12 Physics Chemistry EM
12 Physics Chemistry EM
12 Physics Chemistry EM
mKf
khF jehL Kjyikr mtf Mizgo
btsjh ghfgl khtlf gulh tF
gY khzt khza eyid fU bfhL mtf
fw
juid
ca
nkgLJtjbfd
j,
nj
My,
Gfhoid
fzF,
aa,
mu
khztf
dhjh
nj
tiu
Gfhoid
mogil
mfF
neh
brW,
khztf
njfis
vbfhsjf
Jiw
nfLbfhwJ.
midJ
Ma
bgUkfis
1
Mark
3
5
Marks Marks
10
Marks
Total Marks
1. Electrostatics
25
2. Current
Electricity
20
3. Effects of
Electric Current
20
25
25
6. Atomic Physics
25
7. Dual Nature of
Radiation and
Matter and
Relativity
15
8. Nuclear Physics
25
9. Semiconductor
Devices and their
Applications
30
10. Communication
Systems
20
30
20
12
230
4. Electromagnetic
Induction and
Alternating
Current
5. Electromagnetic
Waves and Wave
Optics
TOTAL
1. There is a possibility of getting 65 marks if the pupil study the question and
answers for the units 1,7 and 8 completely. The distribution of marks for these
units are given in the following table.
UNIT
1 MARK
3 MARKS
5 MARKS
10 MARKS
TOTAL
MARKS
25
7
8
2
4
1
2
2
1
15
25
65
TOTAL MARKS
Photoelectric
effect-Stopping
potential, threshold frequency, Photo
Electric cells, Electron microscope
uses and limitations, relativity.
2. After taking practice in the above units, if they learn very well in the units
2 and 4, the pupil may get high marks.
UNIT 1 MARK
3 MARKS
5 MARKS
10 MARKS
TOTAL
MARKS
20
25
45
TOTAL MARKS
UNIT
velocity,
density,
Ohms
Mobility,
law,
Resistivity, velocity,
Superconductors,
Application
Temperature superconductors,
Comparison
potential
of
difference,
emf
and Kirchhoffs
Difference bridge,
of
Combination
series
and
laws,
of
parallel,
Wheatstones
Potentiometer
Principle,
laws
of
electrolysis
Secondary cells.
induced
emf,
inductance
of
two
long
enclosed
generator,
by the
Eddy
coil,
AC
currents,
3. After learning the above 5 units, if the students learn the units 3 and 5 the students
may get a minimum of 110/150 marks in physics.
UNIT
1 MARK
3 MARKS
5 MARKS
3
5
2
4
1
2
1
1
TOTAL
10 MARKS MARKS
1
1
20
25
45
TOTAL MARKS
UNIT
coefficient,
Particle
in
Motion of charged
uniform
electric
field,
waves
,
and
their
Emission
and
and
photons,
double
slit
experiment
Fresnel
diffraction,
and
Difference
4. After completing 7 lessons, the pupil are asked to learn the lesson 6, 9 and 10 if they
learn all these lessons thoroughly, students may get full mark.
UNIT 1 MARK
3 MARKS
5 MARKS
10 MARKS
TOTAL
MARKS
25
30
10
20
75
TOTAL MARKS
UNIT
Principle
Millikans
Bohrs
experiment,
Drawbacks of
Postulates,
Ionization
energy,
X-rays-soft
X-rays
Extrinsic
semiconductors,
Barkhausen
Advantages
of
integrated
10
Propagation of radio waves, Skip distance, Analysis of A.M, Radio transmission and
Skip
zone,
Modulation,
Modulation
Limitations of
advantages
and
disadvantages.
communication-
merits
and
5. The first excitation potential energy or the minimum energy required to excite the
atom from ground state of hydrogen atom is,
(10.2eV)
6. According to Rutherford atom model, the spectral lines emitted by an atom is,
(continuous spectrum)
7. Energy levels A, B, C of a certain atom correspond to increasing values of energy
(i.e.,)EA<EB<EC. If 1, 2, 3 are the wavelengths of radiations corresponding to the
transitions C to B, B to A and C to A respectively, which of the following statements
is correct.
8. The elliptical orbits of electron in the atom were proposed by (Sommerfeld)
9. X- ray is
(phenomenon of conversion of kinetic energy into radiation)
10. In an X ray tube, the intensity of the emitted X ray beam is increased by
(increasing the filament current)
11. The energy of a photon of characteristic X ray from a Coolidge tube comes from
(an atomic transition in the target)
12. A Coolidge tube operates at 24800 V. The maximum frequency of X rays emitted
from Coolidge tube is
(6 x 1018 Hz)
13. In hydrogen atom, which of the following transitions produce a spectral line of
maximum wavelength
(6
5)
14. In hydrogen atom, which of the following transitions produce a spectral line of
maximum frequency (2
1)
15. After pumping process in laser,
(the number of atoms in the excited state is
greater than the number of atoms in the ground state)
16. The chromium ions doped in the ruby rod (absorbs green light)
UNIT 7. DUAL NATURES OF RADIATION AND MATTER AND RELATIVITY
1. A photon of frequency
( h( - 0))
2. The work function of a photoelectric material is 3.3 eV. The threshold frequency will
be equal to ( 8 x 1014 Hz)
3. The stopping potential of a metal surface is independent of
(intensity of incident radiation)
4. At the threshold frequency, the velocity of the electron is (zero)
5. The photoelectric effect can be explained on the basis of (quantum theory of
light)
6. The wavelength of the matter wave is independent of
(charge)
7. If the kinetic energy of the moving particle is E, then the de Broglie wavelength is,
8. The momentum of the electron having wavelength 2A0 is (3.3 x 10-24 kg ms-1)
9. According to relativity, the length of a rod in motion (is less than its rest length)
10. If 1 kg of a substance is fully converted into energy, then the energy produced is
(9 x 1016 J)
9
UNIT 8
NUCLEAR PHYSICS
UNIT 9
1. The electrons in the atom of an element which determine its chemical and electrical
properties are called (valance electrons)
2. In an N type semiconductor, there are
(immobile positive ions)
3. The reverse saturation current in a PN junction diode is only due to
(minority carriers)
4. In the forward bias characteristic curve, a diode appears as
(ON switch)
5. Avalanche breakdown is primarily dependent on the phenomenon of
(collision)
6. The colour of light emitted by a LED depends on (type of semi conductor material)
7. The emitter base junction of a given transistor is forward biased and its collector
base junction is reverse biased. If the base current is increased, then its
(IC will increase)
8. Improper biasing of a transistor circuit produces
(distortion in the output signal)
9. An oscillator is
(an amplifier with feedback)
10. In a Colpitts oscillator circuit
(capacitive feedback is used)
10
(101)
14. According to the laws of Boolean algebra, the expression (A+AB) is equal to (A)
15. The Boolean expression ABC can be simplified as A + B + C
UNIT 10
COMMUNICATION SYSTEMS
11
r = / o
7. State the super position principle in electrostatics.
The total force on a given charge is the vector sum of the forces exerted on it
due to all other charges.
times
]
max=8.5x10
-26
Nm
-7
C located at 0.09 m
Solution :
NC
-1
at a distance of 2 cm.
E=
9
=Ex
=9x104x
x10-9x2x10-2
=10-7 Cm-1
32. Three capacitors each of capacitances 9 pF are connected in series. What is the
total capacitance of the capacitor?
Solution :
= + +
= ;
Cs=3pF
14
10F
10F
Solution : C1 = 5F ; C2 = 10 F ;
C3 = 10 F
C2 and C3 are in series.
=
=
Cs = 5F
Cp = C1 + Cs
Cp = (5+5) F
Cp = 10F
15
= qE 2d sin( p = q x 2d)
= pE sin
In vector notation> p E
2.Electric potential energy of an electric dipole in uniform electric field.
It is the work done in rotating the dipole to the desired position in the electric field.
3. The expression for electric potential at any point due to a point charge.
The electric potential at P is the work done in moving a unit positive charge
from infinity to that point
r
q
dx
2
x
0
q
4 0 r
4. The expression for electric potential energy of two point charge system.
The electric potential energy of a two point charge system is equal to the work
done to assemble the charges.
q1
The potential at B due to q1charge , V 4 r
0
V q2
The capacitor is a charge storage device. This work done to store the charges is
stored as electrostatic potential energy in the capacitor.
If dq is the additional charge given to the plate,
q
dW
C
dq
V C
q
q2
Total work done W q dq, W
0
2C
q CV
17
2.
The expression for electric field at any point due to electric dipole along the
equatorial line
-q and +q charges at A and B Constitute
an electric dipole.
P is a point at a distance r from the centre
of the dipole O along the equatorial line
Electric field at P due to +q
18
x cos
But, cos =
d << r,
E=
The direction of E is along the axis of the dipole and opposite to that of the dipole moment.
3.
q
4 0 r1
q
Electric potential at P due to -q charge
4 0 r2
1 q
1 q
q
4 0 r1
q
Electric potential at P due to -q charge
4 0 r2
Electric potential at P due to +q charge
19
1 q
1 q
4 0 r1 4 0 r2
V =
2
d << r,
r 1 2 = r2 ( 1 -
),
1 1 d cos 1 1 d
1
1 cos
r1 r
r , r2 r r
V =
( 1+
V =
( p = q x 2d)
V
) ]
( 1-
p cos
4 0 r 2
Special cases
1.
=00
If
2. If=1800
3. If
=900
V=
V=
p
4 0 r 2
p
4 0 r 2
V =
4. Expression for electric field due to an infinite long straight charged wire.
Consider an uniform the charged wire of
infinite length having +q charge. Its linear
charge density is = . Let P be a point at a
distance r from the wire. Consider a cylindrical
Gaussian surface of length
and radius r ,
closed at each end by plane caps normal to the
axis.
Electric flux through the curved surface ) = E dS cos
= E dS [ = , cos =
=E(2 r )
E and d are perpendicular to each other , the flux through the plane caps is equal to zero
By Gausss law, =
E (2 r ) = ( q =
E=
The direction of E is radially outward for positive charge. The direction of E is radially
inward for negative charge.
20
5. The expression for electric field due to uniformly charged spherical shell
i) At a point outside the shell
Consider a charged shell of radius R . Let P be a point at a distance r from the centre.
The sphere with radius r is the Gaussian surface. Electric field acts perpendicular to the
surface.
Electric flux crossing normally to the surface,
= E (4 r2)
By Gausss law
E (4 r2)
E
= ]
[ =
By Gausss law =
Here q = 0, (The total charge inside the surface is zero)
Gaussian surface
of A is C=q/V.
When another insulated metal plate B is brought near A, negative charges are induced on
the side of B near A. An equal amount of positive charge is induced on the other side of
B. The negative charge in B decreases the potential of A, and the capacitance of A is
increased.
21
If the plate B is earthed, positive charges get neutralized. Then the potential of A
decreases further, and capacitance of A is considerably increased.
The capacitance depends on the geometry of the conductors and nature of the
medium.
A parallel plate
capacitor consists of two
parallel metal plates X
and Y each of area A, separated by a distanced, having a surface charge
density . A charge+q is given to the plate X. It induces a charge q on the upper
surface of earthed plate Y.
Charge q = A
By the application of Gausss law, electric field at a point between the two
plates is,
=
The potential difference between X and Y
C=
22
Capacitors in parallel
C1, C2, C3 capacitors are connected in series. C1, C2, C3 capacitors are connected in parallel .
Cs is the effective capacitance
Cp is the effective capacitance
V1 =
q 1 = C 1V ; q 2 = C 2V ; q 3 = C 3V
q = q1 + q2 + q3
; V2 =
; V3 =
V = V1 + V2 + V3
q = C pV
V=
CPV = V(C1+C2+C3)
q
q
q
q
Cs
C1
C2
C3
CP = C1 + C2 + C3
1
1
1
1
Cs C1 C2 C3
23
Working :
Because of the high electric field near the comb D, the air gets ionised due to
action of points, the negative charges in air move towards the needles and
positive charges are repelled on towards the belt. These positive charges stick
to the belt, moves up and reaches near the comb E.
The machine, continuously transfers the positive charge to the sphere. After
this stage no more charge can be placed on the sphere, it starts leaking to the
surrounding due to ionization of the air.
The high voltage produced in this generator can be used to accelerate positive
ions (protons, deuterons) for the purpose of nuclear disintegration.
5.
24
6.
0
ii. No particle can attain the velocity of light.
20. The work function of a metal is 1.8 eV. Calculate its threshold wave length.
Solution:
W = 1. 8eV = 1. 8 x 1. 6 x 10-19J
h0 = W
h =W
i. If; v = c, =
0 =
0 =
0 =
0 = 6. 902 x 10 m or 0 = 6902 A
-7
26
21.
Solution :
=
= 1. 121 x 10-10m
(or)
= 1. 121 A
22.
Calculate the De Broglie wave length of an electron in the 4th orbit of hydrogen atom .
Solution :
r4 = 42 r1 = 16 x 0.53A
2 r4 = n,
=
=
= 3.14 x 0.53 x 10-10 x 8
= 13.313 x 10-10m
The photo electric current increases linearly with a intensity of the incident radiation.
The photo electric current is directly proportional to number of photo electrons.
The number of photo electrons emitted per second is proportional to intensity of the
incident radiation.
2. Photo electric effect, the laws of photo electric effect
Photo electric effect is the phenomena by which a good number of substances,
chiefly metals , emit radiations under the influence of radiation such as rays , X-rays,
ultraviolet and even visible light
The laws of photo electric effect :
(i) For a given photo sensitive material, there is a minimum frequency called the
threshold frequency, below which emission of photo electrons stops completely, how
ever great the intensity may be.
27
(ii) The photo electric current is directly proportional to the intensity of the incident
radiation, provided the frequency is greater than the threshold frequency.
(iii)The photo electric emission is an instantaneous process.
(iv) The maximum kinetic energy of the photo electrons is directly proportional to
the frequency of incident radiation, but is independent of its intensity.
3.The construction and working of photo electric cells
It is a device to convert light energy into electrical energy
Construction :
h mc2
E = h
E = mc2
mc 2
( = )
If
c=v
h
h
or
p
mv
28
2eV
m
12.27 0
A
V
h
E=eV,
2mE
m
Since
h
2meV
h
mv
The electron in various orbits behaves as a wave .
The stationary orbits are those in which the orbital circumference (2r ) is an integral
multiple of De Broglie wave length (2r = n )
(n=1, 2, 3, . . . )
mvr
2 r = n(
nh
2
Consider two frames of references S and S' . The length of the rod as measured by an
observer in S frame of reference is l0Consider the frame of reference S' moves with the
velocity v. Now the length measured by the observer is .
v2
1 2
c
v2
1 2
c
10.Time dilation
The clock in the frame of reference S' gives out signals in t0seconds
The time measured by the observer is t in the frame of reference S
t
t0
1
v2
c2
t > t0
The time interval is lengthened by a factor
1
1
v2
c2
Eg: The clock in the moving ships will appear to go slower than the clocks in the earth.
30
Let mo be the rest mass and m be the mass of the body moving with velocity v
d
According to Newtons second law, F (mv)
(1)
dt
According to relativity theory
dv
dm
(2)
F m
v
dt
dt
The increase in kinetic energy
dEk = F dx
dEk =m v d v + v2dm (3)
According to Einsteins relativity theory
m
m0
1
v2
c2
(4)
dEk = c2 dm
Ek
(5)
dEk c 2 dm
m0
106 eV
32
The three types of mesons are (1) -meson (pion) (2) Kmeson
(3) - meson.
The mesons are the interaction agents between nucleons.
34
(kaon) and
zX
He 4 + 2 He 4 + 2 He 4 + -1eo+ -1eo
A+4+4+4= 238
A= 238 12 = 226
Z + 2 + 2 + 2 1 -1= 92
Z= 92-6+2
Z=88
Hence the Isotope is 88Ra226
35.The half life of radon is 3.8 days. Calculate its mean life.
=
T (or)
= 1.443 T
= 1.443 x 3. 8
= 5. 4834 days
= 5. 5 days
35
36.What percentage of given radioactive substance will be left after 5 half life periods
Half life Period
Remaining Percentage Decayed Percentage
I
50%
50%
II
25%
III
12.5%
IV
6.25%
3.125%
(93.75+3.125)% = 96.875%
Decayed Percentage
50%
(50 + 25)% = 75%
(75 + 12.5)% = 87.5%
(87.5 + 6.25)% = 93.75%
(93.75+3.125)% = 96.875%
38.Tritium has a half life of 12.5 years. What fraction of the sample of will be left over
after 25 years?
Half life Period
Remaining Fraction
Decayed fraction
1/2
I (12. 5 Years)
3/4
II (25 Years)
No. of half lives = Total life time
Half life
=25/12.5 = 2
Sample left after 25 years =
The BE/A8.8 MeV at A=56, (26Fe56). Hence, iron nucleus is the most stable.
The average B.E./A value is about 8.5 MeV for nuclei having mass number ranging
between 40 and 120. These elements are comparatively more stable and non radio
active.
For higher mass numbers the curve drops slowly and the BE/A is
about 7.6 MeV for uranium. Hence, they are unstable and radioactive.
The lesser amount of binding energy for lighter and heavier nuclei explains nuclear
fusion and fission respectively.
2. Nuclear force and properties of nuclear force.
There is some other force in the nucleus which overcomes the electrostatic
repulsion between positively charged protons and binds the protons and neutrons
inside the nucleus called nuclear force.
Nuclear force is charge independent. It is the same for all the three types of pairs of
nucleons (nn), (pp) and (np).It force is not electrostatic in nature.
Nuclear force is the strongest known force in nature.
Nuclear force is not a gravitational force. Nuclear force is about 1040 times stronger
than the gravitational force.
Nuclear force is a short range force. It is very strong between two nucleons which are
less than 1015m apart.
3. Properties of rays
They move along straight lines with high velocities.
They are deflected by electric and magnetic fields.
They produce intense ionization in the gas through which they pass. (The
ionizing power is 100 times greater than that of -rays and 10,000 times
greater than that of rays.)
They affect photographic plates.
They produce fluorescence.
Their penetrating power is less .
4. Properties of rays
(i) They move with over the range of 0.3c to 0.99c, where c is the velocity of light.
(ii) They are deflected by electric and magnetic fields.
(iii) The ionization power is comparatively low. (less than alpha particles)
(iv) They affect photographic plates.
(v) They produce fluorescence.
(vi) Their penetrating power is greater than that of rays.
5. Properties of rays
(i) They travel with the velocity of light.
(ii)They are not deflected by electric and magnetic fields.
(iii)They produce very less ionisation.
(iv)They affect photographic plates.
(v)They have a very high penetrating power.
(vi)They produce fluorescence.
37
Neutrons are neutral particles with no charge and mass slightly greater than
that of protons.
Neutrons are stable inside the nucleus. But outside the nucleus they are unstable.
The half life of neutron is 13minutes.
1
1
0
0n 1H +1e +
As neutrons are neutral, they can easily penetrate any nucleus.
Neutrons are classified according to their kinetic energy as (a) slow neutrons(0 to
1000eV) and (b) fast neutrons(0.5MeV to 10MeV), (c) Thermal neutrons (0.025eV)
8. Medical applications of radio isotopes.
Radio cobalt (Co60) used in the treatment of cancer.
Radio-sodium (Na24) - used to detect the presence of blocks in blood vessels, to
check the effective functioning of heart Radio-iodine (I131) -used in the detection
of the nature of thyroid gland and to locate brain tumours.
9.
Biological hazards of nuclear radiations
The biological effects of nuclear radiation can be divided into three groups
(i)Short term recoverable effects
(ii)long term irrecoverable effect sand
(iii)genetic effect.
The extent to which the human organism is damaged depends upon (i) the dose and
the rate at which the radiation is given and (ii)the part of the body exposed to it.
Short term recoverable effects :
Smaller doses of radiation exposure produce skin disorder and loss of hair.
Long term irrecoverable effects :If the exposure is 100 R*, it may cause diseases like leukemia (death of red blood
corpuscle in the blood) or cancer. When it U 600 R, ultimately it causes death. Safe
38
the
principle
and
working
function
of
on
Effects : The explosion releases tremendous amount of energy in the form of heat, light
and radiation.
Temperature of millions of degree celsius and pressure of millions of atmosphere
are produced.
Explosions produce shock waves.
The release of radioactive rays, neutrons and radioactive materials produce a
health hazards.
39
atom
12.
Bainbridge
mass spectro- meter is an instrument used for the accurate
determination of atomic masses.
Construction :
A beam of positive ions produced in a discharge tube is collimated in total fine
beam by two narrow slits S1 and S2.
This fine beam enters into a velocity selector.
The velocity selector allows the ions of a particular velocity of to come out of it.
40
Working :The electric field (E) and magnetic field (B) are perpendicular to each other.
They are adjusted that the deflection so that the ions do not suffer any deflection
within the velocity selector.
qE=Bqv
v=E/B
Ions having this velocity v, pass out of the velocity selector and then through
the slit S3, to enter the evacuated chamber D.
These positive ions are subjected to another strong uniform magnetic field of
induction B at right angles to the plane of the paper acting in wards.
These ions are deflected along circular path of radius R and strike the
photographic plate.
The force due to magnetic field Bqv provides the centripetal force.
B qv=mv2/R
m= B qR/v
Substituting v=E/B
m=B B qR/E
Ions with different masses trace semi-circular paths of different radii and produce
dark lines on the plate.
The distance between the opening of the chamber and the position of the dark line
gives the diameter 2 R.
Since q, B, B, E and R are known, the mass of the positive ions
and hence isotopic masses can be calculated.
2. Obtain an expression to deduce the amount of the radioactive substance present at
any moment.
Law of disintegration : The rate of disintegration at any instant is directly proportional to the number of
atoms of the element present at that instant.
Let N0 be the number of radio active atoms present initially and N, the number of
atoms at a given instant t.
here
- decay constant
At
t=0 N=N0
loge N0
loge N =
+ loge N0
loge(N/N0)=
N/N0=
N=N0
41
,
2.3026
T1/2 =
T1/2 = 0.6931
Chadwick in the same year discovered that the emitted radiation consists of
particles of mass nearly equal to proton and no charge.
He called them as neutrons. (0n1)
9
4
12
1
4Be +2He 6C +0n
Whereon1 represents neutron.
42
Properties of neutrons :(i) Neutrons are the constituent particles of all nuclei, except hydrogen.
(ii) Neutrons are neutral particles with no charge and mass slightly greater
than that of protons.
(iii) Neutrons are stable inside the nucleus. But outside the nucleus they are
unstable. The half life of neutron is 13 minutes.
1
1
0
0n 1H +1e +
(iv) As neutrons are neutral, they can easily penetrate any nucleus.
(v) Neutrons are classified according to their kinetic energy as (i) slow neutrons (0
to 1000eV) and (ii) fast neutrons (0.5MeV to 10MeV). (iii) Thermal neutrons
(0.025eV)
4. GeigerMuller counter
Principle :When nuclear radiations pass through gas, ionization is produced.
Construction:tube with glass envelope (C) acts as the cathode.
A metal
A fine tungsten wire (W) along the axis of the tube acts as anode.
The tube is filled with an inert gas like argon at a low pressure.
One end is fitted with a thin mica sheet and this end acts as a window through which
radiations enter the tube.
A high potential difference of about 1000 V is applied between the electrodes
through a high resistance R of about 100 mega ohm.
Operation:
A ionizing radiation enters the counter.
Due to the high potential difference and they cause further ionisation
43
5. Nuclear reactor.
A nuclear reactor is a device in which the nuclear fission reaction takes place
in a self sustained and controlled manner. The essential parts of nuclear reactor are
i) Fissile material or fuel
(i)
Fissile material or fuel
(ii)
Moderator
(iii)
Neutron source
(iv)
Control rods
(v)
The cooling system
(vi)
Neutron Reflector
(vii)
Shielding
The fissile material or nuclear fuel generally used is U235. Pu239 and U233 are used as
92
fissile material.
In the pressurised heavy water reactors (PHWR), natural uranium oxide is used as fuel.
In the pressurised light water reactors (PWR), low enriched uranium is used as fuel
In Kamini reactor U233 is used.
ii) Moderator
A Moderator converts neutrons of a moderator is to slow down fast neutrons of
energy about 2 MeV to thermal neutrons of energy about 0.025 eV,)
Moderators slow down the fast neutrons. E.g. Ordinary water and heavy water.
(iii)Neutron source
A source of neutron is required to initiate the fission chain reaction for the
first time.
44
6. Stellar energy
ProtonProton cycle
1
1
2
0
1H +1H 1H +1e +(emission of positron and neutrino)
1
2
3
1H +1H 2He + (emission of gamma rays)
2 2He3 2He4 + 21H1
There action cycle is written as
41H1 2He4 +21e0 +2 +energy (26.7MeV)
CarbonNitrogen Cycle
The following cycle of reactions take place in carbon nitrogen cycle in which
carbon acts as a catalyst.
1
12
13*+ (emission of gamma rays)
1H +6C 7N
13* C13 + e0 + (emission of positron and neutrino)
7N
6
1
1
13
14
1H +6C 7N + (emission of gamma rays)
1
14
15* + (emission of gamma rays)
1H +7N 80
15* N15 + e0 + (emission of positron and neutrino)
80
7
1
1
15
12
4
1H +7N 6C +2He
The overall reaction of the above cycle is given as
41H1 2 He4 +21e0 +2 +energy(26.7MeV)
7. Cosmic Rays Latitude effect , Altitude effect .
Cosmic Rays:
The ionising radiation many times stronger than -rays entering the earth from
all the directions from cosmic or inter stellar space is known as cosmic rays.
Latitude effect :
The variation of cosmic ray intensity with geo magnetic latitude is known as
latitude effect.
Intensity is maximum at the poles (=900), minimum at the equator(=0) and
constant between latitudes of 420 and 900.
The decrease in cosmic ray intensity at the earths equator is be due to the earths
magnetic field.
The charged particles approaching poles travel almost along the direction of the
magnetic lines of force and hence maximum intensity at poles.
The charged particles approaching equator have to travel in a perpendicular
direction to the field and hence minimum intensity at the equator.
45
Altitude effect :
The study of variation of cosmic ray intensity (I) with altitude (h) is known as altitude
effect.
The intensity increases with altitude and reaches a maximum at a height of about 20 km.
Above this height there is a fall in intensity.
46
of
unit ohm()
47
Power P = VI
Energy E = VIt
Unit: Joule(J)
Practical unit KWh
48
23.
Cannotbe recharged
Canbe recharged
steady
current
If 6.251018 electrons flow through a given cross section in unit time, find the
current.(Given: Charge of an electron is 1.61019 C)
Solution:
I= I=
I=
24.
= 1A
An incandescent lamp is operated at 240V and the current is 0.5A. What is the
resistance of the lamp?
Solution:
R =
R =
R=
R = 480
25. A manganin wire of length 2m has a diameter of 0.4mm with a resistance of
70. Find the resistivity of the material.
Solution: =
=
= 1.57 x 7 x 4 x 10-7
= 4.396x10-6 m
49
by
for
26. In the given network, calculate the effective resistance between points
A and B
Solution:
R1, R2 are in Parallel combination
,
= 7.5
27. Three resistors are connected in series with 10V supply as shown in the figure. Find
the voltage drop across each resistor.
Solution:
Effective resistance of series combination Rs = R1 + R2 + R3
Rs = 5 + 3 + 2 Rs = 10
Current in circuit I =
=1A
50
28. In the given circuit, what is the total resistance and current supplied by the
battery.
Solution:
3, 3, 3 are parallel combination.
+ +
Rp = 1
I=
= = 2A
I = 2A
29. Two wires of same material and length have resistances 5 and
10 respectively. Find the ratio of radii of the two wires.
Solution: Let R1 = 5, R2 = 10, 1 = 2 =
=
=
=
r1: r2 =
:1
30. Calculate the current in the given circuit and also find the direction of the current.
A
5
10V
7
2V
B
3
D
8V
51
Solution:
Let the current flowing the circuit is I. Current flowing in the direction ABCDA(Clock wise
direction)
5 I + 7I + 3I + 5I = 10 + 2 8
20 I = 4, I = I = 0.2 A
Current is flowing in the Clock wise direction
31. Calculate the current in the given circuit and also find the direction of the current.
A
5
10V
10
B
D
20 V
According to Kirchoffs second law
5 I + 10 I + 5 I = 10 + 20,
20 I = 30 I = I = 1.5 A
10V
10
Solution:
According to Kirchoffs second law
5I+10I+5I = 10-20
20I = -10
I= I=I=-0.5A
Current I = 0.5A
Currents flows in the anti clock wise direction ( ADCBA)
52
33. The resistance of a nichrome wire at 0oC is 10. If its temperature coefficient of
resistance is 0.004/oC, find its resistance at boiling point of water. Comment on
the result.
Solution:
R100
Rt = Ro (1 + t)
R100 = Ro (1+100)
= 10 (1+ 100 x 0.004)
=10 (1 + 0.4)
= 10 x 1.4
R100 = 14
An iron box of 400 W power is used daily for 30minutes. If the cost
per unit is 75 paise, find the weekly expense on using the iron box.
Solution: Energy Consumed
E= Pxt
E = 400 x x 7
E = 1400 Wh
E = 1.4 Unit
Cost of 1 unit = Rs. 0.75
Cost of 1.4 Units = 1.4 x 0.75
Expense = Rs 1.05
53
I nAe vd
q
(nAL)e
t
L
v
d
Let us
consider
4. Resistors in parallel
Consider four resistors of resistances R1, R2, R3 and R4 are connected in parallel.A
source of emf V is connected to the
parallel combination in parallel connection the
potential difference (V)across each resistor is the same.
V
V
V
V
; I 2 ; I3 ; I 4
R1
R2
R3
R4
Net current I = I1 +I2 +I3 + I4.
I1
V V V V
R1 R2 R3 R4
1
1
1
1
I V
---- 1
R1 R2 R3 R4
Let the effective Resistance be Rp
V
------ 2
I
Rp
1
1
1
1
1
From equations (1) and (2)
Rp R1 R2 R3 R4
55
With key K open the emf of cell E is found by connecting a high resistance voltmeter
across it. A small value of resistance R is included in the external circuit and Key K is
closed. The potential difference across R is equal to the potential difference across
cell(V).
V = IR
Internal resistance of the cell (r) , V is less than E
V = E Ir
Ir = E V
equations (1) / (2 )
=
E V
r
R
V
7. Kirchhoffs second law (Voltage law)
Kirchhoffs voltage law states that the algebraic sum of the products of resistance
and current in each part of any closed circuit is equal to the algebraic sum of the emfs in
that closed circuit.
It is based on the principle of law of conservation of energy
The current in clockwise direction is taken as positive and the current in anti clock
wise direction is taken as negative.
For the circuit shown in fig;
56
8. Wheatstones bridge
I1 P
R
Q
S
1 1
P
R
P R
Q S
9. Principle of potentiometer
The potentiometer wire B is connected in series with a battery (Bt), Key(K), rheostat
(Rh) This forms the primary circuit.
A primary cell is connected in series with the positive terminal A of the potentiometer, a
galvanometer, high resistance and jockey. This forms the secondary circuit.
If the potential difference between A and J is equal to the emf of the cell, no
current flows through the galvanometer. It shows zero deflection.
57
If the balancing length is l the potential difference across AJ = Irl where r is the
Resistance per unit length of the potentiometer wire
E = Irl,
El
The potentiometer wire AB is connected in series with the battery (Bt), key(K),
Rheostat(Rh) .This forms the primary circuit
The cells with emfs E1, E2are connected with the terminals C1D1 and C2 D2 of the
DPDT switch.
Current in the primary circuit is I. The resistance per unit length of the wire is r
(1)
(2)
Dividing 1 2
E1 1
E2 2
Law:
The mass of a substance liberated at an electrode is directly proportional to the charge
passing through the electrolyte. A battery, a rheostat, a key and an ammeter are connected
in series to an electrolytic cell
58
A current I1 is passed for a time t. the mass m1 of the substance deposited is obtained.
(1)
The experiment is repeated for same current I for time mass of the s u b s t a n c e
deposited is
The same current I is passed for time t2, the mass of the substance deposited is m4,
m3 t1
m4 t2
mt
(2)
Rh
mE
m2 E 2
mE
59
Action :
Zinc rod reacts with H2SO4 and zinc rod becomes negative charge by removing Zn++ions
Copper neutralizes 2H+ ions and thus becomes positive.
The current passes from copper to zinc in the external circuit.
Emf produced by the cell 1.08V
The zinc rod reacting with dilute sulphuric acid produces Zn++ ions and 2electrons
and thus becomes negative.
Zn++ ions pass through the pores of the porous potand reacts with copper
sulphate solution, producing Cu++ ions the Cu++ ions deposit on the copper vessel
and the vessel becomes positive.
When Daniel cell is connected in a circuit, the two electrons on the zinc rod
pass through the external circuit and eutralizing t h e c o p p e r ions.
Electric current passes from copper to zinc, in the external circuit
Emf produced by the cell 1.08V.
60
Chloride
VesselGlass
Action:
At the zinc rod, due to oxidation reaction Zn atom is converted in to Zn++ ions
and 2 electrons. Zn++ions reacting with ammonium chloride produces zinc
chloride and ammonia gas.
Zn++ +2NH4Cl2NH3 +ZnCl2+2H+ +2e
The positive charge of hydrogen ion is transferred to carbon rod and the two
electrons from the zinc rod move towards carbon and neutralizes the positive
charge.
Thus current flows from carbon to zinc.
Action:
The spongy lead reacting with dilute sulphuric acid produces lead sulphate and two
electrons due to oxidation.
At the positive electrode due to reduction process lead oxide on reaction with
sulphuric acid produces lead sulphate and the two electrons are neutralized in this
process.
The cell has low internal resistance and hence can deliver high current.
The emf of a freshly charged cell is 2.2Volt.
The emf falls to about 2 volts during discharge .
61
UNIT 4
e
State Lenzs law of electromagnetic induction?
The induced current produced in a circuit always flows in such a direction
that it opposes the change or cause that produce sit.
5. State Flemings Right hand rule.(Generator Rule)
4.
The forefinger, the middle finger and the thumb of the right hand are held in the three
mutually perpendicular directions. If the forefinger points along the direction of the
magnetic field and the thumb is along the direction of motion of the conductor,
then the middle finger points in the direction of the induced current.
6.What is self induction ?
The property of a coil which enables to produce an opposing induced emf in it when
the current in the coil changes is called self induction.
7. Define coefficient of self induction
The coefficient of self induction of a coil is numerically equal to the magnetic flux
linked with a coil when unit current flows through it. Unit : Henry(H)
63
Step-down transformer
1.
2.
3.
4.
S.No
64
24. What happens in the current if the frequency of a.c voltage increases in R.L.C.
series circuit?
If the frequency of the alternating voltage increases , the impedance decreases and the
current increases . At the resonant frequency the current reaches its maximum value. If
the frequency is greater than the resonant frequency, the current decreases slowly.
25.What is resonant frequency in R.L.C. series circuit?
The particular frequency at which the impedance of the circuit becomes minimum
and therefore, the current becomes maximum is called resonant frequency of the circuit.
26.Define Q factor (Quality factor)
The Q factor of a series resonant circuit is defined as the ratio of the voltage
across a coil or capacitor to the applied voltage.
voltage across L or C
Q= applied voltage
Q=
27. What is power factor of an a.c circuit?
Power factor = cos
Here is the phase difference between alternating current and voltage. It is the ratio of
average power to its apparent power.
28.What is a choke coil?
A choke coil is an inductance coil of very small resistance used for controlling
current in an a.c.circuit.
29. Distinguish between AF choke coil and RF choke coil
S.No AF choke coil
RF choke coil
1.
Used in
circuits.
2.
3.
Self-inductance is high.
Self-inductance is low
low
30. A coil of area of cross section 0.5m2 with 10 turns is in a plane which is
perpendicular to an uniform magnetic field of 0.2Wb/m2. What is the flux
through the coil?
Solution:
Magnetic flux = NBAcos
= NBAcos0o
(...= 0o)
= 10 x 0.2 x 0.5
= 1 Wb
65
31. An emf of 10 mv is induced when the current in the coil changes at the rate of
2A s 1. W h a t i s t he coefficient of self-induction of the coil?
Solution :
e = -L
Coefficient of self-induction L =
32. An emf of 5V is induced when the current in the coil changes at the rate of
100A s 1. W h a t i s t he coefficient of self induction of the coil?
Solution :
e = -L
Coefficient of self-induction
L=
L = -0.05H
L= 0.05 H
34. Calculate the mutual inductance between two coils when a current of 4A
changing to 8A in 0.5s in one coil, induces an emf of 50mv in the other coil.
Solution:
e2 = -M(
Coefficient of mutual induction M =
M=
M = 6. 25 mH
66
x 10-3 = -6. 25 mH
35. Magnetic field through a coil having 200 turns and cross sectional area
0.04m2 changes from 0.1wbm2 to0.04 wb m2 in 0.02s.Find the induced
emf.
Solution :
200x4x10-2 x3
2x4x3
24V
The magnitude of induced emf e =24V
36. An aircraft having a wing span of 20.48m flies due north at a speed of 40
ms1. If the vertical component of earths magnetic field at the place is
2105T, Calculate the emf induced between the ends of the wings.
Solution:- Induced emf e= - B v
e = -2 x 10-5 x 20.48 x 40
= -20.48 x 80 x 10-5
= -1638.4 x10-5
e = -0.0164V
37.
An aircraft having a wing span of 10m flies due north at a speed of 720 km/ hr . If
the vertical component of earths magnetic field at the place is 3 105T, Calculate
the emf induced between the ends of the wings.
Solution:-Induced emf
e = -B v
-5
e = -3 x 10 x 10 x 720 x
e = -3 x 10 x 200 x 10-5
e = -6000 x 10-5e = - 0.06 V
38.Two rail so far railway track insulated from each other and the ground are
connected to a millivolt meter.The train runs at a speed of 180 Km/hr. Vertical
component of earths magnetic field is 0.2104 Wb/m2 and the rails are
separated by1m. Find the reading of the voltmeter.
Solution:-Induced emf
e = -B v
39. The transformer ratio of an ideal transformer is 1:20 .Its input power and voltages
are 600mW, 6V respectively. Find the primary and the secondary current.
Solution :
= , Ep Ip = 600 mW; Ep = 6V
Ep Ip = 600 mW
But
= 100x10-3 = 0.1 A
Ip =
=
Is=
x Ip =
x 0.1 = 2A
Electric power
P = VI
I =
I =
Power loss
Power loss
I = 0.5A
= I2R
= (0.5)2x 2
= 0.25 x 2
= 0.5 W
41. Write the equation of a 25 cycle currents in a wave having rms value of 30 A.
Solution :
= sin t
=
Xc =
Effective current Irms=
=
Irms=
=0.126A
68
1.
Consider a long solenoid of length and area of cross section A and number of
turns N.and the current be I
Magnetic flux per turn = BArea of each turn
NI
NI
0 A B 0
0 N 2 IA
N
(1)
Magnetic flux = LI
(2)
From equations 1 and 2
0 N 2 AI
LI
`
N2A
L 0
N 2 A
L
In a medium of permeability
dt
dI
I dt
dt
dW = -L I d I
The total work done to increase the current from zero to maximum
I0
W dW LIdI
0
1
W L I 02
2
1
L I 02
2
69
S1 and S2 are two long solenoids with length and area of cross section A. N1 and
N2 are their number of turns
The magnetic flux linked with S2 due to I1 current in S1 = B1 A
N
N
B1 0 1 I1
0 1 I1 A
N
The total magnetic flux in S2 2 0 1 I1 A N 2
N1 N 2
(1)
2 0
I1 A
2 = M I1
(2)
From equations 1 and 2
MI1
0 N1 N 2 AI 1
0 N1 N 2 A
In a medium of permeability ,
N1 N 2 A
M
70
Irms
I0
2
( sin2
dt
I 02 RT
(1)
2
The heat produced by RMS value of the current (Irms)
2
H I rms
RT
(2)
H
I 02
2
I rms
I0
2
71
(1)
(2)
The applied voltage and current are in phase with each other
Phase diagram
Phasor diagram
The instantaneous power of an A.C circuit is the product of the instantaneous emf
and the instantaneous current flowing through it.
emf
e = E0 sin t
Current i = I0 sin( t + )
=
Pav =
cos
72
Pav =
cos
= Erms Irmscos
coil.
(NBA cos t )
e = NBA sin
e = Eosin
Here Eo = NBA
73
Perpendicular
90o
parallel
Eo
180o
Perpendicular
270o
parallel
-Eo
360o
Perpendicular
1) AB moves downwards
CD moves downwards
2) CD moves upwards
3) The current flows in
armature along DCBA.
the
Induced emf
(ii)Induction furnace
The material to be melted is placed in a varying magnetic field
of high frequency.
The drum rotates along with the wheel when the train is in
motion.
When the brake is applied, a strong magnetic field is developed
and eddy currents are produced in the drum .
The eddy current oppose the motion of the drum and the train
comes to rest.
(v)Speedometer
Construction : It consists of insulated primary and secondary coils wound on a soft iron core .
A laminated soft iron core is used.
Working:
A varying alternating voltage is given to primary coils.
The magnetic flux changes in the primary coils
Magnetic flux in the secondary coil changes. An emf is induced in the secondary
coils.
Ep, Es the emfs Np, Ns the number of turns in the coils Ip, Is the currents
76
Efficiency
Step
down
transformer
Es> Ep
Ep> Es
Ns>Np
Np>Ns
Ip>Is
Is>Ip
K> 1
K< 1
= output power
Input power
e=-L
But
e = - e'
Eo sin t = L
i=
sin t dt
Current; i =
77
i=
i=
sin t dt
sin ( t - )
Current i = Iosin ( t - )
From equations (1) and (2)
Phase diagram
(2)
L = XL
For d.c.
= 0 XL = 0 so a pure inductor offers zero resistance to d.c. . But the
inductive reactance varies proportional to the frequency for a.c.
6. A.C circuit with capacitor only
e = Eo sin t
(1)
= (Ce)
i = (CEo sin
i = E0 C sin
i=
sin
i = Io sin
)
)
)
78
(2)
.
Phase diagram
Phasor diagram
Xc =
For d.c.
= 0, XC =
For a.c. XC
7. R, L, C series circuit
A resistor R , an inductor L , a capacitor C are connected in series and the
combination is connected across alternating source of emf
VR = I R
VR, I are in phase
VL= I XL
VL leads the current by a phase of
Vc= I Xc
Vc lags behind the current by a phase of
The circuit is considered as predominantly inductive
(i) Effective voltage
2
V = VR + (VL-VC)
V=
V=
V=I
(ii) Impedance
(iii) Phase angle between V and I
tan =
= tan-1(
Current I = Io sin (
79
5 Mark Questions
1.Explain Biot-Savart law.
2.Derive an expression for magnetic induction due to a current carrying long solenoid.
3.Give the special features of magnetic Lorentz force.
4.Obtain an expression for force between two long parallel current carrying conductors.
5. How will you convert a galvanometer into an ammeter?
6. How will you convert a galvanometer into a voltmeter?
10 mark questions
1.Explain Joule heating effect with the calorimeter experiment
2.Derive an expression for magnetic induction at any point due to an infinitely long current
carrying straight conductor .
3.Derive an expression for magnetic induction at any point along the axis of a current
carrying circular coil.
4.Explain the principle, construction and working of a tangent galvanometer.
5.Discuss the motion of a charged particle in a uniform magnetic field.
6.Explain the principle, construction and working of Cyclotron
7.Derive an expression for the force acting on a current carrying conductor kept in a
magnetic field.
80
1)
2)
3)
4)
5)
10 Mark Questions
Explain emission spectra and absorption spectra.
Explain Raman effect.
Explain total internal reflection by wave theory
Derive the expression for bandwidth in Youngs double slit experiment.
Discuss the theory of interference in thin transparent film due to reflected light and
obtain condition for the intensity to be maximum and minimum.
81
82
5 Mark Questions
1) Explain the working of diode as a half wave rectifier.
2) Deduce the relation between and of a transistor.
3) Explain the working of a transistor as a switch .
4) Explain voltage divider bias with circuit diagram
5) State and prove De-Morgans theorem.
6) Explain OR and AND gates by using electrical circuits.
7) Explain frequency response curve of a transistor amplifier.
8) How multimeter is used as ohm meter?
10 Mark Questions
1) Explain the working of bridge rectifier.
2) Describe the working of a transistor amplifier.
3) What is meant by feedback? Derive and expression for voltage gain of an amplifier
with negative feedback?
83
84
CHEMISTRY
BLUE PRINT
S.NO
LESSONS
10
marks
marks
marks
marks
TOTAL
Atomic Structure
10
Periodic classification
09
P Block Elements
12
d Block Elements
18
f - Block Elements
07
11
09
Coordination
Components
Nuclear Chemistry
Solid State
09
Thermodynamics
10
10
Chemical equilibrium
10
11
Chemical Kinetics
12
12
Surface Chemistry
11
13
Electro Chemistry I
1(1)
14
14
Electro Chemistry II
10
08
16
Isomerism in Organic
Chemistry
Hydroxy Derivatives
12
17
Ethers
07
18
Carbonyl Compounds
14
19
Carboxylic Acids
14
11
07
08
30
21
12
14
233
15
21
Organic Nitrogen
Compounds
Bio molecules
22
Chemistry in Action
20
Total
We classify the learning capacity of categories. In the first category, this package is used for
scoring pass mark. In the second stage, it is used for scoring 80 marks, the third stage is used
for scoring 120 marks and the fourth stage ,they can able to get 150/150.
Stage - I
TABLE 1
Lesson
No
5
Lesson
1 mark
3 Mark
5 Mark
10 Mark
Total
F block Elements
07
Nuclear Chemistry
09
Solid State
09
Thermodynamics
10
10
Chemical Equilibrium
10
22
Chemistry in Action
08
53
Total
Stage - II
TABLE 2
Lesson
Lesson
No
2
Periodic Classification
1 mark
3 Mark
5 Mark
10 Mark
Total
09
12
Surface Chemistry
11
17
Ethers
07
Total
27
Stage III
TABLE 3
Lesson Lesson
No
1
Atomic Structure
1 mark
3 Mark
5 Mark
10 Mark
Total
10
d Block Elements
18
Coordination
Components
Electro Chemistry
11
10
14
49
Total
Hydroxy Derivatives
1 mark
3 Mark
5 Mark
10 Mark
Total
12
12
24
Total
NOTE
To score 150/150
Practice the units mentioned in the four tables .
Practice Book back one mark questions (self evaluation) for 19 units.
Practice the questions that where asked in the PTA guide as well as previous
year public question papers.
Practice for the chapters Hydroxy derivatives and d-block elements problems.
Practice for the chapters Electro chemistry Chemical kinetics and
Isomerism in organic chemistry
1.Based on the blue print Without
one mark lessons
2. Based on the blue print Without
three mark lessons
14,15,22
5,6,14,17,21
Uses of actinides :
(i)
(ii)
Lanthanides
+3
+2,+4
Actinides
+4
+2,+3,+5,+6
Actinides
higher.
lower.
effect.
effect.
U+(Red)
Radioactive .
6. They do not form oxocation .
With H 2S O 4 for
several hours
Grey Mud
Cold Water
Filtrate Containing
(Ln , Th4+ , H3O , SO4 2- , HSO4-, H2PO4- )
3+
Neutralised to
(or) added HF
proper acidity
Precipitate of Th3(PO4)4
(or) Precipitate Th
Filtrate containing
lanthanide and phosphate ions
NaOH (or)
Oxalic acid
Lanthanide hydroxide (or) oxalate
individual metals
Lesson 7
- NUCLEAR CHEMISTRY
63
1
1
37
+2He4+400MeV 17Cl +141H +160n
Nuclear reactions
nucleus is unaffected.
3.
5.
14
Animals too consume C14 by eating plants, on death, organisms cease to take in
fresh carbonations.
0
14
14
6C 7N + -1e
Half life period of C14 = 5700 years. Therefore by knowing either the amount of C14 or
the number of - particles emitted per minute per gram of carbon at the initial and
final stages, the age of carbon material can be determined by
2.303xt1/2
t=
0.693
Uses :
1. It is a great tool for correlating facts of historical importance
2. It is very useful in understanding the evolution of life and rise and fall of
civilizations
4. Write the medicinal uses of radioactive isotopes.(March -06)
S.No
Names
Uses
1
Tritium 1H3
Measure water content of the body
2
Carbon - 11 6C11
Brain scan
Carbon - 14 6C14
Radio immunology
Iron - 59 26Fe59
Diagnosis of anemia
Cobalt - 60 27Co60
Treatment of cancer
10
nuclear fission
A heavy nucleus splits in lighter nuclei
It does not require high temperature.
It is a chain reaction.
+
Deuterium
8. What is nuclear fission reaction?
3
1H
Tritium
2He
+0n
Helium
+ Energy
Nuclear fission is the process in which a heavy nucleus breaks up into two
lighter nuclei of almost equal size with the release of an enormous amount of
Energy.
10
141
+ 36Kr92 +
56Ba
Further, the neutrons released (say three) from the fission of first uranium
atomos can hit three other uranium atoms. In this way a chain reaction is set up
resulting into the liberation of an enormous amount of energy. In the case of nuclear
235
fission, 92U formed breaks up in several ways.
235
+ 0n1
92U
140
+ 36Kr93 + 30n1
56Ba
144
+ 38Sr90 + 20n1
54Xe
144
+ 37Rb90 + 20n1
55Cs
236
92U
6CO2 + 6H2O
C6H12O6 + 6O2
n is order of reflection
is the wave length of X-rays
d is the interplanar distance in the crystal
is the angle of reflection
11
12
13
Na+ Missing
Cl- Missing
Frenkel defects
1. This defect arise when an ion occupies an interstitial position between the lattice
points.
2. This defect occurs generally in ionic crystals in which the size of anion is much larger
than the cation.
3. Frenkel Defect on a crystal.
4. The crystal remains neutral since the number of positive ions is the same as the
number of negative ions. Ex: AgBr.
3. Explain Braggs spectrometer method.
1. This method is one of the important method for studying crystals using x rays. The
apparatus consists of a x-ray tube from which a narrow beam of x-rays allowed to fall on
the crystal mounted on a rotating table.
2. The rotating table is provided with scale and vernier, from which the angle of
incidence can be measured.
3. An arm which is rotating about the same axis as the crystal table, carries an
ionisation chamber.
4. The rays reflected from the crystal enter into the ionisation chamber and ionise the
gas present inside.
14
Sin
Ratio
5.9
11.85
18.15.
0.103
1
0.205
2
0.312
3
2. Covalent Crystals
3. Metallic Crystals
4. Ionic crystals
Molecular Crystals
1. The lattice points in molecular crystals consists of molecules which do not carry any charge.
15
Covalent Crystals
The lattice in covalent crystals consists of atoms linked together by a continuous system of
covalent bonds. Eg. diamond.
Metallic crystal
Metallic crystal consists of an assemblage of positive ions immersed in a sea of mobile electrons.
Thus each electron belongs to a number of positive ions and each positive ion belong to a number of
electrons. The force that binds a metal ion to a number of electrons within its sphere of influence is
known as metallic bond.
The Vanderwaals forces are more general and occur in all kinds of molecular solids.
Ionic crystal
In ionic crystals the units occupying lattice points are positive and negative ions. Each of a
given sign is held by columbic forces of attraction to all ions of opposite sign. The forces are very
strong.
-1
Process
S
Spontaneous
(+)ve
Equilibrium
0
Non-Spontaneous
(-)ve
8. The energy of the universe remains constant although the entropy of the universe tends to a
maximum.
9. Units of entropy: Unit of entropy is cal / degree / mole or eu/mole
10. S is related to H, for a reversible and isothermal process Srev=qrev/T .Since
H is the heat absorbed or evolved in the process at constant temperature and
pressure.S is also calculated from H as S=H/T
18
Non-Spontaneous
(+)ve
H = E + PV and
E = q w.
TS = q .
G = q w + PV q
G = w + PV= Net Work
Lesson 10
CHEMICAL EQUILIBRIUM II
c C+d D
19
[ PCl 5 ]
If ng = 0
ng = (-)ve
ng = (+)ve
Kp = Kc
Kp < Kc
Kp > Kc
2. H2O
n
(g)
+ 2 Cl2 (g)
= (n
4HCl
(g)
+ O2 (g)
- n r)g = 5 - 4 = 1
20
Catalyst
Fe
% of NH3 formed
37%
The equilibrium conditions, steam is passed to remove away the ammonia as and when it is
formed so that the equilibrium remains shifted towards the product side.
2. Write synthesis of SO3 by Contact process.
Catalyst
V 2 O5
% of SO3 formed
97%
SO3 from contact process along with steam is used in oleum and H2SO4 manufacturing
processes.
21
H2
a
x
I2
b
x
HI
0
-
(a-x)
(b-x)
2x
PCl5
a
x
PCl3
0
-
Cl2
0
-
(a-x)
22
Lesson 22
CHEMISTRY IN ACTION
3 Marks Question and Answers ( Public Q.No : 51 )
1. What are Anaesthetics? Give two examples.
The drugs which produce loss of sensation are called anaesthetics. They are two types.
(i)
General anaesthetics are the agent, which bring about loss of all modalities of
sensation, particularly pain along with reversible loss of conciousness.
(ii)
Local anaesthetics prevent the pain sensation in localised areas without affecting
the degree of consciousness
Example : Nitrous Oxide, Diethyl ether, chloroform
2. In what way Antipyretics are important?
1. Antipyretics are the compounds which are used for the purpose of reducing fever
2. lowering the body temperature to the normal
Ex. aspirin, antipyrine, phenacetin, and paracetamol.
3. What are antiseptic?
Antiseptic is a substance that rendors micro organisms innocuous by killing them or
preventing their growth.
Ex. Iodoform, 0.2 % solution of phenol .
4. Write a note on Antiprotozoals (or) Antimalarials.
1. Antiprotozoals are the chemical compounds used to cure malaria.
2. Extracts of certain plants, specially te roots and stems are extensively used as anti malarial.
Ex: Cinchona park which gives rise to quinine acts as anti malarial.
23
24
25
2. Chromogen
The compounds containing the chromophore group is called chromogen. The colour
intensity increases with the number of chromophores or the degree of conjugation.
26
It
It
It
It
should
should
should
should
3 P- Block elements ( 1 x 1 = 1 )
1. Which of the following does not belong to group -13
Ans:-Ge
2. Which of the following is most abundant in earths crust?
Ans:-Si
3. An element which was burnt in limited supply of air to give oxide A which
treatment with water gives an acid B acid B on heating gives acid a which gives
yellow precipitate with AgNo3 solution A is
Ans:-P2O3
4. The compound with garlic odur is
Ans:- P2O3
5. The shape of PCl5 is
Ans:-trigonal bipyramidal
6. The compound used as smoke screen
Ans:-PH3
7. Which shows only - 1 oxidation state?
Ans:- Fluorine
8. One can draw the map of building on a glass plate by
Ans:- HF
9. Among the halogen acid, the weakest acid is
Ans:- HF
10. Halogens belongs to the group number
Ans:- 17
11. The noble gas are un reactive because they
Ans:- have stable electronic configuration
12. The shape of XeF4 is
Ans:-square planner
28
4. d. Block elements ( 2 x 1 = 2 )
1. The general electronic configuration of d- black elements is
Ans:- (n-1) d 1-10 ns1-2
2. Formation of coloured ions is possible when compounds contain
Ans:-lone pairs of electrons
3. Paramagnetism is common in
Ans:-d-block elements
4. The colour of [Ti(H2O)6]3+ion to
Ans:- d-d transition
5. The electronic configuration of chromium is
Ans:- 3d5 4s1
6. Paramagnetism is a property of
Ans: unpaired electrons
7. d - block elements formed coloured ions because
Ans;- They absorb some energy for d-d transition
8. The correct electronic configuration of copper atom is
Ans;- 3d10 3s1
9. Copper is extracted from
Ans:- copper pyrites
10. Silver salt used in photography is
Ans:-AgBr
11. Sodium thiosulphate is used in photography because of its
Ans:- complexing behaviour
12. Excess of sodium hydroxide reacts with zinc to form
Ans:-Na2ZnO2
13.Which of the following compounds will not give positive chromyl chloride test?
Ans:-C6H5Cl
14. Which of the ions will give colourless aqueous solution ?
Ans:-Cu+
15. Which of the following compounds is not coloured?
Ans:-NaCd Cl4
16. In the extraction of cu, the reaction which does not takes place in the Bessemer
converter is
Ans:- 2CuFes2 O2Cu2s + 2Fes + SO2
17. Select the correct statement
Ans:-mercury is a liquid metal
18. Choose the wrong statement regarding K2Cr2O7
Ans:-It reduces ferric sulphate to ferrous sulphate
19. For a transition metal ion the effective magnetic moment in BM is given by the
formula
Ans: n(n 2)
29
4. F- Block elements ( 2 x 1 = 2 )
1. The electronic configuration of Lanthanides is
Ans:-[Xe] 4f1-14 5d16S2
2. The electronic configuration of actinides is
Ans:-[Rn]5f 0-14 6d 7S2
3. The lanthanide is responsible for the fact that
Ans:- Zr and Hf have about the same radius
4. The most common oxidation state of lanthanides
Ans:-+3
5. Lanthanides are extracted from
Ans:-monozite
6. The elements in which the extra electron enters (n-2)f orbitals are called
Ans:-f- block elements
7. The Lanthanides contraction is due to
Ans:-imperfect shielding of 4f electron
8. Ceria used in
Ans:-gas lamp materials
9. --------- is used in gas lamp material.
Ans:- CeO2
10. Alloys of Lanthanides are called as
Ans:- mish - metals
11. Metallo thermic process involving lanthanides are called as
Ans:-Lanthanido thermic process
12. --------- form oxocations.
Ans:- actinides
13. Maximum oxidation state exhibited by lanthanides is
Ans:- +4
14. Lanthanides are separated by
Ans:-fractional crystallisation
30
6. Co - ordination compounds ( 1 x 1 = 1 )
1. Which is a double salt?
Ans:-. K2SO4 Al2(SO4)3 .
2. An example of a complex compound having co-ordination number 4
Ans:- [Cu(NH3)4]Cl2
3. The geometry of (Cu NH3)4]2+ complex ion
Ans:- square planar
4. An example of a chelating ligand is
Ans:- en
5. The geometry of complex ion [Fe(CN)6]4- is
Ans:-octahedral
6. The oxidation number of nickel in the complex ion, [NiCl4]2- is
Ans:- +2
7. Which is not an anionic complex?
Ans:- [Cu(NH3)4] Cl2
8. The geometry of (Ni (CN)4]2- is
Ans:-square planar
9. An example of ambidentate ligand is
Ans:- NO2
10. [FeF6]4- is paramagnetic because
Ans:- F- is a weaker ligand
11. In [FeII (CN)6]4- the central metal ion is
Ans:- Fe+
12. The coordination number of Ni(II) in Ni(CN4)2- is
Ans:- 4
13. The name of [ptIV (NH3)2Cl2]2
Ans:-. Diammine dichloroplatinum (IV) ion
14. For a compound K4[Fe(CN)6] 4K+ + [Fe(CN6)]4- the complex ion is
Ans:- [Fe(CN)6]415. A metal ion form the first transition series forms an octahedral complex with
magnetic moment of 4.9 BM and another octahedral complex which is diamagnetic
The metal ion is
Ans:- Fe+
16. Paramagnetic moment is expressed in
Ans:- BM
17. The type of isomerism found in the complexes [Co(NO2)(NH3)5] SO4 and
[Co(SO4)(NH3)5] NO2
Ans:- ionisation isomerism
18. Valence bond theory doesnt explain the property of complex compounds
Ans:- magnetic
7. Nuclear chemistry ( 1 x 1 = 1 )
1. The phenomenon of radio activity was discovered by
Ans:- Henry Becquarrel
2. The most penetrating radiations are
ns:-rays
3. In the nuclear reaction 92U238 82Pb 206 , the no of & particles emitted are
Ans:- 8, 6
31
4. Which one of the following particles is used to bombard 13 Al 27 to give to give 15 P30
and a neutron
Ans:- particle
5. The reaction 5B84Be8 takes place due to
Ans:- positron decay
6. Radio activity is due to
Ans:- un stable nucleus
7. In the following radio active decay 92 x 232 89y220 how many and particles are
ejected
Ans:- 3 , 3
8. 92 U 235 nucles absorbs a neutron and disintegrates into 54 xe139, 38 sr 94 and x. What
will be the product?
Ans:- 3 neutrons
9. Loss of particle is equivalent to
a) increase of proton only b) decrease of one neutron only c) both a & b
10. Which of the following is used as neutron absorber in the nuclear reactor?
Ans:- cadmium.
8. Solid State ( 1 x 1 = 1)
1. The number of chloride ions that surrounds the central Na + ion in NaCl crystal is
______.
Ans:- 6
2. The Braggs equation is ________.
Ans:- nd sin
3. A regular three dimensional arrangement of identical points in space is called
________.
Ans:- space lattice
4. The smallest repeating unit in space lattice which when repeated over and again
results in the crystal of the given substance is called ________.
Ans:- unit cell
5. The crystal structure of Cscl is ________.
Ans:-Body - centred cubic
6. An example for frenkel defect is _________.
Ans:- Agcl
7. Semi conductors which exhibit conductivity due to the flow of excess negative
electron are called ________.
Ans:- n-type semi conductors
8. In the Braggs equation for diffraction of x-ray n represents _______.
Ans:-Order of reflection
9. The number of close neighbors in a body centred cubic lattice of identical spheres
is __________.
Ans:- 8
10. The crystals which are good conductors of electricity and heat are _________.
Ans:- Molecular crystals
11. In a simple cubic cell, each point on a corner is shared by __________.
Ans:- 8 unit cell
12. The ability of certain ultra cold substances to conduct electricity without
resistance is called _____.
Ans:- super conductor
13. The total number of atoms per unit cell is bcc is
Ans:- 2
32
14. Rutile is
Ans:- Tio2
15. Semi conductors are used as
a) rectifiers b) transistors c) solar cells d) all the above
16. An example of metal deficiency defect.
Ans:- FeS
9. Thermodynamics ( 2 x 1 = 2 )
1. The amount of heat exchanged with the surrounding at constant temperature.
Ans: H
2. All the naturally occurring processes proceed spontaneously in a direction which
leads to
Ans: decrease of free energy.
3. In an adiabatic process which of the following is true?
Ans: q = 0
4. When a liquid boils, there is
Ans: an increase in entropy
5. If G for a reaction is negative, the change is
Ans: Spontaneous
6. Which of the following does not result in an increase in the entropy?
Ans: crystallisation of Sucrose from solution
7. In which of the following process, the process is always non-feasible?
Ans: H>O, S<O
8. Change in Gibbs free energy is given by
Ans: G=H-TS
9. For the reaction 2Cl(g)Cl2(g)the Signs of H and S respectively are ________.
Ans: - , -
11.Chemical kinetics ( 1 x 1 = 1 )
1. Hydrolysis of an ester by dilute HCl is an example for
Ans: pseudo first order reaction
2. The unit of zero order rate constant is
Ans: (b) mol litre1 sec1
3. The excess energy which a molecule must posses to become active is
known as
Ans: activation energy
4. Arrhenius equation is
Ans: ) k = AeEa/RT
5. The term A in Arrhenius equation is called as
Ans: Frequency factor
6. The sum of the powers of the concentration terms that occur in the rate
equation is called
Ans: order
7. Reactions in which the reacting molecules react in more than one way
yielding different set of products are called
Ans: parallel reactions
8. The half life period of a first order reaction is 10 minutes. Then its rate
constant is
Ans 6.932 102 min1
9. For a reaction : aA bB, the rate of reaction is doubled when the
concentration of A is increased by four times. The rate of reaction is
equal to
Ans: k [A]
10. 2N2O5 + 4NO2 + O2
d[N205] = k1[N2O5],
dt
d [NO2 ] = k2 [N2O5] and d[O2] = k3 [N2O5], the relation between k1, k2 and k3 is
dt
dt
Ans:2k1 = k2 = 4k3
11. For a reaction, Ea = 0 and k = 4.2 105 sec1 at 300K, the value of k at
310K will be
Ans:4.2 105 sec1
13.Electro chemistry I ( 1 x 1 = 1)
1. The process in which chemical change occurs on passing electricity is termed as ...............
Ans electrolysis
2. The laws of electrolysis were enunciated first by ...............
Ans Faraday
3. When one coulomb of electricity is passed through an electrolytic solution, the mass
deposited on the electrode is equal to ...............
Ans electrochemical equivalent
4. Faradays laws of electrolysis are related to ...............
Ans: equivalent weight of the electrolyte
5. The specific conductance of a 0.01 M solution of KCl is 0.0014 ohm-1 cm-1 at 25oC.
Its equivalent conductance is ...............
Ans: 140 ohm1 cm2 eq1
6. The equivalent conductivity of CH3COOH at 25oC is 80 ohm-1 cm2 eq-1 and at infinite
dilution 400 ohm-1 cm2 eq-1. The degree of dissociation of CH3COOH is ...............
Ans: 0.2
7. When sodium acetate is added to acetic acid, the degree of ionisation of acetic acid
...............
Ans: decreases
8. NH4OH is a weak base because ...............
Ans: it is only partially ionised
9. Which one of the following formulae represents Ostwalds dilution law for a binary
electrolyte whose degree of dissociation is and concentration C .
Ans: K = C
(1)
10. Ostwalds dilution law is applicable in the case of the solution of ...............
Ans: CH3COOH
35
36
17 Ethers ( 2 x 1 = 2 )
1. The isomerism exhibited by C2H5OC2H5 and CH3 O CH CH3 is
|
CH3
Ans: metamerism
37
38
13. During reduction of aldehydes with hydrazine and C2H5ONa the product
formed is
Ans : RCH3
14. Aldol is
Ans : 3-hydroxy butanal
15. In the reduction of acetaldehyde using LiAlH4 the hydride ion acts as
Ans : nucleophile
16. Which of the following statement is wrong ?
Ans : aldehydes and ketones undergo nucleophilic substitution
17. A cyanohydrin of a compound X on hydrolysis gives lactic acid. The X is
Ans : CH3CHO
18. The IUPAC name of CH3 C = CH C CH3 is
|
||
CH3
Ans : 4-methylpent-3-en-2-one
19. Which of the following does not give iodoform test ?
Ans : benzophenone
20. The compound which does not reduce Fehling solution is
Ans : benzaldehyde
21.CH3COCH3 Conc. H2SO4 The product is
Ans : mesitylene
22. Which compound on strong oxidation gives propionic acid ?
Ans : CH3 CH2 CH2 OH
23. The compound used in the preparation of the tranquilizer, sulphonal is
Ans : acetone
24. Calcium acetate + calcium benzoate gives
Ans : acetophenone
25. Bakelite is a product of reaction between
Ans : phenol and methanal
19.Carboxlic acids ( 1 x 1 = 1)
1. Which of the following is least acidic
Ans : C2H5OH
2. Weakest acid among the following is
Ans : Acetylene
3. Ester formation involves the reaction of
Ans : An acylhalide with an alcohol
4. Heating a mixture of sodium acetate and soda lime gives
Ans : methane
5. The acid which reduces Tollen's reagent is
Ans : formicacid
CH3
|
6. The IUPAC name of CH3 CH2 CH COOH is
Ans : 2-methyl butanoic acid
7. The Isomerism exhibited by CH3CH2COOH and CH3COOCH3 is
Ans : functional
8. The acid that cannot be prepared by Grignard reagent
Ans : formic acid
39
The product is
H
Ans : H2 + CO2
12. When chlorine is passed through acetic acid in presence of red P, it forms.
Ans : Trichloro acetic acid
13. Which of the following compounds will react with NaHCO3 solution to give sodium salt
and CO2 ?
Ans : acetic acid
14. When propanoic acid is treated with aqueous sodium - bicarbonatate, CO2 is liberated.
The "C" of CO2 comes from
Ans : bicarbonate
15. Carboxylic acids are more acidic than phenol and alcohol because of
Ans : greater resonance stabilisation of their conjugate base
16. Among the following the strongest acid is
Ans : Cl3CCOOH
17. Which of the following compound is optically active ?
Ans : (c) CH3CH(OH)COOH (d) Cl2CHCOOH
18.CH3CH(OH)COOH
? The product is
H2O2/Fe2+
17.C6H5NH2
Ans:C6H5N2Cl
X. Identify X.
42
1-Mark
Practice Book back one mark questions (self evaluation) for 19 units.
Practice the questions that where asked in the PTA guide as well as previous
year public question papers.
3-Mark
Important Public exam questions are given below
ATOMIC STRUCTURE-II
1.
2.
3.
4.
5.
6.
7.
8.
9.
PERIODIC CLASSIFICATION-II
1. Define Ionic radii?
2. Compare Ionisation Energy?
a.) B & Be
b.) N & O
c.) Li & Be
d.) B & C
e.) F & Ne
f.) Mg & Al
3.Why Electron affinity of fluorine less than of chlorine?
4. State Muliken scale?
5.Mention the disadvantage of pauling and muliken scale?
6. Define Electron affinity
7. Define Ionisation Energy
43
P-BLOCK ELEMENTS
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
SURFACE CHEMISTRY
1. What is catalysis?
2. What is auto catalyst ? give example
3. what is Induced catalyst? give example
4. what is promoters? give Example?
5. what is catalytic poison? Give example
6. A colloidal solution of gas in gas is not possible Why?
7. What is Peptisation?
8. What is Helmholtz double layer?
9. What is Tyndall effect?
10. What is Brownian Movement?
11. Write note on Tanning?
12. Write Purification of drinking water by colloids?
13. How is Delta formed?
14. What are emulsion?
15. Write Medical uses of colloids?
44
5 Mark
ATOMIC STRUCTURE-II
1.
2.
3.
4.
5.
6.
7.
8.
1.
2.
3.
4.
5.
PERIODIC CLASSIFICATION
Explain the Factors affecting Electron affinity?
How electron negativity values help to find out the nature of bond?
Explain pauling method to determination of ionic radii ?
Explain pauling scale electron negativity ?
Explain the factors affecting ionization energy?
P-block Elements
1.
2.
3.
4.
5.
6.
7.
1.
2.
3.
4.
5.
6.
45
46