Full Chapter Structural Modeling of Metamaterials Vladimir I Erofeev PDF
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Advanced Structured Materials
Vladimir I. Erofeev
Igor S. Pavlov
Structural
Modeling
of Metamaterials
Advanced Structured Materials
Volume 144
Series Editors
Andreas Öchsner, Faculty of Mechanical Engineering, Esslingen University of
Applied Sciences, Esslingen, Germany
Lucas F. M. da Silva, Department of Mechanical Engineering, Faculty of
Engineering, University of Porto, Porto, Portugal
Holm Altenbach , Faculty of Mechanical Engineering, Otto von Guericke
University Magdeburg, Magdeburg, Sachsen-Anhalt, Germany
Common engineering materials reach in many applications their limits and new
developments are required to fulfil increasing demands on engineering materials.
The performance of materials can be increased by combining different materials to
achieve better properties than a single constituent or by shaping the material or
constituents in a specific structure. The interaction between material and structure
may arise on different length scales, such as micro-, meso- or macroscale, and offers
possible applications in quite diverse fields.
This book series addresses the fundamental relationship between materials and their
structure on the overall properties (e.g. mechanical, thermal, chemical or magnetic
etc.) and applications.
The topics of Advanced Structured Materials include but are not limited to
• classical fibre-reinforced composites (e.g. glass, carbon or Aramid reinforced
plastics)
• metal matrix composites (MMCs)
• micro porous composites
• micro channel materials
• multilayered materials
• cellular materials (e.g., metallic or polymer foams, sponges, hollow sphere
structures)
• porous materials
• truss structures
• nanocomposite materials
• biomaterials
• nanoporous metals
• concrete
• coated materials
• smart materials
Advanced Structured Materials is indexed in Google Scholar and Scopus.
Structural Modeling
of Metamaterials
123
Vladimir I. Erofeev Igor S. Pavlov
Mechanical Engineering Research Institute Mechanical Engineering Research Institute
of the Russian Academy of Sciences of the Russian Academy of Sciences
Federal Research Center ‘Institute of Federal Research Center ‘Institute of
Applied Physics of the Russian Academy Applied Physics of the Russian Academy
of Sciences’ of Sciences’
Nizhny Novgorod, Russia Nizhny Novgorod, Russia
This Springer imprint is published by the registered company Springer Nature Switzerland AG
The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland
Preface
v
vi Preface
to Prof. Gerard A. Maugin (1944–2016) from Pierre and Marie Curie University
(French: Université Pierre-et-Marie-Curie, Paris, France), in collaboration with
whom there were obtained scientific results presented in Chaps. 3 and 4;
to Prof. Alexander Vasilievich Vikulin (1947–2017) from the Institute of
Volcanology and Seismology, Far Eastern Branch of the Russian Academy of
Sciences (Petropavlovsk-Kamchatsky, Russia), who was a specialist in geody-
namics and seismology—discussions with him helped us make the transition from
nanomaterials to geomedia;
to Prof. Leonid lsaakovich Manevitch (1938–2020) from N. N. Semenov Federal
Research Center for Chemical Physics, Russian Academy of Sciences (Moscow,
Russia), who was a specialist in nonlinear dynamics and materials science—
collaboration with him gave us new ideas to choose materials for elaboration
of their models.
We consider as a pleasant duty to thank our colleagues, in co-authorship with
whom the most important results of the monograph were obtained: Professor
I. V. Miloserdova (Nizhny Novgorod Technical State University n.a. R. E.
Alekseev, Nizhny Novgorod, Russia); Doctors V. V. Kazhaev, A. V. Leontyeva, and
A. O. Malkhanov (Mechanical Engineering Research Institute of the Russian
Academy of Sciences, Nizhny Novgorod, Russia); Prof. A. V. Porubov (Institute of
Problems of Mechanical Engineering of the Russian Academy of Sciences,
St. Petersburg, Russia); and Dr. A. A. Vasiliev (Tver State University, Tver, Russia).
We are grateful to Academician of the Russian Academy of Sciences
V. P. Matveenko; Corresponding Members of the Russian Academy of Sciences
D. A. Indeytsev and A. N. Morozov; Foreign Member of the Russian Academy of
Sciences H. Altenbach; Profs. I. V. Andrianov, S. A. Lurie, A. V. Metrikine,
W. Muller, V. M. Sadovsky, I. N. Shardakov, V. S. Shorkin, and
D. V. Tarlakovsky, for useful scientific discussions and recommendations for
improvement of our book.
We also thank the staff of Mechanical Engineering Research Institute of the
Russian Academy of Sciences: Profs. V. N. Perevezentsev, S. I. Gerasimov,
B. A. Gordeev, V. V. Mishakin, V. M. Rodyushkin, and G. F. Sarafanov for their
attention to our work.
We would like to express our special gratitude to Anastasia Demareva and
Vladimir Sadovsky, postgraduate students of Lobachevsky State University of
Nizhny Novgorod, and to Anna Muravieva, a student of Lobachevsky State
University of Nizhny Novgorod, for their contribution to the development of a
three-dimensional model of a granular medium presented in Chap. 6 of this
monograph.
References
1. Gulyaev, Yu.V., Lagar’kov, A.N., Nikitov, S.A.: Metamaterials: basic research and potential
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6. Fedotovskii, V.S.: A porous medium as an acoustic metamaterial with negative inertial and
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Introduction
ix
x Introduction
system of particles coupled by the interaction forces determined from the first
principles (quantum postulates). This approach allows one to understand the nature
of physical laws and to explain the origin of some properties having no substan-
tiation in the classical theory.
Until the middle of twentieth century, the quantum mechanics was considered,
basically, as the microworld mechanics. Being constructed on the basis of quantum
postulates, it does not appear at all on the macroscales, where the continuum
mechanics is valid, which is created on the basis of the laws of conservation of
mass, momentum, kinetic momentum, and the thermodynamics laws (the macro-
scopic first principles). The first fundamental step of the quantum mechanics in the
field of macroscopic phenomena was the creation of the hydrodynamic theory of
superfluidity of helium-II by L. D. Landau in 1941 and the idea of L. Onsager
(1948) to quantize vortex motion in it [7]. The next step in this direction was made
by A. F. Andreev and I. M. Lifshits, who developed in 1969 the phenomenological
theory of defects in quantum crystals [8]. According to this theory, defects are
considered as delocalized excitations (defectons) that move дeфeкты almost freely
through the crystal. A crystal with defectons is neither a liquid nor a solid. Two
different types of motion are possible in it. The first type of motion is associated
with small vibrations of the lattice sites near the equilibrium states and is described
by the classical equations of elastic solid mechanics. The second type is charac-
teristic for a liquid and is associated with quantum diffusion that leads to mass
transfer by defectons, when lattice sites are fixed. At present, such studies are the
subject of quantum macrophysics [9].
The second approach to modeling of microstructured media means passing from
description of a medium on a macrolevel to mesoscale models. Within its scope, the
elaboration of mathematical models of such media proceeds in three directions. The
first of them—the continuum-phenomenological direction—is associated with the
construction of generalized continuum models (generalized continua) of the
mechanics of a deformable solid and is based on the classical physics laws. It
involves expanding of the concept of a representative volume of the medium and
taking into account the rotational degrees of freedom of microparticles (polarity
of the material), as well as affine deformations of the mesovolume and non-locality
of the material [10–11]. Polarity indicates that rigid rotation is allowed, which is not
related to the field of displacements in the general case, whereas non-locality tes-
tifies the dependence of the physical properties of the material on the influence of
environmental particles. Continual theories are elaborated by the deductive way:
All the results are consequences of a system of fundamental assumptions—axioms
or postulates. The advantages of this elaboration are logical consistency, a rigor
of the derivation of various particular versions of the models, and the possibility of
a consistent classification of theories according to selected attributes. A decisive
contribution to the development of this direction was made by the works of
E. and F. Cosserat [12], C. Truesdell and R. Toupin [13, 14], E. L. Aero and
E. V. Kuvshinskii [15, 16], R. Mindlin [17], A. C. Eringen [18–21], W. Nowacky
[22], V. A. Palmov [23, 24], L. I. Sedov [25–27], V. I. Erofeev [28], A. I. Potapov
[29], V. P. Matveenko, I. N. Shardakov, M. A. Kulesh, and E. F. Grekova [30, 31],
Introduction xi
S. A. Lurie [32, 33], etc. At present, structurally heterogeneous materials are fre-
quently simulated by the generalized micropolar theories of the Cosserat continuum
type [34–39]. However, these theories involve a large number of material constants,
which have to be determined experimentally. Moreover, relationships between
these constants and the material structure are not always clear.
The second direction—structural modeling, which is the subject of study of this
monograph, is devoid of such a drawback. In accordance with this method, a
material is represented by a regular or quasiregular lattice consisting of finite-sized
particles. The elaboration of a structural model starts with selection in the material of
some minimal volume—a structural cell that is an analog of the periodicity cell in a
crystalline material. The cell is capable of characterizing the basic features of the
macroscopic behavior of the material [40–43]. As a rule, a structural cell is a particle,
which behavior is characterized by interaction with the environment and is described
by kinematic variables [44–61]. The role of these body particles can be played by
domains, grains, fullerenes, nanotubes, or clusters consisting of nanoparticles.
Sometimes, particles are represented as material points, i.e., force centers possessing
the properties of mass, charge, etc. The interaction forces are assumed to be rapidly
decreased with growing distance, so they can be neglected if the distance between
the points exceeds “the radius of molecular action.” This direction originates from
Max Born’s works on the theory of crystal lattices and until recently has developed
mainly in the framework of the solid-state physics [62, 63]. The founder of the
structural modeling method in Russia is a professor of Moscow State University
Nikolai Pavlovich Kasterin (1869–1947). He was a student of a great Russian
physicist Alexander Grigorievich Stoletov (1839–1896). N. P. Kasterin studied the
dispersion of sound waves by means of this method [64, 65].
Special attention in the structural modeling method is paid to studying the
propagation and interaction of elementary excitations—quasiparticles (phonons,
magnons, excitons, etc.)—and various defects inherent in real bodies [66, 67]. Both
quantum and classical approaches to the analysis of dynamic processes coexist
organically within the scope of this direction [68].
As distinct from the continual models, the structural ones explicitly contain the
geometric parameters of the structure—the size and shape of the particles. Finally,
the effective elastic moduli of various orders depend on these parameters [69, 70].
Structural models enable one not only to reveal the qualitative influence of local
structure on the effective moduli of elasticity but also to perform numerical esti-
mations of their quantities and even to control physical and mechanical properties
of a medium, these being generally unavailable from continuum-phenomenological
theories.
The clear coupling between a structure of a medium and its macroparameters
discloses major opportunities for the purposeful design of materials with given
physical–mechanical properties. Shortcomings of the structural modeling are
absence of universality of modeling procedure and complexity of the accounting of
nonlinear and non-local effects of interparticle interactions. A significant contri-
bution to the development of the structural modeling method was made by the
works of I. A. Kunin [71], E. Kroner [72], A. Askar [73–75], G. Maugin and
xii Introduction
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Contents
xix
xx Contents
The principles of the structural modeling method, the development of the theoretical
foundations of which this monograph is devoted, are formulated in the first chapter.
Moreover, the problem of the applicability of the classical mechanics laws to a
theoretical description of media with micro- and nanostructure is discussed here.
One of the main hypotheses of the classical continuum mechanics is the Cauchy
stress principle, which postulates that the effect of all the internal forces applied to
an elementary area is equivalent to the effect of their resultant force applied to the
center of this area [1]. However, in the general case, the action of an arbitrary system
of forces is equivalent to the action of the main vector and the main moment. In
this case, couple stresses also appear in the medium, forming, generally speaking,
asymmetric tensors [2, 3]. Thus, the rejection of the Cauchy stress principle makes
possible taking into account the presence in the medium of internal pairs of forces
and moment interactions that arise naturally when considering a physically infinitely
small volume (over which the medium’s properties are averaged) not as a mate-
rial point, but as a more complex object with new degrees of freedom: rotational,
oscillatory, or the ability to microdeforming. The assumption about the existence of
an internal structure (microstructure) of a physically infinitesimal object, which is
provided by the discreteness or fibrous structure of real materials, leads to a significant
expansion of the spectrum of properties of a continuous medium. In particular, this
assumption enables one describing some experimentally observed acoustic effects,
for example, the dispersion of shear waves [4]. A brief description of the history of
studies of microstructured media is given below.
Isaak Newton was the first to use a discrete model in problems of the mechanics of
continuous deformable media [5]. He considered a one-dimensional lattice consisting
of pointwise particles and calculated the speed of sound in air using this model. His
model represented a chain of particles of uniform mass located at equal distances
from each other on a straight-line coinciding with the wave propagation direction.
According to his assumption, a force proportional to their relative displacement acts
on each particle from the side of its neighboring particles.
The reason, due to which I. Newton had to consider a chain of point particles, was
that the study of continuous media wosuld lead to partial differential equations, which
had been then unknown. The motion of the mechanical model chosen by Newton was
described by the set of ordinary differential equations already known at that time.
However, as it will be shown in Chap. 3, only longitudinal waves can be considered
in the framework of this model, whereas the study of transverse waves principally
necessitates taking into account either an additional degree of freedom provided by
the rotation of anisotropic particles or the initial deformation of the springs (see [6,
7] and Sect. 7.2).
A systematic study of one-dimensional lattices began in 1727 from the works
of Johann Bernoulli and his son—Daniel Bernoulli. They revealed that a one-
dimensional system of n point particles possesses n independent types of vibrations
and, as a consequence, n natural frequencies.
In 1753, D. Bernoulli established the superposition principle, according to which
any movement of the oscillatory system can be represented as a superposition of its
own vibrations. This most important principle is one of the particular consequences of
Fourier expansion. Later, it was generalized. Now it is known as “Fourier theorem.”
After Johann and Daniell Bernoulli gave a complete solution to the problem about
a one-dimensional lattice consisting of point particles, and Leonard Euler solved the
problem of an oscillating string, their results were interconnected in 1759 by J. L.
Lagrange, who established the transition from the continuous model to the discrete
one. The related work was published in the Proceedings of the Turin Academy. Later,
it was developed in the famous book “Analytical Mechanics” by J. L. Lagrange
(1788).
In 1830, O. L. Cauchy, using a discrete model of the medium (ether), tried
to explain the dispersion of light under the assumption that light is elastic waves
with a very high frequency [8]. He showed that for wavelengths much larger than
the distance between neighboring particles in a one-dimensional lattice, the wave
velocity does not depend on the wavelength. For short wavelengths (i.e., at high
frequencies), the wave velocity is a function of wavelength and can vary drasti-
cally. In 1839, W.R. Hamilton, considering waves in a discrete chain, introduced the
concept of the group wave velocity.
Cauchy’s ideas expressed in [8] served as the starting point for the studies of
Baden Powell, who, based on Newton’s model of a one-dimensional lattice, derived
1.1 Review of References 3
a formula related the wave propagation velocity and its length [9]. However, he did
not notice one of the most important properties of such systems, namely the existence
of a maximum frequency at which the waves can still propagate in a lattice. This
discovery was made in 1881 by Lord Kelvin (W. Thomson), who paid attention to the
fact that frequency is a function of the wavenumber [10]. Using a model of a chain
of particles of two kinds, Kelvin was able to explain the phenomenon of dispersion,
avoiding the difficulties that arose in Cauchy’s theory.
Since the middle of nineteenth century, most of the results of the deformable solid
mechanics had been obtained in the framework of the continuum theory of elasticity,
whereas discrete models were used in the solid-state physics and in the crystal lattice
theory [11, 12]. The emphasis on continuum models was associated with successes
in the theory of functions of the real and complex variables, the theory of boundary
and initial-boundary value problems of differential equations in ordinary and partial
derivatives, with the development of the theory of integral equations, i.e., with those
branches of science that operate mainly continuous and continuously differentiable
functions.
Historically, one of the first continuum models of an elastic medium that cannot be
described in the framework of the classical theory of elasticity considering a medium
as a continuum of material points possessing, in general, three translational degrees
of freedom is the Cosserat medium, which consists of solid non-deformable bodies-
particles possessing three translational and three rotational degrees of freedom. The
microdisplacement tensor acquires an antisymmetric part, which can be expressed
through the vector of particle rotation with respect to the particle axis. The role of such
rotations increases with increasing frequency, whereas as the frequency decreases,
the translational displacements of the centers of mass of the particles (elements of
the medium) become the governing factor [2]. The theoretical foundations of such
a continuum were laid by the brothers Eugène and François Cosserat [13] in 1909.
It is traditionally assumed that the work [13] exists as if in a vacuum, without any
predecessors or, until the beginning of the 1960s, followers. But this is not true.
So, yet in 1839, J. Mac Cullagh’s work [14] had been published, which was
devoted to construction of an elastic medium model capable describing both the
observed reflection and refraction. In the Mac Cullagh continuum, the strain energy
depends on the rotational components of the strain.
Ideas distinguishing from the classical continuum canons were contained in books
by Mossoti (1851) [15], Clebsh (1862) [16], Kirchhoff (1874) [17], Duhem (1891)
[18], and Hertz (1894) [19]. So, the concepts of “couple stresses” and “the rotational
energy” were introduced in their works by A. Clebsch in 1862 [16] and by G. Kirch-
hoff in 1874 [17]. The importance of taking into account couple stresses was also
mentioned by W. Voigt in 1887 in Ref. [20], and in 1891 P. Duhem [18] introduced
the rotational measure of deformation. Thus, in 1909, the Cosserat brothers gener-
alized and developed works of G. Kirchhoff, A. Clebsch, P. Duhem, and W. Voigt.
But the Cosserat theory remained forgotten until the middle of 1960s years.
However, discrete models of media consisting of non-point particles possessing
rotational degrees of freedom began to be developed after the elaboration of the
Cosserat continuum theory. So, in the late 1930s Ya.I. Frenkel considered a model of
4 1 Theoretical Basis of the Structural Modeling Method
a chain of oriented dipoles with fixed mass centers and showed that “waves of rota-
tional oscillations” [21] (i.e., orientational waves) can propagate in such a chain. The
first model of the interaction of translational and rotational oscillations in a molecular
lattice was proposed by Anselm and Porfiryeva in 1949 [22]. Only the linear interac-
tion of orientational waves with one type of translational oscillations—longitudinal
waves—was taken into account in this model. Nevertheless, the authors showed that,
basically, mixed orientational–translational oscillations, which frequencies depend
both on the mass and the moment of inertia of molecules, propagate in molecular
crystal lattices. There exist four branches of the rotational–translational oscillation
spectrum in a one-dimensional molecular lattice model with two molecules in a unit
cell. In the long-wavelength range, one branch (acoustic) corresponds to purely trans-
lational oscillations, the second branch—to purely rotational oscillations depending
only on the moment of inertia, and the other two ones are responsible for mixed
rotational–translational oscillations depending on both the mass and the moment of
inertia. Further research by N. N. Porfiryeva [23] showed that these results obtained
for a one-dimensional lattice model are, in general, saved for a three-dimensional
crystal lattice.
From the beginning of the 1960s generalized models of the Cosserat continuum
are intensively developed [24]: the theory of oriented media, asymmetric, multipolar,
micromorphic, gradient theories of elasticity. So, on the basis of assumption of the
rotational interaction of particles of elongated shape in an anisotropic elastic medium,
Aero and Kuvshinsky [25, 26] generalized the phenomenological theory of elasticity
in order to explain some anomalies in the dynamic behavior of plastics, to which
the classical theory of elasticity did not provide a satisfactory treatment. Later, the
idea of an “oriented” continuum, each point of which is assigned a direction (the
field of a director), was developed in the theory of liquid crystals [27–29], where the
director waves in liquid crystals are, in fact, analogs of rotational waves in solids,
like spin waves in ferromagnets [30]. A significant contribution to the development
of moment theories was also made by the works of Hermann and Gunther [24],
Green and Rivlin [31], Koiter [32], Ilyushin and Lomakin [33–35], Mindlin [36],
Nowacky [3], Palmov [37, 38], Savin [39], Toupin and Truesdell [40, 41], Eringen
[42–45], Kunin [2], and others (see also the List of references in [46]). By the middle
of 1960s, a new direction was formed that was closely related to the theory of the
crystal lattice—the nonlocal theory of elasticity, containing generalized Cosserat
continuum models as a long-wavelength approximation (Kroner [47], Krumhansl
[48], Kunin [2]). The nonlocal theory of elasticity was further developed by Green
et al. [49], Eringen [44, 50], and other authors [2, 47, 51].
On the other hand, the classical theory of elasticity was shown to be insufficient
in the solid-state physics when studying the thermodynamic properties of materials.
In 1952, Lifshits [52], when considering the thermal properties of chain and layered
structures at low temperatures, paid attention to the influence of the transverse rigidity
of atomic layers or chains on the dispersion law of acoustic oscillations of a layered
crystal in the long-wavelength section of the spectrum, where it should be absent
according to the laws of the theory of elasticity. In this paper, the dispersion laws
for longitudinal and transverse (bending) waves are given. Later on, bending waves
1.1 Review of References 5
in the crystal lattice were studied in more detail by Kosevich [53]. He remarked
that bending waves, in contrast to longitudinal waves provided by central forces of
interaction, are caused by weaker noncentral forces arising due to transverse displace-
ments of particles. He also showed that a more accurate description of the nonlinear
dynamics of the crystal lattice necessitates taking into account in the governing equa-
tions the couple stresses described by the fourth spatial derivatives of the transverse
displacements of the particles. It should be noted that couple stresses can also be
taken into account if one considers the rotational degree of freedom of particles
and then, using the method of step-by-step approximations, reduces the three-mode
system to a two-mode system admitting only translational displacements of particles
(see Chap. 4).
In mechanics, interest in discrete models has resumed since the mid-twentieth
century (see, for example, the works of M.Ya. Leonov [54], L.I. Slepyan [55, 56],
M.R. Korotkina [57], S.A. Nazarov and M.V. Paukshto [58]) and continues in the
current century (see, particularly, the works of A.M. Krivtsov and N.F. Morozov
et al. [59–62], A.V. Porubov et al. [63–67], A.A. Vasiliev, S.V. Dmitriev, and A.E.
Miroshnichenko [68–71], A. Suiker, A.V. Metrikine and R. de Borst [72, 73]).
According to N.F. Morozov and M.V. Paukshto [74], interest in discrete models
is associated with the following circumstances:
• A lot of scientists believed that employing of discrete methods is more justified
due to discreteness of computing processes.
• The development of personal computers currently enables one solving systems
containing great amount of equations. This fact partially disproves hypothesis
about the inadequacy of real and computing situations.
• Discrete methods had allowed, for example, in problems of fracture [54–56, 75,
76], to discover some effects that could not be found by continual methods. And
this is not accidental, because a continuum model is a certain concept of the long-
wavelength approach of the discrete model, whereas the destruction occurs at the
microstructure level and is described by the long-wavelength asymptotics only
approximately.
• Discrete models simulate a real atomic structure of substances.
In recent decades, more and more models are being developed taking into account
the rotational degrees of freedom of particles and the moment interactions between
them. For example, in [77], J. Pouget and G. Maugin studied the nonlinear dynamics
of oriented media using the microscopic theory, modeling the medium as a system of
material objects with translational and rotational degrees of freedom. M. Sayadi and J.
Pouget proposed a one-dimensional chain of rotating dipoles as a model of an oriented
medium [78]. But this model took into account only one of the possible types of
6 1 Theoretical Basis of the Structural Modeling Method
anharmonic interactions between the nearest neighbors in the chain, associated only
with the rotational movements of dipoles (dipole interaction). A lattice consisting of
identical particles with both transverse and rotational degrees of freedom was studied
by A. Askar [79, 80]. The central forces of interaction between the particles were
simulated by tensile springs, whereas the noncentral forces were modeled by flexible
beams (rods). Later, this model was generalized to the case of a lattice consisting of
particles of two types with different masses and moments of inertia [81]. The cubic
lattice, consisting of identical dipoles, was considered by Japanese scientists K. Fujii,
T. Fuka, H. Kondo, and K. Ishii in [82], where the interaction between the particles
was described by the Lennard–Jones potential. In the linear approximation, a three-
dimensional model of a granular medium consisting of spherical particles interacting
by means of elastic springs of three types was constructed by K. Berglund [83].
One of the variants of the theory describing the moment dynamics of a deformable
solid has been proposed by A.G. Ugodchikov in [84]. Based on the physical and
mechanical properties of geomaterials with complex structure, V.N. Nikolaevsky
[85–87] elaborated mathematical models of the deformation and destruction of
mountain massifs and layers under external influences.
The academician of the Russian Academy of Sciences V.E. Panin and his students
were actively developing an alternative way to construct mathematical models of
microstructured media—the method of movable cellular automata [88–92]. This is
a discrete modeling method that describes the behavior of materials at the meso-
and macrolevels. In its framework, a rotation is taken into account as an independent
degree of freedom of the automat along with the translational motion of its mass
center.
At present, the concept of the existence of rotational degrees of freedom and
various types of interactions in a crystal lattice is widely used in the study of dynamic
processes in microstructured media [7, 14, 71, 77, 78, 93–101].
In the middle of 1930s and early 1940s, experimental physicists paid attention to the
importance of taking into account the rotational degrees of freedom of the elements
(particles) of the medium. Thus, the experiments of B. Bauer and M. Mag are very
interesting (see References in [102]). They compared the scattering spectra for heavy
and light water. From the comparison of spectra of these two substances, which
molecules have approximately the same mass, but different moments of inertia,
the authors made a conclusion about existence of both translational and rotational
oscillations of molecules. J. Bernal and J. Tamm [103] explained the differences
between some physical properties of light and heavy water under the assumption
about the existence of rotational oscillations.
1.1 Review of References 7
In 1940 E.F. Gross [102] observed the effect of variation of the wavelength of
scattered light in a liquid associated with orientation fluctuations of anisotropic
molecules. He remarked that the axes of molecules can rotate by a significant
angle, if the oscillation period is much larger than the relaxation time. Later, E.F.
Gross and A.V. Korshunov established experimentally [104] that in crystals of some
organic substances (for instance, benzene and naphthalene) the scattering spectrum
of small frequencies is associated with rotational vibrations of molecules. The scat-
tering spectrum is the most intensive in substances, which molecules have a large
optical anisotropy (carbon disulfide, naphthalene, benzene). The crystal lattices of
such substances consist of large molecules. In them, the intermolecular forces are
usually much larger than the van der Waals forces acting between the molecules;
therefore, the molecules can be regarded as solid bodies oscillating with respect
to each other. Among molecular crystals, the most popular objects for study are
naphthalene crystals [104–106]. There are translational oscillations of molecules,
rotational oscillations, as well as mixed translational–rotational oscillations. Experi-
mental studies of oscillations in such crystals, carried out by Raman scattering, have
shown that in the vicinity of the Rayleigh lines there are characteristic scattering lines
due to the rotational nature of molecular oscillations [105, 106]. In experiments on
spectrograms of light scattering in organic substances, estimates have been obtained
for the threshold frequency of benzene and naphthalene [105].
In the late 1950s, some experiments were performed to observe the optical–
acoustic effect in liquids and solids. So, in [107], experiments are described to study
the spectral dependence of the optical-acoustic effect in ferroelectric crystals (in
particular, Rochelle salt). The study of the spectral dependence of such an effect in
a Rochelle salt crystal and the comparison of the results with the infrared absorption
spectrum was interesting from the viewpoint of problems associated with the molec-
ular mechanism of the piezoelectric phenomenon. However, the degree of influence
of oscillation types on the excitation of the optical–acoustic effect has not been still
studied.
The first experiments on acoustics of microstructured solids were performed yet in
1970 by G.N. Savin et al. [4, 108]. The authors established the correlation between
the grain size in different metals and aluminum alloys and the dispersion of the
acoustic wave. In these works, they used the Cosserat and Mindlin models. Based on
the Mindlin model [36], where each of the material points of an elastic continuum
can both rotate and be deformed, the presence of wave dispersion for both shear and
longitudinal waves propagating in a microstructured medium was explained in [4].
A nonlinear problem for an isotropic elastic Cosserat continuum was considered in
[108]. The inclusion of microrotations caused the appearance of an additional elastic
constant with the dimension of length, as well as to the dispersion of shear waves.
Dispersion of the ultrasound waves was observed by V.I. Erofeev and V.M.
Rodyushkin in an artificial composite—ferrite pellets in epoxy resin [109]. The
appearance of a wave dispersion “forbidden” by the classical theory of elasticity
can be explained, in particular, by the influence of rotational modes. Moreover,
A.I. Potapov and V.M. Rodyushkin [110] experimentally observed the transfer of
momentum in a microstructured material with the velocity that is distinct from the
8 1 Theoretical Basis of the Structural Modeling Method
longitudinal wave velocity. A clear separation of the impact pulse into two compo-
nents was observed in this case. This fact indicates that pulse is carried by two
types of oscillations differing from each other in velocity. Nevertheless, still nobody
could observe experimentally the propagation of rotational waves in “laboratory
conditions.”
It should be noted that in microstructured media there are several types of waves—
the so-called acoustic and optical phonons, and it is possible to transfer energy from
one type of wave to another [111]. This fact should be taken into account both for
theoretical and experimental studies. So, in the monograph by V.E. Lyamov [112],
it was shown that the account of microrotations in crystals leads to the appearance
of the spatial dispersion and new wave modes. Chapter 4 of the monograph [30]
by A.I. Akhiezer, V.G. Barjahtar, and S.V. Peletminsky deals with the analysis of
coupled spin and acoustic waves in ferromagnets. Elastic waves are considered in
the framework of the classical theory without taking into account microrotations,
but it is shown that, due to the relatedness of the elastic deformations with the
magnetic field of spins, the stress tensor is no longer symmetric; i.e., in an elastic
ferromagnet, there appear couple stresses at the excitation of the spin waves. The
analysis of the dispersion properties showed that the acoustic wave with the “left”
circular polarization interacts with the spin wave much stronger than the acoustic
wave with the “right” polarization.
In the last thirty years, the processes of propagation and interaction of elastic
(acoustic) waves in microstructured solids have been extensively studied theoreti-
cally and experimentally (see, e.g., [110, 113–118]). However, the main attention is
paid to the analysis of the propagation of the longitudinal and shift waves, and the
propagation of rotational waves (waves of microrotations) is studied less. Thereby,
some articles by V.N. Nikolaevsky et al. [85, 86], where the nonlinear interactions
of longitudinal and microrotational waves were studied in relation to seismic acous-
tics problems (in the framework of a gradient-consistent model of a medium with
complex structure, they attempted to explain the generation of ultrasound during the
propagation of seismic waves), and by A.I. Potapov et al. [7, 119–123], including a
co-author of this monograph, in which the processes of propagation and interaction of
longitudinal, transverse, and rotational waves in crystalline media were investigated,
should be remarked.
It was amongst these wild and lawless Rifians that Mr. Hay found
the most thorough sportsmen, and also men capable of great
attachment and devotion. Always much interested in the history of
this race, in their customs and mode of life, he wrote an interesting
account of the tribes which inhabit the north of Morocco and of his
personal intercourse with them.