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    Che (Set A) Xi - 3RD Term 80 Final Print

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    Che (Set A) Xi - 3RD Term 80 Final Print

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    CHE (SET A) XI - 3RD TERM 80 FINAL PRINT

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    Che (Set A) Xi - 3RD Term 80 Final Print

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    of 6

    Third Terminal Examination - 2080

    Subject: Chemistry (3011)


    Class: XI Full Marks: 75
    Time: 3 hrs. SET ‘A’ Pass Marks: 30
    Candidates are required to give their answers in their own words as far as
    practicable. The figures in the margin indicate full marks.
    Attempt all the questions.
    Group ‘A’
    Rewrite the best alternative of each question in your answer sheet. [11 × 1 = 11]
    1. Which has maximum number of molecules?
    a. 7g N2 b. 16g O2
    c. 2g H2 d. 16g NO2
    2. Which of the following set of quantum number is not possible for 4p electron?
    1
    a. n =4 , l =1, m = -1, s = + 2
    1
    b. n =4 , l =1, m = 0, s = + 2
    1
    c. n =4 , l =1, m = 2, s = + 2
    1
    d. n =4 , l =1, m = -1, s = -
    2

    3. How many electrons are present in 1 mole of methane?


    a.1NA b. 6 NA
    c.10 NA d. 4 NA
    4. Oxidizing agent is a substance which can
    a. accepts electrons
    b. donates electrons
    c. accepts protons
    d. donates protons

     
    5. When ammonia gas is passed over excess Cl2 the products formed are
    a. NH4Cl + HCl b. NH4Cl + N2
    c. NH4Cl + NCl3 d. NCl3 + HCl
    6. For the precipitation of Group IIIB metal ions as their sulphides, H2S gas is
    passed in presence of
    a. dil. HCl b. NH4OH
    c. NH4OH + NH4Cl d. NH4OH + (NH4)2CO3
    7. Ammonia can be dried by using
    a. Conc. Sulphuric acid b. Quick lime
    c. Phosphorous pentoxide d. Fused calcium chloride
    8. Fluorine shows only one oxidation state because
    a. Its atom is smaller in size b. It is volatile
    c. It is highly electronegative d. It is highly electropositive
    9. Which of the following alkane has highest boiling point?
    a. butane b. pentane
    c. 2-methylbutane d. 2,2-dimethylpropane
    10. Tautomerism involves
    a. delocalization of sigma electrons b. Migration of electron
    b. delocalization of Pi - electrons d. Migration of H+
    11. The IUPAC name of the given compound is
    CH3
    CH3 – C - CH3
    CH3
    a. Dimethylhexane b. Tetramethane
    c. Neopentane d. 2,2-Dimethylpropane
     
    Group - B

    Give short answer to the following questions. [8 × 5 = 40]

    1. a. Rutherford’s nuclear model of atoms is based on alpha particle


    scattering experiments. Write all the three observations and conclusions
    made. [3]
    b. State Pauli's exclusion principle. [1]
    c. An element "A" has 2 electrons in K-shell, 8-electrons in L shell,
    9-electron in M-shell and 2 electrons in N-shell. Write the all values of
    the quantum number for valence electrons of element “A”. [1]

    2. a. The reaction of sulphur with sodium hydroxide to give sodium sulphide


    and sodium thiosulphate is an auto redox reaction. [3+2]
    S + NaOH ⎯⎯→ Na2S + Na2S2O3 + H2O
    Balance the redox reaction with help of oxidation number method.

    b. Calculate the oxidation number of the underlined elements.


    i. C6H12O6
    ii. MnO4 –
    OR
    A copper voltameter and a hydrogen voltameter are connected in series and
    same number of Faraday is passed through them.
    a. Define One Faraday. [1]
    b. State Faraday’s second law of electrolysis. [1]
    c. How long will it take to plate out 1.6g of Chromium by passing 12.5
    ampere current through molten Cr2O3?
    (Given: atomic weight of Cr is 52) [3]

     
    3. Consider a reaction: (Given: atomic weight of Fe is 56) [1+1+1+2]
    Fe2O3 + 3CO ⎯⎯→ 2Fe + 3CO2
    10g of Fe2O3 is reacted with 9g of CO
    a. Which is the limiting reagent and why?
    b. How many moles of unreacted reactant left over?
    c. Calculate the mole of CO consumed in the reaction.
    d. Prove that: molecular weight = 2 × Vapor density.

    4. Sulphuric acid also known as oil of vitriol, having molecular formula H2SO4.
    a. How would you obtain sulphuric acid, starting from Iron pyrite (FeS2)
    and oxygen? [3]
    b. Draw the flowsheet diagram for manufacture of sulphuric acid by
    contact process? [2]
    OR
    a. Write the reaction involved in the preparation of hydrogen sulphide gas
    in lab. Draw the diagram of Kipp's apparatus and explain, how it works.
    [3]
    b. What happens when H2S is passed through the acidified KMnO4? [1]
    c. Write one use of H2S. [1]

    5. Oxygen is the third most abundant element by mass in the universe which
    readily forms oxides with other elements. Some of the oxides are given
    below

    Na2O Al2O3 CO SO2 Fe3O4 H2O2

    a. Identify the acidic oxide, basic oxide, mixed oxide and peroxide from
    the above oxide with reason. [2]
    b. Identify amphoteric oxide from above table. Justify with reaction. [1]
    c. Write the difference between nascent and molecular hydrogen. [2]
     
    6. a. How can we prepare hydrochloric acid in laboratory using H2SO4?
    Why HI cannot be prepared by same method? How is HI prepared in
    lab? [3]
    b. What are allotropes? Write any two amorphous allotropes of carbon. [2]

    7. The compounds obtained from vegetables and animals directly or indirectly


    were organic compounds.
    a. What is homologous series? Write the first three homologous series of
    aldehyde with IUPAC name. [3]
    b. What are gasoline additives? Give one example. [2]

    8. Organic compound containing carbon and hydrogen only are hydrocarbon.


    a. Give an example of: i) Ozonolysis ii) Peroxide effect
    b. Complete the following sequence of reaction:
    𝐻2 /𝑃𝑑−𝐵𝑎𝑆𝑂4 𝐻𝐵𝑟 𝑁𝑎/𝑑𝑟𝑦 𝑒𝑡ℎ𝑒𝑟
    CH3 – C ≡ CH → A→ B → C
    𝐻𝑒𝑎𝑡

    Identify A, B, C with their IUPAC names. [2+3]

    Group - C
    Give long answer to the following questions. [3 × 8 = 24]

    9. a. Write the differences between orbit and orbitals. [3]


    b. 12 gram of carbon and 32 gram of oxygen combine to give 44 grams of
    CO2. Which law does this data illustrate? State the law. [1+1]
    c. 6.3g of the nitric acid is dissolved in 68g of the water. Calculate the
    number of oxygen atom in the solution. [2]
    d. Calculate the mass of 0.1 mole of ammonia. [1]
    10. Ammonia is a hydride of nitrogen with molecular formula NH3.
    a. How would you obtain ammonia from Nitrogen and Hydrogen? Briefly,
    explain and write the reaction involved. Also, explain the favorable
    condition for manufacture of ammonia. [4]
     
    b. Draw a flow sheet diagram for the manufacture of ammonia by the
    Haber’s process. [2]
    c. What happens when ammonia gas is passed through copper sulphate
    solution for a long time? [2]

    11. a. Lassaigne’s test can be performed for the detection of hetero-elements


    present in organic compounds by fusing the compound with active metal
    like sodium.
    i. What is the purpose of preparing sodium extract? [1]
    ii. Write the reactions involved in the detection of Nitrogen in the
    organic compound? [3]
    b. How would you prepare ethane from
    i. Sodium propanoate
    ii. Ethyne
    iii. Chloroethane [3]
    c. Why alkene are more reactive than alkane? [1]
    OR,
    Isomerism is the phenomenon in which more than one compounds have the
    same chemical formula but different chemical structures.
    a. What is Positional isomerism? Write the positional isomers of formula
    C3H7Cl with structure and IUPAC names. [1+2]
    b. A primary alcohol (X) which undergoes dehydration to give compound
    (Y). The compound (Y) undergoes ozonolysis to produce methanal and
    ethanal as a major product.
    i. Identify (X) and (Y) with necessary reaction and condition. [3]
    ii. What product would you expect when compound (Y) is heated with
    water in presence of dil.H2SO4? [1]
    c. Why methanoic acid is more acidic than ethanoic acid? [1]

     - The End - 
     

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