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Yakeen NEET 4.0 (2024)

Practice Sheet (Chemistry)

Chemical Bonding
Single Correct Type Questions (1 to 15)
1. The amount of energy released when one mole of 9. What is the geometry of the IBr2− ion?
ionic solid is formed by packing of gaseous ion is
(1) Linear
called:
(2) Bent shape with bond angle of about 90°
(1) Ionisation energy (2) Solvation energy
(3) Lattice energy (4) Hydration energy (3) Bent shape with bond angle of about 109°
(4) Bent shape with bond angle of about 120°
2. Which of the following is arranged order of
increasing boiling point? 10. The shape of XeF4, XeF5− and SnCl2 are:
(1) H2O < CCl4 < CS2 < CO2 (1) Octahedral, trigonal bipyramidal and bent
(2) CO2 < CS2 < CCl4 < H2O (2) Square pyramidal, pentagonal planar and linear
(3) CS2 < H2O < CO2 < CCl4 (3) Square planar, pentagonal planar and angular
(4) CCl4 < H2O < CO2 < CS2 (4) See-saw, T-shaped and linear
3. Compound having maximum bond angle is:
(1) BBr3 (2) BCl3 11. How many sigma bond are in a molecule of diethyl
(3) BF3 (4) None of these ether, C2H5OC2H5 ?
(1) 14 (2) 12
4. Which of the following statement is correct? (3) 8 (4) 16
(1) All carbon to carbon bonds contain a sigma bond
and one or more -bonds 12. Which one of the following species does not exist?
(2) All carbon to carbon bonds are sigma bonds (1) Be +2 (2) Be2
(3) All oxygen to hydrogen bonds are hydrogen bonds
(3) B2 (4) N2
(4) All carbon to hydrogen bonds are sigma bonds
13. Which of the following is correct for the shapes of
5. The “O–N–O” bonds angle is maximum in:
NH3 and BF3?
(1) N2O (2) NO+2
(1) NH3 – Pyramidal and BF3 – Pyramidal
(3) NO−2 (4) NO3− (2) NH3 – Planar and BF3 – Planar
(3) NH3 – Planar and BF3 – Pyramidal
6. Which of the following is the correct order for (4) NH3 – Pyramidal and BF3 – Planar
increasing bond angle?
(1) NH3 < PH3 < AsH3 < SbH3 14. Which of the following chemical compound is also
(2) H2O < OF2 < Cl2O known as Lunar Caustic?
(3) H3Te+ < H3Se+ < H3S+ < H3O+ (1) Silver nitrate
(4) BF3 < BCl3 < BBr3 < BI3 (2) Sodium hydroxide
7. The incorrect order of lattice energy is: (3) Hydrochloride acid
(1) AlF3 > MgF2 (2) Li3N > Li2O (4) Calcium oxide
(3) NaCl > LiF (4) TiC > ScN
15. Hybridization involves:
8. Which ionic compound has the largest amount of (1) Addition of electron pair
lattice energy? (2) Mixing of atomic orbitals
(1) NaF (2) AlF3 (3) Removal of electrons
(3) AlN (4) MgF2 (4) Separation of orbitals
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Assertion & Reason Type Questions (16 to 20) 20. Assertion: The dipole moment helps to predict
16. Assertion: N2 and NO+ both are diamagnetic whether molecule is polar or non-polar.
substances. Reason: The dipole moment helps to predict the
Reason: NO+ is isoelectronic with N2. geometry of molecules.
(1) Both Assertion and Reason are true and the (1) Both Assertion and Reason are true and the
Reason is the correct explanation of the Assertion Reason is the correct explanation of the Assertion
(2) Both Assertion and Reason are true but the Reason (2) Both Assertion and Reason are true but the Reason
is not the correct explanation of the Assertion is not the correct explanation of the Assertion
(3) Assertion is true statement but Reason is false (3) Assertion is true statement but Reason is false
(4) Both Assertion and Reason are false statements (4) Both Assertion and Reason are false statements

17. Assertion: HOF bond angle is higher than HOCl. Match the Column Type Questions (21 to 25)
Reason: Oxygen is less electronegative than chlorine. 21. Match the following:
(1) Both Assertion and Reason are true and the Column – I Column – II
Reason is the correct explanation of the Assertion (Molecule) (Bond order)
(2) Both Assertion and Reason are true but the Reason (A) O2 (P) Bond order = 2
is not the correct explanation of the Assertion (B) N2 (Q) Bond order = 1
(3) Assertion is true statement but Reason is false (C) H2 (R) Bond order = 3
(4) Both Assertion and Reason are false statements (D) O − (S) Bond order = 1.5
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18. Assertion: Na2SO4 is soluble in water while BaSO4 A B C D

is water insoluble. (1) P R Q S
Reason: Lattice energy of BaSO4 exceeds its hydration (2) S P Q R
energy. (3) P S R Q
(1) Both Assertion and Reason are true and the (4) S Q P R
Reason is the correct explanation of the Assertion
(2) Both Assertion and Reason are true but the Reason 22. Match the following:
is not the correct explanation of the Assertion Column – I Column – II
(Molecule) (Hybridization)
(3) Assertion is true statement but Reason is false
(A) C2H2 (P) Sp2 hybridization
(4) Both Assertion and Reason are false statements
(B) SO2 (Q) sp3d hybridization
(C) SO 2 − (R) sp3 hybridization
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19. Assertion: NaCl is more ionic than NaI.
Reason: Chlorine is more electronegative than iodine.
(D) I3− (S) sp hybridization

(1) Both Assertion and Reason are true and the A B C D

Reason is the correct explanation of the Assertion (1) P R Q S
(2) Both Assertion and Reason are true but the Reason (2) S P R Q
is not the correct explanation of the Assertion (3) P S R Q
(3) Assertion is true statement but Reason is false (4) S Q P R
(4) Both Assertion and Reason are false statements
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23. Match the following: 25. Match the following:

Column – I Column – II Column – I Column – II
(Type of (No. of hybrid (A) SO3 (P) Largest bond angle
Hybridization) orbitals) (B) BeCl2 (Q) Lowest bond angle
(A) sp (P) 3 (C) NH3 (R) sp2-hybridisation
(B) sp2 (Q) 2 (D) NO − (S) sp3–hybridisation
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(C) sp3 (R) 5
(D) dsp3 (S) 4 A B C D
(1) P, Q Q S R
A B C D
(2) R P Q, S R
(1) S Q R P
(3) S Q S P
(2) Q P S R
(4) P S P, Q R
(3) R S Q P
(4) R Q S P

24. Match the following:

Column – I Column – II
(Hybridisation) (Geometry)
(A) sp3d (P) Pentagonal
bipyramidal
(B) sp3d3 (Q) Trigonal
bipyramidal
(C) sp3d2 (R) Octahedral
(D) sp3 (S) Tetrahedral
A B C D
(1) Q P R S
(2) P Q S R
(3) S P Q R
(4) R P S Q
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Answer Key
1. (3) 14. (1)
2. (2) 15. (2)
3. (4) 16. (2)
4. (4) 17. (4)
5. (2) 18. (1)
6. (3) 19. (2)
7. (3) 20. (2)
8. (3) 21. (1)
9. (1) 22. (2)
10. (3) 23. (2)
11. (1) 24. (1)
12. (2) 25. (2)
13. (4)

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