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Class: XII XII – MH-CET- 2017/18
Marks: 45
Sub: Biology Time:
1 hr.
Topic: Hydrocarbons

01) By wurtz reaction a mixture of methyl iodide and ethly iodide gives
(a) butane (b) ethane
(c) propane (d) a mixture of the above three

02) What would be the product formed when 1-bromo-3-chlorocyclobutane

reacts with two equivalents of metallic sodium in ether?

(a) (b) (c) (d)

03) Formation of alkane by the action of zinc on alkyl halide is called

(a) Wurtz reaction (b) Kolbe’s reaction
(c) Ulmann’s reaction (d) Frankland reaction
04) Which isomer of hexane has only two different sets of structurally
equivalent hydrogenatoms?
(a) 2,2-dimethylbutane (b) 2-methylpentane
(c) 3-methylpentane (d) 2,3-dimethylbutane
05) The increasing order of reduction of alkyl halides with zinc and dilute
HCl is
(a) R – Cl < R – I < R – Br (b) R – Cl < R – Br < R - I
(c) R – I < R – Br < R – Cl (d) R – Br < R – I < R – I < R – Cl

06) Ozonolysis of an organic compounds gives formaldehyde as one of the

products. This confirms the presence of
(a) two ethylenic double bonds (b) a vinyl group
(c) an iso-propyl group (d) an acetylenic triple bond

07) Identify B and D in the following sequence of reactions

(a) Methanol and bromoethane (b) ethyl hydrogen sulphate and

alcoholic KOH (c)Ethyl hydrogen sulphate and aqueous KOH(d) Ethanol and alcoholic
KOH

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08) Which of the following will not show geometrical isomerism?

(a) (b)

(c) (d)

09) A gas which reacts with aqueous KMnO 4 solution but does not give precipitates
with ammoniacal Cu2Cl2 solution is
(a) ethylene (b) methane (c) acetylene (d) ethane

10) Addition of HI on double bond of propene yields isopropyl iodide as

major product. It is because the addition proceeds through
(a) more stable carbocation (b) more stable carboanion
(c) homolysis (d) more stable free radical

11) Which does not follow markownikoff’s rule?

(a) (b)

(c) (d)

12) on ozonolysis gives

(a) (b) (c) (d) None of these

13) Arrange the following hydrogen halides in the order of their decreasing
reactivity with propene
(a) HCl > HBr < HI (b) HBr > HI > HCl (c) HI > HBr > HCl (d) HCl > HI > HBr

14) Acid catalysed hydration of alkenes except ethane leads to the

formation of
(a) primary alcohol
(b) secondary or tertiary alcohol
(c) mixture of primary and secondary alcohols
(d) mixture of secondary and tertiary alcohols
15) The reaction of propene with HOCl proceeds via the addition of
(a) H+ in the first step (b) Cl+ and OH- in a single step
(c) CH in the first step
-
(d) Cl+ in the first step

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16) The best method to prepare cyclohexene from cyclohexanol is by using
(a) HBr (b) conc.H3PO4 (c) conc.HCl + ZnCl2 (d)
conc.HCl

17) Ozonolysis products of an olefin are and

(a) (b) (c) (d)

18) Predict the product C obtained in the following reaction of bytyne -1

(a) (b)

(c) (d)

19) The enthalpy of combustion of H 2, cyclohexene and cyclohexane are –

241, -3800 and -3920 kJ per mol respectively. Heat of hydrogenation of
cyclohexene is
(a) -121 kj per mol (b) + 121 kj per mol
(c) +242 kj per mol (d) – 242 kj per mol

20) 2-hexyne give trans-2-hexene on treatment with

(a) pt / H2 (b) Li/NH3 (c) pd/ BaSO4 (d) LiAlH4
21) Products of the following reaction are
(ii) Hydrolysis

(a) (b)
(c) (d)

22) Identify A and B in the given reaction

(a) C2H2 and CH3CHO (b) CH4 and HCOOH
(c) C2H4 and CH3COOH (d) C2H2 and CH3COOH

23) The compound ‘C’ in the following reaction is

(a) o-bromotoluene (b) m-bromotoluene
(c) p-bromotoluene (d) 3-brome-2,4,6-
trichlorotoluene

24) The compound X in the reaction,

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 (a) (b) (c) (d)

25) Isopropyl benzene on air oxidation in the presence of dilute acid gives
(a) C6H5COOH (b) C6H5COOH3 (c) C6H5CHO (d) C6H5OH

26) Using anhy. AlCl3 as catalyst. Which one of the following reactions
produce ethyl benzene?
(a) CH3CH2OH+C6H6 (b) CH3 – CH = CH2 + C6H6
(c) H2C = CH2 + C6H6 (d) CH3 – CH3 + C6H6

27) The treatment of benzene with isobutene in the presence of sulphuric

acid gives
(a) iso-butyl benzene (b) n-butyl benzene
(c) tert-butyl benzene (d) None of these

28) Toluene on oxidation with dil. HNO3 give

(a) benzaldehyde (b) nitrotoluene (c) benzoic acid (d) phenol
29) Aromatisation of n-heptane by passing over (Al2O3+Cr2O3) catalyst at 773
K gives
(a) benzene (b) toluene (c) mixture of both (d)
heptylene

30) Arrange the following set of compounds in the order of their

decreasing relative reactivity with an electrophile

(a) I > II > III (b) I > III > II (c) II > I > III (d) II > III > I
31) Which of the following can be used to distinguish between 1-butyne
and 2-butyne?
(a) Grignard reagent (b) Ammoniacal AgNO3
(c) Ammoniacal Cu2Cl2 (d) Baeyer’s reagent

32) Match the column I with column II and Choose the correct codes given
below:
Column I Column B
(A) Benzene 1. Phosgene
(B) Ethylene 2. Silver mirror
(C) Acetaldehyde 3. Mustard gas
(D) Chloroform 4. (4n+2) - electrons
Codes:
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 A B C D A B C D
(a) 4 3 2 1 (b) 3 2 1 4
(c) 2 4 1 3 (d) 2 1 4 3

Direction: (Q. Nos 33 - 34) Each of these of these question contains two
statements: Assertion and reason. Each of these questions also has four
alternative choice, only one of which is the correct answer. You have to select
one of the codes (a), (b), (c) and (d) given below:
(a) assertion is true, reason is true, reason is a correct explain for assertion
(b) assertion is true, reason is true, reason is not a correct explanation for
assertion
(c) assertion is true, reason is false
(d) assertion is false, reason is true
33) Assertion C – H bond in ethylene is shorter than C – H bond in ethane
Reason: carbon atom in ethane is sp-hybridised while it is sp 2 in ethyne

34) Assertion Addition of HBr on 2-butene gives two isomeric products

Reason : Addition of HBr on 2-butene follows markownikoff’s rule

35) The reaction of C6H5CH = CHCH3 with HBr produces

(a) (b) (c) (d)

36) A single compound of the structure

Is obtained from ozonolysis of which of the following cyclic compounds?

(a) (b)

(c) (d)

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37) What products are formed when the following compound is treated
with Br2 in the presence of FeBr3?

(a) (b)

(c) (d)

38) Some meta-directing groups in aromatic substitution are given. Which

one is most deactivating?
(a) – SO3H (b) - COOH (c) – NO2 (d) – C = N

39) Which of the following compounds will not undergo friedel – Crafts
reaction easily?
(a) Xylene (b) Nitrobenzene (c) Toluene (d) Cumene

40) In the following reaction,

B
+A
Major
The
Major major product is
product product

(a) (b)

(c) (d)

41) The function of AlCl3 in Friedel Crafts reaction is

(a) to absorb HCl (b) to absorb water

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 (c) to produce nucleophile (d) to produce electrophile

42) Acetylene can be obtained by the reaction

(a) (b)

(c) (d)

43) Which of the following compounds is aromatic?

(a) (b) (c) (d)

44) Which one of the following alkenes will react faster with H 2 under
catalytic hydrogenation conditions? (R = alkyl substituent)

(a) (b)

(c) (d)

45) Which one of the following is aromatic?

(a) Cyclopentadienyl cation (b) Cyclococtateraene
(c) Cycloheptratriene (d) Cycloheptatrieylcation

ANSWERS KEY
(Scalar and Vector)
1 2 3 4 5 6 7 8 9 10
11 12 13 14 15 16 17 18 19 20
21 22 23 24 25 26 27 28 29 30
31 32 33 34 35 36 37 38 39 40
41 42 43 44 45 46 47 48 49 50

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