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CHEMICAL BONDING
1. Which of the following pair of species are 9. Which of the following can not be explained on
iso-structural ? the basis of polarisation ?
– +
(1) ICl 2 & I 3 (1) Ag 2 S is less soluble than Ag 2 O
(2) NO 2 & CO 2 (2) BeCO 3 is thermally less stable than BaCO 3
–
(3) XeF 4 , ICl 4 (3) BaCO 3 is less soluble than MgCO 3
(4) SO 3 –2, ClO 4 –
(4) Melting point of AlCl 3 is less than that of
2. When iodine is dissolved in aqueous potassium NaCl.
iodide KI 3 is formed the shape of the Anionic
10. Which of the following order of Bond strength is
part :-
not correct ?
(1) Linear (2) Angular
(1) Diamond < Graphite (C–C bond)
(3) Triangular (4) See-Saw –2 –2
(2) SO 2 > SO 3 > SO 4 (S–O bond)
3. Which of the following pairs of species have

®
largest difference in spin only magnetic moment? (3) CO 3 –2 < HCO 2 – (C–O bond)
– +
(4) O 2 < O 2 < O 2 (O–O bond)
(1) O2 ,O2+ (2) O2 ,O22 −
11. A molecule XY 2 contains two σ, two π bond and
(3) O2+ ,O22 − (4) O2− ,O2+
one lone pair of electron in the valence shell of
4. Which of the following statements is not correct X. The arrangement of lone pair as well as bond
from the point of view of molecular orbital pair is :
theory?
(1) Square pyramidal
(1) Be 2 is not a stable molecule
(2) Linear
(2) He 2 is not stable but is expected to exist
(3) Bond strength of N 2 is maximum amongst (3) Trigonal planar
the homonuclear diatomic molecules (4) Unpredictable
(4) The order of energies of molecular orbitals 12. The molecule which contain σ bonds, π bonds
in F 2 molecule is π2 p = π2 py < σ2 pz
x and lone pairs in 1 : 1 : 1 ratio :-
5. Two hybrid orbitals have a bond angle of 120º. (1) C 2 N 2 (Cyanogen)
The percentage of p-character in the hybrid (2) C 6 H 6 (Benzene)
orbital is nearly:-
(3) C(CN) 4 (Tetracyano methane)
(1) 25% (2) 33%
(4) C 3 O 2 (Carbon suboxide)
(3) 50% (4) 66%
13. In CO 2 , SO 2 , SiO 2 each central atom is
6. In ICl Θ4 , shape is square planar. The number of
covalently bonded with :-
bond pair – lone pair repulsion at 90° are:-
(1) 6 (2) 4 (1) 2,2,4 oxygen atoms respectively
(3) 12 (4) 8 (2) 2,2,2 oxygen atoms respectively
7. Which of the following set of molecules have (3) 2,4,4 oxygen atoms respectively
same shape but different hybridisation ? (4) 4,4,4 oxygen atoms respectively
(1) XeO 4 , SF 4 (2) XeO 3 , BrF 3
14. The incorrect order of bond angle :-
(3) H 2 O, SnCl 2 (4) I3− , I3+
(1) CO2 > CO23− > CF2 Cl2
8. Which of the following compound gives
paramagnetic gas on heating ? (2) NO2+ > NO3− > NO2−
(1) LiNO 3 (2) NaNO 3 (3) XeF 2 > XeO 3 > XeO 4
(3) KNO 3 (4) All of these
(4) PH 3 > AsH 3 > SbH 3

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15. Which of following statement is incorrect ? 20. Which of the following does not contain PX 4+
(1) Boiling point of H 2 O 2 is greater than that of type cation in solid phase ?
H 2 O. (X=halogen atom)
(2) Ethylene glycol is less viscous than glycerol. (1) PF 5 (2) PCl 5
(3) o–nitrophenol can be separated from its (3) PBr 5 (4) None of these
meta and para isomer, using its order of 21. Incorrect order of bond angle is :-
volatile property. (1) NH 3 > PH 3 > AsH 3
(4) In ice, each 'O' atom is tetrahedrally arranged (2) H 2 O > H 2 S > H 2 Se
by four H-atom which are all in the equal (3) BCl 3 > AlCl 3 > GaCl 3
+ –
distance. (4) NO 2 > NO 2 > NO 2
1
16. Which of the following combination of orbitals is 22. In which of the following molecule 2π and σ
2
correct ?
bond is present ?
+ – + + –

®
(1) (1) O 2 –1 (2) O 2 + (3) N 2 –1 (4) N 2 +1
23. Order H 3 PO 4 >H 2 SO 4 >HNO 3 > HCl is correct
(2)
for:-
+ – + + – + – + –
(3) (1) Acidic nature (2) Basic strength
(3) Viscosity (4) Oxidation state
+

(4) 24. In which of the following compound all the bond

+

angles are equal :-

+

(1) SF 4 (2) CCl 4

17. Which of the following statements is not correct
(3) CHCl 3 (4) XeF 6
regarding bonding molecular orbital ?
25. Correct order of Bond angle is
(1) Bonding molecular orbitals possess less (1) NO 2 + < NO 2 < NO 2 –
energy than the atomic orbitals from which (2) BeCl 2 > BF 3 < CF 4
they are formed. +
(3) NH 4 > NH 3 > NH 2
–

(2) Bonding molecular orbitals have low (4) OF 2 > OCl 2 > OBr 2
electron density between the two nucleus 26. Which of the following do not exhibit resonance?
(3) Every electron in bonding molecular orbitals (1) CO 3 –2 (2) ClO 3 –
contributes to the attraction between atoms (3) SiO 2 (4) SO 3 –2
(4) They are formed when the lobes of the 27. The incorrect statement regarding chloral
combining atomic orbitals have same sign hydrate CCl 3 CH(OH) 2 is :-
18. Which of the following statement is correct. (1) It exhibits intramolecular hydrogen bonding
As the %s- character of a hybrid orbital (2) It has 9 lone pair and 9 bond pair
decreases? (3) It is stable inspite of coexistence of two-OH
groups on a carbon atom
(1) The bond angle decreases
(4) Compound is non-planar and polar
(2) The bond strength increases
28. Which of the following statements is incorrect?
(3) The bond length decreases
(1) CF 3 has T-shape
(4) Size of orbital decreases
19. Which of the following molecule has two lone (2) In SF 4 , F-S-F equatorial bond angle is less
than 120°
pairs and bond angle < 109°28' ?
–
(3) In [IC 4 ] , C-I-C bond angle is 109°
(1) SF 2 (2) KrF 4
(4) Shape of XeF 2 molecule is linear
(3) ICl 4− (4) All of these

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29. Identify the correct option :- (4) Four half filled pure orbital of carbon form
(1) NO 3 – > NH 3 > NH 2 – (order of bond angle) same kind of bonds in CH 4
(2) (CH 3 ) 3 B is a planar molecule 39. Select in which both have sea-saw shape :-
3
(3) In NH 4 Cl, ‘N’ atom is in sp d Hybridisation (1) XeO 2 F 2 , SiF 4
(4) BF 3 < BCl 3 < BBr 3 < BI 3 (Order of bond (2) XeO 2 F 2 , IO 2 F 2 --
angle)
(3) TeCl 4 , ICl 4 --
30. Which of the following is not correctly match
between given species and type of overlapping? (4) BrO 3 F, XeOF 2
(1) XeO 3 : Three (dπ–pπ) bonds 40. Which of the following have same geometry ?
(2) H 2 SO 4 : Two (dπ–pπ) bonds (1) SbF 5 2–, XeF 5 –, IF 5
(3) SO 3 : Three (dπ–pπ) bonds (2) SF 4 , XeOF 4 , PCl 4 +
(4) HClO 4 : Three (dπ–pπ) bonds –
(3) SF 6 , PF 6 , IOF 5
31. In which of the following molecules no. of lone
(4) COCl 2 , SOCl 2 , XeOF 2
pairs and bond pairs on central atom are not
equal ? 41. In which hybridisation, all orbitals are NOT

®
1 equivalent ?
(1) H 2 O (2)
2 (1) sp3
(3) O 2 F 2 (4) SCl 2 (2) sp3d
32. Number of carbon atom present linearly in (3) sp3d2
C 3 O 2 :- 2
(4) sp
(1) 2 (2) 3
(3) 6 (4) 1 42. Out of CHCl 3 , CH 4 and SF 4 , the molecules not
33. In which pair both are not isostructural ? having regular geometry are :-
(1) BH 4 – & AlH 4 – (2) NH 4 + & PH 4 + (1) CHCl 3 only
– –2
(3) PCl 6 & [SiF 6 ] (4) BCl 4 – & ICl 4 – (2) CHCl 3 & SF 4
34. In which of the following molecule all bond (3) CH 4 only
length are equal ?
(4) CH 4 & SF 4
(1) SF 4 (2) B 2 H 6
43. The correct order of increasing %s-character in the
(3) PCl 5 (4) SiF 4
35. Which of the following set do not have sp d
3 hybrid orbitals of following molecule/ion is :-
hybridization ? (I) CO3−2 (II) XeF 4 (III) I3−
–
(1) PF 4 & BrF 3 (2) ICl 2 + & SF 4
– (IV) NCl 3 (V) BeCl 2
(3) XeF 2 & I 3 (4) AsF 4 –
& SCl 4 (1) II < III < IV < I < V
36. Which of the following has different hybridization (2) II < IV < III < V < I
than other ? (3) III < II < I < V < IV
–
(1) I 3 (2) XeO 3 (4) II < IV < III < I < V
(3) SeCl 4 (4) AsF 4 – 44. Which of the following will have pyramidal
37. Which of the following molecule exhibit
shape ?
p π –p π bonding ?
–2 (1) XeO 3 (2) ICl 4 –
(1) CO 3 (2) NO 3 –1
(3) SiO 2 (4) (1) & (2) both (3) ICl 2 – (4) All of these
38. Which of the following statement is not correct? 45. Which of the following is electron deficient
(1) PCl 3 F 2 has zero dipole moment compound ?
+
(2) PH 4 is having tetrahedral geometry with (1) PF 3 (2) ClF 3
3
sp hybridisation of central atom. (3) AlF 3 (4) BF 3
(3) All diatomic molecules with polar bonds have
46. Maximum number of identical bond lengths are
dipole moment.
present in :-

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(1) SF 6 (2) IF 7 (3) SOCl 2 (4) SO 2 Cl 2
(3) PCl 5 (4) SO 4 –2
53. Which of the following molecule has some dipole
47. Match column-I with column-II and select the moment ?
correct answer :- OH OCH3
Column-I Column-II
(Molecules) (Property) (1) (2)

P IF 7 1 Planar and polar

OH OCH3
Q SO 2 2 Non planar and polar
R SF 4 3 planar and nonpolar (3) PF 3 Cl 2 (4) All

S CS 2 4 Non planar and nonpolar 54. Which of the following species is non polar with
presence of polar bond and lone pair of electron
(1) (P) → (4) ; (Q) → (1) ; (R) → (2) ; (S) → (3)
on central atom ?
(2) (P) → (4) ; (Q) → (2) ; (R) → (1) ; (S) → (3)
(1) CO 2 (2) SF 4

®
(3) (P) → (3) ; (Q) → (1) ; (R) → (2) ; (S) → (4)
(3) XeF 4 (4) CF 4
(4) (P) → (3) ; (Q) → (1) ; (R) → (4) ; (S) → (2)
48. In which type of molecule, the dipole moment 55. Which of the following species are Hypovalent ?
will be nonzero ? (I) CO 4
–
(II) BF 3
Where B is Bond pair
(III) SO 4 –2 (IV) CO 3 –2
L is Lone pair
A is Central atom (1) I, II, III (2) Only II
(1) AB 2 L 2 (2) AB 2 L 3 (3) II, IV (4) I, III, IV
(3) AB 4 L 2 (4) AB 4 56. Bond Bond dissociation energy
49. Which of the following compounds give (kJ mole–1)
paramagnetic gas on decomposition ?
C-I 240 → Element A
(I) Pb(NO 3 ) 2 (II) LiNO 3
(III) NaNO 3 (IV) NH 4 NO 2 C-II 328 → Element B
(1) I, II, III (2) II, III C-III 276 → Element C
(3) I, II (4) III, IV C-IV 485 → Element D
50. Arrange the following compound in order of Elements A, B, C and D, which element has the
increasing dipole moment :- smallest atom ?
(I) 1, 3, 5-Trichloro benzene (1) I (2) III (3) II (4) IV
(II) 1, 2, 4-Trichloro benzene
57. Which have maximum number of lone pair on
(III) 1, 2, 3, 4-Tetrachloro benzene
central atom ?
(IV) P-dichloro benzene
(1) I = IV < II < III (1) SO 2 (2) SCl 2
(2) IV < I < II < III (3) XeF 2 (4) XeO 2 F 2
(3) IV = I < III < II 58. Identify the wrong statement :-
(4) IV < II < I < III (1) Generally a sigma bond has free rotation
51. Which of the following molecule is planar as well along the axis
as polar ?
(2) p-orbitals always have only sideway
(1) PC 3 (2) SF 4 overlapping
(3) CF3 (4) None of these (3) s-orbital never form π-bond
52. Which of the following compound have number (4) There can not be more than one sigma
of pπ–pπ bond equal to pπ–dπ bond ? bond between two atoms
(1) SO 3 (2) SO 2

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59. Which of the following statement is incorrect :- 68. Shape of molecule having 4-bond pair and one
(1) Both CO 2 and SiO 2 are linear lone pair is :-
(2) If internuclear axis is Z-axis then p z orbital (1) Trigonal bipyramidal
overlaps to form σ bond (2) T-Shape
(3) The average formal charge on each 'O' atom (3) See-saw
–
in ClO 4 is –1/4. (4) Square planar
(4) 3d xy – 2p x colateral overlapping is stronger 69. Which of the following molecules has both pπ-pπ
than 3p x -3p x sideway overlapping and pπ-dπ bonds ?
60. If compound AX 3 is a hypervalent compound (1) XeO 2 F 2 (2) SO 2 Cl 2
then the group number of element A is :- (3) SO 3 (4) XeO 3
(1) III A (2) V A 70. Select the correct statement :
(3) VI A (4) VII A (1) The order of (C–O) B.O. in various species
61. Correct order of extent of overlapping is :- 2–
CO 3 < CO 2 < CO

®
(1) 2s – 2s > 2p – 2p > 2s – 2p (2) PH 5 can undergo sp3d hybridisation to have
(2) 1s – 1s > 2p – 2p > 2s – 2p octahedral geometry
(3) 1s – 1s < 2s – 2s < 3s – 3s (3) Dipole moment of CH 3 F is greater than of
(4) 3s – 3s > 3s – 3p > 3p – 3p CH 3 Cl
62. Which one is formed in IInd excited state ? (4) Increasing strength of hydrogen bonding is
(1) PCl 5 (2) SH 6 Cl–H---Cl<O–H---N<N–H---N < F–H---F

(3) SO 3 (4) IF 7 71. Species present in acidic aq. solution are :-

+
63. When two same A.O. combine they form (1) H 3 O (2) H 5 O 2 + (3) H 7 O 3 + (4) All
B.M.O. & A.B.M.O. During B.M.O. 'x' energy is 72. Intramolecular hydrogen bonding is not present
released & during A.B.M.O. 'y' energy is in :-
absorbed. So the correct relation for bond (1) Urea
formation will be ? (2) Chloral hydrate
(1) x = y (3) Salicylaldehyde
(2) x < y (4) o-fluoro phenol
(3) y < x 73. Which of the following order of H-bond strength
(4) None of these is not correct ?
64. Dative Bond is present in :- (1) HF > H 2 O > NH 3 > H 2 S
(1) CsBr 3 (2) KNO 2 (2) D 2 O > H 2 O
(3) KHF 2 (4) All (3) H 2 O > H 2 O 2
65. Which of the following element never form (4) HF 2 – < (HF) 2
compound in ground state :- 74. Dipole-dipole (Keesom) attraction is present in :-
(1) N (2) B (1) KCl + H 2 O
(3) C (4) P (2) CH3–C–CH3 + CH3–C≡N
66. Which of the following pair have same O
hybridisation :- –
– –
(3) NO 3 + Cl 2
(1) ClO 4 & ClO 2 (2) SF 4 & CCl 4
(4) HCl + Cl 2
(3) BF 3 & NF 3 (4) CO 2 & SO 2
75. The solubility of inert gases in water is due to:-
67. Which orbital is not involved in the formation of
(1) Keesom attraction
PCl 5 molecule :-
(2) Debye attraction
(1) s (2) d z2
(3) London force
(3) d x2 − y2 (4) p z (4) Ion-dipole attraction

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76. Dispersion force is present between :- 86. In which of the following process, weaking of
(1) Polar + Polar molecules covalent bond take place :-
(2) Nonpolar + Non-polar molecules (1) Boiling of H 2 O (2) Melting of KCN
(3) Polar + Nonpolar molecules
(3) Boiling of CF 4 (4) Melting of SiO 2
(4) All of these
87. Find the total number of molecule / ions in
77.
– +
Stability of the species Li 2 , Li 2 and Li 2 increases
in the order of :- which d orbitals is / are not involve in
– +
(1) Li 2 < Li 2 < Li 2 +
(2) Li 2 < Li 2 < Li 2 –
hybridisation :-
(3) Li 2 < Li 2 – < Li 2 + (4) Li 2 – < Li 2 < Li 2 + PC −6 ,PC +4 ,IF4− , IF5 ,XeO3 F2 ,IC +2 , SF 2 , SF 6 ,
78. Which of the following compound doesnot exist? +
AsF 4 , SiF 4
(1) PCl 5 (2) OF 6 (3) OF 2 (4) BrF 5
(1) 3 (2) 4 (3) 5 (4) 6
79. Among the following, VWF are maximum in :-
(1) HBr (2) LiBr 88. Number of molecules or ions which has/have
any bond angle of 120° is :-

®
(3) LiCl (4) AgBr
80. Which of the following can not be calculated by CH3− ,CH3⊕ ,NH3 ,CO23− ,BC 3 ,PC 3
Born Haber cycle in the formation of MgO?
(1) 3 (2) 4 (3) 5 (4) 6
(1) Lattice energy of MgO
(2) EA of oxygen 89. The species having diamagnetic nature and bond
(3) Hydration energy of Mg
+2
order 1.0 is :-
(4) I.E. of Mg (1) O22 − (2) O2+ (3) O22 + (4) O 2
81. Which pair is not isomorphous pair ?
90. Which specie doesn't exist ?
(1) Green vitriol, Epsum salt
(2) KNO 3 , CaCO 3 (1) B 2 (2) Be 2
(3) NaF, Na 2 O (3) Li 2 (4) H 2 +
(4) Potash alum, chrome alum 91. Which of the following order is incorrect ?
82. How many compounds show conductivity ?
(1) MCl < MCl 2 < MCl 3 ; Ionic character
HCl(aq), AlCl 3 (molten), AlF 3 (molten), Graphite,
(2) F– < Cl– < Br– < I–; Polarisibility
Na(s), AlCl 3 (aq)
+ +2 +2 +3
(1) 4 (2) 5 (3) 6 (4) 3 (3) Na < Ca < Mg < Al ; Polarising power
83. In which of the following set do all the three (4) LiF < LiCl < LiBr < LiI; Covalent character
compounds have bonds that are mainly ionic? 92. Which is the correct decreasing order of covalent
(1) NaCl, NCl 3 , CCl 4
nature ?
(2) CsBr, BaBr 2 , SrO
(1) SiCl 4 > AlCl 3 > ZnCl 2 > CaCl 2 > MgCl 2
(3) CsF, BF 3 , NH 3
(4) Al 2 O 3 , CaO, SO 2 (2) SiCl 4 > AlCl 3 > MgCl 2 > CaCl 2 > ZnCl 2
84. Which of the following B.P. order is not correct? (3) ZnCl 2 > SiCl 4 > AlCl 3 > MgCl 2 > CaCl 2
(1) SiF 4 < SiCl 4 (4) SiCl 4 > AlCl 3 > ZnCl 2 > MgCl 2 > CaCl 2
(2) CH 4 < SiH 4 < GeH 4 93. Which of the following order is not correct ?
(3) CH 4 < CD 4
(1) CrO < Cr 2 O 3 < CrO 3 (covalent character)
(4) He > Xe
85. Which of the following order is not correct ? (2) ZnO(Philosopher's wool) > ZnS(Zinc blend)
(ionic character)
(1) H 2 O > NH 3 (melting point)
(2) CH 3 –O–CH 3 < C2 H 5 –OH (boiling point) (3) BeCl 2 > MgCl 2 > CaCl 2 > SrCl 2 > BaCl 2
(3) (CH 3 ) 2 SO 4 > H 2 SO 4 (volatility) (ionic character)
(4) HCl > HF (Boiling point) (4) KCl < AgCl (covalent character)

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94. Which of following will not conduct electricity? 103. Which of the following halide can be converted
(1) KOH (aq.) (2) Fused NaCl into anhydrous form on heating ?

(3) Solid KCl (4) Graphite (1) BeCl 2 ·H 2 O (2) KCl·6H 2 O

95. Which of the following statement is not correct? (3) AlCl 3 ·6H 2 O (4) FeCl 3 ·6H 2 O

(1) Ortho nitro phenol can be separated from its 104. Which of the following thermal stability order is
meta and para isomer using its steam volatile not correct ?
property. (1) NaHCO 3 < KHCO 3 < RbHCO 3
(2) HF(s) has zig-zag structure (2) CaO 2 > SrO 2 > BaO 2
(3) HF is more volatile than HCl. (3) Na 2 SO 4 > MgSO 4 > Al 2 (SO 4 ) 3
(4) Ethylene glycol is less viscous than glycerol. (4) CCl 4 > SiCl 4 > GeCl 4 > SnCl 4
96. Which of the following solubility order is not 105. Least stable hydride is :-
correct ? (1) SnH 4 (2) SiH 4

®
(1) MgF 2 < MgCl 2 < MgBr 2 < MgI 2 (3) PbH 4 (4) GeH 4
(2) Be(OH) 2 < Mg(OH) 2 < Ca(OH) 2 < Sr(OH) 2 106. Which of the following compound give metal and
(3) Li 2 O < Na 2 O < K 2 O < Rb 2 O < Cs 2 O oxygen gas at high temp :-
(1) NaNO 3 (2) Ag 2 CO 3
(4) CsF < CsC < CsBr < CsI
(3) K 2 CO 3 (4) Li 2 CO 3
97. If Hunds rule is not applicable then which of the 107. In which of the following species presence of
following specie is paramagnetic ? lone pair does not affect idealized bond angle ?
(1) B 2 (2) N 2
(I) PF 3 (II) BrF 3 (III) IF 5
(3) O 2 –1 (4) O 2 −
(IV) IC 4
(V) XeF 2
98. The salt having least solubility in water :-
(1) I, II, III (2) IV, V
(1) CaSO 4 (2) BeSO 4
(3) II, V (4) None of these
(3) MgSO 4 (4) BaSO 4
108. The incorrect order of bond angle :-
99. The fluoride which is most soluble in water :-
(1) CO 2 > CO 3 –2 > CF 2 Cl 2
(1) CaF 2 (2) BaF 2
(2) NF 3 > NH 3 > NCl 3
(3) SrF 2 (4) BeF 2
(3) NO 2 + > NO 3 – > NO 2 –
100. Which of the following compound will release
brown color gas on heating ? (4) PH 3 > AsH 3 > SbH 3

(1) CaCO 3 (2) NaNO 3 109. Which of the following is correct decreasing
(3) Zn(NO 3 ) 2 (4) NaHCO 3 order of bond length ?

101. Which of the following statement is incorrect? (1) P–O > S–O > Cl–O

(1) AgCl < AgF (solubility in H 2 O) (2) P–O > Cl–O > S–O

(2) KCl < KI (solubility in acetone) (3) S–O > Cl–O > P–O

(3) BeC 2 O 4 < BaC2 O 4 (solubility in H 2 O) (4) Cl–O > S–O > P–O

(4) CaCrO 4 > BaCrO 4 (solubility in H 2 O) 110. Which of the following species are hypervalent?

102. Correct solubility order :- (A) ClO 4 – (B) BF 3

–2
(1) CaCrO 4 > BaCrO 4 (C) SO 4 (D) CO 3 –2
(2) BeCO 3 < BaCO 3 (1) A, B, C (2) C, D
(3) LiNO 3 < CsNO 3 (3) A, C (4) A, B
(4) NaClO 4 < KClO 4

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111. The correct order of increasing C–O bond length 115. Among MgCl 2 , RbCl, BeCl 2 and LiCl. The
of CO, CO 3 –2 and CO 2 is :- compounds with highest and lowest ionic
–2
(1) CO 3 < CO 2 < CO characters are :-
(2) CO < CO 2 < CO 3
–2 (1) RbCl and BeCl 2 (2) MgCl 2 and BeCl 2
–2
(3) CO < CO 3 < CO 2 (3) BeCl 2 and MgCl 2 (4) RbCl and LiCl
–2
(4) CO 2 < CO 3 < CO 116. Which of the following is correct order of dipole
112. The specie having pyramidal shape is :- moment ?
(1) NH 3 > NF 3
(1) OSF 2 (2) BrF 3 (3) ClO 2 –1 (4) SO 3
(2) BF 3 > BCl 3
113. PCl 5 exist but NCl 5 does not because :-
(3) CF 4 > CH 4
(1) Nitrogen atom is much smaller than P
(4) XeF 2 > XeO 3 F 2
(2) NCl 5 is unstable
(3) Nitrogen has no vacant d-orbitals
(4) Nitrogen is highly inert

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114. The correct order of increasing s-character (in
percentage) in the hybrid orbitals of following
molecules/ions is :-
–2
(A) CO 3 (B) NCl 3 (C) BeCl 2
(1) B < A < C (2) A < B < C
(3) C < A < B (4) C < B < A

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans 3 1 2 4 4 4 3 4 3 2 3 4 1 3 4
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans 3 2 1 4 1 3 4 3 2 3 3 2 3 1 3
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans 2 2 4 4 2 2 4 4 2 3 2 2 1 1 4
Que. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans 1 1 1 1 1 3 2 4 3 2 4 3 2 1 4
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans 2 3 1 1 2 1 3 3 3 1 4 1 4 2 2
Que. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans 4 1 2 4 3 3 2 2 4 4 4 3 1 1 2
Que. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105
Ans 1 4 3 3 3 4 3 4 4 3 3 1 2 2 3
Que. 106 107 108 109 110 111 112 113 114 115 116
Ans 2 2 2 1 3 2 1 3 1 1 1

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