MATERIAL SAFETY DATA SHEET

Polyken Liquid Adhesive (1019 Series)

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATIONS AND OF THE COMPANY UNDERTAKING

Product Name Polyken Liquid Adhesive (1019 Series)

Use/Size Pipe Corrosion Protection
Product Numbers 1019, 1019R, 1019 SPR, 1019SY
Manufacturer/Supplier Berry Plastics Corporation, Tapes and Coatings Division
Address 2320 Bowling Green Road
Franklin, Kentucky
Phone Number (270) 586-3261 (Monday – Friday 8:00 am to 5:00 pm)
Chemtrec Number (800) 424-9300
Revision Date: May 8, 2009
MSDS Date: August 9, 2007
Safety Data Sheet according to EC directive 2001/59/EC and OSHA’s Hazcom Standard (29 CFR 1910.1200)

2. HAZARDS IDENTIFICATION

EU Main Hazards
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
R68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if
swallowed.

Routes of Entry
- Absorption - Eye contact - Ingestion - Inhalation - Skin contact
Carcinogenic Status
Not considered carcinogenic by NTP, IARC, and OSHA.
Target Organs
Central Nervous System - Skin - Eye - Liver - Kidney - Respiratory System - Reproductive - Optic
Nerve - Heart
Health Effects - Eyes
Liquid, mist or vapor may cause pain, transient irritation and superficial corneal effects.
Health Effects - Skin
Material may cause irritation and allergic sensitization. Repeated or prolonged contact may produce
defatting of the skin leading to irritation and dermatitis. Material can be absorbed through the skin and
cause effects similar to those resulting from inhalation.
Health Effects - Ingestion
Swallowing may have the following effects:
- abdominal pain - vomiting - central nervous system depression - kidney damage - liver damage –
testis damage – aspiration into the lungs may occur during ingestion or vomiting causing lung damage -
visual impairment and blindness
A large dose may have the following effects:
- systemic effects similar to those resulting from inhalation
Revision Date: May 8, 2009 MSDS-1019-REV2-FEB11 LEXPS-0090 Page 1 of 7
 Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken Liquid Adhesive (1019 Series)

2. HAZARDS IDENTIFICATION

Health Effects - Inhalation

Exposure to vapor may have the following effects:
- irritation of nose, throat and respiratory tract - central nervous system depression - dizziness -
drowsiness - headache - mental confusion - allergic sensitization
Exposure to vapor at high concentrations may have the following effects:
- nerve damage leading to numbness and muscle weakness - lung damage - liver damage - kidney
damage - testis damage – adverse reproductive effects – cardiac arrhythmias - visual impairment and
blindness

3. COMPOSITION/INFORMATION ON INGREDIENTS

Component Name CAS#/Codes Concentration R Phrases Classification

Toluene 108-88-3 3-5% R11, R38, F, Xn
203-625-9 R48/20, R63,
R65, R67
Heptane 142-85-5 65-80% R11, R38, F, Xn, N
205-563-8 R50/53, R65,
R67
Carbon Black 1333-86-4 <5% None None
215-609-9
Methanol 67-56-1 3-5% R20/21/22, F, Xn
200-659-6 R68/20/21/22
Polymers and Resins N.A. <25% None None

4. FIRST AID MEASURES

Eyes
Immediately flood the eye with plenty of water for at least 15 minutes, holding the eye open. Obtain
medical attention if soreness or redness persists.
Skin
Immediately flood the skin with large quantities of water for at least 15 minutes, preferably under a
shower. Remove contaminated clothing and continue washing. Contaminated clothing should be washed
or dry-cleaned before re-use. Obtain medical attention if blistering occurs or redness persists.
Ingestion
Do not induce vomiting, unless directed to do so by a physician. Have victim drink 1-3 glasses of water to
dilute stomach contents. If there is difficulty in breathing, give oxygen. Obtain medical attention
immediately.
Inhalation
Remove from exposure. If there is difficulty in breathing, give oxygen. Obtain medical attention
immediately.
Advice to Physicians
Treat symptomatically.

5. FIRE - FIGHTING MEASURES

Extinguishing Media
Use foam, dry chemical or carbon dioxide. Be aware of the possibility of re-ignition. Keep containers and
surroundings cool with water spray.
Unusual Fire and Explosion Hazards
Vapors can travel a considerable distance to a source of ignition and flashback. Flashback can occur if
air temperature exceeds flash point. Be aware of possibility of re-ignition.

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 Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken Liquid Adhesive (1019 Series)

5. FIRE FIGHTING MEASURES

Protective Equipment for Fire-Fighting

Wear full protective clothing and self-contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES

Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for
recovery or disposal. Wear appropriate protective clothing. Eliminate all sources of ignition. Use non-
sparking scoops for flammable materials. Vapors can accumulate in low areas. Consider need for
evacuation. Prevent the material from entering drains or watercourses. Notify authorities if spill has
entered watercourse or sewer or has contaminated soil or vegetation.

7. HANDLING AND STORAGE

Keep from reach of children. Use in well ventilated area. Use local exhaust ventilation. Avoid inhaling
vapor. Avoid contact with eyes, skin and clothing. Keep container tightly closed when not in use.
Store away from sources of heat or ignition. Storage area should be: - cool - dry - well ventilated - out of
direct sunlight – away form sources of ignition(heat, sparks, flames, pilot lights) - away from incompatible
materials (see Section 10)

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Standards

Exposure limits are listed below, if they exist.
Toluene
3
ACGIH: TLV 20ppm (75 mg/m ) 8h TWA
OSHA: PEL 200ppm 8h TWA. 300 ppm CEILING, 500 ppm 10-min peak per shift.
Heptane
3 3
ACGIH: TLV 400 ppm (1640 mg/m ) 8h TWA. 500 ppm (2050 mg/m )STEL.
3
OSHA: PEL 500 ppm (2000 mg/m ) 8h TWA.
Methanol
3 3
ACGIH TLV: 200 ppm (262 mg/m ) 8h TWA, 250 ppm (328 mg/m ) STEL (15 min.)
Skin Designation: air sampling alone is insufficient to accurately quantitate exposure. Measures to
prevent significant cutaneous absorption may be required.
3
OSHA PEL: 200 ppm (260mg/m ) 8h TWA
Polymers and Resins
None assigned.
Engineering Control Measures
Use engineering methods to prevent or control exposure. Methods include process or personnel
enclosure, mechanical ventilation (dilution and local exhaust), and control of process conditions.
Respiratory Protection
Wear respiratory protection if there is a risk of exposure to high vapor concentrations, aerosols or if
applied to hot surfaces. A NIOSH approved full face respirator may be worn. The specific respirator
selected must be based on the airborne concentration found in the workplace and must not exceed the
working limits of the respirator.
Hand Protection
Butyl gloves are recommended.
Eye Protection
Chemical goggles or safety glasses with side shields
Body Protection
If there is danger of splashing, wear: - overall or apron

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 Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken Liquid Adhesive (1019 Series)

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Liquid

Color Black
Odor Hydrocarbon solvent
pH Neutral
Density (lbs/gal) 1019: 6.5
1019R: 6.5
1019SPR: 5.89
1019SY: 5.89
Boiling Range/Point (°C/F) ~93/199
Melting Point (°C/F) Not determined
Flash Point (PMCC) (°C/F) -12/10
Vapor Pressure 64 mm Hg (75F) (heptane)
Evaporation Rate (BuAc=1) >2 (heptane)
Solubility in Water Negligible
Vapor Density (Air = 1) 3.5 (heptane)
VOC (g/l) 1019: 620
1019R: 581
1019SPR: 610
1019SY: 615

10. STABILITY AND REACTIVITY

Stability
Stable under normal conditions.
Conditions to Avoid
- Heat, sparks, flames - High temperatures - sources of ignition - welding arcs - pilot lights - static
electricity - contact with incompatible materials
Materials to Avoid
- Strong oxidizing agents - acids – bases - reducing agents
Hazardous Polymerization
Will not occur.
Hazardous Decomposition Products
- oxides of carbon - hydrocarbons - phenolic vapors - aldehydes - sodium oxide - phosphorous oxides

11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Toluene: Oral LD50 rat 636 mg/kg
Dermal LD50 rabbit 12124 mg/kg
Inhalation LC50 rat 28.1 mg/l 4h
Heptane: Oral LD50 rat 5,000 mg/kg.
Dermal LD50 rabbit 3,160 mg/kg
Methanol: Oral LD50 (rat) 5300 mg/kg
Dermal LD50 (rabbit) 15,800 mg/kg
Inhalation LC50 (rat) 64 mg/l, 4h
Chronic Toxicity/Carcinogenicity
This product contains carbon black which is classified by IARC as a Group 2B possible human
carcinogen. When encapsulated in the liquid matrix the risk of exposure is reduced.

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 Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken Liquid Adhesive (1019 Series)

11. TOXICOLOGICAL INFORMATION

Genotoxicity
Methanol: Negative Ames test with and without metabolic activation.
Toluene: Negative Ames Test with and without metabolic activation.
Heptane: Negative Ames Test with and without metabolic activation.
Reproductive/Developmental Toxicity
Toluene: In laboratory studies, birth defects, increased fetal lethality and delayed fetal development have
been observed in offspring of female animals exposed during pregnancy. Toluene has been
demonstrated to be embryofetotoxic and teratogenic in laboratory animals.
Methanol: There are conflicting laboratory animal studies as to whether methanol causes adverse
reproductive effects. Some studies results show methanol has produced fetotoxicity in rats and
teratogenicity in mice exposed by inhalation to high concentrations that did not produce significant
maternal toxicity.

12. ECOLOGICAL INFORMATION

Mobility
No relevant studies identified.
Persistence/Degradability
No relevant studies identified.
Bio-accumulation
No relevant studies identified.
Ecotoxicity
Toluene: EC50 Fathead minnow 96hr 34mg/l
EC50 Daphnia magna 48hr 11.5 mg/l
EC50 Algae (Selenastrum capricornutum) 433 mg/l 96 hr
Heptane: LC50 Carassius auratus (goldfish) 4.00 mg/l 24 h
Methanol: Bluegill sunfish LC50:15,400 mg/l 96hr
Daphnia Magna EC50: >100 mg/l 96 hr

13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with all applicable local and national regulations. Labels should not be
removed from containers until they have been cleaned. Do not cut, puncture or weld on or near to the
container. Use non-sparking tools. Do not incinerate closed containers. Empty containers may contain
hazardous residues. Dispose of containers with care.

14. TRANSPORT INFORMATION

DOT CFR 172.101 Data Coating Solution (3) UN1139, ll

UN Proper Shipping Name Coating Solution
UN Class (3)
UN Number UN1139
UN Packaging Group ll
Classification for AIR Consult current IATA Regulations prior to shipping by air.
Transportation (IATA)

15. REGULATORY INFORMATION

EU Label Information
Classification and labelling have been performed according to EU directives 67/548/EEC and 99/45/EC
including amendments(2001/60/EC and 2006/8/EC)
EU Hazard Symbol and Indication of Danger
Xn - Harmful
N- Dangerous for the environment
F- Flammable

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 Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken Liquid Adhesive (1019 Series)

15. REGULATORY INFORMATION

R phrases
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
R68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if
swallowed.
S phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 Wear suitable protective clothing and gloves.
S57 Use appropriate containment to avoid environmental contamination.
S60 This material and its container must be disposed of as hazardous waste.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or
label.
US REGULATIONS (Federal, State) and INTERNATIONAL CHEMICAL REGISTRATION LAWS
TSCA Listing
All ingredients have been verified for inclusion on the EPA Toxic Substance Control Act Chemical
Substance Inventory.
EINECS Listing
All ingredients in this product have not been verified for inclusion on the European Inventory of Existing
Commercial Chemical Substances (EINECS) or specifically exempted.
DSL (Canadian) Listing
All ingredients in this product have not been verified for inclusion on the Domestic Substance List (DSL).
California Proposition 65
This product contains the following materials which the State of California has found to cause cancer,
birth defects or other reproductive harm: Toluene (108-88-3) - Quartz (14808-60-7) <0.01% -
Ethylbenzene (100-41-4) <0.1% - Formaldehyde (50-00-0) trace - Benzene ( 71-43-2) <0.01%
SARA Title III Sect. 302 (EHS)
This product does not contain any chemicals subject to SARA Title III Section 302.
SARA Title III Sect. 304
The following chemicals have reportable quantities: - Toluene 1000# - Methanol 5000#
SARA Title III Sect. 311/312 Categorization
Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard, Fire Hazard
SARA Title III Sect. 313
This product contains a chemical that is listed in Section 313 at or above de minimis concentrations.
The following listed chemicals are present: Toluene (108-88-3) - Methanol (67-56-1)

16. OTHER INFORMATION

NFPA Ratings
NFPA Code for Flammability - 4
NFPA Code for Health - 2
NFPA Code for Reactivity - 0
NFPA Code for Special Hazards – None
HMIS Ratings
HMIS Code for Flammability - 4
HMIS Code for Health - 2
HMIS Code for Reactivity - 0
HMIS Code for Personal Protection - See Section 8
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 Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken Liquid Adhesive (1019 Series)

16. OTHER INFORMATION

Abbreviations
N/A: Denotes no applicable information found or available
CAS#: Chemical Abstracts Service Number
ACGIH: American Conference of Governmental Industrial Hygienists
OSHA: Occupational Safety and Health Administration
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit
NTP: National Toxicology Program
IARC: International Agency for Research on Cancer
R: Risk
S: Safety
For further Information email: [email protected]

Prepared By: EnviroNet LLC.

The information and recommendations presented in this MSDS are based on sources believed to be
accurate. Berry Plastics Corporation, Tapes and Coatings Division assumes no liability for the accuracy
or completeness of this information. It is the user's responsibility to determine the suitability of the
material for their particular purposes. In particular, we make NO WARRANTY OF MERCHANTABILITY
OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, with respect to such information, and we
assume no liability resulting from its use. Users should ensure that any use or disposal of the material
is in accordance with applicable Federal, State, and local laws and regulations.

Revision Date: May 8, 2009 MSDS-1019-REV2-FEB11 LEXPS-0090 Page 7 of 7