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    Che (Set B) Xi - 2nd Term 79 Final Print

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    Che (Set B) Xi - 2nd Term 79 Final Print

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    Che (Set B) Xi - 2nd Term 79 Final Print

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    of 6

    Second Terminal Examination - 2080

    Class : XI Subject: Chemistry (3011) Full Marks: 75


    Time: 3 hrs. SET ‘B’ Pass Marks: 30
    Candidates are required to give their answers in their own words as far
    as practicable. The figures in the margin indicate full marks.
    Attempt all the questions.
    Group ‘A’
    Rewrite the best alternative of each question in your answer sheet. [11 × 1 = 11]
    1. If W is Mass Number and N is the atomic number of an elements, then
    a. Number of e - = W-N b. Number of 0n1 = W-N
    c. Number of 0H1 = W-N d. Number of 0n1 = W
    2. Which of the following electron transition in a hydrogen atom will required
    the largest amount of energy.
    a. From n = 1 to n = 2 b. From n = 2 to n = 3
    c. From n = 3 to n = 4 d. From n = 4 to n = 5
    3. Which of the following involves transfer of maximum number of electrons
    per atom.
    a. MnO4- Mn+2
    b. CrO4- - Cr+3
    c. MnO4- MnO2
    d. Cr2O7- - 2Cr+3
    4. Which of the following is not a reducing agent?
    a. SO2 b. NO2
    c. CO2 d. H2O2
    1
    5. Which of the following shows Passivity with concentrated HNO3
    a. Zn b. Cr c. Mg d. Cu
    6. What happens when Sulphur dioxide (SO2) gas is passed through an
    acidified solution of hydrogen sulfide (H2S) gas?
    a. SO2 is oxidized to Sulphur b. H2S is reduced to Sulphur
    c. SO2 is oxidized to H2SO4 d. SO2 is reduced to Sulphur
    7. Hydrogen is evolved by the action of cold dil HNO3 on
    a. Fe b. Cu c. Mg d. Al
    8. Oxygen is more electronegative than Sulphur. Yet H2 S is acidic while H2O
    is neutral. This is because
    a. water is a highly associated compound
    b. molecular mass of H2S is more than H2O
    c. H2O is liquid while H2S
    d. H-S bond is weaker than H-O
    9. Which of the following compounds exhibit geometrical isomerism?
    a. But-1-ene b. 2,3-Dimethylbut-2-ene
    c. 2-Methylbut-2-ene d. Pent-2-ene
    10. Which of the following belongs to a homologous series?
    a. propane, propene, propyne
    b. methanol, ethanol, propanal
    c. chloromethane, chloroethane, chloropropane
    d. methanal, ethanal, propanol
    11. Which of the following compounds is assigned the octane number of 100?
    a. n-heptane b. n-octane
    c. 2,3,3-Trimethylpentane d. 2,2,4-Trimethylpentane

    2
    Group – B

    Give short answer to the following questions. [8 × 5 = 40]


    1. The "atom" was regarded as a small indivisible particle-the unit of matter
    in all chemical changes.
    i. Which model improved by Bohr. Write the postulates of Bohr’s atomic
    model. [1+3]
    ii. What is Zeeman effect and Stark effect. [1]

    2. Quantum number gives the information about the location and motion of
    an electron in an atom.
    i. Write all the four-quantum numbers of valence electrons of cuprous
    ion with the electronic configuration. [2]
    ii. State the “Hund's Rule of Maximum Multiplicity”. [1]
    iii. Name the quantum number which explain the orientation of orbitals
    and number which give information about shape of orbitals. Explain.[2]

    3. Oxidation and reduction are the chemical process which is based on


    transfer of electron.
    i. Differentiate between oxidation and reduction. [1]
    ii. Write the chemical reaction of chlorine where oxidation number of
    Cl2 undergoes oxidation and reduction. [1]
    iii. Oxidation and Reduction occur simultaneously. Explain with suitable
    example. [2]

    4. Over the last decades the contact process has been used to produce sulfuric
    acid,
    i. Explain different steps for the manufacturing of sulphuric acid by
    contact process starting form iron pyrite. [3]
    ii. Is Hydrogen sulphide combustible? How can you test for its acidic
    nature? [2]

    3
    5. Hydrogen and oxygen are the abundant elements in the earth.
    i. Write one chemical reaction to show that nascent hydrogen is better
    reducing agent than molecular hydrogen. [1]
    ii. Classify the following oxides with a suitable reason. [2]
    Cr2O3, P2O5,
    iii. How CFCs deplete the ozone layer in stratosphere? [2]

    6. Romans used sulphur dioxide in wine making as they discovered that the
    empty wine glass smelled fresh on burning sulphur candles inside the
    glass.
    i. The nature of SO2 is different when it reacts with Cl2 from that when it
    reacts with H2S water. Explain [2]
    ii. Give a reaction of each to show [3]
    a. H2S acts as a reducing agent
    b. H2S acts as analytical agent
    c. SO2 acts as bleaching agent

    7. J.L. Lassaigne, A French chemist in 1843, developed a method to detect N,


    S and halogens in organic compound.
    i. Why sodium extract is alkaline in nature?
    ii. How would you detect Sulphur as foreign element present in the
    organic compound?
    iii. Why is sodium extract boiled with conc. HNO3 before the detection of
    halogen? Explain with necessary reactions. [1+2+2]

    8. Two compounds having same molecular formula but different physical and
    chemical properties are isomer.
    i. Define chain isomer.
    4
    ii. Write functional isomer of compound having molecular formula.
    a) C3H6O
    b) C3H6O2
    iii. What are optically active compounds? Give an example of it. [1+3+1]

    Group – C

    Give long answer to the following questions. [3 × 8 = 24]

    9. i. Balance the given redox reaction with the help of the oxidation number
    method or ion-electron method. Also, find the oxidant and reductant in
    the given reaction. [3+1]
    C12H22O11 + HNO3 → C2H2O4 + NO2 + H2O
    ii. Determine the oxidation number of the underlined elements. [2]
    i) (NH4)2SO4 ii) MnO4¯
    iii. Why H2SO4 acts only as oxidizing agent whereas SO2 acts both as
    oxidizing as well as reducing agent? [2]

    10. Nitric acid, also known as aqua fortis, is a highly corrosive mineral acid.
    i. How is ammonia manufactured by Haber’s process? Write the favorable condit
    ii. Draw a flowsheet diagram of manufacture of nitric acid by Ostwald’s
    process. [2]

    iii. How would you perform the test of nitrate ion NO3 – in its aqueous
    solution? [2]
    iv. List out the oxyacids of nitrogen with their molecular formula [1]

    5
    11. Organic compounds are characterized by forming a typical homologous
    series. [1+1+4+2]
    i. Mention any two characteristics of homologous series.
    ii. Write down the structure and IUPAC name of third member of
    Carboxylic acid.
    iii. Write the IUPAC name of the following compounds:
    O
    ||
    a) H – C – CH2 – COOH

    O
    ||
    b) CH3 – C – O – CH2 – CH3

    c) CH3 – CH = CH – CH3

    CH2 CH3
    || |
    d) CH3 – CH2 – C – CH2 – CH – NH2

    iv. Write the structure of the following organic compounds.


    a) 2-methoxy-2-methylpropanal
    b) 4-hydroxy-3-methyl-pent-3-en-2-one

     - The End - 

    6

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