DALIC, B.P.

90139, 35501 VITRE CEDEX, FRANCE

[email protected]
16.02.2009
Code: 10051, DSF8075, document code: FDS10051

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SAFETY DATA SHEET

1 - IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY
IDENTIFICATION OF THE PREPARATION

OXYDATION ANODIQUE TA91 or ANODISATION Ti (code: 10051)

or ANODISING SOLUTION TA91 (code: DSF8075)
USE OF THE PREPARATION
This solution is used for anodising titan parts locally, using the selective brush plating process or the Dalistick tool.
The treatment reduces the tendency to jamming and is sometimes completed by a lubricating operation. These
electrolysis processes (brush or DALISTICK) can be applied locally, i.e. without immersion of the part, just where it is
necessary. Thus, only small quantities of solutions are stored or used.
With the DALISTICK, the solution circulates in a closed loop without flowing on the area to be treated.
COMPANY IDENTIFICATION
DALIC - ZI de Plagu - 41, rue des Eaux - B.P. 90139 - 35501 VITRE CEDEX, FRANCE
Manufacturer and Seller, tel.: (33) 2.99.75.36.99, fax: (33) 2.99.74.49.31.
For information: [email protected], tel.: (33) 2.99.75.53.88.
RELEVANT OFFICIAL ADVISORY BODY (France): INRS / Orfila, tel. (33) 1.45.42.59.59.
________________________________________________________________________________________________
2 HAZARDS IDENTIFICATION
CHEMICAL NATURE
Aqueous solution of acids containing notably more than 15% sulphuric acid.
PRODUCT CLASSIFICATION ACCORDING TO 1999/45/EC and 67/548/EC
Symbol: C, risks phrases: R35
MAIN HAZARDS
Adverse physicochemical effects
- Fire or explosion: this product is not classified as flammable or explosive. However, it can be a secondary source of fire
or explosion, for example following its action on metals (hydrogen that forms is flammable and exploding in some
concentrations with air).
Adverse effects on health
Acidic and CORROSIVE preparation that can cause serious burns following a short contact (less than 3 minutes). Skin
damages in its whole depth and disabling after-effects of eyes are possible if decontamination with water is not quickly
achieved.
Effects on the environment
Is not classified as dangerous for the environment providing that the recommendations of the section 13 relative to
disposal as well as the national or local provisions are followed.
Refer also to the paragraphs 11, 12, 13 and 15.
________________________________________________________________________________________________
3 - COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENTS OR IMPURITIES CONTRIBUTING TO THE HAZARDS (according to 1999/45/EC and 67/548/EC)
Substances present in concentrations higher than the minimal level of danger: YES.
th

Regulated substance
Classification of the
pure substance
S phrases
Classification of the
substance according to
its concentration (in %)
Concentration range in
the preparation

H2SO4 (19 adaptation)

Sulphuric Acid
EC index N: 016-020-00-8
CAS N: 7664-93-9
EINECS N: 231-639-5
C R35
(1/2)- 26-30-45
15%
5-15%

C R35
Xi R 36/38
15%

Substances present in concentrations lower than the minimal level of danger (if 1%): NO.
Substances with the R33 phrase (if 1%) or the R64 phrase (if 1%) or sensitising substances (if 0.1%): NO.
OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.
________________________________________________________________________________________________

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

[email protected]
16.02.2009
Code: 10051, DSF8075, document code: FDS10051

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4 - FIRST AID MEASURES

CONTACT WITH SKIN
Take off contaminated clothing and shoes. Wash immediately with plenty of water for 10 to 15 minutes. Dont hesitate to
take a shower. In all cases, dont try to neutralize with bases and dont apply any cream. If an irritation appears or if the
contamination is large or in case of prolonged contact, seek medical advice.
CONTACT WITH EYES
Rinse immediately with plenty of water for approximately 15 minutes. Always call an ophthalmologist.
INHALATION
Theoretically, not applicable. Under abnormal conditions of use causing considerable inhalation, remove the casualty
from the contaminated area, let him take a rest in a well-ventilated room and seek medical advice. A delayed pulmonary
oedema may appear. A clinical, biological and radiological supervision and a treatment may be necessary in that case.
INGESTION
Dont try to induce vomiting. Do not give anything to drink. Transfer quickly into hospital. Complications may appear later.
PROTECTION OF THE FIRST-AIDERS
Wear gloves and according to the situation: glasses, clothes and protective shoes, a mask.
________________________________________________________________________________________________
5 - FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
Dry ice, powders.
EXTINGUISHING MEDIA WHICH SHALL NOT BE USED
Water.
SPECIFIC HAZARDS
Prevent any material from entering drains or waterways or soil.
Dangerous thermal decomposition products: in particular, vapours of sulphur oxides and oxygen. Hydrogen evolution is
possible.
PROTECTION OF THE FIRE-FIGHTERS
Because of the substances produced during thermal decomposition, use approved self-contained breathing equipment
and protective clothing in case of intervention.
________________________________________________________________________________________________
6 - ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Avoid contact with skin and eyes: wear gloves, glasses, overalls and safety boots. In case of contact, dispose of all
contaminated clothing and shoes and wash thoroughly in water.
ENVIRONMENTAL PRECAUTIONS
Do not allow the product to be thrown away. Recover as much as possible for processing within the firm or by an
approved centre.
METHODS FOR CLEANING UP
With water to remove all non-recoverable product. Before throwing rinsing water, check the pH is between 5.5 and 8.5.
________________________________________________________________________________________________
7 - HANDLING AND STORAGE
HANDLING
Use as supplied. Close containers (in PE) tightly after use with the original cap. Do not re-use containers with another
product.
STORAGE
Store in a room on a spill-retaining vat away from alkaline or reducing products, metals and flammable compounds. Keep
in original containers only, between 5 and 30C if possible away from direct sun-light. The maximum recommended shelf
life is three years from the date of manufacture under normal conditions of storage.
________________________________________________________________________________________________
8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
TECHNICAL MEASURES
No drinking, eating or smoking on the workplace.
Maintain the premises and the workplace in a perfect state of cleanliness and clean them frequently.
As the product is used at ambient temperature during a short time, the values below are generally not reached. They
depend on the treatment time, the surface area treated and on the quality of the workshop air extraction.

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

[email protected]
16.02.2009
Code: 10051, DSF8075, document code: FDS10051

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EXPOSURE LIMIT VALUES IN AIR

France: decisions of 26 October
2007, of 30 June 2004, INRS file
ND 2098
Directives 2006/15/EC,
2000/39/EC and 91/322/EC

Sulphuric acid
3
Average value (8h) = 1 mg/m
3
Limit value (15 min) = 3 mg/m
(INRS file ND 2098)
Not applicable

PERSONAL PROTECTION
Provide a shower, a powerful tap and sink unit and an eye basin near the workplace.
Respiratory protection: during brush electrolysis, provide as far as possible an inhaling of the sprays / vapours where
they are created and extraction out of the premises. Or work in a ventilated room and wear if necessary a filtering
FFP3 mask (EN 149:2001 standard) or a E2P3 cartridge (EN 405:2002 standard).
During electrolysis with the DALISTICK tool, these measures are not necessary, work taking place in a closed loop.
Hand protection: wear imperatively gloves (in nitrile, neoprene or PVC).
Eye protection: wear imperatively glasses with lateral protections or a facial screen. Do not wear contact lenses.
Skin protection: wear overalls and safety boots.
________________________________________________________________________________________________
9 - PHYSICAL AND CHEMICAL PROPERTIES
-

Appearance: colourless liquid.

Odour: odourless.
pH: <1.
Relative density: 1.16.
Solubility: miscible in water in all proportions.
Boiling point: approximately 100C.
Crystallisation / melting point: < 0C.
Flammability: nil.
Oxidising properties: nil.
Danger of fire or explosion: no, but the product can be a secondary source of fire or explosion, for example following
its action on metals (if large quantities of hydrogen are produced in a small space). It can also react vigorously with
some compounds (see section 10) especially in a concentrated or dehydrated state.
Other properties: not applicable.
________________________________________________________________________________________________
10 - STABILITY AND REACTIVITY
STABILITY
Good at ambient temperature with water evaporation for only risk. Good in humidity and light.
CONDITIONS TO AVOID
High temperatures: decomposition of some constituents from 290C.
MATERIALS TO AVOID
Notably bases, reducing products, metals (notably in powder), flammable or organic compounds, carbides, chlorates,
chromates, permanganates, nitrates, fulminates, cyanides
HAZARDOUS DECOMPOSITION PRODUCTS
Fumes containing in particular oxides of sulphur (from 290C) and oxygen (above 450C).
________________________________________________________________________________________________
11 - TOXICOLOGICAL INFORMATION
No data are available regarding the preparation. The evaluation of health hazards has been realised thanks to
directives 67/548/EC, 1999/45/EC and bibliographical data.
SKIN, EYE MUCOSA, IN CASE OF INGESTION
Serious burns following a short contact (less than 3 minutes). Skin damages in its whole depth and disabling after-effects
of eyes are possible. Bloody vomiting, ulcerations and haemorrhages in case of ingestion with risk of delayed
complications in the following days. The gravity depends on the length of contact before treatment and on the applied
quantity.
RESPIRATORY SYSTEM
Theoretically, not applicable: little sprays during brush electrolysis and very little sprays with the DALISTICK.
Under abnormal situation, exposure to weak or to moderate concentrations of sprays gives a slight irritation of the
superior respiratory system, or even an acceleration of the respiratory rhythm.
Exposure to high concentrations induces an intense irritation with pains and cough. After exposure, in case of massive
inhalation, a delayed pulmonary oedema may appear with risk of bacterial infection. Finally, after treatment, the
respiratory and ocular after-effects are generally small.
OCCUPATIONAL DISEASES: no (in FRANCE).
________________________________________________________________________________________________

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

[email protected]
16.02.2009
Code: 10051, DSF8075, document code: FDS10051

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12 - ECOLOGICAL INFORMATION
There are no ecological data on the preparation.
Prevent any material from entering drains or waterways or earth.
In general, a pH lower than 5 is fatal.
ECOTOXICITY
Bibliographic data concerning sulphuric acid at 94-98 %:
FISH-LC50 (24h) = 82 mg / L, DAPHNIA-EC50 (24h) = 29 mg / L.
MOBILITY
Sulphuric acid is very mobile in soils and dissolves quickly in water.
PERSISTENCE AND DEGRADABILITY
BIOACCUMULATION
Sulphuric acid has a weak bioaccumulative potential.
OTHER ADVERSE EFFECTS
No other information.
According to the applicable EC directives, it is not appropriate to apply theN symbol DANGEROUS FOR THE
ENVIRONMENT to this preparation.
________________________________________________________________________________________________
13 - DISPOSAL CONSIDERATIONS
This product and water used for rinsing must not be thrown away notably because of their acidity and their content in
metals after use. They must be processed within the firm or destroyed by an approved organization.
Contaminated packaging if not re-used with the same product is also special waste to be sent to an approved
organization for recycling or disposal.
Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (in particular
2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.
06 03 13* or Solid salts and solutions containing heavy metals
11 01 05*
Pickling acids
11 01 11*
Aqueous rinsing liquids containing dangerous substances
15 01 10*
Packaging containing residues of or contaminated by dangerous substances
As the volume of rinsing water is small, it can be added to the waste solutions.
NOTE: in addition to the community provisions, it can be specific legislative and administrative, national or local
provisions on this topic.
________________________________________________________________________________________________
14 - TRANSPORT INFORMATION
A.D.R. (road transport)
Sulfuric acid with 51 % or less acid, UN N2796, class 8, classification code: C1, packaging group II, hazard label model
8, restricted quantities LQ22, hazard code 80, material identification n 2796.
I.M.D.G. (sea transport)
Sulfuric acid with not more than 51 % acid, UN N 2796, class 8, subsidiary risk label: not applicable, packaging group II,
restricted quantities: 1 L, stowing and separation: category B, safety sheets F-A, S-B.
I.A.T.A. (air transport)
Sulphuric acid with 51 % or less acid, UN N 2796, class 8, subsidiary risk: not applicable, risk label: CORROSIVE,
packaging group II, Passenger and cargo aircraft: packaging instructions 809, maximum quantity per package: 1 L,
Cargo aircraft only: packaging instructions 813, maximum quantity per package: 30 L, instruction IDC: 8L.
________________________________________________________________________________________________
15 - REGULATORY INFORMATION
This safety data sheet has been established in accordance with the Corrigendum to Regulation (EC) n 1907/2006 of the
European Parliament and of the Council of December 18, 2006, OJ L136, 29.05.2007.
th
The preparation labelling has been established in compliance with the directive 67/548/EC (until the 29 adaptation:
directive 2004/73/EC of April 29, 2004) and the directive 1999/45/EC reviewed in last in January 23, 2006 by the
directive 2006/8/EC.
EC LABELLING: CORROSIVE
Aqueous preparation containing in particular sulphuric acid (> 15 %).
R35: causes severe bums.
S26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28: after contact with skin, wash immediately with plenty of water.
S36/37/39: wear suitable protective clothing, gloves and eye / face protection.
S45: in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

[email protected]
16.02.2009
Code: 10051, DSF8075, document code: FDS10051

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HEALTH SURVEILLANCE
Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to
chemical agents at work
An appropriate health surveillance of workers must be carried out according to the risk.
For each worker who undergoes this health surveillance, individual health and exposure records are to be made and kept
up-to-date.
Other paragraphs in the French version of this safety data sheet summarize French rules regarding:

administrative declarations and rules,

environment laws regarding rinsing water treatment.

The situation of the company has to be examined in relation to the specific legislative and administrative, national or local
provisions on these topics.
Additional information is provided in paragraphs 8, 11, 12, 13 and 14.
________________________________________________________________________________________________
16 - OTHER INFORMATION
RESTRICTION OF USE
For industrial use only.
We remain available to bring you the advice or training you may need.
R PHRASES OF THE PURE COMPONENTS LISTED IN SECTION 3
R35: causes severe burns.
R PHRASES OF THE PREPARATION ACCORDING TO THE SECTIONS 2 AND 15
R35: causes severe burns.
BIBLIOGRAPHIC REFERENCES
European directives, INRS files, safety data sheets of the components established by their manufacturers or distributors,
information of European Office of the chemical substances (ECB).
MODIFICATIONS
Information about Dalistick added.
OTHER INFORMATION
This sheet is provided to complement, not replace, the user instructions.
Information contained herein is bona fide and based on current knowledge relating to the product on the date of
publication. Furthermore, the attention of the user is drawn to the risks which may be incurred when the product is used
for purposes other than those for which it is designed.
Information provided herein relates to this product only; it cannot take account of every situation which may arise at every
work place. This safety data sheet therefore represents only a part of the information required for establishing a safety
programme.
Under no circumstances does this sheet dispense the user from the need to know and to apply all of the regulations
governing its activity, which are not all necessarily quoted herein in an exhaustive manner.
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