Teg Dehydration
Teg Dehydration
Teg Dehydration
EXAMPLE PURPOSE
This example illustrates a process to remove water from natural gas using Triethylene Glycol (TEG) as dehydration
solvent. The interesting points of this example lie in the use of the absorption module for the contactor model and
in the representation of two columns connected in series (the TEG regenerator and the TEG stripper) by a single
ProSimPlus stripper module. Additionally, the Windows Script module is used in different parts of the flowsheet to
perform specific calculations (gas water dew point, TEG losses for make-up calculation).
ACCESS
Confidential
E12_TEG_Dehydration.pmp3
Reader is reminded that this use case is only an example and should not be used for other purposes. Although this example is based on actual
case it may not be considered as typical nor are the data used always the most accurate available. ProSim shall have no responsibility or liability
for damages arising out of or related to the use of the results of calculations based on this example.
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TABLE OF CONTENTS
1.
2.
PROCESS MODELING..................................................................................................... 3
1.1.
1.2.
1.3.
Simulation flowsheet............................................................................................................................ 5
1.4.
Components ........................................................................................................................................ 6
1.5.
1.6.
Operating conditions............................................................................................................................ 7
1.7.
Initialization ........................................................................................................................................ 10
1.8.
RESULTS ........................................................................................................................ 11
2.1.
2.2.
2.3.
3.
4.
REFERENCES ................................................................................................................ 18
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1. PROCESS MODELING
1.1. Process description
This process is the traditional Triethylene Glycol (TEG) based dehydration process and represent a unit with gas
absorption and extraction solvent regeneration. The objective is to reduce the amount of water in the natural gas
with TEG, used as the extraction solvent. This process is required to prevent hydrates formation at low
temperatures or corrosion problems due to the presence of carbon dioxide or hydrogen sulfide (regularly found in
natural gas).
The wet gas feeds the contactor D200 (stream 1) at 71 bar gage. This column absorbs a part of the water in the gas
in the Triethylene Glycol (TEG) mixture. At the end of the regeneration loop, the lean TEG feeds the top part of the
contactor (stream 16) and absorbs water. Rich TEG leaves the bottom (stream 3) by level control and is
depressurized to 5 bar gage (valve V200). The rich stream flows through a cartridge filter (F200 A/B) to remove
solid particles coming from corrosion or TEG degradation. These solid particles and degradation are not taken into
account in this model and consequently, the filtration does not have any impact in terms of simulation and is not
represented. Once filtered, this flow is used as cold fluid of the condenser (E200) of the TEG regeneration column
(C201). It is to be noted that in the simulation this condenser is represented separately from the column. The
amount of heat to be removed in the C201 column condenser is transferred through an information stream in the
heat exchanger module E200.
The wet TEG then enters a flash tank B200 (stream 5) in which gaseous hydrocarbons that were absorbed along
with the water in the contactor are vaporized. These hydrocarbons are heated in heat exchanger E204 (stream 7)
and used as stripping fluid in the stripper C202 (stream 9). The liquid phase heated in the heat exchanger E202
(stream 6) then feeds the regenerator C201 head (stream 11). This column is used to strip water from the TEG and
operates at atmospheric pressure. Waste gases consisting of water and the hydrocarbons dissolved in the TEG,
leave the regenerator at the top. The liquid bottom stream feeds the stripping column C202. This column decreases
of the TEG water concentration by stripping using hydrocarbons vapors from B200. Lean TEG (stream 8) is then
sent from the bottom of the column to storage tank R200. This storage tank has no meaning in terms of steadystate simulation but allows the regulation of the TEG flow. Consequently, it is represented by a mixer module. The
TEG make-up (stream 14) is required to compensate the losses due to gas entrainment or degradation. Lean TEG
is then pumped in P200 A/B and feed the contactor D200 head (stream 16).
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1.4. Components
Components taken into account in the simulation, chemical formula and CAS number are presented in the following
table. Pure components physical properties are extracted from the ProSimPlus standard database.
Component name
Chemical formula
CAS number
Methane
CH4
74-82-8
Ethane
C2H6
74-84-0
Propane
C3H8
74-98-6
n-butane
C4H10
106-97-8
Isobutane
C4H10
75-28-5
n-pentane
C5H12
109-66-0
Isopentane
C5H12
78-78-4
n-hexane
C6H14
110-54-3
n-heptane
C7H16
142-82-5
n-octane
C8H18
111-65-9
n-nonane
C9H20
111-84-2
n-decane
C10H22
124-18-5
n-undecane
C11H24
1120-21-4
n-dodecane
C12H26
112-40-3
Nitrogen
N2
7727-37-9
Carbon dioxide
CO2
124-38-9
Water
H2O
7732-18-5
Triethylene glycol
C6H14O4
112-27-6
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25
Pressure (barg)
71
37.2080
Mass fraction
Methane
0.8227
Ethane
0.0592
Propane
0.0476
n-butane
0.0188
Isobutane
0.0109
n-pentane
0.0063
Isopentane
0.0074
n-hexane
0.0065
n-heptane
0.0042
n-octane
0.0014
n-nonane
0.000217
n-decane
4.27E-005
n-undecane
3.8E-006
n-dodecane
1.01E-006
Nitrogen
0.0045
Carbon dioxide
0.0095
Water
Triethylene glycol
0.000622
0
Value
Absorber
Feed tray
70.75
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Valve V200
Operating parameters
Type of valve
Pressure (barg)
Type of exchanger
Information stream specification
Type of separator
Type of flash
Heat duty exchanged
Pressure
Value
Simple heat exchanger
-
Value
Diphasic L-V separator
Pressure and heat duty fixed
Adiabatic
The lowest of the feed streams
Expansion valve
Value
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Value
Cooler / heater
175
Value
Stripper
Feed tray
1.05
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Additional specifications
Tray N 1 temperature (C)
100
204
Intermediate boiler
100
194
Type of exchanger
Outlet temperature (C)
Value
Cooler / heater
28.7
Mixer R200
Operating parameters
Type of mixer
Pressure
Value
Value
Other mixer
The lowest of the feed streams
Value
Centrifugal pump
70.75
Volumetric efficiency
0.65
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1.7. Initialization
The TEG flowrate in the loop is fixed by initializing the flash drum B200 inlet stream (stream 5). From the knowledge
of this flowrate, it is possible to calculate B200, C201 / C202 and the TEG feed to contactor D200. Initialization is
set in order to obtain a dry gas dew point at -40C .
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2. RESULTS
2.1. Mass and energy balance
This table presents only the most relevant stream results. In ProSimPlus, mass and energy balances are provided
for every stream. Results are also available at the unit operation level (result tab in the configuration window).
Streams
1
3
5
8
From
Wet Gas
D200
E200
C201 / C202
To
Dew_C 1
V200
B200
E202
Partial flows
t/h
t/h
t/h
t/h
METHANE
30.614496 0.00892193
0.008922
0.00019248
ETHANE
2.20296361 0.00031979 0.00031979
7.04E-06
PROPANE
1.77130183 0.00039308 0.00039308
9.61E-06
n-BUTANE
0.6995898 0.00047217 0.00047217
8.69E-06
ISOBUTANE
0.40561323 0.00021306 0.00021306
3.74E-06
n-PENTANE
0.23443701 0.00016836 0.00016836
3.61E-06
ISOPENTANE
0.27537045 0.00016215 0.00016215
3.42E-06
n-HEXANE
0.24187945 0.00017607 0.00017607
4.40E-06
n-HEPTANE
0.15629134 0.00011506 0.00011506
3.18E-06
n-OCTANE
0.05209711
3.87E-05
3.87E-05
1.18E-06
n-NONANE
0.00807505
6.14E-06
6.14E-06
2.00E-07
n-DECANE
0.00158896
1.25E-06
1.25E-06
4.30E-08
n-UNDECANE
0.00014141
1.21E-07
1.21E-07
4.07E-09
n-DODECANE
3.76E-05
3.32E-08
3.32E-08
1.14E-09
NITROGEN
0.167455
6.48E-05
6.48E-05
6.74E-07
CARBON DIOXIDE
0.35351612 0.00020549 0.00020549
4.13E-06
WATER
0.023146
0.02315561 0.02315563 0.00027511
TRIETHYLENE GLYCOL
0
0.56314148 0.56314742 0.56308308
Total flow
t/h
37.208
0.59755524 0.59756128 0.5636006
Total flow
m3(n)/h 46352.7933 126.367223 126.368238 84.6751459
Mass fractions
METHANE
0.82279338 0.01493071 0.01493069 0.00034152
ETHANE
0.05920672 0.00053516 0.00053516
1.25E-05
PROPANE
0.0476054 0.00065782 0.00065781
1.71E-05
n-BUTANE
0.01880213 0.00079016 0.00079016
1.54E-05
ISOBUTANE
0.01090124 0.00035656 0.00035656
6.63E-06
n-PENTANE
0.00630072 0.00028175 0.00028175
6.41E-06
ISOPENTANE
0.00740084 0.00027136 0.00027136
6.07E-06
n-HEXANE
0.00650074 0.00029464 0.00029464
7.80E-06
n-HEPTANE
0.00420048 0.00019255 0.00019254
5.64E-06
n-OCTANE
0.00140016
6.47E-05
6.47E-05
2.10E-06
n-NONANE
0.00021702
1.03E-05
1.03E-05
3.55E-07
n-DECANE
4.27E-05
2.10E-06
2.10E-06
7.63E-08
n-UNDECANE
3.80E-06
2.02E-07
2.02E-07
7.23E-09
n-DODECANE
1.01E-06
5.56E-08
5.56E-08
2.01E-09
NITROGEN
0.00450051 0.00010837 0.00010837
1.20E-06
CARBON DIOXIDE
0.00950108 0.00034388 0.00034388
7.33E-06
WATER
0.00062207 0.03875058 0.03875021 0.00048814
TRIETHYLENE GLYCOL
0
0.94240908 0.94240948 0.99908177
Physical state
Vapor
Liquid
Liq./Vap.
Liquid
Temperature
C
25
25.2382295 25.8503908 195.744508
Pressure
barr
70.9999805 70.7499806 4.99999837 0.03674972
Enthalpy
kW
-933.947796 -105.15569 -103.83171 -26.6041535
Vapor fraction
1
0.09324884
Copyright 2010 ProSim, Labge, France All rights reserved
9
E204
C201 / C202
t/h
0.00785102
0.00029981
0.00034463
0.00029736
0.00014873
9.56E-05
0.00010174
9.11E-05
5.36E-05
1.61E-05
2.23E-06
3.88E-07
3.02E-08
6.91E-09
5.62E-05
0.00016576
1.12E-05
1.48E-08
0.00953553
11.783692
0.82334371
0.03144177
0.03614116
0.03118463
0.01559709
0.01002903
0.01066959
0.0095507
0.00562361
0.00168666
0.00023372
4.07E-05
3.17E-06
7.24E-07
0.00589571
0.01738332
0.00117321
1.55E-06
Vapor
175
4.99999837
0.92407112
1
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Streams
10
13
14
12
From
C201 / C202
E203
Make up (TEG)
E202
To
Waste gas
R200
R200
E203
Partial flows
t/h
t/h
t/h
t/h
METHANE
0.0087295 0.00019248
0
0.00019248
ETHANE
0.00031275
7.04E-06
0
7.04E-06
PROPANE
0.00038347
9.61E-06
0
9.61E-06
n-BUTANE
0.00046348
8.69E-06
0
8.69E-06
ISOBUTANE
0.00020933
3.74E-06
0
3.74E-06
n-PENTANE
0.00016475
3.61E-06
0
3.61E-06
ISOPENTANE
0.00015873
3.42E-06
0
3.42E-06
n-HEXANE
0.00017167
4.40E-06
0
4.40E-06
n-HEPTANE
0.00011188
3.18E-06
0
3.18E-06
n-OCTANE
3.75E-05
1.18E-06
0
1.18E-06
n-NONANE
5.94E-06
2.00E-07
0
2.00E-07
n-DECANE
1.21E-06
4.30E-08
0
4.30E-08
n-UNDECANE
1.17E-07
4.07E-09
0
4.07E-09
n-DODECANE
3.21E-08
1.14E-09
0
1.14E-09
NITROGEN
6.41E-05
6.74E-07
0
6.74E-07
CARBON DIOXIDE
0.00020136
4.13E-06
0
4.13E-06
WATER
0.02288049 0.00027511
0
0.00027511
TRIETHYLENE GLYCOL
5.84E-05
0.56308308
8.83E-05
0.56308308
Total flow
t/h
0.0339547
0.5636006
8.83E-05
0.5636006
Total flow
m3(n)/h 41.6921514 84.6751459 0.01318003 84.6751459
Mass fractions
METHANE
0.25709263 0.00034152
0
0.00034152
ETHANE
0.00921083
1.25E-05
0
1.25E-05
PROPANE
0.01129369
1.71E-05
0
1.71E-05
n-BUTANE
0.01364984
1.54E-05
0
1.54E-05
ISOBUTANE
0.00616491
6.63E-06
0
6.63E-06
n-PENTANE
0.00485212
6.41E-06
0
6.41E-06
ISOPENTANE
0.00467473
6.07E-06
0
6.07E-06
n-HEXANE
0.00505584
7.80E-06
0
7.80E-06
n-HEPTANE
0.0032949
5.64E-06
0
5.64E-06
n-OCTANE
0.0011046
2.10E-06
0
2.10E-06
n-NONANE
0.00017508
3.55E-07
0
3.55E-07
n-DECANE
3.57E-05
7.63E-08
0
7.63E-08
n-UNDECANE
3.44E-06
7.23E-09
0
7.23E-09
n-DODECANE
9.45E-07
2.01E-09
0
2.01E-09
NITROGEN
0.00188728
1.20E-06
0
1.20E-06
CARBON DIOXIDE
0.00593029
7.33E-06
0
7.33E-06
WATER
0.67385331 0.00048814
0
0.00048814
TRIETHYLENE GLYCOL
0.00171989 0.99908177
1
0.99908177
Physical state
Vapor
Liquid
Liquid
Liq./Vap.
Temperature
C
100
28.7
28.7
56.424346
Pressure
barr
0.03674972 0.03674972
-2.74E-07
0.03674972
Enthalpy
kW
1.37124506 -85.8591173 -0.01342316 -75.8857401
Vapor fraction
1
0.00969686 0.00017069
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16
P200 A/B
D200
t/h
0.00019248
7.04E-06
9.61E-06
8.69E-06
3.74E-06
3.61E-06
3.42E-06
4.40E-06
3.18E-06
1.18E-06
2.00E-07
4.30E-08
4.07E-09
1.14E-09
6.74E-07
4.13E-06
0.00027511
0.56317139
0.56368891
84.6883259
18
Dew_C200
Dry Gas
t/h
30.6057666
2.20265086
1.77091835
0.69912632
0.40540391
0.23427225
0.27521172
0.24170778
0.15617946
0.05205961
0.00806911
0.00158775
0.00014129
3.76E-05
0.16739092
0.35331476
0.0002655
2.99E-05
37.1741337
46311.1144
0.00034147
1.25E-05
1.70E-05
1.54E-05
6.63E-06
6.40E-06
6.07E-06
7.80E-06
5.64E-06
2.10E-06
3.55E-07
7.63E-08
7.23E-09
2.01E-09
1.20E-06
7.32E-06
0.00048806
0.99908192
Liquid
30.0329608
70.7499806
-84.3434882
0.82330813
0.05925224
0.04763846
0.0188068
0.01090554
0.00630202
0.00740331
0.00650204
0.00420129
0.00140043
0.00021706
4.27E-05
3.80E-06
1.01E-06
0.00450289
0.00950432
7.14E-06
8.05E-07
Vapor
25.52827 23
70.7499806
-913.135691
1
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Inlet stream
Result (C)
Dew_C 1
24.7
Dew C200
17
-40.6
Note that in ProSimPlus the stages are numbered from top to bottom. Stage 1 is the condenser, the last stage is the
boiler.
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Stage
Mole-fraction
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
1
Stage
METHANE
ISOPENTANE
n-UNDECANE
ETHANE
n-HEXANE
n-DODECANE
PROPANE
n-HEPTANE
NITROGEN
n-BUTANE
n-OCTANE
CARBON DIOXIDE
ISOBUTANE
n-NONANE
WATER
n-PENTANE
n-DECANE
TRIETHYLENE GLYC
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Stage
Mole-fraction
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
1
Stage
METHANE
ISOPENTANE
n-UNDECANE
ETHANE
n-HEXANE
n-DODECANE
PROPANE
n-HEPTANE
NITROGEN
n-BUTANE
n-OCTANE
CARBON DIOXIDE
ISOBUTANE
n-NONANE
WATER
n-PENTANE
n-DECANE
TRIETHYLENE GLYC
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Mole-fraction
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
1
Stage
METHANE
ISOPENTANE
n-UNDECANE
ETHANE
n-HEXANE
n-DODECANE
PROPANE
n-HEPTANE
NITROGEN
n-BUTANE
n-OCTANE
CARBON DIOXIDE
ISOBUTANE
n-NONANE
WATER
n-PENTANE
n-DECANE
TRIETHYLENE GLYC
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4. REFERENCES
[ABR75]
Industrial & Engineering Chemistry Process Design & Development, 1978, Vol. 17, No 4, p. 552560
[DAH 90]
Michelsen M.L.
A modified Huron-Vidal mixing rule for cubic Equation of state
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