Haloalkenes and Haloarenes

Download as pptx, pdf, or txt
Download as pptx, pdf, or txt
You are on page 1of 6

HALOALKENES AND HALOARENES

By Amishee Sood
What are Haloalkenes and Haloarenes?
 Haloalkanes and haloarenes are the hydrocarbons in
which one or more hydrogen atoms have been replaced
with halogen atoms (fluorine, chlorine, bromine, iodine,
and astatine). 
 The primary difference between haloalkanes and
haloarenes is that haloalkanes are derived from open-
chain hydrocarbons (alkanes) whereas haloarenes are
derived from aromatic hydrocarbons (Methylbenzene,
Naphthalene, Phenanthrene, Trinitrotoluene, and o-
dihydroxybenzene).
Overview of Haloalkenes and Haloarenes
 Haloalkanes are commonly referred to as alkyl halides whereas haloarenes are
commonly referred to as aryl halides. These compounds can contain multiple
halogen atoms, as illustrated below.

 Generally, the halogens are attached to sp 3 hybridized carbon atoms in these
compounds. The presence of halogens makes haloalkanes and haloarenes more
chemically reactive than the parent alkanes and aromatic compounds. These
compounds have many medicinal uses as well.
Classification of Haloalkanes and Haloarenes

Alkyl halides and aryl halides can be classified based on the


following parameters:
 Number of halogen atoms in the molecule
 sp3 hybridized carbon-halogen bond.
 sp2 hybridized carbon-halogen bond.
Monohaloalkanes and Contain 1 halogen atom
Monohaloarenes
Classification based on the Dihaloalkanes and Dihaloarenes 2 halogen atoms are attached
number of halogen atoms.
Trihaloalkanes and Trihaloarenes Contain 3 halogen atoms

Alkyl Halide Halogen is attached to an alkyl


Haloalkanes and haloarenes in chain.
which the halogen is attached to Allylic Halide The halogen atom is attached to
an sp3 hybridized carbon. an sp3 hybridized carbon which is
adjacent to C=C (double bond or
sp2 hybridized carbon)
Benzylic Halide The halogen is attached to an
sp3 hybridized carbon which is
attached to a benzene ring
Vinyl Halide The halogen atom is attached to
Compounds in which the halogen C=C (sp2 hybridized carbon).
is attached to a sp2 hybridized Aryl Halide The halogen is attached to a
carbon sp2 hybridized carbon which
belongs to an aromatic ring.
Uses of Haloalkanes and Haloarenes
Some important applications of these compounds are listed below.
 These organic compounds can dissolve non-polar compounds and are
therefore used as solvents.
 Many derivatives of alkyl and aryl halides are used in medicine. One such
example is the compound chloramphenicol, which is used to treat cases
of typhoid.
 Another example is chloroquine, which is very useful in the treatment of
malaria.
 They are also used as insecticides (DDT).
Some haloalkanes and haloarenes have adverse effects on the environment
and are labelled as pollutants. One such example is chlorofluorocarbons (or
CFCs), which lead to the depletion of the ozone layer which protects the
Earth from the harmful radiation coming from the sun.