Designation: D 167 93 (Reapproved 1999)

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An American National Standard
Standard Test Method for
Apparent and True Specic Gravity and Porosity of Lump
Coke
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This standard is issued under the xed designation D 167; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
e
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NOTESections 15, 16.1.1, and 16.1.2 were editorially changed in September 1999.
1. Scope
1.1 This test method describes the determination of apparent
specic gravity (Sections 2 to 9) and true specic gravity
(Sections 10 to 13) of lump coke larger than 25-mm (1-in.) size
and calculating porosity (Section 14) from the specic gravity
data.
1.2 The values given in SI units shall be regarded as the
standard. Inch-pound units shall be accepted on an equivalent
basis.
1.3 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use.
APPARENT SPECIFIC GRAVITY
2. Referenced Documents
2.1 ASTM Standards:
D 121 Terminology of Coal and Coke
2
D 346 Practice for Collection and Preparation of Coke
Samples for Laboratory Analysis
2
D 4621 Guide for Accountability and Quality Control in the
Coal Analysis Laboratory
2
E 11 Specication for Wire-Cloth Sieves for Testing Pur-
poses
3
E 323 Specication for Perforated-Plate Sieves for Testing
Purposes
3
3. Signicance and Use
3.1 Apparent and true specic gravity, as determined by this
test method, are inuenced by the type of coals carbonized and
the operating and preparational conditions of that carboniza-
tion, that is, charge bulk density, heating rate, and pulverization
level. In turn, these properties directly inuence the perfor-
mance in processes using coke.
4. Apparatus
4.1 The apparatus for the determination of the apparent
specic gravity of coke shall consist of the following:
4.1.1 An Elliptical or Rectangular Cross-Sectioned Con-
tainer, approximately 560 mm (22 in.) in length, 280 mm (11
in.) in width, and a minimum of 330 mm (13 in.) in height,
provided with a spout consisting of a short 13-mm (
1
2-in.)
nipple extending horizontally from the container about 270 mm
(10
1
2 in.) above the bottom.
4.1.2 Wire Cage or Basket, of about 13-mm (
1
2-in.) square-
mesh screen wire cloth provided with a cover and two long
handles, suitable for holding the entire sample of coke and so
made as to t inside the container below the spout.
4.1.3 Bucket or Other Vessel, 11-L (3-gal), suitable for
receiving the displaced water.
4.1.4 Pan, about 380 mm (15 in.) square and 76 mm (3 in.)
in height or the equivalent for containing the coke during the
determination of its weight.
4.1.5 Balance, sensitive to 0.05 kg (0.1 lb).
5. Sampling at Source
5.1 When the porosity test is desired on run-of-oven coke,
the sample shall be collected from the coke wharf.
5.1.1 By-Product CokeAbout 23 kg (50 lbs) of represen-
tative pieces of coke shall be selected from the coke wharf for
each test. This is best accomplished by dividing the coke on the
wharf into approximately equal areas and selecting an equal
number of pieces from each area. Each piece of coke selected
shall be approximately equal in length to one half of the width
of the coke ovens, and shall show a cauliower end produced
at the walls of the ovens, and an inner end produced at the
center of the ovens.
6. Sampling at Delivery
6.1 If the porosity test is desired on coke for furnace or
cupola use, the sample shall be representative of the material in
question and collected at the place of delivery.
6.1.1 By-ProductThe sample is best collected as the coke
is delivered from the railroad cars into the bins. This can be
accomplished by securing a representative sample of 4.5- to
6.8-kg (10- to 15-lbs) capacity in the coke stream at regular
intervals during the period of unloading. The sample collected
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This test method is under the jurisdiction of ASTM Committee D-5 on Coal and
Coke and is the direct responsibility of Subcommittee D05.15 on Metalurgical
Properties of Coal and Coke.
Current edition approved Jan. 15, 1993. Published April 1993. Originally
published as D 167 23 T. Last previous edition D 167 73 (1979).
2
Annual Book of ASTM Standards, Vol 05.06.
3
Annual Book of ASTM Standards, Vol 14.02.
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Copyright ASTM, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959, United States.
shall be large enough to give about 23 kg (50 lbs) of coke
pieces, none of which would in any position pass through a
25-mm (1-in.) square-mesh sieve.
NOTE 1Since the cage or basket is of 13-mm (
1
2-in.) square-mesh
screen wire cloth, it is necessary to have pieces that will remain in the cage
when it is removed from the water.
6.1.2 Since it is very difficult to collect a representative
sample from coke exposed in bins and cars, care shall be taken
to take pieces representing the entire exposed area, if sampling
must be done in this manner. It is best accomplished by
dividing the exposed surface to be sampled into approximately
equal areas, and selecting an equal number of pieces from each
area. A 23-kg (50-lbs) sample of representative pieces shall be
collected, none of which shall in any position pass through a
25-mm (1-in.) square-mesh sieve.
7. Calibration
7.1 Calibrate the Hogarth specic gravity bottle to deter-
mine the mass of the bottle and the distilled water required to
ll it (variable P). This can be done by (1) constructing a table
graph of actual mass measurements of the bottle lled with
distilled water at various temperatures or (2) using the data in
the tables of corrections for determining the true capacities of
glass vessels from the mass of water in air (Lange or CRC
Handbooks).
8. Procedure
8.1 Select about 11.4 kg (25 lbs) of coke from the sample so
that it is representative of the material under consideration with
regard to size, shape, and general appearance. Dry the coke to
constant mass at a temperature of from 105 to 200C. Weigh
the coke when cool, after shaking and brushing off any
adhering dust.
8.2 Place a cork in the spout of the container, which has
been placed on a level and rigid base or oor. After the empty
cage has been placed into the container, pour water at room
temperature into the container until the water level is above the
spout. After the water has come to rest, remove the cork from
the spout and permit the excess water to drain out for 1 min
after the overow stream starts to discharge drop by drop. Then
replace the cork and remove the cage from the water, care
being taken to shake all adhering water back into the container.
Then place the weighed dried coke sample into the cage and
after fastening the cover, lower the cage containing the coke
into the water.
NOTE 2If there is not sufficient capacity in the container above the
spout to retain the displaced water, some of the water may be drawn off
into a weighed bucket, or other suitable vessel, by removing the cork from
the spout while the coke is being lowered.
8.3 Permit the cage to remain in the water for 15 min, with
occasional shaking to detach any air bubbles adhering to the
surface of the coke, care being taken not to disturb the position
of the container. At the end of the 15-min period, during which
the coke shall have been completely submerged at all times,
remove the cork after the water has come to rest and permit the
displaced water to drain into a weighed bucket or other suitable
vessel for 1 min after the overow stream starts to discharge
drop by drop. Replace the cork, remove the cage containing the
coke from the water and permit it to drain for 1 min. Remove
the wet coke from the cage and weigh it.
8.4 Determine the mass of the displaced water, which has
been caught in the bucket.
9. Calculation
9.1 Calculate the apparent specic gravity as follows:
Apparent specic gravity 5 A/@B 1 ~C 2 A!#
where:
A 5 mass of dry coke,
B 5 mass of water displaced by wet coke, and
C 5 mass of wet coke.
TRUE SPECIFIC GRAVITY
10. Apparatus
10.1 The apparatus for the determination of the true specic
gravity of coke passing a 75-m (No. 200) sieve shall consist
of a Hogarths specic gravity bottle with side tubulure, having
a capacity of about 100 mL.
11. Sample Preparation
11.1 Select about 4.5 kg (10 lbs) of coke from the sample
(see Section 5) so that it is representative of the material under
consideration with regard to size, shape, and general appear-
ance. Crush the coke to pass through a 6.3-mm (
1
4-in.) screen
and split the sample size to about 2.3 kg (5 lbs). Crush this
fraction to pass through a 850-m (No. 20) sieve and further
split the sample to approximately 200 g. Grind the 200-g
fraction to pass through a 250-m (No. 60) sieve and split the
sample size to approximately 50 g. Pulverize this entire
fraction to minus 75-m (No. 200) and dry for 1 h at 105C.
NOTE 3It may be necessary to dry the sample before crushing or
pulverizing during the sample preparation.
NOTE 4Equipment used for reducing the sample particle size and
quantity is described in Method D 346. In all cases, care must be taken to
select equipment that will not abrade and add unwanted impurities to the
sample during the size-reduction steps.
12. Procedure
12.1 Carefully introduce a 10-g portion of 75-m (200-
mesh) coke, which has been previously dried for 1 h at 105C,
into the specic gravity bottle with a sufficient quantity of
distilled water to ll the bottle about one half full. Bring to a
boil, keeping the contents boiling for 1 h. Shake the specic
gravity bottle frequently so as to wash down any coke adhering
to the sides. Remove the bottle from the plate, after boiling for
1 h, ll it to the tubulure with recently boiled and cooled
distilled water, and insert the stopper. Permit the bottle to stand
until the contents have cooled to room temperature (Note 5);
then ll the bottle to slightly above the mark on the capillary of
the stopper with recently boiled distilled water which has been
cooled to room temperature (Note 6). Adjust the water level to
the mark on the capillary by touching a piece of lter paper to
the end of the tubulure. Then wipe the bottle dry and weigh it
immediately. Immediately after the weighing, remove the
stopper and take the temperature of the contents. This tempera-
ture is used to determine the exact capacity of the Hogarth
bottle (10.1).
D 167
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NOTE 5Cooling may be hastened by placing the bottle in water.
NOTE 6This is conveniently done by inserting the end of the tubulure
in a small beaker of the distilled water and applying a slight suction on the
stopper.
13. Calculation
13.1 Calculate the true specic gravity as follows:
True specic gravity 5 W/@W 2 ~W8 2 P!#
where:
W 5 mass of dry coke,
W8 5 mass of the bottle and the dry coke and water required
to ll it, and
P 5 mass of the bottle and the dry coke and water required
to ll it.
POROSITY
14. Calculation
14.1 Calculate the porosity (percentage of cell space) of
lump coke from the apparent specic gravity of the moisture-
free lump coke and the true specic gravity of the moisture-
free coke passing a 75-m (No. 200) size, as follows:
Porosity 5 100 2 100 ~apparent sp. gr./true sp. gr.! (1)
15. Report
15.1 Apparent specic gravity and true specic gravity shall
be reported to the nearest 0.01. Porosity is reported to the
nearest whole percent.
16. Precision and Bias
16.1 Both Specic Gravity Methods:
16.1.1 RepeatabilityDuplicate results by the same opera-
tor should be considered suspect if they differ by more than
0.01.
16.1.2 ReproducibilityResults submitted by each of two
laboratories should be considered suspect if they differ by more
than 0.01.
16.1.3 BiasSince these test methods are empirical stan-
dards, the degree of their absolute bias cannot be determined.
17. Keywords
17.1 apparent specic gravity; coke; porosity; true specic
gravity
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D 167
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