One Compenent Water System
One Compenent Water System
One Compenent Water System
THEORY
P=1 :
(ii)
P=2 :
F=1 (Univariant)
(iii) P=3 :
F=0 (invariant)
From above, it is clear that for any one component system, the
maximum number of degrees of freedom is two.
PHASE RULE
THEORY
or e
ng rv
ezi cu
Fre hi nd
l
Me
Ice
Va
po
cu uri s
rv at n
e
218 atm
Liquid
F.P. of H2 O
1 am
Pressure
in atm
4.58 mm.
Super cooling or
Metastable curve
Triple
point
B
273C
Vapour
0.075
TempC
B.P.
for H 2 O
100
374
PHASE RULE
THEORY
Univariant
PHASE RULE
THEORY
PHASE RULE
THEORY
AOC
AOB
gaseous phase
= 1-1+2
BOC
solid phase
=2
V) Triple pointAll the three curves OA, OB & OC meet at P & O called
as tripple point. Where all the three phases. Solid, Liquid
& Vapour are simultaneously in equilibrium.
System is Zero
PHASE RULE
THEORY
The
super
cooled
water
system
is
unstable
i.e.
VII) Applicationsi)
ii)
PHASE RULE
iii)
THEORY