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Numerical Assingment
Thermodynamics
Q1. Enthalpies of formation of CO(g), CO2 (g), N2O(g) and N2O4(g) are -110, -393, 81 and 9.7 kJ mol-1 respectively. Find the value of ΔγH for the reaction: (-92.4 kJ mol-1 )
Q2. The enthalpy of combustion of methane, graphite and dihydrogen at 298k are, -890.3kj mol -1, -393.4kj mol-1 and - 285.8 kj mol-1 respectively. Calculate enthalpy of formation of CH4 (g). (-74.8 kj mol-1)
Q3. Calculate ΔrGo for conversion of oxygen to ozone 3/2 O2(g)⇔O3(g) at 298 K, if K for this conversion is 2.47×10−29.
(163 kJ mol-1 )
Q4. Calculate the equilibrium constant, K for the following reaction at 400K?
Q5. Calculate the standard enthalpy change and standard internal energy change for the following reaction at 300K:
OF2(g)+H2O(g)→O2(g)+2HF(g)
Given the standard enthalpy of formation of OF2, H2O and HF are 23 kJ mol-1,−241.8 kJ mol-1 and −268.6 kJ mol-1 respectively. (-320.8942kJ)
Q6. Calculate ΔfH of HCl if bond energy of H – H bond is 437 kJ mol-1 , Cl – Cl bond is 244 kJ mol-1, and H – Cl bond is 433 kJ mol-1 . (-92.5 kJ mol-1 )
Q7. The combustion of one mole of benzene takes place at 298 K and 1 atm. After combustion, CO2 (g)and H2O (l) are produced and 3267.0 kJ of heat is liberated. Calculate the standard enthalpy of formation, Δf H° of benzene. Standard enthalpies of formation of CO2 (g) and H2O (l) are -393.5 kJ mol-1 and -285.83 kJ mol-1, respectively.
(48.51 kJ mol-1 )
Q8. Hydrolysis of sucrose gives,
Sucrose + H2O → Glucose + Fructose
Equilibrium constant Kc for the reaction is 2 × 1013 at 300 K. Calculate ΔGo at 300K (76.402 kJ)
Q9. The equilibrium constant for a reaction is 10. What will be the value of ΔGo ? R=8.314 J K−1mol−1,T=300K.
(-5744.1 J) Q10. For the reaction
2A(g)+B(g)→2D(g)
Δ Uθ= −10.5 kJ and Δ Sθ= –44.10 JK−1
θ Calculate Δ G for the reaction, and predict whether the reaction may occur spontaneously. (Δ Gθ = 0.16 kJ)
