Mass Spectrometry
Mass Spectrometry
Mass Spectrometry
Base Peak
MS of n-Pentane
MS of Isopentane
MS of n-Pentane MS of Isopentane
Isotope Peaks: [M+1]
[M+2]
Calculating the Relative Abundance of
Isotope Peaks
Calculating the Relative Abundance of
Isotope Peaks
Applications of Isotope Peaks
(i) To calculate the number of CARBON atoms
MS of n-Pentane MS of Isopentane
Rules For Fragmentation in MS
Rules For Fragmentation in MS
Rules For Fragmentation in MS
Rules For Fragmentation in MS
Rules For Fragmentation in MS
Rules For Fragmentation in MS
Rules For Fragmentation in MS
McLafferty Rearrangement
McLafferty Rearrangement
Arene
MS of NAPHTHALENE C10H8
MS of CYCLOHEXANE C6H12
MS OF MYRCENE
Alkyl Halide
Intensities of isotopic peaks
(Relative to the Molecular ion peak)
for combinations of Bromine and Chlorine
MS Ethyl sec-butyl ether
MS of Isomers of Pentanol
MS of o-Ethylphenol
MS of Nonal
MS of p-Chlorobenzophenone
MS of Hexanoic acid
MS of METHYL OCTANOATE
IONIZATION TECHNIQUES
The excess carrier gas is ionized by electron impact to the primary ions
CH4.+ and CH3+. These react with the excess methane to give secondary
ions.
Field Desorption (FD)
Stable molecular ions are obtained from a sample of low volatility, which is
placed on the anode of a pair of electrodes, between which there is an intense
electric field.
Desorption occurs, and molecular and quasimolecular ions are produced with
insufficient internal energy for extensive fragmentation.