DALIC, B.P.

90139, 35501 VITRE CEDEX, FRANCE,

03.03.2010
[email protected]
Y1, codes : 10025, DSF 8070, document code: FDS10025

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SAFETY DATA SHEET

1 - IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY
IDENTIFICATION OF THE MIXTURE

ANODISATION OAC Y1 or CAA ANODISING AL Y1 (code 10025)

or Y1 ANODISING (code DSF 8070)
USE OF THE MIXTURE
This solution is used with brush or with the DALISTICK tool to anodize aluminium parts. These electrolysis processes (brush
or DALISTICK) can be applied locally without immersion of the part, just where it is necessary.
Thus, only small quantities of solution are stored or used. With the DALISTICK process, the solution circulates in a closed
circuit without flowing on the treatment area.
The resulting oxide layer improves the characteristics of aluminium alloys, notably their resistance to wear and corrosion.
COMPANY IDENTIFICATION
DALIC - ZI de Plagu - 41, rue des Eaux - B.P. 90139 - 35501 VITRE CEDEX, FRANCE
Manufacturer and Seller, tel.: (33) 2.99.75.36.99, fax: (33) 2.99.74.49.31.
For information: [email protected], tel.: (33) 2.99.75.53.88.
RELEVANT OFFICIAL ADVISORY BODY (France): INRS / Orfila, tel. (33) 1.45.42.59.59.
____________________________________________________________________________________________________
2 HAZARDS IDENTIFICATION
CHEMICAL NATURE
Aqueous acidic preparation containing in particular chromium trioxide.
PRODUCT CLASSIFICATION ACCORDING TO EC REGULATION
Symbols: T and N, risk phrases: R34-42/43-21/22-23-45-46-48/20-51/53
MAIN HAZARDS
Fire or explosion: this product is not classified as flammable or explosive but it can favour the combustion of other matters
if it is present in large quantities especially in the dehydrated state.
Adverse effects on health: according to the available data, the preparation is:

corrosive,

sensitising by inhalation and by contact with skin,

harmful in case of contact with skin and if swallowed,

toxic by inhalation.
If protective measures are not taken, the risk of a cancer development is very likely increased because of the presence of
chromic acid (agent of category 1, certainty of the effects on man), as well as the risk of hereditary genetic changes
(chromic acid is an agent of category 2, unproved but very likely effects on man).
Effects on the environment: the preparation is classified as TOXIC for the aquatic environment.
Refer also to the paragraphs 11, 12, 13 and 15.
____________________________________________________________________________________________________
3 - COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENTS OR IMPURITIES CONTRIBUTING TO THE HAZARDS ACCORDING TO EC REGULATION
Substances present in concentrations higher than the minimal level of danger: YES
Regulated substance

Classification of the pure

substance
Symbols
Classification of the
substance according to its
concentration (%). Only the
useful limits to classify the
preparation are indicated.

Weight % in the preparation

CrO3 - Chromium (VI) trioxide

H2SO4 - Sulphuric acid

EC index N: 024-001-00-0
CAS N: 1333-82-0
EC N: 215-607-8

EC index N: 016-020-00-8
CAS N: 7664-93-9
EC N: 231-639-5

O; R9
T+; R26
Carc. Cat. 1; R45
C; R35
Muta. Cat. 2; R46
R42/43
Repr. Cat. 3; R62
N; R50-53
T; R24/25-48/23
O, T+, N
10% C R35; 5-10% C R34
1-5% Xi R36/37/38
Other limits >> 1999/45/EC
5-7%
T, N
3-5%
T, N

R21/22-23-34-42/43-4546-48/20-51/53-62
R21/22-23-36/37/3842/43-45-46-48/20-51/53

3-5%

C R35

15% C R35
5-15% Xi R36/38

< 5%

Substances with the R33 phrase (if 1%) or the R64 phrase (if 1%) or other sensitizing substances: NO.
OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.
OTHER INFORMATION: contains also other EC non-regulated substances or regulated ones at a level below the
classification point.
____________________________________________________________________________________________________

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE,

Y1, codes 10025, DSF 8070,

03.03.2010
[email protected]
Safety Data Sheet, document code: FDS10025

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4 - FIRST AID MEASURES

CONTACT WITH SKIN
Take off contaminated clothing and shoes. Wash immediately with plenty of water.
CONTACT WITH EYES
Rinse immediately with plenty of water for approximately 15 minutes. In case of pain, redness, local oedema or visual
discomfort, call an ophthalmologist.
INHALATION
Theoretically, not applicable. Under abnormal conditions of use causing considerable inhalation, remove the casualty from the
contaminated area, let him take a rest in a well-ventilated room and seek medical advice.
INGESTION
Do not give anything to drink. Do not try to induce vomiting. Call medical service to transfer immediately into hospital.
PROTECTION OF THE FIRST-AIDERS
Wear gloves and goggles and according to the situation, protective clothes and shoes or a mask.
____________________________________________________________________________________________________
5 - FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
Dry ice, powders.
EXTINGUISHING MEDIA WHICH SHALL NOT BE USED
Avoid water.
SPECIFIC HAZARDS
Dangerous thermal decomposition products:
Beginning of decomposition of several constituents from 190C that notably gives chromium oxides, oxygen and sulphur
oxides susceptible to reinforce the combustion.
Prevent any material from entering drains or waterways or soil. The contaminated extinguishing agents must be treated and
eliminated in accordance with regulations.
PROTECTION OF THE FIRE-FIGHTERS
Because of the substances produced during thermal decomposition, use approved self-contained breathing equipment and
protective clothing in case of intervention.
____________________________________________________________________________________________________
6 - ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Avoid contact with the skin, clothes and eyes: wear gloves and glasses and if needed a FFP3 mask or an E2P3 cartridge in
case of sprays or vapours.
Dispose of all contaminated clothing or shoes and wash thoroughly with water.
ENVIRONMENTAL PRECAUTIONS
Do not allow the product to be thrown away. Recover as much as possible for processing within the firm or by an approved
centre. Reduce the remaining product for example with sodium bisulphite or iron (II) sulphate.
METHODS FOR CLEANING UP
With water to remove all non-recoverable product. Collect the recoverable rinsing water for processing within the firm or by an
approved centre.
____________________________________________________________________________________________________
7 - HANDLING AND STORAGE
HANDLING
Use as supplied. Close containers (of PE) tightly after use with the original cap. Do not re-use containers with another product.
STORAGE
Store on a spill-retaining vat in a room, away from alkaline, reducing or combustible products. Keep in tightly closed original
containers only, between 5 and 30C, away from direct sunlight and heat. The maximum recommended shelf life is THREE
years from the date of manufacture under normal conditions of storage.
____________________________________________________________________________________________________
8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
TECHNICAL MEASURES
No drinking, eating or smoking on the workplace.
Maintain the premises and the workstations in perfect state of cleanliness and clean them frequently.
Observe a very strict cutaneous hygiene and change clothes after work.
Check periodically that the limit values below are not reached. They depend on the treatment time, the surface area treated
and on the quality of the workshop air extraction.
During brush electrolysis, even if the product is used during a short time, it is important to protect the respiratory system and
to avoid contact with skin.

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE,

Y1, codes 10025, DSF 8070,

03.03.2010
[email protected]
Safety Data Sheet, document code: FDS10025

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EXPOSURE LIMIT VALUES IN AIR

France : decisions of 26 October 2007,
of 30 June 2004, INRS file nND 2098
Directives 2009/161/EU, 2006/15/EC,
2000/39/EC and 91/322/EC

Chromium (VI) trioxide, in Cr

Sulphuric acid
3
Average value (8h) = 0.05 mg/m 3
Average value (8h) = 1 mg/m
3
3
Max. limit value (15 min) = 0.1 mg/m Max. limit value (15 min) = 3 mg/m
(INRS ND 2098 file)

No

(INRS ND 2098 file).

Average value (8h) = 0.05 mg/m

(2009/161/EU, for mist, defined as the

thoracic fraction)

PERSONAL PROTECTION
Provide a shower, a powerful tap and sink unit, an eye basin and a protective breathing mask for emergency interventions
near the workplace.
Respiratory protection: during brush plating, provide an effective inhaling of the sprays / vapours where they are created
and extraction out of the premises, and if insufficient, wear a filtering FFP3 mask (EN 149:2001 standard) or an E2P3
cartridge (EN 405:2002 standard).
During electrolysis with the DALISTICK tool, these measures can be eased, work taking place practically in a closed loop.
Hand protection: wear imperatively gloves (preferably of CVP, neoprene and possibly of latex or nitrile).
Eye protection: wear glasses with lateral protections or a facial screen. Do not wear contact lenses.
Skin protection: wear overalls and safety shoes.
____________________________________________________________________________________________________
9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: clear orange red liquid.
Odour: odourless.
pH < 1.
Relative density: 1,14.
Solubility: miscible in water in all proportions.
Boiling point: approximately 100C.
Crystallization / Melting point: - 8C.
Flammability: no.
Oxidising properties, risk of explosion or fire: risk in case of contact with easily oxidizible materials if the preparation is
concentrated or dehydrated.
Other properties: no.
____________________________________________________________________________________________________
10 - STABILITY AND REACTIVITY
-

STABILITY
Good at room temperature with water evaporation for only risk. Good in humidity and light.
CONDITIONS TO AVOID
Beginning of thermal decomposition of several constituents from 190C.
MATERIALS TO AVOID
Avoid contact with alkaline, reducing or combustible products.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS
Notably fumes of sulphur oxides, chromium oxides and oxygen above 190C.
____________________________________________________________________________________________________
11 - TOXICOLOGICAL INFORMATION
No data are available regarding the mixture. The evaluation of health hazards has been realised thanks to applicable
regulations and bibliographical data.
Chromic acid can be absorbed by cutaneous or pulmonary way. It is quickly eliminated (60% in 8 to 24 hours) essentially by
urinary way (more than 80%).
SKIN
Can cause more or less serious burns according to the length of contact if decontamination with water is not quickly achieved.
May also cause recurring eczemas on some sensitive people. Harmful.
EYE MUCOSA
Can cause burns and lesions in case of contact if decontamination with water is not quickly achieved.
RESPIRATORY SYSTEM
Toxic. Danger of serious damage to health by prolonged exposure. May cause sensitisation by inhalation (asthma, rhinitis)
and may increase the risk of cancer.
IN CASE OF INGESTION
Damage to the digestive tract, pains, possible vomiting and other disorders according to the situations. Harmful.
MUTAGENIC EFFECTS
According to studies on animals, is suspected to be able to cause hereditary genetic changes on man.
EXPOSURE BIOLOGICAL VALUES
Reference values for the general population: serum chromium < 0,5 g/L. Urinary chromium: < 0,5 g/g of creatinine. For
chromium and its inorganic compounds: total urinary chromium = 0,6 g/L (BAR value).
French guide value at work (exposure to soluble chromium VI): total urinary chromium = 30 g/g of creatinine Sample to be
taken at the end of the shift and of week.
OCCUPATIONAL DISEASES: table n10 (in FRANCE).
____________________________________________________________________________________________________

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE,

Y1, codes 10025, DSF 8070,

03.03.2010
[email protected]
Safety Data Sheet, document code: FDS10025

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12 - ECOLOGICAL INFORMATION
There are no ecological data on the mixture.
Prevent any material from entering drains or waterways or earth.
In general, a pH lower than 5 is fatal.
Bibliographic data concerning chromium trioxide
ECOTOXICITY (ACUTE AQUATIC HAZARD)
LC 50 (96 h)- FISH, Colisa fasciatus = 20 mg Cr/L.
EC50 (24 h) - Daphnia magna = 0.53 mg Cr/L
EC50 (72h)- Algae, Scenedesmus subspicatus = 0.30 mg Cr/L
DEGRADABILITY
Chromium VI in water can be reduced in Chromium III by organic matters in water; Chromium III will settle in the sediments.
The oxidizing character of Chromium VI increases in water when the pH is low.
BIOACCUMULATIVE POTENTIAL
The bioaccumulation of chromium in soil and on the plants in surface is unlikely. Chromium is found in many organisms living
in soft water and accumulates moderately. There is no indication of the biologic increase of the chromium concentration along
the food chain (earth, plant and animal).
According to directive 1999/45/EC, there is enough chromium trioxide to consider this preparation as TOXIC to aquatic
organisms (N symbol and R51/53 phrase mandatory).
Bibliographic data concerning sulphuric acid ( 15 %)
ECOTOXICITY (ACUTE AQUATIC HAZARD): FISH-LC50 (24 h) = 82 mg/L, DAPHNIAS-EC50 (24 h) = 29 mg/L.
BIOACCUMULATION: low potential.
MOBILITY: high in soil and dissolves quickly in water.
OTHER ADVERSE EFFECTS: no other information.
____________________________________________________________________________________________________
13 - DISPOSAL CONSIDERATIONS
This product and water used for rinsing must not be thrown away notably because of their acidity and content in chromium.
They must be processed within the firm or destroyed by an approved organization.
Contaminated packaging if not re-used with the same product is also special waste to be sent to an approved organization for
recycling or disposal.
Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (in particular
2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.
16 09 02*
11 01 11*
15 01 10*
15 02 02*

Chromates, for example potassium chromate, potassium or sodium dichromate

Aqueous rinsing liquids containing dangerous substances
Packaging containing residues of or contaminated by dangerous substances
Absorbents, filter materials (including oil filters not otherwise specified), wiping
cloths, protective clothing contaminated by dangerous substances
As the volume of rinsing water is small, it can be added to the waste solutions.
NOTE: in addition to the community provisions, it can be specific legislative and administrative, national or local provisions on
this topic.
____________________________________________________________________________________________________
14 - TRANSPORT INFORMATION
A.D.R. (road transport)
Chromic acid solution, class 8, classification code C1, packaging group III, hazard label model: 8, restricted quantities LQ7,
hazard identification n 80, material identification n1755.
I.M.D.G. (sea transport)
Chromic acid solution, UN N 1755, class 8, packaging group III, subsidiary risk label: not applicable, restricted quantities 5 L,
stowing and separation: category C. Away from houses. Separation of products as for the class 5.1 but far from classes 4.1,
5.1 and 7, safety sheets F-A, S-B.
I.A.T.A. (air transport)
Chromic acid solution, UN N 1755, class 8, subsidiary risk: not applicable, risk label: CORROSIVE, packaging group III,
Passenger and Cargo aircraft: packaging instructions 818, maximum quantity per package: 5 L ; Cargo aircraft only:
packaging instructions 820, maximum quantity per package: 60 L, instruction IDC 8L.
____________________________________________________________________________________________________
15 - REGULATORY INFORMATION
This safety data sheet has been established in accordance with Annex II of the Corrigendum to Regulation (EC) n 1907/2006
of the European Parliament and of the Council of December 18, 2006, OJ L136, 29.05.2007 (Reach regulation).
The preparation labelling has been established in compliance with Annex VI, table 3.2 of regulation (EC) n1272/2008 of the
European Parliament and of the Council of December 16, 2008, OJ L353, 31.12.2008 (CLP regulation) and with the
1999/45/EC directive reviewed in January 23, 2006 by 2006/8/EC directive.
EC LABELLING: TOXIC, DANGEROUS FOR THE ENVIRONMENT
Aqueous acidic preparation containing in particular chromium trioxide.
Restricted to professional users
R34: causes burns.
R42/43: may cause sensitization by inhalation and skin contact.

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE,

Y1, codes 10025, DSF 8070,

03.03.2010
[email protected]
Safety Data Sheet, document code: FDS10025

5/5

R23: toxic by inhalation.

R45-48/20: may cause cancer. Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R46-21/22: may cause heritable genetic damage. Harmful in contact with skin and if swallowed.
R51/53: toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S23: do not breathe gas/fumes/vapour/spray.
S26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28: after contact with skin, wash immediately with plenty of water.
S36/37/39: wear suitable protective clothing, gloves and eye / face protection.
S45: in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S53: avoid exposure - obtain special instructions before use.
S60: this material and its container must be disposed of as hazardous waste.
HEALTH SURVEILLANCE
Corrigendum to Directive 2004/37/EC of the European Parliament and of the Council of 29 April 2004 on the protection of
workers from the risks related to exposure to carcinogens or mutagens at work, (OJ L229, 29.06.2004).
An appropriate health surveillance of the exposed workers must be carried out according to the risk.
For each worker who undergoes this health surveillance, individual health and exposure records are to be made and kept upto-date.
Other paragraphs in the French version of this safety data sheet summarize French rules regarding:

occupational diseases,

health surveillance,

work in another company,

administrative declarations and rules according to the involved quantity,

environment laws regarding rinsing water treatment.

See please the specific legislative and administrative, national or local provisions on these topics.
Additional information is provided in paragraphs 8, 11, 12, 13 and 14.
____________________________________________________________________________________________________
16 - OTHER INFORMATION
RECOMMENDATIONS
For industrial use only (Restricted to professional users).
Only people trained to the Dalic processes and informed about the risks should use this product. We remain available to bring
you the training, advice or studies you may need.
R PHRASES OF THE PURE COMPONENTS LISTED IN SECTION 3
R9: explosive when mixed with combustible material.
R24/25: toxic in contact with skin and if swallowed.
R26: very toxic by inhalation.
R35: causes severe burns.
R42/43: may cause sensitization by inhalation and skin contact.
R45: may cause cancer.
R46: may cause heritable genetic damage.
R48/23: toxic: danger of serious damage to health by prolonged exposure through inhalation.
R50/53: very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62: possible risk of impaired fertility.
R PHRASES OF THE PREPARATION ACCORDING TO THE SECTIONS 2 AND 15
R34: causes burns.
R42/43: may cause sensitization by inhalation and skin contact.
R23: toxic by inhalation.
R45-48/20: may cause cancer. Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R46-21/22: may cause heritable genetic damage. Harmful in contact with skin and if swallowed.
R51/53: toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
BIBLIOGRAPHIC REFERENCES
European directives, INRS and INERIS websites, safety data sheets of the components established by their manufacturers or
distributors, websites of the Consumer Products Safety and Quality Unit (ex-ECB, http://ecb.jrc.ec.europa.eu/), of ECHA and
FIM.
MODIFICATIONS
Updating in relation to annex XVII of regulation (EC) n1907/2006 of the European Parliament and of the Council.
Revised paragraphs: n15, 16.
OTHER INFORMATION
This sheet is provided to complement, not replace, the user instructions.
Information contained herein is bona fide and based on current knowledge relating to the product on the date of publication.
Furthermore, the attention of the user is drawn to the risks which may be incurred when the product is used for purposes other
than those for which it is designed.
Information provided herein relates to this product only; it cannot take account of every situation which may arise at every
work place. This safety data sheet therefore represents only a part of the information required for establishing a safety
programme.
Under no circumstances does this sheet dispense the user from the need to know and to apply all of the regulations governing
its activity, which are not all necessarily quoted herein in an exhaustive manner.
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