Ee1electrolysis Process

Electro – dialysis
• Electro-dialysis is an electro membrane process

in which ions are transported through ion
permeable membranes from one solution to
another under the influence of a potential
gradient
The ion permeable membranes used in electro

dialysis are essentially sheets of ion-exchange
Resins
• A typical ED system includes a membrane
stack with a number of cell pairs, each
consisting of a cation transfer membrane, a
demineralized flow spacer, an anion transfer
membrane, and a concentrate flow spacer.
Compartments for the electrodes are at
opposite ends of the stack. The electrodes are
continually flushed to reduce fouling or
scaling.
 A dc potential applied across the stack,
causes ; the positive and negative ions to
migrate in opposite directions.
 In all practical electrodialysis processes,

multiple electrodialysis cells are arranged into
a configuration called an electrodialysis stack
 a cation-exchange membrane would have
negatively charged groups (e.g., -SO3-)
 anion membrane would have positively

charged groups (e.g. Na+)
 Cation exchange membranes permit passage only of

positive ions, under the influence of electric field
 while anion exchange membranes permit passage

only of negatively charged ions.
Electro dialysis Cells
• The cell consists of a
feed (diluate)
compartment and a
concentrate (brine)
compartment
• An anion exchange
membrane and a cation
exchange membrane
placed between two
electodes.
• Contents
 1) Method
 2)Anode and Cathode Reactions
 3)Efficiency
 4)Applications
 5)Limitations
 Method =

 In an electro-dialysis stack, the diluate (D)
feed stream, brine or concentrate (C) stream,
and electrode (E) stream are allowed to flow
through the appropriate cell compartments
formed by the ion exchange membranes.
 Under the influence of an electrical potential

difference, the negatively charged ions (e.g.,
chloride) in the diluate stream migrate toward
the positively charged anode.
 therefore stay in the C stream, which becomes
concentrated with the anions.
 The positively charged species (e.g., sodium)

in the D stream migrate toward the negatively
charged cathode and pass through the
negatively charged cation exchange
membrane.
 These cations also stay in the C stream,
prevented from further migration toward the
cathode by the positively charged anion
exchange membrane.
 As a result of the anion and cation migration,
electric current flows between the cathode and
anode.
 Only an equal number of anion and cation
charge equivalents are transferred from the D
stream into the C stream and so the charge
balance is maintained in each stream.
 The overall result of the electro-dialysis
process is an ion concentration increase in the
concentrate stream with a depletion of ions in
the diluate solution feed stream
Anode and Cathode Reactions
 Reactions= take place at each electrode.

At the cathode,
2e- + 2 H2O → H2 (g) + 2 OH-
while at the anode,
H2O → 2 H+ + ½ O2 (g) + 2e- or 2 Cl- → Cl2 (g)
+ 2e-
 Small amounts of hydrogen gas are generated
at the cathode
 small amounts of either oxygen or chlorine

gas (depending on composition of the E stream
and end ion exchange membrane arrangement)
at the anode.
Efficiency
 Efficiency =
Current efficiency is a measure of how effective
ions are transported across the ion exchange
membranes for a given applied current.
 Typically current efficiencies >80% are

desirable in commercial stacks to minimize
energy operating costs.
 . Low current efficiencies indicate water
splitting in the diluate or concentrate streams
Where ,
• ξ = current utilization efficiency

• z = charge of the ion
• F = Faraday constant, 96,485 Amp-s/mol
• Qf= diluate flow rate, L/s
• = diluate ED cell inlet concentration,
mol/L
• = diluate ED cell outlet concentration,
mol/L
• N = number of cell pairs
• I = current, Amps.
Applications
 electro-dialysis systems can be operated as
continuous production or batch production
processes
 Electro-dialysis is usually applied to

deionization of aqueous solutions.
• Large scale brackish and seawater
desalination and salt production.
• Small and medium scale drinking water

production (e.g., towns & villages, construction
& military camps, nitrate reduction, hotels &
hospitals)
• Food processing
• Water reuse (e.g., industrial laundry wastewater,
produced water from oil/gas production, cooling
tower makeup & blow down, metals industry
fluids, wash-rack water)
• Pre-demineralization (e.g., boiler makeup &

pre-treatment, ultrapure water pretreatment,
process water desalination, power generation,
semiconductor, chemical manufacturing, food
and beverage)
• Agricultural water (e.g., water for
greenhouses, hydroponics, irrigation, livestock)
• Glycol desalting (e.g., antifreeze / engine-
coolants, capacitor electrolyte fluids, oil and
gas dehydration, conditioning and processing
solutions, industrial heat transfer fluids,
secondary coolants from heating, venting, and
air conditioning (HVAC))
• Glycerine Purification
Limitations
 Electro-dialysis has inherent limitations,
working best at removing low molecular
weight ionic components from a feed stream
 Non-charged, higher molecular weight, and

less mobile ionic species will not typically be
significantly removed.
 Also, in contrast to RO, electro-dialysis
becomes less economical
 efficiency typically decreases as the feed salt

concentration becomes lower
Waste Disposal
The concentrate waste stream, electrode
cleaning flows, and residuals from the
pretreatment process will be a part of a
typical waste stream flow and will require
disposal. Common disposal methods include:
surface water discharge, evaporation ponds,
etc. Spent membranes will also require
disposal.
References
 www.google.co.in
 www.wikipedia.org
 Hazardous Waste processing technology
 DRINKING WATER – SPECIFICATION (IS 10500)
 www.water.siemens.com
 www.lenntech.com/electrodialysis
 www.thewatertreatments.com

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Electro – dialysis

• Electro-dialysis is an electro membrane process

The ion permeable membranes used in electro

 In all practical electrodialysis processes,

 anion membrane would have positively

 Cation exchange membranes permit passage only of

 while anion exchange membranes permit passage

 Under the influence of an electrical potential

 The positively charged species (e.g., sodium)

 Reactions= take place at each electrode.

 small amounts of either oxygen or chlorine

 Typically current efficiencies >80% are

• ξ = current utilization efficiency

 Electro-dialysis is usually applied to

• Small and medium scale drinking water

• Pre-demineralization (e.g., boiler makeup &

 Non-charged, higher molecular weight, and

 efficiency typically decreases as the feed salt

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