5070 w12 QP 12
5070 w12 QP 12
5070 w12 QP 12
CHEMISTRY Paper 1 Multiple Choice Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB recommended)
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October/November 2012 1 hour
*6291679584*
READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16.
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2 1 Which is a property of hydrogen gas? A B C D 2 It burns in air. It has an unpleasant smell. It relights a glowing splint. It turns moist litmus paper red.
Four identical balloons are filled with different gases all at the same temperature and pressure.
ammonia NH3
ethene C 2H 4
nitrogen N2
The gases gradually diffuse out of the balloons. Which pair of balloons will deflate at the same rate? A P and Q B Q and R C R and S D S and P
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3 3 Hydrogen chloride is very soluble in water, whereas chlorine is only slightly soluble in water. Both gases can be dried using concentrated sulfuric acid. Which diagram represents the correct method of obtaining pure dry chlorine from damp chlorine containing a small amount of hydrogen chloride?
A damp Cl 2 and HCl damp Cl 2 and HCl B
water
water
water
water
Which statement about X and Y is correct? A B C D They are both positively charged. They are particles of the same element. They have the same mass number. They have the same number of nucleons.
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4 5 Which of the following is not a mixture? A B C D 6 ethanol petrol steel tap water
When concentrated aqueous sodium chloride is electrolysed using carbon electrodes, which row correctly states the products at the electrodes and the solution remaining? cathode () A B C D chlorine hydrogen hydrogen sodium anode (+) hydrogen chlorine oxygen chlorine solution remaining hydrochloric acid sodium hydroxide sodium chloride water
Carbon and silicon are both in Group IV of the Periodic Table, but at room temperature CO2 is a gas whereas SiO2 is a solid. Which statement explains this? A B C D Covalent bonding is weaker in CO2. Covalent bonds in CO2 are double bonds and in SiO2 the covalent bonds are single bonds. CO2 is a covalent compound and SiO2 is ionic. CO2 is a simple covalent molecule and SiO2 is a macromolecule.
An ionic compound has the formula X3Y2. To which groups of the Periodic Table do X and Y belong? group for X A B C D II III II V group for Y III II V II
When two solutions are mixed, a precipitate of a magnesium compound is formed. Which salt would be formed from solution as a precipitate? A MgCO3 B MgCl 2 C Mg(NO3)2 D MgSO4
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5 10 Which substance has metallic bonding? conducts electricity when solid A B C D when liquid state of substance formed on reaction with oxygen solid gas no reaction solid
11 In separate experiments sulfur dioxide, a reducing agent, was passed through acidified solutions of potassium dichromate(VI) and potassium manganate(VII). Which pair describes the colour changes observed in the experiments? colour change of potassium dichromate(VI) A B C D orange to green colourless to green colourless to orange orange to green colour change of potassium manganate(VII) pink to colourless green to pink pink to green colourless to pink
12 In the experiment shown in the diagram, the bulb lights and two colourless gases are formed, one at each electrode.
What is X? A B C D concentrated aqueous sodium chloride dilute sulfuric acid methanol molten sodium chloride [Turn over
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6 13 0.5 mol / dm3 hydrochloric acid is added gradually to a flask containing 20 cm3 of 2 mol / dm3 sodium hydroxide solution. What is the total volume, in cm3, of the mixture in the flask when the solution is just neutral? A 30 B 40 C 60 D 100
14 Two of the reactions used in the manufacture of nitric acid, HNO3, are shown. 2NO + O2 2NO2 4NO2 + 2H2O + O2 4HNO3 What is the maximum number of moles of nitric acid which could be formed from one mole of nitrogen monoxide, NO? A 0.5 B 1.0 C 2.0 D 4.0
15 Sulfur trioxide is produced by the following reaction. 2SO2(g) + O2(g) 2SO3 (g) H = 195 kJ
Which change in conditions would produce a greater yield of SO3 at equilibrium? A B C D adding a catalyst increasing the pressure increasing the temperature removing some SO2 and O2
16 Solution X has a pH value of 12. It is added to aqueous ammonium chloride and the mixture is warmed. Which information is correct? solution X is A B C D acidic acidic alkaline alkaline when the mixture is warmed ammonia gas is given off no gas is given off ammonia gas is given off no gas is given off
B CH2OH CH3
C COOH COOH
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D COOH CH2OH
7 18 Why does an increase in pressure increase the rate of reaction between the gases nitrogen and hydrogen in the manufacture of ammonia? A B C D The activation energy is lowered. The molecules collide more frequently. The molecules have more energy. The reaction is more exothermic.
19 The diagram shows the steps by which carbon dioxide can be converted into organic products and finally returned to the atmosphere. Which step is an example of combustion?
A CO2 C6H12O6
CH3CO2H
C2H5OH
20 The diagram shows some reactions of copper compounds. Which change is made by adding an acid?
malachite CuCO3
copper Cu
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8 21 What is the effect of a catalyst on the activation energy and on the enthalpy change, H, of a reaction? activation energy A B C D decreases decreases increases increases H decreases unchanged decreases unchanged
22 Which substance in the table could be an amphoteric oxide? reaction with dilute hydrochloric acid A B C D dissolves dissolves insoluble insoluble reaction with water insoluble insoluble dissolves insoluble reaction with sodium hydroxide dissolves insoluble insoluble dissolves
23 Which element in the table is an alkali metal? melting point C A B C D 39 7 98 1083 density g / cm3 13.60 3.10 0.97 8.92
24 Which compound is present in sand in the largest proportion? A Al 2O3 B CaSO4 C NaCl D SiO2
25 Atoms of elements X and Y have the electron configurations 2,5 and 2,8,5 respectively. Which deduction about these elements can be made from this information? A B C D The atoms are isomers. The atoms are isotopes. The elements are in the same group of the Periodic Table. The elements are in the same period of the Periodic Table.
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9 26 What is the function of silica, SiO2, in the equation shown below? CaO + SiO2 CaSiO3 A B C D a basic oxide a reducing agent an acidic oxide an oxidising agent
27 Which gas can be removed from the exhaust gases of a petrol-powered car by its catalytic converter? A B C D carbon monoxide carbon dioxide nitrogen steam
28 Metal M will displace copper from aqueous copper(II) sulfate solution, but will not displace iron from aqueous iron(II) sulfate solution. M is extracted from its oxide by heating the oxide with carbon. What is the order of reactivity of these four metals? least reactive A B C D sodium sodium copper copper metal M iron iron metal M iron metal M metal M iron most reactive copper copper sodium sodium
29 Which substance in the table is the element iodine? state at room temperature A B C D liquid liquid solid solid electrical conductivity when molten good none good none
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10 30 Iron pipes corrode rapidly when exposed to sea water. Which metal, when attached to the iron, would not offer protection against corrosion? A B C D aluminium copper magnesium zinc
31 Which method is used in industry to extract aluminium from bauxite? A B C D electrolysis heating alone heating with carbon heating with magnesium
32 Which row shows both the correct source and the correct effect of the named pollutant? pollutant A B C D carbon monoxide oxides of nitrogen ozone sulfur dioxide source incomplete combustion of carbon-containing materials decaying vegetable matter photochemical reactions volcanoes effect global warming global warming acid rain acid rain
33 A sample of soil has a nitrogenous fertiliser in the form of an ammonium salt added to it. The ammonium salt dissolves in the water in the soil. When tested a week later, the water in the soil contained 15.3 % of dissolved nitrogen and had a pH of 4.6. Calcium hydroxide was added to the soil and then the water in the soil was tested the next day, both for nitrogen content and pH. What would be the most likely result of the final test? % of nitrogen A B C D 11.4 12.7 15.3 19.8 pH 3.8 6.9 4.6 4.2
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In the flow chart, what are W, X, Y and Z? W A B C D H2 O2 O2 N2 X N2 SO2 SO2 H2 Y high high low high Z NH3 SO3 SO3 NH3
35 A factory manufactures poly(ethene). Which raw material will the factory need? A B C D bitumen methane methanol naphtha
36 Starch is a carbohydrate and is broken down to simple sugars by saliva in the mouth. What is the name for this reaction? A B C D condensation fermentation hydrolysis polymerisation
37 If 1 mole of each alkane is completely burned in oxygen, which will provide 7 moles of products? A CH4 B C2H6 C C3H8 D C4H10
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12 38 An alcohol contains 60 % carbon by mass. What is its formula? A CH3OH B C2H5OH C C3H7OH D C4H9OH
39 The alcohol C4H9OH on oxidation with acidified potassium dichromate(VI) will give a carboxylic acid X. Which acid is X? A C4H9COOH B C3H7COOH C C2H5COOH D CH3COOH
C O H C O H H H C H C
D O H O C H H C H H
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I H
Hydrogen
II
IV
VI
VII
0
4
He
Helium
1 11 12 14 16 19
2 20
Li
Boron Carbon
Be
5 27 28 6 7
N
Nitrogen
O
Oxygen
F
Fluorine
Ne
Neon
Lithium
Beryllium
8 31 32
9 35.5
10 40
23
24
Na
Aluminium
Mg
13 51 52 55 56 59 59 64 65 70
Al
14
Si
Silicon
P
Phosphorus
S
Sulfur
Cl
Chlorine
Ar
Argon
Sodium
Magnesium
11
12
15 73 75
16 79
17 80
18 84
39
40
45
48
K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc
Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
31
Ga
Gallium
Ge
Germanium
As
Arsenic
Se
Selenium
Br
Bromine
Kr
Krypton
Potassium
Calcium
Scandium
Titanium
19
20
21
22
32 115 119
33 122
34 128
35 127
36 131
16
85
88
89
91
Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver
Sr
41 181 184 186 190 192 195 197 42 43 44 45 46 47
Zr
Nb
Mo
Tc
Ru
Rh
Pd
Ag
48
Cd
Cadmium
In
Indium
Sn
Tin
Sb
Antimony
Te
Tellurium
I
Iodine
Xe
Xenon
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49 201
Rubidium
Strontium
Yttrium
Zirconium
37
38
39
40
50 204 207
51 209
52
53
54
133
137
139
178
Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum
Ba
73 77 74 75 76 78
La Ta W Re Os Pt
Hf
Ir
79
Au
Gold
Hg
Mercury
Tl
Thallium
Pb
Lead
Bi
Bismuth
Po
Polonium
At
Astatine
Rn
Radon
Caesium
Barium
Lanthanum
Hafnium
55
56
57
72
80
81
82
83
84
85
86
226
227
Fr
140 141 144 150
Ra
Ac
152 157 159 162 165 167 169 173 175
Francium
Radium
Actinium
87
88
89
Pr
59 60 238 61
Nd
Pm
62
Sm
Samarium
Eu
Europium
Gd
Gadolinium
Tb
Terbium
Dy
Dysprosium
Ho
Holmium
Er
Erbium
Tm
Thulium
Yb
Ytterbium
Lu
Lutetium
58 232
63
64
65
66
67
68
69
70
71
Key Th
Thorium Protactinium Uranium
X Pa
91 92
X = atomic symbol
90
U
93
Np
Neptunium
Pu
Plutonium
Am
Americium
Cm
Curium
Bk
Berkelium
Cf
Californium
Es
Einsteinium
Fm
Fermium
Md
Mendelevium
No
Nobelium
Lr
Lawrencium
94
95
96
97
98
99
100
101
102
103
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).