5070 w09 QP 1
5070 w09 QP 1
5070 w09 QP 1
CHEMISTRY Paper 1 Multiple Choice Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB recommended)
5070/01
October/November 2009 1 hour
*8518512898*
READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16.
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2 1 In which option do the three particles each have the same number of electrons? A B C D 2 Cl F K+ Li+ Br Ne Ca2+ Na+ I Na+ Br K+
Why does neon gas, Ne, diffuse faster than carbon dioxide gas, CO2? A B C D Neon atoms have the lower mass. Neon does not form molecules. Neon is a noble gas. Neon is less dense than air.
Which reagent could be used to distinguish between dilute nitric acid and dilute hydrochloric acid? A B C D aqueous barium chloride aqueous silver nitrate aqueous sodium hydroxide copper(II) carbonate
The conical flask contains compound X which is present in solid, liquid and gaseous states.
gaseous X
solid X liquid X
Which statement is correct? A B C D A gaseous X molecule has a lower mass than a liquid X molecule. Energy is released when X changes from liquid to solid. Liquid X is at a higher temperature than solid X. Liquid X molecules vibrate about fixed positions.
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3 5 Which statement is always true when two atoms join together by a covalent bond? A B C D 6 One atom is a metal, the other atom is a non-metal. One atom loses one electron, the other atom gains one electron. The two atoms share one electron. The two atoms share two electrons.
diamond
Which property do these substances have in common? A B C D 7 They are giant structures. They can act as lubricants. They can conduct electricity. They contain only covalent bonds.
graphite
Calcium reacts with phosphorus to form the ionic compound calcium phosphide. Which ions will this compound contain? A B C D Ca2+ and P3 Ca2+ and P5 Ca2 and P3+ Ca2 and P5+
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4 8 All of the following substances can conduct electricity. Which substances conductivity is not due to the movement of electrons? A B C D aluminium graphite lithium chloride mercury
The relative atomic mass of oxygen is 16. What are possible values of the relative molecular mass of different molecules of water formed by the combination of oxygen and hydrogen? 1 2 3 A B C D 1 only 1 and 2 only 1 and 3 only 1, 2 and 3 18 19 20
10 Calcium reacts with water as shown. Ca(s) + 2H2O(l) Ca(OH)2(aq) + H2(g) What is the total mass of the solution that remains when 40 g of calcium reacts with 100 g of water? A 58 g B 74 g C 138 g D 140 g
11 What products are formed when concentrated aqueous potassium chloride is electrolysed? at the anode (positive) A B C D chlorine chlorine oxygen oxygen at the cathode (negative) hydrogen potassium hydrogen potassium
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5 12 Hydrogen reacts with oxygen as shown in the equation below. 2H2(g) + O2(g) 2H2O(l) How much gas will remain if 2 dm3 of hydrogen are reacted with 1 dm3 of oxygen at room temperature? A 0 dm3 B 1 dm3 C 2 dm3 D 3 dm3
13 Two cells, P and Q, containing different liquids, were connected in series with a battery, a suitable lamp and inert electrodes, as shown in the diagram.
lamp
For which pair of liquids did the lamp light up? in P A B C D concentrated sodium chloride solution copper(II) sulfate solution ethanol mercury in Q concentrated sugar solution propanol molten lead(II) bromide dilute hydrochloric acid
14 The burning of hydrogen is an exothermic reaction. Which statement explains this? A B C D More bonds are broken than are formed. More bonds are formed than are broken. Overall, the bonds broken are stronger than those formed. Overall, the bonds formed are stronger than those broken.
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6 15 In the Contact process for making sulfuric acid, one step involves the oxidation of sulfur dioxide to sulfur trioxide. 2SO2(g) + O2(g) The forward reaction is exothermic. Which change would increase the amount of sulfur trioxide produced at equilibrium? A B C D adding a catalyst decreasing the pressure decreasing the temparature increasing the temperature 2SO3(g)
16 Which graph corresponds to the catalytic decomposition of 1 mole of hydrogen peroxide? 2H2O2 2H2O + O2
A 1 total number of moles of oxygen produced 1 total number of moles 1 of oxygen /2 produced 0 0 time C 1 total number of moles of oxygen produced 1 total number of moles of oxygen 1/2 produced 0 0 time 0 0
/2
time D
/2
time
17 Which row in the table describes the processes occurring at the electrodes when molten sodium chloride is electrolysed? anode (positive) A B C D oxidation reduction oxidation reduction cathode (negative) reduction oxidation oxidation reduction
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7 18 Lithium and rubidium are both in Group I of the Periodic Table. Which statement is correct? A B C D Lithium atoms and rubidium atoms have the same number of electrons in their outer shell. Lithium atoms are larger than rubidium ions. Lithium ions and rubidium ions have the same number of electrons in their outer shell. Rubidium ions are larger than rubidium atoms.
19 Which mixture would react with dilute sulfuric acid to form two different gases? A B C D copper and magnesium carbonate copper(II) carbonate and magnesium copper(II) carbonate and magnesium oxide copper(II) oxide and magnesium
20 Which salts are soluble in water? 1 2 3 4 A 1 only ammonium carbonate, (NH4)2CO3 calcium carbonate, CaCO3 lead(II) carbonate, PbCO3 sodium carbonate, Na2CO3 B 1 and 2 C 1 and 4 D 2 and 3
21 Which compound in a 1 mol / dm3 solution has the lowest pH value? A B C D ethanoic acid hydrogen chloride sodium chloride sodium hydroxide
22 In the Periodic Table, how many periods include the elements of atomic numbers 1-18? A 2 B 3 C 6 D 8
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8 23 The ionic equation shows the reaction between potassium iodide and iron(III) chloride. 2Fe3+(aq) + 2I (aq) 2Fe2+(aq) + I2(aq) Which terms describe the changes to the iron(III) ions and iodide ions? iron(III) ions A B C D oxidised oxidised reduced reduced iodide ions reduced oxidised oxidised reduced
ZO3
25 Which is a property of aqueous potassium iodide? A B C D It does not conduct electricity. It is a purple solution. It is decolourised by chlorine. It reacts with aqueous bromine to form iodine.
26 The carbonate of metal X is a white solid. It decomposes when heated to form carbon dioxide and a yellow solid oxide. What is metal X? A B C D copper iron lead sodium
27 In which reaction do the products formed not include a salt? A B C D calcium(II) carbonate with hydrochloric acid copper(II) oxide with hydrogen copper(II) oxide with sulfuric acid copper(II) sulfate with sodium hydroxide
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9 28 In the manufacture of iron, using a blast furnace, which reaction generates heat? A B C D CaCO3 CaO + CO2 Fe2O3 + 3CO 2Fe + 3CO2 C + O2 CO2 C + CO2 2CO
29 Which oxide is most readily reduced to the metal by heating in a stream of hydrogen? A B C D calcium oxide lead(II) oxide sodium oxide zinc oxide
30 Which ionic equation represents the reaction taking place at the anode during the electrolysis of molten aluminium oxide? A B C D Al 3+ + 3e Al 2Al 3+ + 3O2 Al 2O3 O2 2e O2 2O2 4e O2
31 Which type of compound will liberate ammonia when heated with ammonium sulfate? A B C D an acid an alkali a reducing agent a salt
32 What is the concentration of hydrogen ions in 0.05 mol / dm 3 sulfuric acid? A 0.025 g / dm 3 B 0.05 g / dm 3 C 0.10 g / dm 3 D 2.0 g / dm 3
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10 33 Four current problems in our atmosphere are listed. 1 2 3 4 acid rain depletion of the ozone layer presence of greenhouse gases incomplete combustion of carbon compounds
Which atmospheric pollutant is responsible for each problem? W chlorofluorocarbons X Y Z 1 A B C D W X X Z sulfur dioxide carbon monoxide carbon dioxide 2 X W Z Y 3 Z Z W X 4 Y Y Y W
34 Which process takes place during photosynthesis? A B C D Carbohydrate is decomposed and oxygen is formed. Carbon dioxide is taken in and oxygen is formed. Oxygen is taken in and carbohydrate is formed. Oxygen is taken in and carbon dioxide is formed.
35 Cholesterol is an organic molecule that occurs in the blood stream. What type of compound is cholesterol? A B C D an acid an alcohol an alkane an alkene
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11 36 Substance X, molecular formula C4H8, does not react with hydrogen. What is the structural formula of X?
A H C H H C H C H H C H H C H H H H C C B H C H H H H H H C C H C H C C H H H H H C H H C D H C H C H H
37 Natural gas, petroleum and diesel are all used as energy sources. Which gas is not produced when these sources are burned? A B C D carbon dioxide carbon monoxide hydrogen water
Which statement about butenedioic acid is not correct? A B C D It decolourises aqueous bromine. Its aqueous solution reacts with sodium carbonate. Its empirical formula is the same as its molecular formula. Its relative molecular mass is 116.
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12 39 A mixture of four gases, methane, ethane, propane and butane is cooled until the first drop of liquid is formed. What compound is most likely to be present in this drop? A B C D butane ethane methane propane
40 Which statement about Terylene is correct? A B C D It is an addition polymer. It is an alkene. It is a polyamide. It is a polyester.
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I H
Hydrogen
II
IV
VI
VII
0
4
He
Helium
1 11 12 14 16 19
2 20
Li
Boron Carbon
Be
5 27 28 6 7
N
Nitrogen
O
Oxygen
F
Fluorine
Ne
Neon
Lithium
Beryllium
8 31 32
9 35.5
10 40
23
24
Na
Aluminium
Mg
13 51 52 55 56 59 59 64 65 70
Al
14
Si
Silicon
P
Phosphorus
S
Sulfur
Cl
Chlorine
Ar
Argon
Sodium
Magnesium
11
12
15 73 75
16 79
17 80
18 84
39
40
45
48
K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc
Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
31
Ga
Gallium
Ge
Germanium
As
Arsenic
Se
Selenium
Br
Bromine
Kr
Krypton
Potassium
Calcium
Scandium
Titanium
19
20
21
22
32 115 119
33 122
34 128
35 127
36 131
16
85
88
89
91
Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver
Sr
41 181 184 186 190 192 195 197 42 43 44 45 46 47
Zr
Nb
Mo
Tc
Ru
Rh
Pd
Ag
48
Cd
Cadmium
In
Indium
Sn
Tin
Sb
Antimony
Te
Tellurium
I
Iodine
Xe
Xenon
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49 201
Rubidium
Strontium
Yttrium
Zirconium
37
38
39
40
50 204 207
51 209
52
53
54
133
137
139
178
Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum
Ba
73 77 74 75 76 78
La Ta W Re Os Pt
Hf
Ir
Au
Gold
Hg
Mercury
Tl
Thallium
Pb
Lead
Bi
Bismuth
Po
Polonium
At
Astatine
Rn
Radon
Caesium
Barium
Lanthanum
Hafnium
55
56
57
72
79
80
81
82
83
84
85
86
226
227
Fr
140 141 144 150
Ra
Ac
152 157 159 162 165 167 169 173 175
Francium
Radium
Actinium
87
88
89
Pr
59 60 238 61
Nd
Pm
62
Sm
Samarium
Eu
Europium
Gd
Gadolinium
Tb
Terbium
Dy
Dysprosium
Ho
Holmium
Er
Erbium
Tm
Thulium
Yb
Ytterbium
Lu
Lutetium
58 232
63
64
65
66
67
68
69
70
71
Key Th
Thorium Protactinium Uranium
X Pa
91 92
X = atomic symbol
90
U
93
Np
Neptunium
Pu
Plutonium
Am
Americium
Cm
Curium
Bk
Berkelium
Cf
Californium
Es
Einsteinium
Fm
Fermium
Md
Mendelevium
No
Nobelium
Lr
Lawrencium
94
95
96
97
98
99
100
101
102
103
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).