Safety Data Sheet

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SAFETY DATA SHEET (SDS)

No Item
1 Devcon glue
2 Diesel
3 Bentonite
SAFETY DATA SHEET

1. Identification
Product identifier DEVCON® Plastic Steel® Putty (A) Resin
Other means of identification
SKU# 0100
Recommended use Not available.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name ITW Performance Polymers
Address 30 Endicott Street
Danvers, MA 01923
United States
Telephone Customer Service 978-777-1100
Website www.itwperformancepolymers.com
E-mail Not available.
Contact person EHS Department
Emergency phone number Chemtrec 800-424-9300
International 703-527-3887

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Sensitization, skin Category 1
Specific target organ toxicity, single exposure Category 3 narcotic effects
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Warning


Hazard statement Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May
cause drowsiness or dizziness.
Precautionary statement
Prevention Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Use only
outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the
workplace. Wear eye protection/face protection. Wear protective gloves.
Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable
for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If skin
irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical
advice/attention. Take off contaminated clothing and wash it before reuse.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 1/7


3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Ferrosilicon, [with >= 30% But <= 8049-17-0 60 - 80
70% Silicon]
Epoxy Resin:--reaction Product Of EPOXY RESIN 25068-38-6 10 - 30
Bisphenol A And Epichlorohydrin
(refer To Epichlorohydrin)
Fiberglass Fibers 65997-17-3 0.1 - 1
Other components below reportable levels 2.5 - 10

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions. Wash
contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
symptoms/effects, acute and Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
delayed cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Wash contaminated clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 2/7


7. Handling and storage
Precautions for safe handling Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing.
Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good
industrial hygiene practices.
Conditions for safe storage, Store locked up. Store in tightly closed container. Store away from incompatible materials (see
including any incompatibilities Section 10 of the SDS).

8. Exposure controls/personal protection


Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form

Fiberglass Fibers (CAS TWA 3 fibers/cm3 Fiber.


65997-17-3)
3 fibers/cm3 Fibrous dust.
5 mg/m3 Fiber, total
5 mg/m3 fibers, total dust
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines Occupational Exposure Limits are not relevant to the current physical form of the product.
Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Provide eyewash station and safety
shower.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).

Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Contaminated work clothing should not be allowed out of the
workplace.

9. Physical and chemical properties


Appearance Paste.
Physical state Not available.
Form Paste.
Color Dark grey
Odor Slight.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 608 °F (320 °C) estimated
range
Flash point > 399.2 °F (> 204.0 °C) Pensky-Martens Closed Cup
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 3/7


Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 2.80 g/cm3
Explosive properties Not explosive.
Flammability class Combustible IIIB estimated
Oxidizing properties Not oxidizing.
Specific gravity 2.8

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye irritation.
Ingestion Knowledge about health hazard is incomplete.
Symptoms related to the May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
physical, chemical and Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
toxicological characteristics cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity Not known.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Due to partial or complete lack of data the classification is not possible.
Skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity Due to partial or complete lack of data the classification is not possible.
Carcinogenicity Due to partial or complete lack of data the classification is not possible.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 4/7


OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity Due to partial or complete lack of data the classification is not possible.
Specific target organ toxicity - May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity - Due to partial or complete lack of data the classification is not possible.
repeated exposure
Aspiration hazard Due to partial or complete lack of data the classification is not possible.

12. Ecological information


Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data is available on the degradability of any ingredients in the mixture.
Bioaccumulative potential
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information


DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not established. Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Toxic Substances Control Act (TSCA)
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 5/7


Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Skin corrosion or irritation
categories Serious eye damage or eye irritation
Respiratory or skin sensitization
Specific target organ toxicity (single or repeated exposure)
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations


Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
California Proposition 65
WARNING: This product can expose you to chemicals including Benzene, which is known to the State of
California to cause cancer and birth defects or other reproductive harm. For more information go
to www.P65Warnings.ca.gov.
California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2) Listed: February 27, 1987
California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
Toluene (CAS 108-88-3) Listed: January 1, 1991
California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Fiberglass Fibers (CAS 65997-17-3)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 04-01-2019
Revision date 05-01-2020

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 6/7


Version # 02
HMIS® ratings Health: 2
Flammability: 1
Physical hazard: 0
NFPA ratings Health: 2
Flammability: 1
Instability: 0
Disclaimer ITW Performance Polymers cannot anticipate all conditions under which this information and its
product, or the products of other manufacturers in combination with its product, may be used. It is
the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use. The
information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or
in any process, unless specified in the text. The information given is designed only as a guidance
for safe handling, use, processing, storage, transportation, disposal and release.
Revision information This document has undergone significant changes and should be reviewed in its entirety.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 7/7


SAFETY DATA SHEET

1. Identification
Product identifier Putty Hardener
Other means of identification
SKU# 0200C
Recommended use Not available.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name ITW Performance Polymers
Address 30 Endicott Street
Danvers, MA 01923
United States
Telephone Customer Service 978-777-1100
Website www.itwperformancepolymers.com
E-mail Not available.
Contact person EHS Department
Emergency phone number Chemtrec 800-424-9300
International 703-527-3887

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Acute toxicity, oral Category 4
Acute toxicity, dermal Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Sensitization, skin Category 1
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Danger


Hazard statement Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic
skin reaction. Causes serious eye damage.
Precautionary statement
Prevention Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Do not eat,
drink or smoke when using this product. Contaminated work clothing must not be allowed out of
the workplace. Wear eye protection/face protection. Wear protective gloves/protective clothing.
Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with
plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If skin
irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it
before reuse.
Storage Store away from incompatible materials.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.
Material name: Putty Hardener SDS US
0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 1/8
3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Aliphatic Amines N/A 40 - 60
Benzyl Alcohol 100-51-6 20 - 40
TRIETHYLENETETRAMINE TETA 112-24-3 20 - 40
Silicon Dioxide Silica, amorphous, fumed, cryst.-free 112945-52-5 2.5 - 10
Titanium Dioxide TITANIUM DIOXIDE 13463-67-7 0.1 - 1
Other components below reportable levels 0.1 - 1

4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical
advice/attention if you feel unwell. In case of eczema or other skin disorders: Seek medical
attention and take along these instructions. Wash contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Get medical advice/attention if you feel unwell.
Most important Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
symptoms/effects, acute and vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness
delayed and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
medical attention and special under observation. Symptoms may be delayed.
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated
clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Water spray. Alcohol resistant foam. Powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Use water spray to cool unopened containers.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Following product recovery, flush area
containment and cleaning up with water.

Small Spills: Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 2/8
7. Handling and storage
Precautions for safe handling Do not get this material in contact with eyes. Do not taste or swallow. Avoid breathing
dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. When using, do not
eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective
equipment. Wash hands thoroughly after handling. Wash contaminated clothing before reuse.
Observe good industrial hygiene practices.
Conditions for safe storage, Store in tightly closed container. Store away from incompatible materials (see Section 10 of the
including any incompatibilities SDS).

8. Exposure controls/personal protection


Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value Form

Titanium Dioxide (CAS PEL 15 mg/m3 Total dust.


13463-67-7)
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components Type Value Form

Silicon Dioxide (CAS TWA 0.8 mg/m3


112945-52-5)
20 mppcf
Titanium Dioxide (CAS TWA 5 mg/m3 Respirable fraction.
13463-67-7)
15 mg/m3 Total dust.
50 mppcf Total dust.
15 mppcf Respirable fraction.

US. ACGIH Threshold Limit Values


Components Type Value
Titanium Dioxide (CAS TWA 10 mg/m3
13463-67-7)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Silicon Dioxide (CAS TWA 6 mg/m3
112945-52-5)
US. Workplace Environmental Exposure Level (WEEL) Guides
Components Type Value
Benzyl Alcohol (CAS TWA 44.2 mg/m3
100-51-6)
10 ppm
TRIETHYLENETETRAMIN TWA 6 mg/m3
E (CAS 112-24-3)
1 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines Occupational Exposure Limits are not relevant to the current physical form of the product.
US WEEL Guides: Skin designation
TRIETHYLENETETRAMINE (CAS 112-24-3) Can be absorbed through the skin.
Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Provide eyewash station and safety
shower.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Face shield is
recommended.
Material name: Putty Hardener SDS US
0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 3/8
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene Keep away from food and drink. Always observe good personal hygiene measures, such as
considerations washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants. Contaminated work clothing
should not be allowed out of the workplace.

9. Physical and chemical properties


Appearance Paste.
Physical state Solid.
Form Paste.
Color White
Odor Ammoniacal.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 4.64 °F (-15.2 °C) estimated
Initial boiling point and boiling 420.8 °F (216 °C) estimated
range
Flash point > 199.9 °F (> 93.3 °C)
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 5.73 hPa estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature 640 °F (337.78 °C) estimated
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 1.00 g/cm3 estimated
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
Specific gravity 1 estimated

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 4/8
Conditions to avoid Avoid temperatures exceeding the decomposition temperature. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Peroxides. Phenols.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation No adverse effects due to inhalation are expected.
Skin contact Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye damage.
Ingestion Harmful if swallowed.
Symptoms related to the Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
physical, chemical and vision. Permanent eye damage including blindness could result. Skin irritation. May cause
toxicological characteristics redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity Harmful in contact with skin. Harmful if swallowed.
Components Species Test Results
Benzyl Alcohol (CAS 100-51-6)
Acute
Dermal
LD50 Rabbit 2000 mg/kg
Inhalation
LC50 Rat 1000 mg/l, 8 Hours
Oral
LD50 Rat 1230 - 3100 mg/kg
Silicon Dioxide (CAS 112945-52-5)
Acute
Oral
LD50 Rat > 22500 mg/kg
TRIETHYLENETETRAMINE (CAS 112-24-3)
Acute
Dermal
Liquid
LD50 Rat 1465 mg/kg
Oral
Liquid
LD50 Rat 1716 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Silicon Dioxide (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.
Titanium Dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 5/8
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard.

12. Ecological information


Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data is available on the degradability of any ingredients in the mixture.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Benzyl Alcohol 1.1
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information


DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Toxic Substances Control Act (TSCA)
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Material name: Putty Hardener SDS US
0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 6/8
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Acute toxicity (any route of exposure)
categories Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitization
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations


Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
California Proposition 65
WARNING: This product can expose you to Titanium Dioxide, which is known to the State of California to
cause cancer. For more information go to www.P65Warnings.ca.gov.

California Proposition 65 - CRT: Listed date/Carcinogenic substance


Titanium Dioxide (CAS 13463-67-7) Listed: September 2, 2011
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Titanium Dioxide (CAS 13463-67-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 07-03-2019
Revision date 01-12-2021
Version # 05
HMIS® ratings Health: 3
Flammability: 1
Physical hazard: 0

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 7/8
NFPA ratings Health: 3
Flammability: 1
Instability: 0
Disclaimer ITW Performance Polymers cannot anticipate all conditions under which this information and its
product, or the products of other manufacturers in combination with its product, may be used. It is
the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use. The
information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or
in any process, unless specified in the text. The information given is designed only as a guidance
for safe handling, use, processing, storage, transportation, disposal and release.
Revision information This document has undergone significant changes and should be reviewed in its entirety.

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 8/8
Safety Data Sheet
According to Occupational Safety and Health(Classification, Labelling and
Safety Data Sheet of Hazardous Chemicals) Malaysia Regulations 2013

PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

SECTION 1: Identification of the hazardous chemical and of the supplier

Product identifier
Product name : PETRONAS Dynamic Diesel Euro 5 (B7)
Recommended use of the chemical and restrictions on use
Recommended use : Fuel for diesel internal combustion engine
Restrictions on use : Do not use this product other than stated in recommended use
without first seeking the advice of the principal supplier.
Manufacturer or supplier's details
Headquarters
Company : PETRONAS Dagangan Berhad
Address : Tower 1, PETRONAS Twin Towers,
Kuala Lumpur City Centre,
50088 Kuala Lumpur,
Malaysia
Emergency telephone : Mesralink Contact Number: 1 300 88 8181 / 8282
number 24-Hour Emergency Contact: 1-800-81-5308

SECTION 2: Hazards identification

Classification of the hazardous chemical


Flammable liquids : Category 3
Acute toxicity (Inhalation) : Category 4
Skin corrosion/irritation : Category 2
Carcinogenicity : Category 2
Specific target organ toxicity - : Category 2
repeated exposure
Aspiration hazard : Category 1
Hazardous to the aquatic : Category 2
environment- chronic hazard
Label elements
Hazard pictograms :

Signal word : Danger


Hazard statements : H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or
repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements : Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.
Safety Data Sheet

PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
P281 Use personal protective equipment as required.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/ physician.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P331 Do NOT induce vomiting.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam for extinction.
P391 Collect spillage.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification


No information available.

SECTION 3: Composition and information of the ingredients of the hazardous chemical

Substance / Mixture : UVCB


Chemical nature : Diesel fuel
Components
Chemical name CAS-No. Concentration (%)
Diesel 68334-30-5 >= 90 -<= 100

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Version 1.1 Release Date: 02.06.2022

SECTION 4: First aid measures

If inhaled : If unconscious, place in recovery position and seek medical


advice.
If symptoms persist, call a medical doctor.
Move to fresh air.
Consult a medical doctor after significant exposure.
In case of skin contact : If on skin, rinse well with water.
If on clothes, remove clothes.
If skin irritation persists, call a medical doctor.
In case of eye contact : Flush eyes with water as a precaution.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do NOT give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
If symptoms persist, call a medical doctor.
Do NOT induce vomiting.
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
Symptoms of poisoning may appear several hours later.
Most important symptoms : No information available.
and effects, both acute and
delayed

SECTION 5: Firefighting measures

Extinguishing media
Suitable extinguishing media : Alcohol-resistant foam
Dry chemical
For mixtures containing alcohol or polar solvent, alcohol-
resistant foam may be more effective.
Carbon dioxide (CO2)
Unsuitable extinguishing : High volume water jet
media High Volume Water Jet/stream.
Physicochemical hazards arising from the chemical
Specific hazards during : Fire may produce irritating, corrosive and/or toxic gases.
firefighting Containers may explode when heated.
Do not allow run-off from fire fighting to enter drains or water
courses.
Special protective equipment and precautions for fire-fighters
Special protective equipment : Structural firefighters‘ protective clothing provide thermal
for firefighters protection but has a limitation to chemical protection.
Specific extinguishing : Always stay away from tank engulfed in fire.
methods For massive fire, use unmanned master stream devices or
monitor nozzles.
Withdraw immediately in case of rising sound from venting

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Safety Data Sheet

PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

safety devices or discoloration of tank.


Do not use direct water stream. May spread fire. Do not use a
solid water stream as it may scatter and spread fire.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed off in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.

SECTION 6: Accidental release measures

Personal precautions, : Remove all sources of ignition.Do not handle until all safety
protective equipment and precautions have been read and understood.Do not get in
emergency procedures eyes, on skin, or on clothing.Use special care to avoid static
electric charges.Use personal protective equipment.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Respiratory protection: half-face or full-face respirator with
filter(s) for organic vapor and, when applicable, H2S or Self-
Contained Breathing Apparatus (SCBA) can be used
depending on the size of spill and potential level of exposure.
No action shall be taken involving any personal risk or without
suitable training.
Evacuate personnel in surrounding areas for at least 50
meters (150 feet) in all directions if required.
Consider wind direction.
Do not breathe vapor, mist or spray.
No smoking.

Ensure adequate ventilation.


Environmental precautions : Prevent further leakage or spillage if safe to do so.
Follow federal, state or local requirements for reporting
environmental release where necessary.
Identify and protect nearby sensitive area.
Use foam on spills to minimize vapors.
Use water sparingly to minimize environmental contamination
and reduce disposal requirements.
Prevent product from entering drains.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for : Clean up spill as soon as possible, observing precautions in
containment and cleaning up Exposure Controls/Personal Protection.
Use appropriate techniques such as applying noncombustible
absorbent materials or pumping.
Where feasible and appropriate, remove contaminated soil.
Place contaminated materials in disposable containers and
dispose of in a manner consistent with applicable regulations.
Eliminate sources of ignition
Allow product to evaporate.
Contain spillage, and then collect with non-combustible

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absorbent material, (e.g. sand, earth, diatomaceous earth,


vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

SECTION 7: Handling and storage

Handling
Precautions for safe handling
Advice on protection against : Take necessary action to avoid static electricity discharge
fire and explosion (which might cause ignition of organic vapours).
Normal measures for preventive fire protection.
Do not spray on a naked flame or any incandescent material.
Keep away from open flames, hot surfaces and sources of
ignition.
Advice on safe handling : Avoid formation of aerosol.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Initiate fire preventive and protection measures e.g.
boundary/equipment cooling, isolation/shut down of
equipment or process etc.
It is advisable for Responder or person in-charge to assess
the current situation before taking any necessary actions.
Take precautionary measures against static discharges.
Avoid contact with skin and eyes.
Storage
Conditions for safe storage, including any incompatibilities
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
No smoking.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Further information on : No decomposition if stored and applied as directed.
storage stability

SECTION 8: Exposure controls and personal protection

Control parameters
Components CAS-No. Value type Control Basis

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Safety Data Sheet

PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

(Form of parameters /
exposure) Permissible
concentration
Diesel 68334-30-5 TWA 100 mg/m3 ACGIH
(Inhalable (total
fraction and hydrocarbons)
vapor)
Individual protection measures, such as personal protective equipment
Eye/face protection : Eye wash bottle with pure water.
Tightly fitting safety goggles
Skin protection : Impervious clothingChoose body protection according to the
amount and concentration of the dangerous substance at the
work place.
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Respiratory protection : In the case of vapour formation use a respirator with an
approved filter.
Hygiene measures : Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.

SECTION 9: Physical and chemical properties

Appearance : Liquid
Colour : Yellowish to brownish
Odour : Hydrocarbon-like
Odour Threshold : No data available
pH : No data available
Cloud Point : 19 °C

Initial boiling point and boiling : 163 - 370 °C


range
Flash point : 60 °C Method: ASTM D 93
Evaporation rate : No data available
Upper explosion limit / Upper : No data available
flammability limit
Lower explosion limit / Lower : No data available
flammability limit
Vapour pressure : No data available
Relative density : 0.845
Density : 0.845 g/cm3
Solubility(ies)
Water solubility : No data available
Partition coefficient: n- : No data available
octanol/water
Auto-ignition temperature : >= 210 °C
Decomposition temperature : No data available
Viscosity
Viscosity, dynamic : No data available
Viscosity, kinematic : 1.5 - 5.8 mm2/s (40 °C)

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Safety Data Sheet

PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

SECTION 10: Stability and reactivity

Reactivity : Hazardous polymerisation does not occur.


Chemical stability : Stable under normal conditions.
Possibility of hazardous : No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid : Heat, sparks, flame and build-up of static electricity.
Incompatible materials : Strong oxidizing agents
Hazardous decomposition : Fumes, smoke, carbon monoxide
products

SECTION 11: Toxicological information

Acute toxicity
Product:
Acute inhalation toxicity : Acute toxicity estimate: 11.83 mg/l
Exposure time: 4 h
Test atmosphere: vapour
Method: Calculation method
Components:
Diesel:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): >= 4.1 mg/l
Exposure time: 4 h
Acute dermal toxicity : LD50 (Rabbit): > 4,300 mg/kg
Skin corrosion/irritation
Product:
Remarks : May cause skin irritation in susceptible persons.
Components:
Diesel:
Species : Rabbit
Exposure time : 24 h
Result : Skin irritation
Serious eye damage/eye irritation
Product:
Remarks : Vapours may cause irritation to the eyes, respiratory system
and the skin.
Components:
Diesel:
Species : Rabbit
Result : No eye irritation
Respiratory or skin sensitisation
Components:
Diesel:
Exposure routes : Skin contact
Result : No evidence of skin sensitization.
Exposure routes : Inhalation

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PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

Remarks : No data available


Germ cell mutagenicity
Components:
Diesel:
Germ cell mutagenicity - : Not considered germ cell mutagens
Assessment

Carcinogenicity
Components:
Diesel:
Carcinogenicity - : Suspected human carcinogens.
Assessment

Reproductive toxicity
Components:
Diesel:
Reproductive toxicity - : No data available
Assessment

STOT - single exposure


Components:
Diesel:
Assessment : No specific organ toxicity following single exposure.

STOT - repeated exposure


Components:
Diesel:
Target Organs : Thymus, Liver, Bone Marrow
Assessment : May cause damage to organs through prolonged or repeated
exposure.
Aspiration toxicity
Components:
Diesel:
Statement on Aspiration Tox. : May be fatal if swallowed and enters airways.

SECTION 12: Ecological information

Ecotoxicity
Product:
Ecotoxicology Assessment
Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.

Components:
Diesel:

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PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

Toxicity to fish : LL50 (Fish): > 1 - 100 mg/l


Exposure time: 96 h
Toxicity to daphnia and other : EL50 (Crustaceans): > 1 - 100 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EL50 (Algae): > 1 - 100 mg/l
Exposure time: 72 h
Toxicity to fish (Chronic : Remarks: No data available
toxicity)
Toxicity to daphnia and other : Remarks: No data available
aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms : Remarks: No data available

Persistence and degradability


Components:
Diesel:
Biodegradability : Result: Inherently biodegradable.

Bioaccumulative potential
Components:
Diesel:
Bioaccumulation : Remarks: Potentially bio-accumulative.
Partition coefficient: n- : log Pow: >= 4
octanol/water

Mobility in soil
Components:
Diesel:
Mobility : Remarks: No data available
Other adverse effects
Product:
Additional ecological : Toxic to aquatic life with long lasting effects.
information
An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.
Components:
Diesel:
Additional ecological : No data available
information

SECTION 13: Disposal information

Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.

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Safety Data Sheet

PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

Send to a licensed waste management company.


Dispose of in accordance with local regulations.
The product should not be allowed to enter drains, water
courses or the soil.

Contaminated packaging : Empty remaining contents.


Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

SECTION 14: Transport information

International Regulations

UNRTDG
UN number : UN 1202
Proper shipping name : DIESEL FUEL
Class : 3
Packing group : III
Labels : 3
IATA-DGR
UN/ID No. : UN 1202
Proper shipping name : Diesel fuel
Class : 3
Packing group : III
Labels : Class 3 - Flammable liquids
Packing instruction (cargo : 366
aircraft)
Packing instruction : 355
(passenger aircraft)
IMDG-Code
UN number : UN 1202
Proper shipping name : DIESEL FUEL
Class : 3
Packing group : III
Labels : 3
EmS Code : F-E, S-E
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

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Safety Data Sheet

PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

SECTION 15: Regulatory information

Safety, health, and environmental regulations specific for the hazardous chemical
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous
Chemicals) Regulations 2013.
Occupational Safety and Health (Use and Standards of Exposure of Chemicals Hazardous to
Health) Regulations 2000.

The components of this product are reported in the following inventories:


REACH : Not in compliance with the inventory
DSL : This product contains the following components listed on the
Canadian NDSL. All other components are on the Canadian
DSL.
Palm Methyl Ester (PME)
AICS : Not in compliance with the inventory
NZIoC : Not in compliance with the inventory
ENCS : Not in compliance with the inventory
ISHL : Not in compliance with the inventory
KECI : Not in compliance with the inventory
PICCS : Not in compliance with the inventory
IECSC : On the inventory, or in compliance with the inventory.
TCSI : Not in compliance with the inventory
TSCA : On TSCA Inventory.

SECTION 16: Other information

Revision Date : 02.06.2022


Sources of key data used to : CONCAWE - The oil companies’ European association for
compile the Safety Data Environment, Health and Safety in refining and distribution
Sheet
Full text of other abbreviations
(Q)SAR - (Quantitative) Structure Activity Relationship
ACGIH - American Conference of Governmental Industrial Hygienists
AICS - Australian Inventory of Chemical Substances
ANTT - National Agency for Transport by Land of Brazil
ASTM - American Society for the Testing of Materials
bw - Body weight
C - Ceiling
CCHC - Chemicals Classification and Hazard Communication
CEIL - Ceiling
ChV - Chronic Toxicity Value
CMR - Carcinogen, Mutagen or Reproductive Toxicant
CPR - Controlled Products Regulations
DIN - Standard of the German Institute for Standardisation
DSL - Domestic Substances List (Canada)
ECx - Concentration associated with x% response
ELx - Loading rate associated with x% response
EmS - Emergency Schedule
ENCS - Existing and New Chemical Substances (Japan)
ErCx - Concentration associated with x% growth rate response

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PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

ERG - Emergency Response Guide


GHS - Globally Harmonized System of Classification and Labelling of Chemicals
GLP - Good Laboratory Practice
IARC - International Agency for Research on Cancer
IATA - International Air Transport Association
IBC - International Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk
IC50 - Half maximal inhibitory concentration
ICAO - International Civil Aviation Organization
ICOP - Industry Code of Practice on Chemicals Classification and Hazard
Communication
IECSC - Inventory of Existing Chemical Substances in China
IMDG - International Maritime Dangerous Goods
IMO - International Maritime Organization
ISHL - Industrial Safety and Health Law (Japan)
ISO - International Organisation for Standardization
KECI - Korea Existing Chemicals Inventory
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
MARPOL - International Convention for the Prevention of Pollution from Ships
MY PEL - Malaysian Permissible Exposure Limit
n.o.s. - Not Otherwise Specified
Nch - Chilean Norm
NITE - National Institute of Technology and Evaluation
NO(A)EC - No Observed (Adverse) Effect Concentration
NO(A)EL - No Observed (Adverse) Effect Level
NOELR - No Observable Effect Loading Rate
NOM - Official Mexican Norm
NTP - National Toxicology Program
NZIoC - New Zealand Inventory of Chemicals
OCSPP - Office of Chemical Safety and Pollution Prevention
OECD - Organization for Economic Co-operation and Development
PBT - Persistent, Bioaccumulative and Toxic
PICCS - Philippines Inventory of Chemicals and Chemical Substances
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals
SADT - Self-Accelerating Decomposition Temperature
SDS - Safety Data Sheet
STEL - Short Term Exposure Limit
TCSI - Taiwan Chemical Substance Inventory
TDG - Transportation of Dangerous Goods
TSCA - Toxic Substances Control Act (United States)
TWA - Time Weighted Average
UN - United Nations
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods
UVCB - Unknown or Variable Composition, Complex Reaction Products and
Biological Materials
vPvB - Very Persistent and Very Bioaccumulative
WHMIS - Workplace Hazardous Materials Information System
LLx - Loading rate associated with x% lethality effect

Disclaimer
To the best of PETRONAS knowledge, the information contained herein is accurate and
reliable as of the date of publication. Any use of information provided should be undertaken in

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PETRONAS Dynamic Diesel Euro 5 (B7)


Version 1.1 Release Date: 02.06.2022

consultation with a professional with the appropriate expertise, as necessary in the


circumstances. No warranty, express or implied, is given as to the quality, accuracy, reliability,
applicability or completeness of the contents of this SDS. The information presented here
pertains only to the product as shipped. It is the responsibility of the customer to ensure that
any activities relating to the product comply with all federal, state or local laws. Any hazards
associated with any product regulatory requirements are subject to change and may differ
between various locations. Except to the extent required by law, re-publication or
retransmission of this SDS, in whole or in part, is strictly prohibited. PETRONAS does not take
responsibility for use, transportation, storage, handling, packaging or disposal of the product
that is beyond our knowledge and recommendation by this SDS.

Product Stewardship Advisory:


PETRONAS aims to increase awareness of all the hazards associated with the storage,
handling and use of its products. Thoroughly reviewing the accompanying Safety Data Sheets
and disseminating the information to all dependent and interested parties is an essential part
of any 'Responsible Care' programme.

MY / EN

13 / 13
PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

SECTION 1: Identification of the substance / mixture and of the company / undertaking


1.1 Product Identifier
Product Name: Bentonite / Cement Pellets
Synonyms / Trade Name: Bentonite / Cement Pellets
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use: In construction or drilling and tunnelling projects for sealing applications
where more strength is required than can be achieved with pure
Bentonite alone. Used to seal off contaminated land, seal around pipes or
tunnels, seal up bore holes, fill voids, protect pipes and cables in conduits
or provide a more conductive medium for cable grouting.
Restriction on Use: There are no identified uses advised against within the usual scope of
construction industry applications.
1.3 Details of the supplier of the Safety Data Sheet
Name: MGS Ltd
Address: Rougham Industrial Estate, Bury St Edmunds, IP30 9ND
Country: UK
Phone N°: +44 1359 271167
E-mail: [email protected]
Website: www.mgs.co.uk
1.4 Emergency telephone number
Emergency telephone at the company +44 7738 197 517
Available outside office hours: Yes
Language of the phone service: English
E-mail of competent person responsible [email protected]
National contact: Darren Portway
SECTION 2: Hazard Identification
2.1 Classification of the substance or mixture
The powder is classified as a corrosive dust.

• Direct contact with the skin may cause irritation or an allergic reaction.
• Direct contact with the eyes may cause serious eye damage.
• Inhalation may cause irritation of the – avoid WEL limits.
• Ingestion may cause mild gastric irritation.

When mixed with water it produces a strongly alkaline suspension which if it comes into contact with the skin or
eyes may cause serious burns and ulceration.

The product is not dangerous to the environment within its normal conditions of use.

Classification according to Directive 67/548/EEC:

Irritating to respiratory system and skin hazard category 2 (GHS07)


Risk of serious damage to eyes, hazard category 1(GHS05)
May cause sensitization by skin contact, hazard category 1 (GHS07)
When mixed with water may cause skin corrosion and serious eye damage category 1(GHS05)

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 1 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

2.2 Label elements

GHS05 GHS07

Signal Word: Danger

Contains Portland Cement, EC 266-43-4, CAS 65997-15-1

Hazard Statements
H315 Irritating to respiratory system and skin – Hazard Category 2
H318 Risk of serious damage to eyes - Hazard Category 1
H317 May cause sensitization by skin contact - Hazard Category 2
H313 When mixed with water may be harmful in contact with skin- Hazard Category 1

Precautionary Statements
P102 Keep out of reach of children.
P261 Avoid breathing dust.
P304+P340 If inhaled, remove person to fresh air and keep comfortable for breathing.
P342 + P361 + P315 If experiencing reparatory symptoms, take off immediately all contaminated clothing,
get immediate medical advice or attention.
P280 Wear protective gloves, protective clothing, eye protection.
P302 + P351 + P338 If on skin, wash with plenty of soap and water.
P337 + P313 If eye irritation persists, seek medical attention.
P333 + P313 If skin irritation or rash occurs after washing, seek medical attention.

2.3 Other hazards

SECTION 3: Composition / Information on Ingredients


3.1 Substances
Exceeding the Workplace Exposure Limits (WEL) on a regular basis may increase the danger of lung diseases.
Contamination of the eyes whether with the powder or wet slurry will if not washed immediately risk causing
irreversible damage to the eyes.

Prolonged contact of the skin with the powder or wet slurry may cause burns and contact dermatitis.

3.2 Mixtures
The mixture does not contain any substances of very high concern (SVHCs).

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 2 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

SECTION 4: First Aid Measures


4.1 Description of first aid measures
General advice
No known delayed effects. Consult a physician for all significant exposures.

Inhalation: No special measures: move source of dust or move person to fresh air.
If respiratory irritation persists or breathing becomes difficult seek medical
attention immediately.
Skin Contact: Wash affected area with soap and plenty of water. If necessary, seek medical advice.

Eye Contact: Rinse eyes immediately with plenty of water. If irritation persists, seek medical advice.

Ingestion: No special measure; clean mouth with water and drink afterwards plenty of water.
If gastric upset occurs, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
The acute symptoms would be pain in the eyes because of dust or wet slurry entry.
Follow first aid procedures outlined in 4.1

4.3 Indication of any immediate medical attention and special treatment needed
Follow the advice given in section 4.1.

SECTION 5: Fire Fighting Measures


5.1 Extinguishing media
Suitable extinguishing media:
The product is not combustible. Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. By preference use a dry powder, foam or CO2 fire extinguisher to extinguish the
surrounding fire as the mixture may become very slippery and hard to clean up when wet.

Unsuitable extinguishing media:


No restriction on the extinguishing media to be used in cases of fire in its vicinity – though it should be noted that
the mixture may become slippery when wet.

5.2 Special hazards arising from the substance or mixture


The material is not flammable, and it does not support fire. No hazardous thermal decomposition products.

5.3 Advice for fire fighters


Avoid generation of dust. Use breathing apparatus.

Product on floor when wetted will become corrosive to skin and eyes and may become slippery and may present
a significant slip hazard: wear anti-slip boots Use extinguishing measures that are appropriate to local circumstances
and the surrounding environment.

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 3 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

SECTION 6: Accidental Release Measures


6.1 Personal precautions, protective equipment, and emergency procedures
Refer to protection measures listed under sections 7 & 8.

6.1.1. For non-emergency personnel

Ensure adequate ventilation.


Keep dust levels to a minimum respect Workplace Exposure Limits (WEL)
Keep unprotected persons away.
Avoid contact with skin, eyes, and clothing – wear suitable protective equipment (see section 8).
Avoid inhalation of dust – ensure that sufficient ventilation or suitable respiratory protective equipment is used,
wear suitable protective equipment (see section 8).
Try not to wet, and take care of wet product on floor, which becomes corrosive and may present a slip hazard.

6.1.2. For emergency responders

Ensure appropriate PPE is worn by all personnel


Keep dust levels to a minimum.
Ensure adequate ventilation.
Keep unprotected persons away.
Avoid contact with skin, eyes, and clothing – wear suitable protective equipment (see section 8).
Avoid inhalation of dust – ensure that sufficient ventilation or suitable respiratory protective equipment is used,
wear suitable protective equipment (see section 8).
Try not to wet and take care of wet product on floor, which becomes corrosive to skin and eyes and may
present a slip hazard.

6.2 Environmental precautions


No special requirement.
Contain the spillage. If product is released from trucks in roads, place signposts to divert traffic and remove the spill
using vacuum cleaning systems, or shovel into bags – do not attempt to wash away.

The product must not be allowed into sewers or water courses.

6.3 Methods and material for containment and cleaning up


Avoid dust formation; avoid dry sweeping where possible.
Use vacuum suction unit, or shovel into bags.
Do not use water.

6.4 Reference to other sections


For more information on exposure controls/personal protection or disposal considerations, please refer to
sections 8 and 13 of this safety data sheet.

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 4 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

SECTION 7: Handling & Storage


7.1 Precautions for safe handling
Protective measures
Keep dust levels to a minimum and Minimize dust generation.
Respect Workplace Exposure Limits (WEL)
Provide appropriate exhaust ventilation at places where airborne dust is generated. In case of insufficient
ventilation, wear suitable respiratory protective equipment refer to section 8 of this safety data sheet. Handle
packaged products carefully to prevent accidental bursting. If you require advice on safe handling techniques,
please contact your supplier or check the Good Practice Guide referred to in section 16.

Measures to prevent fire


The product is not flammable. No special protective measures against fire required.
Advice on general occupational hygiene Keep dust levels to a minimum.
Minimize dust generation.
Keep dry.

General occupational hygiene measures are required to ensure safe handling of the substance. These measures
involve good personal and housekeeping practices (i.e. regular cleaning with suitable cleaning devices), no drinking,
eating and smoking at the workplace. Shower and change clothes at end of work shift. Do not wear contaminated
clothing at home.

7.2 Conditions for safe storage, including any incompatibilities


Minimize airborne dust generation and prevent wind dispersal during loading and unloading. Keep containers closed
and store packaged products so as to prevent accidental bursting.

Keep dry and do not use water for clean up as becomes corrosive to skin and eyes and slippery when wet.

7.3 Specific end use(s)


In construction or drilling and tunnelling projects for sealing applications where more strength is required than can
be achieved with pure Bentonite alone. Used to seal off contaminated land, seal around pipes or tunnels, seal up
bore holes, fill voids, protect pipes and cables in conduits or provide a more conductive medium for cable grouting.

SECTION 8: Exposure Controls / Personal Protection


8.1 Control parameters
8.1.1 Components with occupational exposure limits and/or biological occupational exposure limits requiring
monitoring
Air limits values:
Maintain personal exposure below occupational exposure limit for inhalable and respirable dust as according to
COSHH E40/ 2005 amended Oct 2007 (For data on EU TWA for dust see Appendix 1)

Substance Description Inhalable Dust Respirable Dust


WEL – (Workplace Exposure Limit) Fraction ,7.1μ
8 hr TWA (Time Weighted Average) WEL – (Workplace
Exposure Limit)
8 hr TWA (Time
Weighted Average)

Blend of Bentonite & Nuisance dust 10mg/m3 4mg/m3


Slag Cement
HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 5 of 12
PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

Crystaline Silica Respirable Dust ,7.1μ 0.1mg/m3

For further information see “The occupational exposure limit for respirable crystalline silica in EU countries
given in: http://www.crystallinesilica.eu/115-what-are-regulatory-measures-taken-eu-member-states

Biological limit values:


None

8.1.2 Recommended monitoring procedures


None

8.1.3 Occupational exposure limits and/or biological limits for air contaminants
Not applicable

8.1.4 DNEL/DMEL and PNEC values


Not available

8.2 Exposure controls


Engineering Controls:
Minimize airborne dust generation. Use process enclosures, local exhaust ventilation or other engineering controls
to keep airborne levels below specified exposure limits. If user operations generate dust, fumes, or mist, use
ventilation to keep exposure to airborne particles below the exposure limit. Apply organizational measures e.g. by
isolating personnel from dusty areas. Remove and wash soiled clothing.

Eye / Face Protection: Do not wear contact lenses. For dusty environments use tight
fitting goggles with side shields, or wide vision full goggles. It
is also advisable to have individual pocket eyewash.

Respiratory Protection: Use respiratory protection when engineering controls are not
sufficient. FFP2 dust masks face fitted.

Hand Protection: For hands, appropriate protection (e.g. gloves, barrier cream)
is recommended for workers who suffer from dermatitis
or sensitive skin. Wash hands at the end of each work session.

Skin Protection: For skin, full clean overalls are recommended.

Thermal hazards
The substance does not represent a thermal hazard, thus special consideration is not required.

Environmental exposure controls


All ventilation systems should be filtered before discharge to atmosphere. Avoid releasing to the environment.
Contain the spillage.

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 6 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

SECTION 9: Physical and Chemical Properties


9.1 Information on basic physical and chemical properties
Appearance Light grey/white fine powder 1-30μ
Odour Odourless
Odour threshold Not applicable
pH 12 – 13.5 (5% solids in water suspension) @ 20oC
Melting point >450oC (study result, EU A.1 method)
Boiling point Not applicable (solid with a melting point > 450oC)
Flash point Not applicable (solid with a melting point > 450oC)
Evaporation rate Not applicable (solid with a melting point > 450oC)
Flammability Non-flammable (study result, Method 1 of the United Nations, Recommendations
Of the Transport of Dangerous Goods, Manual of Tests and Criteria, fourth revised
edition 2003)
Explosive limits Non-explosive (explosive properties predicted in accordance with Regulation (EC) No
1272/2008, using Appendix 6, screening procedures, specified in the United Nations,
Recommendations on the Transport of Dangerous Goods, Manual of Tests and
Criteria, fourth revised edition 2003 (void of any chemical structures commonly
associated with explosive properties)
Vapour pressure Not applicable (solid with a melting point > 450oC)
Vapour density Not applicable
Relative density 2.8 g/cm³ at 20°C
Bulk density 1 – 1.4 g/cm³
Solubility in water <1.5 g/L at 20°C (study results, EU A.6 method)
Partition coefficient Not applicable (inorganic substance)
Auto ignition temperature No self-ignition temperature below 400 °C (study result, Method 4 of the United
Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests
and Criteria, Fourth revised edition, 2003)
Decomposition temperature Not applicable
Viscosity Not applicable (solid with a melting point > 450 °C)
Oxidising properties No oxidizing properties predicted from the structure in accordance with Appendix 6
section 6 of the United Nations Recommendations on the Transport of Dangerous
Goods, Manual of Tests and Criteria, Fourth revised edition 2003
9.2 Other information
None.

SECTION 10: Stability and Reactivity


10.1 Reactivity
Reacts with water to form complex stable silicates.

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 7 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

10.2 Chemical stability


Chemically stable under normal conditions of use and storage.

10.3 Possibility of hazardous reactions


Uncontrolled use of aluminium powder in wet product should be avoided as hydrogen is produced.

10.4 Conditions to avoid


Minimize exposure to moisture during storage as will reduce product quality.

May be slippery when wet.

10.5 Incompatible materials


Avoid storing together with materials that may be affected by alkaline dust.

10.6 Hazardous decomposition products


None.

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 8 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

SECTION 11: Toxicological Information


11.1 Information on toxicological effects
Toxicity Endpoints Outcome of the effects of the assessment
Acute Toxicity Bentonite – Slag Cement blends are not acutely toxic.
Eye Direct contact by large quantities of dry or wet product may cause effects
ranging from moderate eye irritation up to chemical burns and blindness.
Oral LD50 > 2000 mg/kg bw (OECD 420, rat)
Dermal LD50>2500mg/kg (OECD 420, rabbit)
Inhalation LC50 > 5,27 mg/L (OECD 436, rat) classification for acute toxicity is
not warranted.
Irritation Bentonite-Slag Cement blends are irritating to skin (OECD 420, rabbit).
Bentonite-Slag Cement blends are irritating to eye (OECD 405, rabbit).
Bentonite-Slag Cement blends may cause mild ittitation of the intestinal gut
Sensitization Bentonite –Slag Cement may be a skin sensitizer in accordance with the local
lymph node assay (OECD 429, mouse)
STOT Single Exposure No organ toxicity observed in acute tests
STOT Repeated Exposure – Oral Not available
STOT Repeated Exposure – Animal and in vitro data indicate a difference between crystalline quartz and
Inhalation the quartz-content of Bentonite. A quantitative assessment based on the
animal data is not possible as no relevant repeated-dose inhalation study is
available.
Aspiration Hazard No aspiration hazard envisaged
Mutagenicity In vitro tests for Bentonite (OECD 471, 473 and 476) negative. Tests for OPC and
Slag not available.
Carciogenicity No known effects
Toxicity for reproduction No known effects
SECTION 12: Ecological Information
12.1 Toxicity
No specific adverse effects known with respect to the environment, (LC50 aquatic toxicity not determined) as
powder blend forms an inorganic solid with low leachability, however could cause a rise in PH in water and be toxic
to aquatic life under certain conditions.

12.2 Persistence and degradability


Not relevant for inorganic substances.

12.3 Bio accumulative potential


Not relevant for inorganic substances.

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 9 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

12.4 Mobility in soil


Powder and set mixtures with water are almost insoluble and thus presents a low mobility in most soils.

12.5 Results of PBT and vPvB assessment


Not relevant as Bentonite-Slag Cement compounds are inorganic materials. After hardening they present no toxicity
risks, so substance does not meet the criteria for classification as PBT or vPvB.

12.6 Other adverse effects


If accidentally released into residual water, the Bentonite-Slag Cement powder causes a slight rise in water PH.
Reacted set cement compounds are stable and fix it components permanently and makes them insoluble.

SECTION 13: Disposal Considerations


13.1 Waste treatment methods
The residues/unused product can be disposed in landfills following national and local regulations. Dispose of waste
in accordance with the European Directives 2008/98/EC. Dispose in such a way to avoid dust generation. Do not
pour into drains or water courses. Set product should be disposed of as concrete waste.

Packaging disposal
No specific requirements. In all cases dust formation from residues in the packaging should be avoided and suitable
protection be assured. Empty containers, -dispose of as unused product. The empty and clean containers are to be
reused in conformity with regulations.

SECTION 14: Transportation Information


14.1 UN number
N/A

14.2 UN proper shipping name


N/A

14.3 Transport hazard class(es)


The material is not classified as dangerous in terms of transport regulations and no restrictions apply for
land/sea/air transportation.

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 10 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

14.4 Packing group


N/A

14.5 Environmental hazards


The product must not be allowed into sewers or water courses.

14.6 Special precaution for user


Avoid dust spreading.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
N/A

SECTION 15: Regulatory Information


15.1 Safety, health, and environmental regulations / legislation specific for the substance or mixture
Bentonite – Other regulations
Bentonite is not a SEVESO substance (SEVESO III is the latest EU legislation that deals specifically with the control
of on-shore major accident hazards involving dangerous substances), it is not an ozone depleting substance and not
a persistent organic pollutant.

National regulations: EH / COSH limits for Workplace Exposure Limits (WEL)

International legislation requirements:


The product (Bentonite) is not separately classified by the Occupational Health and Safety Administration (OSHA).
The product has not been classified as a human carcinogen by OSHA, the International Agency for Research on
Cancer (IARC) and the National Toxicology Program (NTP).

OPC –Other regulations


The marketing and use of cement with regard to the content of soluble Cr VI
Regulations from 17 January 2005, regarding those cements which naturally contain more than 2 ppm of soluble
hexavalent chromium (chromium (VI)) by dry weight of cement, relate to pure OPC and as the Bentonite-Slag
Cement blends contain much reduced levels of OPC in the presence of a natural absorption agent (Bentonite),
the regulations regarding storage are not proven to the best of our knowledge relevant.

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 11 of 12


PRODUCT SAFETY DATA SHEET
This generic SDS is provided by MGS Ltd to give information to assist with
material handling of the products listed which are conforming to Annex II of the
Doc No: HS8 C42-092 REACH Regulation (EC) 1907/2006 as amended by
Commission Regulation. Doc No: HS8 C42-092
(EU) 453/2010), and with CLP Regulation (EC) 1272/2008 Version: MGS 2/JS
Date: May 2022
Review Date: May 2023

National legislation/requirement
CONIAC Health Hazard Information Sheet No. 26 (CEMENT)
Health and Safety at Work etc Act 1974
Control of Substances Hazardous to Health (Regulations)
PORTLAND CEMENT DUST – criteria document for an occupational
exposure limit. June 1994 (ISBN 07176 – 0763 – 1)
HSE Guidance Notes EH26 (Occupational Skin Diseases – Health and
Safety Precautions)
HSE Guidance Note EH40 (Workplace Exposure Limits)

References

(1) Portland Cement Dust - Hazard assessment document EH75/7, UK Health and Safety Executive, 2006. Available
from: http://www.hse.gov.uk/pubns/web/portlandcement.pdf

(2) Observations on the effects of skin irritation caused by cement, Kietzman et al, Dermatosen, 47, 5, 184-189
(1999).

(3) European Commission’s Scientific Committee on Toxicology, Ecotoxicology and the Environment (SCTEE)
opinion of the risks to health from Cr (VI) in cement (European Commission, 2002).

(4) Epidemiological assessment of the occurrence of allergic dermatitis in workers in the construction industry
related to the content of Cr (VI) in cement, NIOH, Page 11, 2003

SECTION 16: Other Information

Depending on the handling and use, airborne respirable dust may be generated. Dust contains respirable
crystalline silica. Prolonged and or massive inhalation of respirable crystalline silica dust may cause lung fibrosis,
commonly referred to as silicosis. Principal symptoms of silicosis are cough and breathlessness. Occupational
exposure to respirable dust should be monitored and controlled. The product should be handled using methods
and techniques that minimize or eliminate dust generation.

The product contains less than 1% w/w RCS (respirable crystalline silica) as determined by the SWERF method.
The respirable crystalline silica content can be measured using the “Size-Weighted Respirable Fraction –
SWERF” method. All details about the SWERF method is available at www.crystallinesilica.eu
Data are based on our latest knowledge but do not constitute a guarantee for any specific product features and
do not establish a legally valid contractual relationship.

Disclaimer:
This information relates only to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process. Such information is, to the best of the
company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty
guarantee or representation is made to its accuracy, reliability of completeness. It is the user’s
responsibility to satisfy themselves as to the suitability of such information for their own particular use.

HS4-53 MGS Safety Data Sheet Template V3 May 2022 Page 12 of 12

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