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BIOFUEL
BIOFUEL
Biologically based fuels- produced biologically (from biological materials and by
biological agents and processes). Biofuels are obtained by fermentation of plant materials by microorganisms N.B. Fossil fuels have caused great damage to our ecosystems, and the need to become independent of fossil fuels is a critical environmental issue which accelerated the use of biofuels Another research area is degrading cellulose and hemicellulose in to monosaccharides. This is being done by heating the plant material and treating it by acids. However, this is both expensive and corrosive. Biogas production Biogas is a methane rich fuel gas produced by anaerobic breakdown or digestion of biomass with the help of methanogenic bacteria or methanogens. Methanobacterium is a common methanogenic bacteria. Biogas is made up of methane (50-70%), carbon dioxide (30-40%) with traces of nitrogen, hydrogen sulphide and hydrogen. 50% of the combustible energy present in the organic waste can be changed into methane gas. The energy released from biogas depends upon the proportion of methane present in it. The calorific value of biogas is 23-28 MJ/m3. As the biogas production is an anaerobic process, it is carried out in an air tight, closed cylindrical concrete tank called a digester. The tank has a concrete inlet basin on one side for feeding fresh cattle dung. There is a concrete outlet on the outer side for removing the digested sludge. The top of the tank serves as the gas tank. It has an outlet pipe for the biogas. Biogas generation is a three-stage anaerobic digestion of animal and other organic wastes. The latter consist of lignin, cellulose, hemicellulose, lipids and proteins. Lignin cannot be broken down under anaerobic conditions. Cellulose digestion is slower than that of other substances. In the first stage of anaerobic digestion (solubilisation), facultative anaerobic decomposer microbes bring about enzymatic breakdown of complex organic compounds into simpler and soluble compounds often called ‘monomers’. For this, the decomposer microbes secrete cellulases, proteases and lipases (cellulolytic, proteolytic and lipolytic enzymes). In the second stage (acidogenesis), the simple soluble compounds of microbial digestion or monomers are acted upon by fermentation causing microbes. The latter change the monomers into organic acids. Organic acids, especially acetic acid, are acted upon by methanogenic bacteria in the third or final stage (methanogenesis). The methane bacteria convert organic acids as well as carbon dioxide into methane. The biogas thus formed is stored in tanks for supply. advantages of biogas Using organic wastes first for biogas generation has following advantages over their direct use as fuel or fertiliser: (i) It provides both energy and manure. (ii) Biogas has wider applications than the direct burning of organic wastes. (iii) The energy value of biogas is lower than that of organic matter but due to more efficient handling, the net energy output is roughly equal to the output in direct burning of organic wastes. (iv) Minimises the chances of spread of faecal pathogens. (v) The fertiliser value of the manure produced in biogas plants is similar to that of manure formed directly from organic wastes. (vi) Biogas use does not add to pollution. Ethanol-based biofuel or Bioethanol Bioethanol is an alcohol made by fermentation from carbohydrates, sugar or starch crops such as corn or grain, sugarcane, potato, molasses, fruit wastes, or cellulose. The alcohol is then distilled to separate pure ethanol. Pure ethanol can be used as fuel to run vehicles. For car engines, special engine modification is needed to use pure ethanol as fuel. But it is usually used as a gasoline additive. it can be mixed with gasoline to any percentage Brazil, Zimbabwe and the USA produce ethanol as a renewable source of energy for the motor car. Advantages and disadvantages of ethanol-based fuels Advantages The advantages of bioethanol fuel are: It is efficient energy source It is a renewable resource and that produces less pollution than petrol- doesn’t produce toxic gases when burned Much less polluting than fossil fuels which produce CO2, SO2 and nitrogen oxides Can be mixed with petrol to make a fuel known as gasohol. This is increasingly being done and reduces pollution. Disadvantages The biggest problem in using plant-based fuels for cars is that it takes a lot of plant materials to produce ethanol. Because of this, it is limited to countries that have large space and suitable climate to grow plants. The main problem in many countries is finding enough ethanol. for example, if people in Europe add 5% ethanol to their fuel, it would reduce CO2 emission but would need 7.5 million liters of ethanol per year which they can’t produce themselves
Biodiesel Biodiesel is produced from animal fats, vegetable oils, or recycled greases that are acted up on by microorganisms