Scribd Logo
Upload

Welcome to Scribd!

  • 206 views

    Thermochemistry Formula Sheet

    Uploaded by

    Reinhard Scheer
    All content is owned by The Organic Chemistry Tutor

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Thermochemistry Formula Sheet

    Uploaded by

    Reinhard Scheer
    206 views1 page
    All content is owned by The Organic Chemistry Tutor

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    All content is owned by The Organic Chemistry Tutor

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    206 views1 page

    Thermochemistry Formula Sheet

    Uploaded by

    Reinhard Scheer
    All content is owned by The Organic Chemistry Tutor

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 1

    Thermochemistry Formula Sheet:

    1st Law of Thermodynamics: Internal Energy:

    Endothermic: 𝑞 = + ∆𝑼 = 𝑞 + 𝑊
    Exothermic: 𝑞 = −
    Work Done By/On a Gas:
    𝑾 = −𝑃∆𝑉
    Work done by the system: 𝑊 = −
    Work done on the system: 𝑊 = + 1 𝐿 ∗ 1 𝑎𝑡𝑚 = 101.3 𝐽𝑜𝑢𝑙𝑒𝑠

    Specific Heat Capacity: 𝑱⁄(𝒈 ℃)


    𝑞
    𝑪𝑺 =
    𝑚∆𝑇

    Molar Heat Capacity: 𝑱⁄(𝒎𝒐𝒍 ℃)


    𝑞
    𝑪𝑴 =
    𝑛∆𝑇

    Heat Capacity: 𝑱⁄℃


    𝑞
    𝑪𝑯 =
    ∆𝑇

    Calorimetry – Temperature Change:


    𝒒 = 𝑚𝑐∆𝑇

    𝐽 𝐽 𝐽
    𝐶𝐻2𝑂 = 4.184 𝐶𝐼𝑐𝑒 = 2.09 𝐶𝑆𝑡𝑒𝑎𝑚 = 2.03
    𝑔℃ 𝑔℃ 𝑔℃
    Calorimetry – Phase Change:
    𝒒 = 𝑚∆𝐻 𝒒 = 𝑛∆𝐻

    H2O: ∆𝐻𝑓𝑢𝑠 = 334 𝐽⁄𝑔 ∆𝐻𝑓𝑢𝑠 = 6.01 𝑘𝐽⁄𝑚𝑜𝑙


    H2O: ∆𝐻𝑣𝑎𝑝 = 2260 𝐽⁄𝑔 ∆𝐻𝑣𝑎𝑝 = 40.7 𝑘𝐽⁄𝑚𝑜𝑙
    Final Temperature of a Mixture:
    −𝑞𝐴 = 𝑞𝐵
    TA → Initial Temp. of Substance A
    TB → Initial Temp. of Substance B −𝑚𝐴 𝐶𝐴 (𝑇𝐹 − 𝑇𝐴 ) = 𝑚𝐵 𝐶𝐵 (𝑇𝐹 − 𝑇𝐵 )

    Note: This equation will work if there are no phase changes.


    Coffee Cup Calorimeter:
    𝑞𝑟𝑥𝑛
    ∆𝑯𝒐 𝒓𝒙𝒏 = 𝑞𝑟𝑥𝑛 = −𝑞𝐻2𝑂
    𝑛
    Enthalpy Change:
    ∆𝑯𝒐 𝒓𝒙𝒏 = ∑ 𝑛 𝐻 𝑜𝑓 (𝑝𝑟𝑜𝑑𝑢𝑐𝑡𝑠) − ∑ 𝑛 𝐻 𝑜𝑓 (𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡𝑠)

    www.Video-Tutor.net

    You might also like