Edta
Edta
Edta
EDTA PROCESS
THEORY
Structure of EDTA-
PRINCIPLE
Metal ion solution is titrated with standardized EDTA
solution.
Indicator used is Eriochrome black-T(EBT).
WATER
EDTA PROCESS
THEORY
INITIAL REACTION -
M2++EBT
[M-EBT]
(BLUE)
(WINE RED)
M=Ca2+ or Mg2+
2.
TITRATION REACTION
[M-EBT]complex+ EDTA
M2+ + EBT
[M-EBT] complex
3.
(wine- red)
[M-EDTA]complex +EBT
[M-EDTA]complex+ EBT
WATER
EDTA PROCESS
THEORY
PROCEDURE
I. PREPARATION OF REAGENTS
a) Preparation of standard hard water-Take
1.0 gm of CaCO3 and dissolve in min. amount of HCl.
Evaporate the solution to dryness on a water bath. Make 1L
solution by dissolving residue in
Distilled water. Each ml of this solution will correspond to
1mg of CaCO3 hardness.
b) Preparation
100ml of alcohol.
d) Preparation
WATER
EDTA PROCESS
THEORY
II. PROCEDURE
a) Standardization of EDTA solution- In conical
flask, pipette out 50ml of SHW and add 10-15ml of buffer
solution and 4-5 drops indicator. Titrate with EDTA till wine
color changes to clear blue. Let volume used be V1 ml.
b) Titration
of permanent hardness-
In a large
WATER
EDTA PROCESS
THEORY
III. CALCULATIONS
a) Total hardness
50ml of SHW =V1 ml EDTA
Hence 50 *1mg of CaCO3 =V1 ml of EDTA
1ml of EDTA=50/V1 mg of CaCO3
Now 50ml of hard water=V2 ml of EDTA
= V2*50/V1 mg of CaCO3 eq
1ml of given hard water = V2/ V1 mg of CaCO3 eq
1000ml of given hard water=1000* V2/ V1 mg of CaCO3 eq/L
Total hardness=1000* V2/ V1 ppm
b)
Permanent Hardness
c)
Temporary Hardness
=TOTAL
WATER
EDTA PROCESS
THEORY