18-5 96.87 Not classified
Acetic Acid (CAS-No.) 64-19-7 3.13 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Corr. 1B, H314
Eye Dam. 1, H318
Aquatic Acute 3, H402

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical

5.3. Special protective equipment and precautions for fire-fighters

Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Safety glasses. Gloves.
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
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Acetic Acid, 3% v/v (3+97)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor.
Hygiene measures : Wash exposed skin thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container closed when not in use.
Incompatible products : Strong bases. Strong oxidizers. metals.
Incompatible materials : Sources of ignition. Direct sunlight.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Acetic Acid, 3% v/v (3+97)

No additional information available
Acetic Acid (64-19-7)
USA - ACGIH - Occupational Exposure Limits
Local name Acetic acid
ACGIH OEL TWA 25 mg/m³
ACGIH OEL TWA [ppm] 10 ppm
ACGIH STEL (mg/m³) 37 mg/m³
ACGIH STEL (ppm) 15 ppm
Remark (ACGIH) TLV® Basis: URT & eye irr; pulm func
Regulatory reference ACGIH 2020
USA - OSHA - Occupational Exposure Limits
Local name Acetic acid
OSHA PEL (TWA) [1] 25 mg/m³
OSHA PEL (TWA) [2] 10 ppm
Regulatory reference (US-OSHA) OSHA Annotated Table Z-1
USA - IDLH - Occupational Exposure Limits
IDLH [ppm] 50 ppm
USA - NIOSH - Occupational Exposure Limits
NIOSH REL (TWA) 25 mg/m³
NIOSH REL TWA [ppm] 10 ppm
NIOSH REL (STEL) 37 mg/m³
NIOSH REL STEL [ppm] 15 ppm
Water (7732-18-5)
No additional information available

8.2. Appropriate engineering controls

Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure.

8.3. Individual protection measures/Personal protective equipment

Personal protective equipment:
Safety glasses. Gloves.

Hand protection:
Wear protective gloves.

Eye protection:
Chemical goggles or safety glasses

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Acetic Acid, 3% v/v (3+97)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Respiratory protection:
Respiratory protection not required in normal conditions

Personal protective equipment symbol(s):

Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Colorless
Odor : Vinegar odour
Odor threshold : No data available
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Non flammable.
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Density : 1 g/ml
Solubility : Soluble in water.
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : 1.06 mm²/s
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
No additional information available
10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.

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Acetic Acid, 3% v/v (3+97)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

10.5. Incompatible materials

Strong oxidizers. Strong bases. metals.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Acetic Acid, 3% v/v (3+97)
LD50 oral rat 33866 mg/kg
ATE US (oral) 33866 mg/kg body weight
Acetic Acid (64-19-7)
LD50 oral rat 3310 mg/kg body weight (Rat, Male / female, Experimental value, Oral, 6 day(s))
LC50 Inhalation - Rat 11.4 mg/l (Equivalent or similar to OECD 403, 4 h, Rat, Female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 3310 mg/kg body weight
ATE US (vapors) 11.4 mg/l/4h
ATE US (dust, mist) 11.4 mg/l/4h
Water (7732-18-5)
LD50 oral rat ≥ 90000 mg/kg
ATE US (oral) 90000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

Viscosity, kinematic : 1.06 mm²/s

Likely routes of exposure : Inhalation. Skin and eye contact.

Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.

SECTION 12: Ecological information

12.1. Toxicity

Acetic Acid (64-19-7)

LC50 fish 1 > 1000 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Semi-static
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 > 1000 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)

12.2. Persistence and degradability

Acetic Acid, 3% v/v (3+97)
Persistence and degradability Not established.

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Acetic Acid, 3% v/v (3+97)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Acetic Acid (64-19-7)

Persistence and degradability Readily biodegradable in the soil. Readily biodegradable in water.
Biochemical oxygen demand (BOD) 0.6 – 0.74 g O₂/g substance
Chemical oxygen demand (COD) 1.03 g O₂/g substance
ThOD 1.07 g O₂/g substance

Water (7732-18-5)
Persistence and degradability Not established.

12.3. Bioaccumulative potential

Acetic Acid, 3% v/v (3+97)
Bioaccumulative potential Not established.
Acetic Acid (64-19-7)
BCF fish 1 3.16 (Pisces, Fresh water, QSAR)
Log Pow -0.17 (Experimental value, 25 °C)
Bioaccumulative potential Not bioaccumulative.
Water (7732-18-5)
Bioaccumulative potential Not established.

12.4. Mobility in soil

Acetic Acid (64-19-7)
Surface tension 26.3 mN/m (30 °C)
Ecology - soil Highly mobile in soil. May be harmful to plant growth, blooming and fruit formation.

12.5. Other adverse effects

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Disposal methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT

Not regulated

Transport by sea (IMDG)

Not regulated

Air transport (IATA/ICAO)

Not regulated

SECTION 15: Regulatory information

15.1. US Federal regulations
Acetic Acid, 3% v/v (3+97)
SARA Section 311/312 Hazard Classes Health hazard - Skin corrosion or Irritation
Health hazard - Serious eye damage or eye irritation

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Acetic Acid, 3% v/v (3+97)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Acetic Acid (64-19-7)

Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
RQ (Reportable quantity, section 304 of EPA's 5000 lb
List of Lists)
SARA Section 311/312 Hazard Classes Physical hazard - Flammable (gases, aerosols, liquids, or solids)
Health hazard - Skin corrosion or Irritation
Health hazard - Serious eye damage or eye irritation
Health hazard - Acute toxicity (any route of exposure)
Water (7732-18-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
Acetic Acid (64-19-7)
Listed on the Canadian DSL (Domestic Substances List)
Water (7732-18-5)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
No additional information available
15.3. US State regulations
No additional information available

SECTION 16: Other information

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Revision date : 02/02/2021

Other information : None.

Full text of H-phrases: see section 16:

H226 Flammable liquid and vapor
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H318 Causes serious eye damage
H319 Causes serious eye irritation
H332 Harmful if inhaled
H402 Harmful to aquatic life
NFPA health hazard : 1 - Materials that, under emergency conditions, can cause
significant irritation.
NFPA fire hazard : 0 - Materials that will not burn under typical fire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA reactivity : 0 - Material that in themselves are normally stable, even
under fire conditions.

Hazard Rating
Health : 1 Slight Hazard - Irritation or minor reversible injury possible
Flammability : 0 Minimal Hazard - Materials that will not burn
Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT
react with water, polymerize, decompose, condense, or self-react. Non-Explosives.
Personal protection : B
B - Safety glasses, Gloves

SDS US LabChem

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Acetic Acid, 3% v/v (3+97)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.

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