Safety Data Sheet: 1. Identification

Download as pdf or txt
Download as pdf or txt
You are on page 1of 7

SAFETY DATA SHEET

1. Identification
Product identifier CHEMWORLD 56
Other means of identification None.
Recommended use OXIDIZING CLEANER
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name ChemWorld
Address 885 Woodstock Rd.
Ste 430-111
Roswell, GA 30075
United States
Telephone (800) 668-7716
Website www.chemworld.com
E-mail [email protected]

Emergency phone number 800-255-3924 ChemTel

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Skin corrosion/irritation Category 1B
Serious eye damage/eye irritation Category 1
Label elements

Signal word Danger


Hazard statement Causes severe skin burns and eye damage. Causes serious eye damage. Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Do not breathe mist or vapor. Wash thoroughly after handling. Wear eye protection/face
protection. Wear protective gloves/protective clothing/eye protection/face protection.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison
center/doctor. Wash contaminated clothing before reuse. Collect spillage.
Storage Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Sodium hypochlorite 7681-52-9 10 - 20
Other components below reportable levels 80 - 100

Material name: CHEMWORLD 56 SDS US


834 Version #: 02 Revision date: 05-21-2015 Issue date: 04-25-2015 1/7
4. First-aid measures
Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Call a physician if symptoms develop or persist.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician. Wash
contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
symptoms/effects, acute and include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
delayed blindness could result.
Indication of immediate Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. Fire-fighting measures
Suitable extinguishing media Powder. Foam. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do
emergency procedures not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for This material is classified as a water pollutant under the Clean Water Act and should be prevented
containment and cleaning up from contaminating soil or from entering sewage and drainage systems which lead to waterways.

Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following
product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid
discharge into drains, water courses or onto the ground. Inform appropriate managerial or
supervisory personnel of all environmental releases.

7. Handling and storage


Precautions for safe handling Provide adequate ventilation. Do not breathe mist or vapor. Do not get in eyes, on skin, or on
clothing. Avoid prolonged exposure. Wear appropriate personal protective equipment. Avoid
release to the environment. Observe good industrial hygiene practices. Use care in
handling/storage.

Material name: CHEMWORLD 56 SDS US


834 Version #: 02 Revision date: 05-21-2015 Issue date: 04-25-2015 2/7
Conditions for safe storage, Store locked up. Store in original tightly closed container. Store away from incompatible materials
including any incompatibilities (see Section 10 of the SDS).

8. Exposure controls/personal protection


Occupational exposure limits
US. Workplace Environmental Exposure Level (WEEL) Guides
Components Type Value
Sodium hypochlorite (CAS STEL 2 mg/m3
7681-52-9)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield.

Skin protection
Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier.
Other Wear appropriate chemical resistant clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.

9. Physical and chemical properties


Appearance
Physical state Liquid.
Form Clear Liquid.
Color Light yellow
Odor Characteristic
Odor threshold Not available.
pH 11.2 - 11.4
Melting point/freezing point < -10 °F (< -23.3 °C)
Initial boiling point and boiling 230 °F (110 °C) Decomposes estimated
range
Flash point None
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 12.0 mm Hg estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) 100 %
Partition coefficient Not available.
(n-octanol/water)
Material name: CHEMWORLD 56 SDS US
834 Version #: 02 Revision date: 05-21-2015 Issue date: 04-25-2015 3/7
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 10.00 lb/gal
Percent volatile > 80 % estimated
Specific gravity 1.20

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns.
Symptoms related to the Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
physical, chemical and include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
toxicological characteristics blindness could result.
Information on toxicological effects
Acute toxicity Not available.
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged inhalation may be harmful.

12. Ecological information


Ecotoxicity Toxic to aquatic life with long lasting effects.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Material name: CHEMWORLD 56 SDS US
834 Version #: 02 Revision date: 05-21-2015 Issue date: 04-25-2015 4/7
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information


DOT
UN number UN1791
UN proper shipping name Hypochlorite solutions
Transport hazard class(es)
Class 8
Subsidiary risk -
Label(s) 8
Packing group III
Environmental hazards
Marine pollutant Yes
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions IB3, N34, T4, TP2, TP24
Packaging exceptions 154
Packaging non bulk 203
Packaging bulk 241
Transport in bulk according to Not established.
Annex II of MARPOL 73/78 and
the IBC Code
Transport in bulk according to Not regulated as dangerous goods.
Annex II of MARPOL 73/78 and
the IBC Code
DOT

Marine pollutant

Material name: CHEMWORLD 56 SDS US


834 Version #: 02 Revision date: 05-21-2015 Issue date: 04-25-2015 5/7
General information IMDG Regulated Marine Pollutant. DOT Regulated Marine Pollutant.

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)
Sodium hypochlorite (CAS 7681-52-9) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations


Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. Massachusetts RTK - Substance List
Sodium hypochlorite (CAS 7681-52-9)
US. New Jersey Worker and Community Right-to-Know Act
Sodium hypochlorite (CAS 7681-52-9)
US. Pennsylvania Worker and Community Right-to-Know Law
Sodium hypochlorite (CAS 7681-52-9)
US. Rhode Island RTK
Sodium hypochlorite (CAS 7681-52-9)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes

Material name: CHEMWORLD 56 SDS US


834 Version #: 02 Revision date: 05-21-2015 Issue date: 04-25-2015 6/7
Country(s) or region Inventory name On inventory (yes/no)*
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 04-25-2015
Revision date 05-21-2015
Version # 02
Disclaimer The manufacturer cannot anticipate all conditions under which this information and its product, or
the products of other manufacturers in combination with its product, may be used. It is the user’s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Revision Information Hazard(s) identification: Prevention
Hazard(s) identification: Response
Physical & Chemical Properties: Multiple Properties
Physical and chemical properties: Color
Physical and chemical properties: Form
Other information, including date of preparation or last revision: Disclaimer

Material name: CHEMWORLD 56 SDS US


834 Version #: 02 Revision date: 05-21-2015 Issue date: 04-25-2015 7/7

You might also like