1-_GOC PRACTICE _NEERAJ JAIN

I. Select the strongest acid in each of the following sets –

1 OH OH OH OH

(a) (b) (c) (d)

CH3 NO2 Cl NH2

2 OH OH OH OH

(a) (b) (c) (d)

NO2 F CH3

3 OH OH OH OH
(a) OMe
(b) (c) (d)
OMe
OMe

4 OH OH (c) OH
NO2 OH
(a) (b) NO2 (d)
NO2 NO2 NO2
NO2 O2N NO2

II. Write correct order of acidic strength following compounds

1 d > c > a > b, O–H O–H O O–H O–H

N NO2 NO2 NO2
(a) (b) O (c) (d)

NO2 NO2 NO2

2 a>b>c O–H O–H O–H

(a) (b) (c)

NO2 Cl CH3

3 c>a>b>d (a) O–H O–H O–H

O–H
O
N (b) O (c) d)
O N
O N
O O
 2-_GOC PRACTICE _NEERAJ JAIN

4 d>b>c>a O–H O–H O–H O–H

(a) (b) (c) (d)

5 a>c>b O–H O–H O–H

Cl
(a) (b) (c)
Cl
Cl
6 b>a O O
C–O–H C–O–H
CH3
(a) (b)

7 b>a COOH COOH

Cl Br
(a) (b)

8 c>b>a O O (c)
C–O–H C–O–H O
C–O–H
(a) (b)
OMe OMe
OMe

9 c>a>b O O (c)
C–O–H C–O–H O
C–O–H
(a) (b) NO2
NO2
N
O O

III. Write correct order of acidic strength following compounds

1 a>b O O O (d)
|| || ||
>c> (a) NO2–CH2–C–O–H (b)F–CH2–C–O–H (c) Ph–CH2–C–O–H O
||
d CH3–CH2–C–O–H
2 a>b (a) O (c)
||
>c O (b) CH3–CH–CH2–C–O–H O
|| ||
CH3–CH2–CH–C–O–H | CH2–CH2–CH2–C–O–H
| F |
F F
 3-_GOC PRACTICE _NEERAJ JAIN

3 c>b O O Cl O
|| || | ||
>a (a) Cl–CH2–C–O–H (b) Cl–CH–C–O–H (c) Cl–C–C–O–H
| |
Cl Cl

4 a>b (a) CH3–CH2–O–H (b) CH3–CH–O–H CH3

>c | |
CH3 (c) CH3–C–O–H
|
CH3

5 c>b (a) (b) (c)

>a COOH COOH COOH

6 a>b COOH COOH CH2–COOH

>c (a) | (b) CH2 (c) |
COOH COOH CH2–COOH

7 d>c (a) H–F (b) H–Cl (c) H–Br (d) H–I

>b>
a

8 d>c (a) CH4 (b) NH3 (c) H2O (d) H–F

>b>
a

9 d>b (a) F–CH2–CH2–O–H (b) NO2–CH2–CH2–O–H (c) Br–CH2–CH2–O–H (d)

>a 
NH3–CH2–CH2–O–H
>c

10 d>a (a) CH3COOH (b) CH3CH2OH (c) C6H5OH (d) C6H5SO3H

>0c >
b

11 c>b> OH COOH COOH O

d>a CH3 C OH
(a) (b) (c)
(d)
CH3
12 a>b> COOH COOH COOH COOH
c>d
(a) (b) (c) (d)
NO2 Cl
NO2 Cl

13 c>b> (a) NH3 NH2 O (d) MeNH 2

a>d C – NH2
(b) (c)
 4-_GOC PRACTICE _NEERAJ JAIN

IV. Write increasing order of basic strength of following -

1 a>b>c> (a) CH3 (b) NH2 (c) OH  (d) F

d

2 a>b>c> (a) F (b) Cl  (c) Br  (d) I 

d

3 c>b>d> (a) NH3 (b) MeNH 2 (c) Me2 NH (d) Me3 N

a (In H2O)

4 a<b<c< (a) NH3 (b) MeNH 2 (c) Me2 NH (d) Me3 N

d (Gas
phase)

5 a>b>c (a) R – NH 2 (b) Ph – NH 2 (c) R–C–NH2

||
O

6 a<b<c O
(c)
(a) (b)
NH NH N
|
Me

7 c>a>b NH2 NH2

(c)
(a) (b) NH

8 b>c>a N N N
(a) (b)
Me (c)
O 2N F
9 c>d>b> NH2 NH2 NH2 NH2
a
(a) (b) (c) (d)

NH3 Cl CH3 H
10 a>b>c> (a) OH 
(b) NH3 (c) H 2 O (d) HSO 4
d
11 b>a>c> (a) (b) (c) NH2 (d)
d NH2 CH2 – NH2 C – NH2
NO2
O
12 b>a>d> (a)   (c)  
(b) H 3C  C H 2 N a (d) HC  C N a
c    
H 2C  C H  N a H 3C  C H 2 O N a
13 a>b>c (a) (b) CH3–CH=NH (c) CH3–CN
CH3–CH2–NH2
14 d>c>b> (a) (b)CH3–CH2–NH2 (c) (d)
a
 5-_GOC PRACTICE _NEERAJ JAIN

CH3–C–NH2 CH3–C–NH2 NH2–C–NH2

O NH NH
15 b>c>a (a) NH2
(b)
N N (c)
H
16 d>c>b> NH2 NH2 NH2 NH2
a
(a) (b) (c) (d)

NO2 CN OMe NH2

17 b>a>c NH2 NH2 NH2
NO2
(a) (b) (c)
NO2
NO2
18 c>a>b NMe2 NMe2 (c)
Me Me
(a) (b) N
OMe OMe
OMe
19 b > a, (a) NH2
NH2
Me Me (b)
Me Me
N
N O O
O O
20 c > b > a, (a) NH2 (c)
O NH–CH2–CH3
(b)
NH–C–CH3

21 c>b>a NH2 H NH2 NH2

C–H
(a) (b) (c)
H CH3
CH3
22 a>b>c NH2 NH2 H NH2
C–H
(a) (b) (c)
H
23 a>c>b>d NH2 NH2
(a) (b)
NH N (c) (d)
 6-_GOC PRACTICE _NEERAJ JAIN

23 d>c>b>a NH2 NH2 NH2

(a) (b) (c)

CH3
CH3 (d)
24 b>a>c NH2 (c)
(b)
(a) N N
H