DALIC, B.P.

90139, 35501 VITRE CEDEX, FRANCE

[email protected]

14.05.2007
Code: 10008, document code: FDS10008

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SAFETY DATA SHEET

I - IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
IDENTIFICATION OF THE SUBSTANCE OR PREPARATION

DECAPAGE Z 74 (code: 10008)

USE OF THE SUBSTANCE / PREPARATION
This solution is used at ambient temperature with the brush electrolysis process for degreasing the surface of every
material.
The specificity of the brush process is it can be applied locally just where it is necessary without immersion of the part.
Thus, only small quantities of solutions are stored and used.
COMPANY / UNDERTAKING IDENTIFICATION

DALIC - ZI de Plagu - 41, Rue des Eaux, BP. 90139 - 35501 VITRE CEDEX, France
Manufacturer and Seller Tel.: (33) 2.99.75.36.99 - Fax: (33) 2.99.74.49.31
FRENCH EMERGENCY TELEPHONE

INRS / Orfila, tel.: (33) 1.45.42.59.59

________________________________________________________________________________________________
II - COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENTS OR IMPURITIES CONTRIBUTING TO THE HAZARDS (according to 1999/45/EC and 67/548/EC)
Substances present in concentrations higher than the minimal level of danger: YES
sd

Regulated substance
Classification of the
pure substance
Symbols
S phrases
Classification of the
substance according to
its concentration (in %)
Concentration range in
the preparations

EDA (22 adapt.)

Ethylenediamine
EC index N: 612-006-00-6
EC N: 203-468-6
CAS N: 107-15-3
R10 C R34 - Xn R21/22
R42/43
C
(1/2)-23-26-36/37/39-45
C R 21/22-34-42/43
25%
C R34-42/43
10-25%
Xn R36/38-42/43
2-10%
Xn R42/43
1-2%
2-10%

Substances with the R33 phrase (if 1%) or with the R64 phrase (if 1%) or other sensitising substances (if 0.1%): NO.
OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.
OTHER INFORMATION: contains also not regulated salts.
________________________________________________________________________________________________
III HAZARDS IDENTIFICATION
CHEMICAL NATURE
Alkaline aqueous preparation which contains notably ethylenediamine.
PRODUCT CLASSIFICATION ACCORDING TO 1999/45/EC and 67/548/EC
Xn symbol, R36/38-42/43
MAIN HAZARDS
Adverse physicochemical effects
- Fire or explosion: this product is not classified as flammable or explosive.
Adverse effects on health
According to the directives 67/548/EC and 1999/45/EC, this preparation must be considered as IRRITATING and
SENSITIZING by inhalation and contact with skin.
Effects on the environment
According to the same directives, this preparation do not present a special risk to environment providing that the
recommendations of the section XIII relative to disposal as well as the national or local provisions are followed. Refer also
to the paragraphs XI, XIII and XV.
________________________________________________________________________________________________

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

[email protected]

14.05.2007

Code: 10008, Safety Data Sheet, document code: FDS10008

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IV - FIRST AID MEASURES

CONTACT WITH SKIN
Take off contaminated clothing and shoes. Wash immediately with plenty of water.
CONTACT WITH EYES
Rinse immediately with plenty of water for approximately 15 minutes.
In case of pain, redness, local oedema, visual discomfort or doubt, call an ophthalmologist.
INHALATION
Theoretically, not applicable. Under abnormal conditions of use causing considerable inhalation, remove the casualty from
the contaminated area, let him take a rest in a well-ventilated room and seek medical advice. Do an ocular and cutaneous
decontamination. In case of massive inhalation, hospitalize the person. A supervision of the effects may be necessary.
INGESTION
Do not give anything to drink, do not induce vomiting. Call immediately the medical service. It is advisable to hospitalize the
person.
PROTECTION OF THE FIRST-AIDERS
According to the situation, wear protective clothes, glasses or masks Wear at least gloves.
________________________________________________________________________________________________
V - FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
Dry ice, powders, foam.
EXTINGUISHING MEDIA WHICH MUST NOT BE USED
No.
SPECIFIC HAZARDS
Avoid contact with powerful oxidizing agents and acidic products.
Prevent any material from entering drains or waterways.
Concerning pure ethylenediamine:
- Flash point: 38C (DIN 51755)
- Boiling point: 117-118C at atmospheric pressure,
- Ignition temperature: 405C (DIN 51794)
Dangerous thermal decomposition products: notably emission of ammonia, of nitrogen oxides and carbon oxides.
PROTECTION OF THE FIRE-FIGHTERS
Because of the substances that are produced during thermal decomposition, use approved self-contained breathing
equipment and protective clothing in case of intervention.
________________________________________________________________________________________________
VI - ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Avoid contact with the skin, the clothes and the eyes: wear at least gloves, glasses and if needed a FFP3 mask.
Dispose of all contaminated clothing or shoes and wash thoroughly with water.
ENVIRONMENTAL PRECAUTIONS
Do not allow the product to be thrown away. Recover as much as possible for processing within the firm or by an approved
centre.
METHODS FOR CLEANING UP
With water to remove all non-recoverable product. Check the pH is between 5.5 and 8.5.
________________________________________________________________________________________________
VII - HANDLING AND STORAGE
HANDLING
Use as supplied. Close containers (in PE) tightly after use with the original cap. Do not re-use containers with another
product.
STORAGE
Store away from powerful oxidizing or acidic agents. Keep in original containers only, in a room at 5-30C. The maximum
recommended shelf life is three years from the date of manufacture under normal conditions of storage.
________________________________________________________________________________________________
VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
TECHNICAL MEASURES
No drinking, eating or smoking on the workplace.
It is important to protect its respiratory system and to avoid contact with skin.

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

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14.05.2007

Code: 10008, Safety Data Sheet, document code: FDS10008

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During brush electrolysis, as this product is low concentrated and used at ambient temperature during a short time, it does
not seem very useful to perform checks of atmosphere, except in case of large parts or of continuous use. However, it is
recommended to measure it once in the harder conditions of work and periodically after if necessary.
Maintain the premises and the work stations in perfect state of cleanliness.
EXPOSURE LIMIT VALUES IN AIR
Ethylenediamine
Directives 2006/15/EC,
2000/39/EC, 91/322/EC
France: decision of 30 June
2004 or before (according
to INRS file ND 2098)

No
Average value (8 h) = 25
3
mg/m (10 ppm)
Max. limit value (15 min)
3
= 35 mg/m (15 ppm)

PERSONAL PROTECTION
Provide a shower, a powerful tap and sink unit and an eye basin in the vicinity of the work place.
- Respiratory protection: during brush plating, provide if possible an inhaling of the sprays / vapours where they are created
and extraction out of the premises. Otherwise or if insufficient, wear in a ventilated room a filtering FFP3 mask according to
EN 149:2001 standard or an A2P3 cartridge according to EN 405:2002 standard.
- Hand protection: wear imperatively gloves (in latex or nitrile for example).
- Eye protection: wear glasses with lateral protections or a facial screen. Do not wear contact lenses.
- Skin protection: wear overalls and safety shoes.
________________________________________________________________________________________________
IX - PHYSICAL AND CHEMICAL PROPERTIES
- Appearance: pale yellow liquid.
- Odour: odourless.
- pH: 9.1.
- Relative density: 1.05.
- Solubility: miscible in water.
- Boiling point: approximately 100C.
- Crystallisation / melting point: - 3C.
- Flammability: nil.
- Oxidising properties: nil.
- Risk of explosion and fire: nil.
- Other properties: not applicable.
________________________________________________________________________________________________
X - STABILITY AND REACTIVITY
STABILITY
Good at normal temperature with water evaporation for only risk.
Good in humidity, slight yellowing by light or with air is possible.
CONDITIONS TO AVOID
High temperatures.
MATERIALS TO AVOID
Powerful oxidizing agents and acidic agents (particularly if the product has been accidentally concentrated or dehydrated).
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS
Toxic and pungent fumes; notably emission of ammonia, of carbon oxides and of nitrogen oxides.
________________________________________________________________________________________________
XI - TOXICOLOGICAL INFORMATION
No data are available regarding the preparation. The evaluation of health hazards has been realised thanks to
directives 67/548/EC, 1999/45/EC and bibliographical data.
SKIN
Irritating (more or less according to the contact length). Due to the presence of aliphatic amines, may also cause the
appearance of recurring eczemas on some sensitive people.
EYE MUCOSA
Irritating in case of contact.
RESPIRATORY SYSTEM
Harmful, may cause sensitisation by inhalation (asthma) on some sensitive people because of the presence of
ethylenediamine.
IN CASE OF INGESTION
Gastro-intestinal problems, irritations, pains, vomiting are possible.
INDUSTRIAL DISEASES: tables n49, 49a (in FRANCE).
________________________________________________________________________________________________

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

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14.05.2007

Code: 10008, Safety Data Sheet, document code: FDS10008

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XII - ECOLOGICAL INFORMATION

There are no ecological data on the preparation.
Bibliographic data concerning ethylenediamine:
ECOTOXICITY
FISHES - LC50 (96 h) = 116 mg/L; DAPHNIA MAGNA - EC50 (24 h) = 19 mg/L; MICRO-ORGANISMS: Pseudomonas
putida/EC50 (17 h): 29 mg/L.
MOBILITY - PERSISTENCE AND DEGRADABILITY - BIOACCUMULATIVE POTENTIAL OTHER ADVERSE EFFECTS
Method : OCDE 301C ; ISO 9408 ; 92/69/CEE, C.4-F, activated muds
Destruction level: 93 - 95 % (28 days), easily biodegradable.
According to the applicable EC directives, it is not appropriate to apply theN symbol DANGEROUS FOR THE
ENVIRONMENT to the preparation.
________________________________________________________________________________________________
XIII - DISPOSAL CONSIDERATIONS
This product and water used for rinsing must not be thrown away notably because of their pH and content in greases after
use. They must be processed within the firm or destroyed by an approved organization.
Contaminated packaging if not re-used with the same product is also special waste to be sent to an approved organization
for recycling or disposal.
Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (in particular
2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.
06 03 13*
or 11 01 13*
11 01 11*
15 01 10*

Solid salts and solutions containing heavy metals

Degreasing wastes containing dangerous substances
Aqueous rinsing liquids containing dangerous substances
Packaging containing residues of or contaminated by dangerous
substances

As the volume of rinsing water is small, it can be added to the waste solutions.
NOTE: in addition to the community provisions, it can be specific legislative and administrative, national or local provisions
on this topic.
________________________________________________________________________________________________
XIV - TRANSPORT INFORMATION
A.D.R. (road transport)
Amines, liquid, corrosive, n.o.s. (ethylenediamine, mixture), class 8, classification code C7, packaging group III, hazard
label model n 8, restricted quantities LQ7, hazard identification n 80, material identification n 2735.
I.M.D.G. (sea transport)
Amines, liquid, corrosive, n.o.s. * (ethylenediamine, mixture), UN N 2735, class 8, packaging group III, subsidiary risk
label: not applicable, restricted quantities: 5 L, stowing and separation: category A, away from acids, safety sheets F-A, SB.
I.A.T.A. (air transport)
Amines, liquid, corrosive, n.o.s. * (ethylenediamine, mixture), UN N 2735, class 8, subsidiary risk: not applicable, risk
label: CORROSIVE, packaging group III, Passenger- and Cargo aircraft: packaging instructions 818, maximum quantity per
package: 5 L, Cargo aircraft only: packaging instructions 820, maximum quantity per package: 60 L, instruction IDC 8L.
________________________________________________________________________________________________
XV - REGULATORY INFORMATION
This safety data sheet has been established in accordance with Commission Directive 91/155/EC of 5 March 1991
modified by the directive 2001/58/EC of 27 July 2001. It complies with standards NF T 01-102 and ISO 11014-1.
th
The preparation labelling has been established in compliance with the directive 67/548/EC (until the 29 adaptation:
directive 2004/73/EC of 29 April 2004) and the directive 1999/45/EC last modified by the directive 2006/8/EC of 23 January
2006.
EC LABELLING: HARMFUL
Alkaline aqueous preparation containing particularly ethylenediamine.
R36/38-42/43; S23-26-36/37-45
R36/38: irritating to eyes and skin.
R42/43: may cause sensitization by inhalation and skin contact.
S23: do not breathe gas / fumes / vapours / spray.
S26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37: wear suitable protective clothing and gloves.
S45: in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

[email protected]

14.05.2007

Code: 10008, Safety Data Sheet, document code: FDS10008

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HEALTH SURVEILLANCE
Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to
chemical agents at work
An appropriate health surveillance of workers has to be carried out according to the risk.
For each worker who undergoes this health surveillance, individual health and exposure records are to be made and kept
up-to-date.
Other paragraphs in the French version of this safety data sheet summarize French rules regarding:

professional diseases,

health surveillance,

work in another company,

administrative declarations and rules,

environment laws regarding rinsing water treatment.

See specific legislative and administrative, national or local provisions on these topics.
Additional information is provided in paragraphs VIII, XI, XII, XIII and XIV.
________________________________________________________________________________________________
XVI - OTHER INFORMATION
RESTRICTION OF USE
For industrial use only.
R PHRASES OF THE PURE COMPONENTS LISTED IN SECTION 2
R10: flammable.
R21/22: harmful in contact with skin and if swallowed.
R34: causes burns.
R42/43: may cause sensitization by inhalation and skin contact.
R PHRASES OF THE PREPARATION ACCORDING TO THE SECTIONS 3 AND 15
R36/38: irritating to eyes and skin.
R42/43: may cause sensitization by inhalation and skin contact.
BIBLIOGRAPHIC REFERENCES
European directives, INRS files, safety data sheets of the components established by their manufacturers or distributors,
information of European Office of the chemical substances (ECB).
MODIFICATIONS
Updating in relation to directives 2001/58/EC, 2001/59/EC, 2001/60/EC, 2004/73/EC and 2006/8/EC.
General presentation. Revised paragraphs: all.
OTHER INFORMATION
This sheet is provided to complement, not replace, the user instructions.
Information contained herein is bona fide and based on current knowledge relating to the product on the date of
publication. Furthermore, the attention of the user is drawn to the risks which may be incurred when the product is used for
purposes other than those for which it is designed.
Information provided herein relates to this product only; it cannot take account of every situation which may arise at every
work place. This safety data sheet therefore represents only a part of the information required for establishing a safety
programme.
Under no circumstances does this sheet dispense the user from the need to know and to apply all of the regulations
governing its activity, which are not all necessarily quoted herein in an exhaustive manner.
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