1. 5. The mass of silver(eq. mass = 108) displaced by that What mass of copper will be deposited by passing 2 quantity of current which displaced 5600 mL of faraday of electricity through a solution of Cu(II) salt? hydrogen at STP is: 1. 35.6 g 1. 54 g 2. 63.5 g 2. 108 g 3. 6.35 g 3. 5.4 g 4. 3.56 g 4. none of these 2. 6. A 5A current is passed through a solution of zinc sulphate for 40 min. The amount of zinc deposited at the The same amount of electricity was passed through two cathode is cells containing molten Al2O3 and molten NaCl. If 1.8g of Al were liberated in one cell, the amount of Na 1. 40.65g liberated in the other cell is: 2. 0.4065g 1. 4.6 g 3. 4.065g 2. 2.3 g 4. 65.04g 3. 6.4 g 3. 4. 3.2 g Al2O3 is reduced by electrolysis at low potentials and 7. high currents. If 4.0 x 104 A of current is passed through How many columbs of electricity are consumed when molten Al2O3 for 6 h, what mass of aluminium is 100 mA current is passed through a solution of AgNO 3 produced? (Assume 100% current efficiency, atomic for 30 minute during an electrolysis experiment? mass of Al = 27g mol-1) 1. 108 3 1. 9.0 x 10 g 2. 18000 2. 8.1 x 104 g 3. 180 3. 2.4 x 105 g 4. 3000
4. 1.3 x 104 g 8.
4. When an electric current is passed through acidulated
water, 112 mL of hydrogen gas at STP collects at the When 0.1 mole of MnO2-4 is oxidised, the quantity of cathode in 965 second. The current passed, in ampere is: electricity required to completely oxidise MnO2-4 1. 1.0 to MnO-4 is 2. 0.5 1. 96500 C 3. 0.1 2. 2*96500 C 4. 2.0 3. 9650 C 4. 96.50 C
Page: 1 Mini Test # 32 - Faraday’s Law of Electrolysis Contact Number: 9667591930 / 8527521718 9. 13.
For the cell, TI|TI+(0.001M)||Cu2+(0.1M)|Cu,Ecell at The same amount of electric current is apassed through aqueous solution of MgSO4 and AlCl3. If 2.8 g Mg metal 25°C is 0.83 V. Ecell can be increased: is deposited at amount of Al metal deposited in second cell will be 1. by increasing [Cu2+] (1) 2.1 g 2. by increasing [TI+] (2) 2.49 g 3. by decreasing [Cu2+] (3) 3.15 g 4. none of these (4) 3.73g 10. 14. 4.5 g of aluminium (atomic mass 27u) is deposited at During electrolysis, 2A current is passed through an cathode from Al3+ solution by a certain quantity of electrolytic solution for 965 S'. The number of moles of electric charge. The volume of hydrogen produced at electrons passed will be STP from H+ ions in solution by the same quantity of 1. 0.02 electric charge will be 2. 0.01 1. 44.8 L 3. 200 2. 22.4 L 4. 0.037 3. 11.2 L 15. 4. 5.6 L The number of electrons delivered at the cathode during 11. electrolysis by a current of 1 ampere in 60 seconds is Two electrolytic cells, one containing acidified ferrous (charge on electron = 1.60 x 10-19 C) chloride and another acidified ferric chloride are connected in series. The ratio of iron deposited at (a) 6 x 1023 cathodes in the two cells when electricity is passed through the cells will be: (b) 6 x 1020
1. 3:1 (c) 3.75 x 1020
2. 2:1 (d) 7.48 x 1023 3. 1:1 16. 4. 3:2 The weight of silver (at. wt.= 108) displaced by a quantity of electricity which displaces 12. 5600 mL of O2 at STP will be The quantity of electricity required to reduce 12.3g of nitrobenzene to aniline with 50% current efficienct is:- 1. 5.4g 1. 1 F 2. 10.8g 2. 0.6 F 3. 54.0g 3. 0.5 F 4. 108.0g 4. 1.2 F
Page: 2 Mini Test # 32 - Faraday’s Law of Electrolysis Contact Number: 9667591930 / 8527521718 17. 22. What will be the quantity of iron deposited by ferrous Adiponitrile is manufactured electrolytically from and ferric ion by 1F (Fe = 56) acrylonitrile CH2 = CH CN → CN – (CH2 )4 – CH (1) 14g, 9.3 g How many kg of adiponitrile (molecular mass = 108) is (2) 28g, 18.6 g produced in 9.65 hr using a current of 3750 A with 80% (3) 56g, 37.2g efficiency? (4) None of these (1) 30 kg 18. (2) 58 kg The number of faradays required to produce one mole of (3) 60 kg water from a hydrogen - oxygen fuel cell containing (4) 80 kg aqueous alkali as electrolyte is- 23. (1) 1 With t taken in seconds and I taken in Amp, the variation (2) 3 of I follows the equation : t + I = 25 2 2
(3) 2 what amount of Ag will be electrodeposited with this (4) 4 current flowing in the interval 0–5 second ? (Ag – 108) 19. (1) 22 mg How much current is necessary to produce H gas at the 2 (2) 66 mg rate of 1 cm per second under STP ? 3
(3) 77 mg (A) 4.305 amp (4) 88 mg (B) 17.22 amp 24. (C) 8.61 amp When 0.1 mol is oxidised the quantity of electricity (D) 2.1525 amp. required to completely to is : 20. 1. 96500 C How much charge should be supplied to a cell for the 2. 2 x 96500 C electrolytic production of 245 gm N aClO 4 from N aClO if the anode efficiency for the required reaction 3. 9650 C 3
is 60%? 4. 96.50 C (1) 6.43 × 10 5 C 25. (2) 6.67 F For the reduction of silver ions with copper metal, the standard cell potential was found to be + 0.46 V a t 25 (3) 6.43 × 10 6 C °C. The value of standard Gibbs energy, ΔGo will be (F = (4) 66.67 F 96500C mol-1) 21. 1. -89.0 kJ Number of electrons involved in the electrode position of 2. -89.0 J 63.5g of Cu from a solution of CuSO is- 4
3. -44.5 kJ 1 6. 022 × 10 23
4. -98.0 kJ 2 3. 011 × 10 23
3 12. 044 × 10 23
4 6. 022 × 10 22
Page: 3 Mini Test # 32 - Faraday’s Law of Electrolysis Contact Number: 9667591930 / 8527521718 26. 30. In producing chlorine through electrolysis 100 W power at 125 V is being consumed. How much chlorine per min is The number of Faraday's (F) required to produce 20 g of calcium from molten CaCl2 (Atomic mass of Ca=40 g liberated? ECE of chlorine is 0.367×10-6 kg/C: 1. 17.6 mg mol-1) is: 2. 21.3 mg (1) 2 3. 24.3 mg 4. 13.6 mg (2) 3 (3) 4 27. (4) 1 A current of 9.65 ampere flowing for 10 minutes deposits 3.0 g of the metal which is trivalent. The atomic mass of Fill OMR Sheet* the metal is *If above link doesn't work, please go to test link from 1. 30 where you got the pdf and fill OMR from there 2. 150 3. 90 4. 289.5 28. The density and Eq. wt. of metal are 10.5 g cm and −3
100, respectively. The time required for a current of 3
amp to deposit a 0.005 mm thick layer of the same metal on an area of 80 cm is closest to 2
1. 120 s 2. 135 s 3. 67.5 s 4. 270 s 29. Aluminium oxide may be electrolysed at 1000 C to furnish aluminium metal (Atomic mass = 27 amu; 1 Faraday = 96,500 Coulombs). The cathode reaction is 3+ − o Al + 3e → Al
To prepare 5.12 kg of aluminium metal by this method
would require 1. 5. 49 × 10 7 C of electricity 2. 1. 83 × 10 7 C of electricity 3. 5. 49 × 10 4 C of electricity 4. 5. 49 × 10 1 C of electricity
