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    ELECTROCHEMISTRY

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    briefcinemablitz

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    © All Rights Reserved
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    ELECTROCHEMISTRY

    Uploaded by

    briefcinemablitz
    6 views1 page

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    6 views1 page

    ELECTROCHEMISTRY

    Uploaded by

    briefcinemablitz

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 1

    ELECTROCHEMISTRY

    0
    1. Equilibrium constant (Kc) for the given cell reaction is 10 Calculate Ecell :
    2+ 2+
    A (s) + B (aq) → A (aq) + B(s) [Ans: 0.0295 V]
    0
    2. Calculate ∆rG for the following reaction:
    Mg (s) + Cu2+ (aq) → Mg2+ (aq) + Cu (s)
    0
    [Given: Ecell = + 2.71 V, 1 F = 96500 C mol–1] [Ans: – 523.03 KJ mol–1]
    3. For the reaction,

    ∆G0 = –43600 J at 250C. Calculate the emf of the cell. [log 10–n = –n]

    n = 2,
    using the formula, ∆r G0 = – n E0 F ⇒ 43600 = – 2 x E0 x 96500 ⇒ E0 = 0.226 V
    0.0591 [H+ ]2 [Cl− ]2
    0
    Ecell = Ecell – log
    n p[H2 ]
    0.0591 [0.1]2 [0.1]2
    = [0.226 V – 0] – log = 0.3442 V
    2 1
    4. Calculate the emf of the following cell at 298 K:
    2Cr (s) + 3 Fe2+ (0.1 M) → 2Cr3+ (0.01M) + 3Fe (s)
    0 0
    [Given: ECr 3+ ⁄Cr = –0.74 V, EFe2+ ⁄Fe = – 0.44 V] [Ans: 0.31 V]
    0
    5. Calculate Ecell for the following reaction at 298 K:
    2Al (s) + 3Cu (0.01M) → 2Al3+(0.01M) + 3Cu (s), Given: Ecell = 1.98 V
    2+
    [Ans: 2.00 V]
    0
    6. Calculate Ecell for the following reaction at 250C:
    A + B2+ (0.001M) → A2+ (0.0001M) + B,
    [Given: Ecell = 2.6805 V, 1F = 96500 C mol–1] [Ans: 2.651 V]
    7. Calculate the emf of the following cell at 250C:
    Fe (s) | Fe2+ (0.001 M) || H+ (0.01M) | H2 (g) (1 bar) | Pt(s)
    0 0
    [Given: EH + ⁄H = 0.00 V, EFe 2+ ⁄Fe = – 0.44 V] [Ans: 0.4105 V]
    2
    8. Calculate the emf of the following cell at 250C:
    Zn (s) | Zn2+ (0.001 M) || H+ (0.01M) | H2 (g) (1 bar) | Pt(s)
    0 0
    [Given: EH + ⁄H = 0.00 V, E𝑍𝑛 2+ ⁄𝑍𝑛 = – 0.76 V] [Ans: 0.7305 V]
    2
    0
    9. Calculate Ecell and ∆rG0 for the following reaction at 250C:
    A2+ (aq) + B+ (aq) → A3+ (aq) + B (s),
    [Given: Kc = 1010, 1F = 96500 C mol–1] [Ans: 0.591 V, –57.031 kJ mol–1]
    10. A voltaic cell is set up at 250C with the following half – cell:
    Ag+ (0.001M) | Ag and Cu2+ (0.10 M) | Cu (s)
    0
    What would be the voltage of this cell? (Ecell = 0.46 V) [Ans: 0.3123 V]

    Page 1 of 1

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