Advanced Materials and Processing
Advanced Materials and Processing
Advanced Materials and Processing
COURSE OUTCOME
By the end of semester, students should be able to:
CO1:
Distinguish advanced materials: light-weight alloys,
amorphous alloys, composites, biomaterials, smart materials,
and thin coatings.
CO2:
Explain rapid solidification and casting techniques
for processing light weight alloys, amorphous alloys,
biomaterials, shape memory alloys and reactive alloys.
CO3: Explain powder processing for smart materials and light
weight alloys.
CO4: Distinguish processing techniques for thin coatings and
surface modification.
CO5: Develop and present a process flow of a conceptual
product byconsidering sustainability to the selected product
and process.
Assessme
nt
Assignmen
t
Test
Project
Final Exam
Total
CO1
CO2
CO3
CO4
CO5
10%
30%
20%
40%
100%
Distribution
Topic Contents
Introduction.
Materials Science and Engineering
Classification of Materials
Explain definition and types of advanced
materials and brief history of
engineering materials revolution.
Explain significance of advanced
materials for aerospace and biomedical
applications, high thermal resistance.
and sensor development.
HISTORICAL PERSPECTIVE
10 000 BC 5000 BC
Gold
1000
1500
1800
1900
1940
1960
1980
1990
2000 2010
2020
Copper
Bronze
Iron
METALS
RELATIVE IMPORTANCE
Cast Iron
Glassy Metal
Al - Lithium Alloys Development Slow
Dual Phase Steels Mostly Quality
Micro Alloyed Steels Control and Processing
New Super Alloys
Steels
Wood
Skin
Fibers
POLYMERS,
ELASTOMERS
Alloy Steels
Glues
COMPOSITES
Straw-brick
Stone
Light Alloys
Super Alloys
Rubber
paper
High Temperature
Titanic
Polymers
Zirconium Alloys
Bakelite
High Modulus
Flint
Etc
Polymers
Nylon
c- s
mi site
Pottery
Polyesters
a
r
o
Ce p
Glass
Exposies
C com
PE
M
PMA Arcrylics
Cement
ar-M
evl
P
K
PC
PS
Refractories
R
PP
F
C
CERAMICS
FRP
Portland Cement
GFRP
Fused
Tough Engineering
CermentsPyroSilica
ceramics (Al2O3,Si4,etc)
Ceramics
1800
1900
1940
1960
1980
1990
2000
2010
2020
Evolution of Materials
Understanding of Subject
The relationship among structures,
properties, processing, and
performance of materials
Better understanding of
structure-composition-properties
ENGINEERING
MATERIALS
Mechanical
properties
&
Physical
properties
Properties of Materials
Properties are the way material responds to environmental and external
forces;
Mechanical properties: Response to mechanical forces, strength and etc.
Electrical and magnetic properties: Response to electrical and magnetic
fields, conductivity and etc
Thermal properties are related to transmission of heat and heat capacity
Optical properties include to absorption, transmission and scattering of
lights
Chemical stability in contact with environment corrosion resistance
Metallic Materials
Definition:
Inorganic substances which composed of one or two
metallic elements and may also contain nonmetallic elements.
Properties:
Crystalline structure,
Good thermal and electrical conductors,
Strong and ductile at room temperature,
Good strength at high temperature,
Shiny when polished.
Examples:
Metallic elements:
iron, copper,
aluminium, nickel,
titanium.
Nonmetallic elements:
carbon, nitrogen,
Metals and alloys classification: oxygen.
Ferrous metals and alloys (steels, cast irons)
Nonferrous metals and alloys (aluminium, copper,
zinc, titanium, nickel)
Polymeric Materials
Definition:
Consist of organic long molecular
Chains or networks.
Properties:
Structure: most are crystalline, some are mix.
Vary strength, and ductility.
Poor conductors of electricity
Good insulators
Low density, low softening temperature.
Application example:
Manufacturing of digital video disks (DVDs)
Ceramic Materials
Definition:
Inorganic substances consist of metallic elements
and nonmetallic elements chemically bonded.
There are usually combination of metals or
semiconductor with oxygen, nitrogen or carbon
(oxides, nitrides or carbide).
Properties:
Structure: Crystalline, non-crystalline, mixtures of both.
High hardness, high temperature strength.
Brittle, light weight, high strength.
Good heat and wear resistance, reduced friction.
Insulative properties.
Domestic
Engineering
Industry
Building
Composite Materials
Composite is a material which is made up of two or
more distinct materials (matrix and reinforcement).
Example:
A familiar composite is concrete,
which is basically made up of sand
and cement.
The reinforcement is
usually stiffer than the
matrix, thus stiffening
the composite material.
Types of composite:
PMC, MMC, CMC
Electronic materials-semiconductor
Unique properties :
Capable to alter electrical
conductivities in their surface
chemistries in very localized areas
(E.g. Integrated Circuit).
The conductivity is as good as metals
because no free electron and the
electron valence is full.
ADVANCED MATERIALS:
Pick
Application
2.
Properties
3.
Material
36
Stiffness-Weight Design
Considerations
Example
Stiffer material
Stress
Strain
Engineerin
g
Application
s
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Tendency:
More composite materials
Tailored matieral mix to improve over all systems
performance
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Tmax Tambient
Tmax
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ELASTOMERS
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POLYSULFIDE SEALANTS
Sealants are the true cost
savers throughout an
aeroplanes life
Making the pressurised fuselage
air tight and the integral wing
tank fuel tight is only the most
obvious primary function of a
true but modest champion
Seals crevices to prevent
corrosion due to moisture
entrapment
Releases chromates to prevent
microbial attack in the integral
tank
Chromates also actively inhibit
corrosion in general
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COMPOSITES FOR
PROTOTYPING
Some composites
manufacturing
processes allow
for quick
prototyping at
modest tooling
and production
cost
Ideal for validation
of concept studies
specifically for full
scale aerodynamic
tests
Risk mitigation,
development cost
reduction
PC-21 UWT H-tail fin: 5 days from design to
prototype
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A SPOTLIGHT ON COMPOSITES:
BENEFITS AND CHALLENGES
INTERNAL REFERENCE: MP-00-MI-10-061, ISSUE 1
Challenges
Advantages
Long-term experience
High automation level
Advanced joining technologies
Standardized material
Standard Certification procedure
Fatigue
Corrosion
Subprocesses
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Design
Impact sensitivity
Environmental influences
Material + manufacturing diversity
Certification (not standardized mat.)
High material cost
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UD fabric
Matrix (Polymer)
Woven fabric
Mat
Polymer
Fiber
Carbon
Glass
HTA
HTS
AS4
IMS
T700
T800
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Thermosets
Aramid
Natural
Thermoplastics
Epoxy
PEEK
Bismaleimide
PPS
Cyanesther
PEI
Phenolic
Objective:
Material combination = Design and manufacturing requirem
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MANUFACTURING PROCESS
DIVERSITY
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Process limitations
Laminate quality:
Further considerations:
- Inspection
- Dimensions
- Repair procedure
- Lightning protection
Surface condition
Quantity
Design
Quality control
Process qualification
- Electrical grounding
Interaction
Material properties
Semi-finished products
Material
Costs
Manufacturing
Environmental influences:
- Temperature
- Humidity
Quality control
Availability
Thomann
U.
Price
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CERTIFICATION
Composite
Metal
Proof Tests
Aircraft-specific specimens
Demonstrate ultimate load or
fatigue capability
Include defects, damage,
environmental effects
Validate Design
Same as composite
Material Tests
Generic specimens
Determine material
data
Understand
deformations and
failure modes
Establish Design
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No tests due to
standardized material
and long-term
experience
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CERTIFICATION
E.g. coupons tests:
Mechanical properties, e.g.:
Laminate: Strength and stiffness etc. in tension, compression and shear.
Engineering data: Strength in tension and compression with and without
holes; bearing strength; Compression After Impact strength
Physical properties, e.g.:
Density, glass transition temperature Tg, volume fraction, cured ply
thickness
Environmental influences, e.g.:
From -55C to +55C OAT in dry and wet conditions
Contaminations (hydraulic fluid, jet fuel, solvents, paint stripper)
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QUALITY CONTROL
Mechanical
Manufacturing control
Process
coupons tests
control
Component testing
Visual
inspection
Dimension
Ultrasonic
Mechanical
process
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SUMMARY
Deep knowledge of the present state of the
art in each class of materials is essential
There is no right or wrong material
selection; it is rather a complex decision
making process depending on
OEMs design and manufacturing skill and
experience level
Requirements
Balance of value and cost
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Advanced Machining
Processes
Chemical Milling
Photochemical Blanking
Electrochemical Machining
Pulsed Electrochemical Machining
Electrochemical Grinding
Electrical-Discharge Machining
Electrical-Discharge Grinding
Electrical-Discharge Wire Cutting
Laser-Beam Machining
Electron Beam Machining
Plasma Arc Cutting
Water Jet Machining
Abrasive Water Jet Machining
Abrasive Jet Machining
Examples of Parts
Chemical Milling
Produces shallow cavities on a
workpiece, usually to reduce weight
The area affected by the chemical
reagent is controlled by masking or
by partial immersion
Chemical Milling
Chemical Milling
Procedure:
1. Relieve residual stresses to prevent warping
2. Clean the material surface
3. Apply masking material
4. Remove the masking on regions that require
etching
5. Apply the reagents
6. Wash the part
7. Remove remaining masking
8. Additional finishing or chemical milling
procedures may be used
Photochemical Blanking
Uses chemicals and photographic
processes to remove material,
usually from a thin sheet
Can produce complex shapes on
metals as thin as .0025 mm without
forming burrs
Photochemical Blanking
Examples of Parts
Photochemical Blanking
Procedure:
1. Prepare the design at a magnification of up
to 100x; make a photographic negative and
reduce it to the size of the part
2. Coat the blank with photosensitive material
3. Place the negative over the part and
expose it to ultraviolet light to harden the
exposed photosensitive coating
4. Dissolve the unexposed coating
5. Apply the chemical reagent
6. Remove the masking and wash the part
Chemical Machining
Design Considerations:
- Avoid sharp corners, deep narrow cavities,
steep tapers, folded seams and porous
workpieces
- Undercuts may develop
- Most of the workpiece should be shaped by
other processes to speed production
- Variations may occur depending onhumidity
and temperature
- Computerized designs must be converted to
a format compatible with the photochemical
artwork equipment
Electrochemical Machining
Uses an electrolyte and electrical current
to ionize and remove metal atoms
Can machine complex cavities in highstrength materials
Leaves a burr-free surface
Not affected by the strength, hardness or
toughness of the material
Electrochemical Machining
Electrochemical Machining
Electrochemical Machining
Design Considerations:
- The electrolyte erodes away sharp
profiles
- It is difficult to control electrolyte
flow; irregular cavities may not be
formed accurately
- Allow for small taper in holes made
this way
Pulsed Electrochemical
Machining
A form of electrochemical machining;
the current is pulsed to eliminate the
need for high electrolyte flow
Improves fatigue life of the part
Electrochemical Grinding
Uses a rotating cathode embedded with
abrasive particles for applications
comparable to milling, grinding and
sawing
Most of the metal removal is done by the
electrolyte, resulting in very low tool wear
Adaptable for honing
Electrochemical Grinding
Electrochemical Grinding
Design Considerations:
(in addition to those for
electrochemical machining)
- Avoid sharp inside radii
- Flat surfaces to be ground should be
narrower than the width of the
grinding wheel
Electrical-Discharge
Machining
Uses a shaped electrode and electric
sparks to remove metal; discharges
sparks at about 50-500 kHz
A dielectric (nonconductive) fluid removes
debris and acts as an insulator until the
potential difference is high enough
Can be used on any material that
conducts electricity
Electrical-Discharge
Machining
Electrical-Discharge
Machining
Electrical-Discharge
Machining
Design Considerations:
- Design parts so that the electrodes
can be made economically
- Avoid deep slots and narrow openings
- Do not require very fine surface finish
- Most of the material removal should
be done by other processes to speed
production
Electrical-Discharge
Grinding
The grinding wheel lacks abrasives and
removes material by electrical
discharges
Can be combined with electrochemical
grinding
Can be used for sawing, in which the saw
has no teeth
Electrical-Discharge Wire
Cutting
The wire moves through the workpiece
like a band saw, removing material by
electrical discharge
Dielectric fluid is applied to the work area
The wire is generally used only once; it is
inexpensive
Electrical-Discharge Wire
Cutting
Electrical-Discharge Wire
Cutting
Electrical-Discharge Wire
Cutting
Electrical-Discharge Wire
Cutting
Electrical-Discharge Wire
Cutting
Laser-Beam Machining
Uses a concentrated beam of light to
vaporize part of the workpiece
Usually produces a rough surface with
a heat-affected zone
Can cut holes as small as .005 mm
with depth/diameter ratios of 50:1
Laser-Beam Machining
Laser-Beam Machining
Laser-Beam Machining
Laser-Beam Machining
Design Considerations:
- Non-reflective workpiece surfaces are
preferable
- Sharp corners are difficult to
produce; deep cuts produce tapers
- Consider the effects of high
temperature on the workpiece
material
Summary
Advanced machining processes offer
alternatives where conventional
procedures would be insufficient or
uneconomical