3intermolecular Forces of Attraction

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Intermolecular

Forces
Mr. Rommell B. Gutoman
Intermolecular Forces of Attraction

Forces of Weak compared


attraction or to intramolecular
Intramolecular
repulsion which forces such as the
forces are forces
act between covalent or ionic
that hold atoms
neighboring bonds between
together.
particles (atoms, atoms in a
molecules, ions) molecule
Types of Intermolecular Forces
• 1. Ion-Dipole
• 2. Dipole-Dipole
• 3. Hydrogen-Bonding
• 4. Van der Waals Forces (Van der Waals) or London Dispersion
Ion-Dipole

• Ions interact with the dipole molecule or polar


covalent molecule
Dipole-Dipole
• Attractive forces between the positive end of one polar molecule and
the negative end of another polar molecule
Hydrogen Bonding
• Forms a special type of dipole-dipole attraction when a hydrogen atom
is bonded to a strongly electronegative atom
• Stronger than dipole-dipole and dispersion forces but weaker than
covalent and ionic bonds
Hydrogen Bonding
Van der Waals Forces or London Dispersion
• Attraction of intermolecular forces between molecules
• Weakest of all intermolecular forces
• Any substance can do this type of attraction
• Creates a momentary dipole which will attract an induced dipole
• Also happens in stable elements (group 8)
Van der Waals Forces or London Dispersion
Strongest Intermolecular Force

• 1. Ion-Dipole
• 2. Hydrogen Bonding
• 3. Dipole-Dipole
• 4. Van der Waals (London Dispersion)
Force Type of Interaction Occurrence

ole Summary
Attraction between ions Ion and polar molecules
and dipole or polar
molecules
en Bonding Attraction between two Polar molecules containing
dipoles, one containing H- unpaired electrons and a
bonds hydrogen bonded to N, O
or F
Dipole Attraction between polar Polar molecules
molecules which are
permanent dipoles on one
another
Dispersion Force Attraction between a All atoms and molecules
r Waals) temporary dipole including nonpolar
(momentary dipole) and molecules and stable
another temporary dipole elements
(induced dipole) by the

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