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    KINETiKA ADSORPSI ISOTERMAL p-KAROTEN DARI OLEIN SAWIT KASAR DENGAN MENGGUNAKAN BENTON IT

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    This document discusses a study on the isothermal adsorption kinetics of β-carotene from crude palm olein using bentonite. The objectives were to determine the equilibrium conditions, adsorption rate constant (k), and activation energy (Ea) of β-carotene adsorption using bentonite and activated carbon. Bentonite reached equilibrium faster with a lower β-carotene concentration in olein than activated carbon. The Freundlich isotherm model fit well for both adsorbents. The adsorption rate constant (k) increased with temperature. The activation energy was lower for activated carbon (30.04 kcal/mol) than bentonite (74.28 kcal/mol),

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    KINETiKA ADSORPSI ISOTERMAL p-KAROTEN DARI OLEIN SAWIT KASAR DENGAN MENGGUNAKAN BENTON IT

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    fikosanin
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    This document discusses a study on the isothermal adsorption kinetics of β-carotene from crude palm olein using bentonite. The objectives were to determine the equilibrium conditions, adsorption rate constant (k), and activation energy (Ea) of β-carotene adsorption using bentonite and activated carbon. Bentonite reached equilibrium faster with a lower β-carotene concentration in olein than activated carbon. The Freundlich isotherm model fit well for both adsorbents. The adsorption rate constant (k) increased with temperature. The activation energy was lower for activated carbon (30.04 kcal/mol) than bentonite (74.28 kcal/mol),

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    KINETiKA ADSORPSI ISOTERMAL p-KAROTEN DARI OLEIN SAWIT KASAR DENGAN MENGGUNAKAN BENTON IT

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    This document discusses a study on the isothermal adsorption kinetics of β-carotene from crude palm olein using bentonite. The objectives were to determine the equilibrium conditions, adsorption rate constant (k), and activation energy (Ea) of β-carotene adsorption using bentonite and activated carbon. Bentonite reached equilibrium faster with a lower β-carotene concentration in olein than activated carbon. The Freundlich isotherm model fit well for both adsorbents. The adsorption rate constant (k) increased with temperature. The activation energy was lower for activated carbon (30.04 kcal/mol) than bentonite (74.28 kcal/mol),

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    56 views1 page

    KINETiKA ADSORPSI ISOTERMAL p-KAROTEN DARI OLEIN SAWIT KASAR DENGAN MENGGUNAKAN BENTON IT

    Uploaded by

    fikosanin
    This document discusses a study on the isothermal adsorption kinetics of β-carotene from crude palm olein using bentonite. The objectives were to determine the equilibrium conditions, adsorption rate constant (k), and activation energy (Ea) of β-carotene adsorption using bentonite and activated carbon. Bentonite reached equilibrium faster with a lower β-carotene concentration in olein than activated carbon. The Freundlich isotherm model fit well for both adsorbents. The adsorption rate constant (k) increased with temperature. The activation energy was lower for activated carbon (30.04 kcal/mol) than bentonite (74.28 kcal/mol),

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    KINETiKA ADSORPSI ISOTERMAL p-KAROTEN

    DARI OLEIN SAWIT KASAR DENGAN MENGGUNAKAN BENTON IT

    KINETICS OF ISOTHERMAL ADSORPTION OF P-CAROTENE FROM CRUDE PALM OLEIN

    USING BENTONITE

    Muslich, Prayoga Suryadarma dan R. Indri R. Hayuningtyas


    Departemen Teknologi Industri Pertanian, Fakultas Teknologi Pertanian, Institut Pertanian Bogor

    Kampus IPB Darmaga, Bogor

    E-mail: [email protected]

    ABSTRACT

    The adsorption of fJ-carotene from crude palm olein by using bentonite was investigated Another
    adsorbent, which is activated carbons was used as a reference. The adsorption process offJ-carotene was done
    using a mixed reactor. The objectives of this research are to obtain the equilibrium condition and the value of
    kinetics parameters, which are adsorption rate constant (k) and activation energy (Ea) ofisothermal adsorption
    of fJ-carotene from crude palm olein using bentonite and activated carbons. The achievement of equilibrium
    condition was influenced by adsorption process temperature. Higher adsorption temperature led to faster
    equilibrium time, but give the different influence for the value of fJ-carotene concentration in olein (pglml) for
    each adsorbents. Bentonite showed a faster equilibrium time (minute) and lower fJ-carotene concentration in
    olein (pglml) than activated carbons. For both adsorbents used. Freundlich isotherm model showed a goodjit to
    the adsorption of fJ-carotene. The adsorption rate constant (k) was ascend by the higher of adsorption
    temperature. The activation energy of adsorption (Ea) was determined as bentonite 74.28 keal marl and
    activated carbons 30.04 kcal marl. Value of activation energy (Ea) indicates that adsorption process of fJ
    carotene from crude palm olein by using activated carbon is more effective than that ofbentonite.
    Keywords: adsorption, fJ-carotene, crude palm olein, bentonite.
    PENDAHULUAN
    Minyak sawit kasar merupakan salah satu
    sumber penghasil karotenoid terkaya untuk
    menghasilkan retinol (provitamin A). Minyak sawit
    kasar mengandung 15 sampai 300 kali lebih retinol
    dibandingkan dengan wortel, sayuran berdaull hijau
    dan tomat (Latip et al., 2000). Karotenoid yang
    terkandung pada olein sawit kasar sebesar 680-760
    ppm dan berwama khas merah-kuning (Ong dan
    Tee, 1992 dalam Zeb dan Mehmood, 2004).
    j3-karoten sangat potensial sebagai sumber
    provitamin. Berbagai metode pengambilan kembali
    komponen karotenoid dari minyak kelapa sawit telah
    dilakukan dengan cara saponifikasi, adsorpsi,
    ekstraksi pelarut dan transesterifikasi dengan
    pemisahan fase dan destilasi eter (Baharin et al.,
    1998). Dalam penelitian ini, adsorpsi diterapkan
    dalam upaya pengambilan kern bali komponen p
    karoten yang terkandung dalam minyak sawit.
    Bentonit atau biasa disebut lempung pemucat
    telah digunakan secara luas sebagai adsorben.
    Bentonit digunakan dalam pemisahan 'komponen
    pengotor' dalam minyak dimana kemampuan
    adsorpsinya memiliki peranan sangat besar dalam
    industri minyak pangan. Arang aktif digunakan
    sebagai adsorben pembanding pada penelitian ini.
    Karakteristik
    kemampuan
    penyerapan
    kompo-nen ~-karoten pada adsorben dapat dilihat
    dari laju adsorpsinya. Laju adsorpsi dapat diketahui
    dari konstanta laju adsorpsi (k) yang dihasilkan dari
    suatu model kinetika adsorpsi. Model isoterm
    Freundlich dan Langmuir digunakan untuk
    93

    menentukan parameter kinetika pada suatu proses


    adsorpsi. Energi aktivasi (Ea) merupakan parameter
    yang digunakan untuk mengetahui efektivitas dari
    adsorben yang digunakan dalam proses adsorpsi.

    METODE PENELITIAN
    Bahan dan Metode
    Bahan yang digunakan dalam penelitian ini
    adalah olein sawit kasar hasH fraksinasi dad minyak
    sawit kasar.
    Standar p-karoten (Sigma-Aldrich;
    1.600.000 IU/gram), standar a-tokoferol (Sigma
    Aldrich), adsorben (benton it, arang aktif dengan
    ukuran partikel lolos saringan 150 mesh), heksan,
    isopropanol, etanol dan BHT. Bahan yang digunakan
    untuk analisis an tara lain alkohol netral 95%, kalium
    hidroksida beralkohol (KOH), dan
    indikator
    phenolftalein.
    Peralatan yang digunakan dalam penelitian
    1m
    antara lain reaktor berpengaduk, High
    Performance Liquid Chromatrography (HPLC),
    peralatan gelas, spektrofotometer dan refraktometer.
    Penelitian ini terdiri dari lima tahap, yaitu (a)
    karakterisasi olein sawit kasar dan adsorben yang
    akan digunakan pada proses adsorpsi, (b) penentuan
    kondisi kesetimbangan adsorpsi, (c) penentuan nilai
    konstanta laju adsorpsi (k), (d) Penentuan nilai
    energi aktivasi (Ea) dan (e) Penentuan kualitas
    adsorpsi.
    Perbandingan antara adsorben dengan olein
    sawit kasar yang digunakan adalah 1:3. Campuran
    adsorben (300 g) dengan olein (900 mL) disiapkan
    di dalam suatu reaktor berpengaduk berkapasitas 2

    J. Tek. Ind. Pert. Vol. 19(2), 93-100

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