Class 11 Chemistry em May 2022 Answer Key V.suresh Kanna, P.g.asst, GHSS, Thirumanjolai

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DEPARTMENT OF GOVERNMENT EXAMINATIONS

HIGHER SECONDARY FIRST YEAR EXAMINATION MAY- 2022

KEY ANSWER FOR CHEMISTRY – ENGLISH MEDIUM

Maximum Marks - 70
Answer all the Questions Part -I 15 x 1 = 15

Q.NO Option A Type Q.NO Option B Type

1 c) C8H18 1 a) 1p + 2n

2 b) - 2ºC 2 c) (1) – (iv), (2) – (iii), (3) – (i), (4) – (ii)

–C(CH3)3 > -CH(CH3)2 >- CH2


3 a) – CH3 > -CH3 3 b) NO

4 b) NO 4 c) Mass / volume
d) Both assertion and reason
are true but reason is not the
5 d) correct explanation of 5 c) C8H18
assertion

6 c) Mass / volume 6 a) Lithium


for a system at equilibrium Q
is always less than the –C(CH3)3 > -CH(CH3)2 >- CH2 –
7 b) 7 a)
equilibrium constant CH3 > -CH3

8 c) (1) – (iv), (2) – (iii), (3) – (i), (4) – (ii) 8 c) Stark effect

for a system at equilibrium Q is


9 a) Lithium 9 b) always less than the equilibrium
constant

10 b) MgCl2 10 d) tautomers

11 a) 1p + 2n 11 b) MaCl2

12 a) O22– 12 b) - 2oC

13 c) Stark effect 13 a) O22-

Both assertion and reason are


near the hydrogen chloride
14 d) 14 d) true but reason is not the
bottle
correct explanation of assertion

near the hydrogen chloride


15 d) tautomers 15 d)
bottle

SHANMUGAM S, ST. JOHN’S MAT.HR.SEC.SCHOOL PORUR, CHENNAI – 600116


Part – II

Answer any SIX Questions and Questions No.24 is Compulsory. 6 X 2 =12

16 Gram equivalent mass is defined as the mass of an element (compound


or ion) that combines or displaces 1.008 g hydrogen or 8 g oxygen or 2
35.5 g chlorine.
Correct definition ………………………………………………….

17 n = 2 represents L shell, 2n2 …………………………………………... 1


Maximum number of electron in L shell is 2 x 22 = 8 electrons …….. 2
1
18 Types of Covalent (Molecular) hydrides
1
i) electron precise (CH4, C2H6, SiH4, GeH4), ½ 2
ii) electron deficient (B2H6) ½
iii) electron-rich hydrides (NH3, H2O).
19 The spontaneity of any process depends on three different factors.
i) If the enthalpy change of a process is negative, then the process is ½

exothermic (ΔH is negative)


½
ii) If the entropy change of a process is positive, (ΔS is positive)
2
iii) The Gibbs free energy which is the combination of the above two
1
(ΔH -TΔS) should be negative for a reaction to occur spontaneously
ΔH -TΔS < 0 (OR)
i) ΔH < 0 ii) ΔS > 0 iii) ΔG < 0
20 Sign convention of heat
i) If heat flows into the system from the surrounding, energy of a system 1
increases. Hence it is taken to be positive (+q).
2
ii) If heat flows out of the system into the surrounding, energy of the
1
system decreases. Hence, it is taken to be negative (–q).
21 4NO + 6H2O ⇌ 4NH3 + 5O2 (Correct balanced equation )…………………..
(unbalanced equation ………………………………………….. 1M) 2 2
Isotonic solutions
22
Two solutions having same osmotic pressure at a given temperature are
called isotonic solutions. 2 2
(Correct definition)
23 Conversion of ethyl chloride into ethane:
2
2

Explanation only ……………………………………………………… 1 M


24 Compulsory questions:

1
i) 2
1
ii)
SHANMUGAM S, ST. JOHN’S MAT.HR.SEC.SCHOOL PORUR, CHENNAI – 600116

Part – III

Answer any SIX Questions and Questions No.33 is Compulsory. 6 X 3 =18

25 i) CO2 ii) H2SO4 1½


x + 2 (– 2) = 0 2 (+ 1) + x + 4 (– 2) = 0
x=4 2+x–8=0 x=+6 1½ 3

26 i) It is defined as the amount of energy released (required in the case noble


2
gases) when an electron is added to the valence shell of an isolated neutral
gaseous atom in its ground state to form its anion. 3
1
ii) It is expressed in kJ mol-1 A + e- → A- + EA ……………………
27 John Dalton stated that
“ the total pressure of a mixture of non-reacting gases is the sum of
3
partial pressures of the gases present in the mixture”. 3
Correct statement……………………………..
28
2

3
The molar mass of the solute (MB) can be calculated using the known values
1
of wA, wB, MA and the measured relative lowering of vapour pressure.
29 Electronic configuration of hydrogen atom is 1s1 ½
Valence shell electronic configuration of fluorine atom : 2s2 2px2, 2py2, 2pz1 ½
3
When half filled 1s orbital of hydrogen linearly overlaps with a half filled 2pz
2
orbital of fluorine, a σ-covalent bond is formed between hydrogen and
fluorine. (OR)

30 Optical Isomerism
Compounds having same physical and chemical property but differ only
3
in the rotation of plane of the polarized light are known as optical isomers and
the phenomenon is known as optical isomerism
Correct statement……………………………..
31 S.NO Nucleophiles Electrophiles
1 Nucleophiles are reagents that Electrophiles are reagents that are 1
has high affinity for electro attracted towards negative charge
positive centre. or electron rich centre.
2 All Lewis bases All Lewis acids
act as nucleophiles. act as electrophiles 1 3
3 Ex: Neutral Nucleophiles: Ex: Neutral electrophiles :
NH3, H2O, R-OH, R-O-R’ CO2, AlCl3 , BF3 , FeCl3 :CCl2
-Ve charged nucleophiles +Ve charged Electrophiles:
X- (Cl-, Br -, I - ) H+, X +, O+ , N+ 1
RCOO-, RO-, OH- , CN – ( any one example )
(any one example)

32 Alkenes react with Baeyer’s reagent to form vicinal diols. The purple solution
(Mn7+) becomes dark green (Mn6+), and then produces a dark brown
precipitate (Mn4+) (OR)

33 Compulsory questions:
1

3
1

Part – IV
Answer all the Questions 5 x 5 = 25
34 a) i) n = 4 l = 0, 1, 2, 3 four sub-shells ⇒ s, p, d, f

l=0 ml = 0 ; one 4s orbital.


½

l=1 ml = –1, 0, +1 ; three 4p orbitals. ½


2
½
l=2 ml = –2, –1, 0, +1, +2 ; five 4d orbitals.
½
l=3 ml = -3, –2, –1, 0, +1, +2 , +3; seven 4f orbitals

Over all (16)Sixteen orbital


ii) Electronic configuration of N atom is 1s2 2s2 2p3
Electronic configuration of N2 molecule
σ1s2 < σ*1s2< σ2s2< σ*2s2 < π2py2 = π2pz2 < σ2px2 1

1
Molecule has no unpaired electrons. Hence, it is diamagnetic
(OR)
b) Pauling Method :
1
d = rC+ + rA- ------------------ (1)
rC+, r A- are the radius of the cation and anion respectively.

Where Zeff is the effective nuclear charge and Zeff = Z - S


1
Dividing the equation 2 by 3

1
On solving equation( 1) and (4) the values of rC+ and rA- can be calculated
35 a) i) Reason for the anomalous behaviour of beryllium
1
1) Its small size and high polarising power
2) Relatively high electronegativity and ionisation enthalpy as compared to other
1
members
3) Absence of vacant d-orbitals in its valence shell 1
ii) Comparison of Properties of Beryllium with other elements of the group
Beryllium Other elements of the family
Forms covalent compounds form ionic compounds 5
High melting and boiling point Low melting and boiling point
Does not react with water even at elevated React with water 2
temperature
Does not combine directly with hydrogen Combine directly with hydrogen
Does not combine directly with halogens. Combine directly with halogens
Halides are covalent Halides are electrovalent.
(Correct two points)
(OR)
b) Characteristics of internal energy (U):
i) The internal energy of a system is an extensive property. It depends on
1
the amount of the substances present in the system. If the amount is doubled,
the internal energy is also doubled.
ii) The internal energy of a system is a state function. It depends only upon 1
the state variables (T, P, V, n) of the system. The change in internal energy
5
does not depend on the path by which the final state is reached.
iii) The change in internal energy of a system is expressed as ΔU= Uf – Ui
½
iv) In a cyclic process, there is no internal energy change. ΔU(cyclic) = 0
½
v) ΔU= Uf − Ui = − ve (Uf < Ui)
1
vi) ΔU=Uf − Ui = + ve (Uf > Ui) 1

36 a) Determination of molar mass of solute from elevation of boiling point


If the solution is prepared by dissolving wB g of solute in wA g of solvent,
then the molality is,

Where, MB = molar mass of the solute Therefore,


1

(OR)
b) i) Bond length
The distance between the nuclei of the two covalently bonded atoms is called
1
bond length.
ii) Bond angle
Covalent bonds are directional in nature and are oriented in specific directions
in space. This directional nature creates a fixed angle between two covalent
2
bonds in a molecule and this angle is termed as bond angle.
5
iii) Bond enthalpy
The bond enthalpy is defined as the minimum amount of energy required to
break one mole of a particular bond in molecules in their gaseous state. The
unit of bond enthalpy is kJ mol-1. 2

37 a) The extent of ionic character in a covalent bond can be related to the electro
2
negativity difference to the bonded atoms. In a typical polar molecule, Aδ— Bδ+,
the electronegativity difference (χA - χB) can be used to predict the percentage of
ionic character as follows.
5
If the electronegativity difference (χA - χB ), is
1
i) equal to 1.7, then the bond A-B has 50% ionic character
ii) if it is greater than 1.7, then the bond A-B has more than 50% ionic character, 1
iii) if it is lesser than 1.7, then the bond A-B has less than 50% ionic character.
1
(OR)
b) i) 2-bromo-3-methylbutane 1
ii) methoxymethane 1
iii) 2-hydroxybutanal 1
iv) buta-1,3-diene 1
5
v) 4-chloropent-2-yne 1
38 a) i) nitrobenzene
Nitration:
When benzene is heated at 330K with a nitrating mixture (Con. HNO3 + Con.
H2SO4), nitro benzene is formed by replacing one hydrogen atom by nitronium 2
ion(electrophile) Concentrated H2SO4 is added to produce nitronium ion NO2+

ii) benzene sulphonic acid

Sulphonation: Benzene reacts with fuming sulphuric acid (Con H2SO4 + SO3)
2
and gives benzene sulphonic acid. The electrophile SO3 is a molecule. Although
5
it does not have positive charge, it is a strong electrophile. This is because the
octet of electron around the sulphur atom is not reached. The reaction is
reversible and desulphonation occurs readily in aqueous medium.

iii) BHC : Benzene reacts with three molecules of Cl2 in the presence of sun
light or UV light to yield Benzene Hexachloride (BHC) C6H6Cl6. This is known as

gammaxane or Lindane which is a powerful insecticide.

(or)

(OR)
b) 1. Ethene reacts with HCl to give Chloroethane CH3 - CH2Cl as (B) by addition
reaction.
CH2 = CH2 + HCl → CH3 - CH2Cl 1
2. Chloroethane reacts with ammonia to give Ethylamine CH3 -CH2NH2 as (C). It is a
primary amine and Carbylamine test is the characteristic test for 1° amine.
CH3 - CH2Cl + NH3 → CH3 -CH2NH2 + HCl
1
5

A CH2 = CH2 Ethene (or) Ethylene


1
B CH3 - CH2Cl Chloroethane (or) Ethyl chloride
1
C CH3 -CH2NH2 Ethylamine(or) Ethanamine
1

SHANMUGAM S
ST. JOHN’S MAT.HR.SEC.SCHOOL PORUR, CHENNAI – 600116
9841945665

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