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Tungsten Trioxide and Powders That Shape Your World

Tungsten Blue Oxides


Technical Information Bulletin

Tungsten trioxide is a thermally stable and water insoluble tungsten compound. Tungsten trioxide and
Tungsten blue oxides are both used in the production of tungsten metal powders. Both products are
produced from internally manufactured ammonium paratungstate (APT).
Yellow tungsten trioxide is a finely divided, yellow, crystalline pow-
der. It is produced by roasting ammonium paratungstate at closely
controlled temperatures to drive off combined water and ammonia.
Yellow tungsten oxide is commonly
used in the manufacture of coars-
er tungsten carbide powders.
Tungsten blue oxides (TBO) are
finely divided blue-violet powders.
They are produced by heating am-
monium paratungstate at closely
controlled temperatures in a re-
ducing atmosphere. GTP produces
two standard grades differing mainly in oxygen content. Tung-
sten blue oxides are used primarily for the production of tungsten
metal powder and fine tungsten carbide as well as wire products.
Polyhedral Representation of WO3
Exact time and temperature control determines, to a large extent,
the physical properties of the tungsten oxide. Physical characteristics, impurity levels, or packaging,
other than our standards, can be discussed upon request by customer.

Impurity Content (ppm):


Composition:
Element Content
Al 20 Oxide Type: Comp. Oxygen Content
As 25 Yellow Oxide: WO3 20.7%
Ca 50 Blue Oxide: WO2.95 20.4%
Cr 20 Blue Oxide: WO2.81 19.6%
Cu 15
Fe 80 Physical Properties:
K 50 Oxide Particle Density Density
Comp.
Mg 50 Type: Size 1 g/in3 g/cm3
Mn 50 Yellow Oxide: WO3 10-20 32-55 1.95-3.36
Mo 150 Blue Oxide: WO2.95 5-20 30-55 1.83-3.36
Na 70 Blue Oxide: WO2.81 10-20 25-55 1.53-3.36
Ni 30
Footnotes:
Si 35 1
Particle size is Fisher-Sub-Sieve-Size (m)
Sn 15
Purity, % by difference (excluding gases): 99.75% Min.

Global Tungsten & Powders Corp. Phone: (570) 268-5000


1 Hawes Street Fax: (570) 268-5323
Towanda, PA 18848 / USA e-mail: [email protected]
Powders That Shape Your World
Tungsten Oxide (Blue & Yellow)
Technical Information Bulletin

Yellow Tungsten Oxide


Magnified 250 times
WO3
Particle size 10-20 m (FSSS)

200 m

Tungsten Blue Oxide


Magnified 250 times
WO2.95
Particle size 5-20 m (FSSS)

200 m

Customization
GTP can customize the oxides to specific applications. Customer specifications can be developed after
technical discussions at time of inquiry.

Ordering
Specify blue or yellow oxide, oxygen level and particle size.

Certification
Each shipment of powder is accompanied by a standard report, which includes FSSS average particle size,
Scott density, and purity level. SEMs are provided on an as requested basis.

Packaging
Available in uniform blends of up to 9,000 kgs. Each lot is packaged in leverpack drums of about 160 kgs
per drum. Other packaging includes supersacks of about 1,500 kgs per sack.

Global Tungsten & Powders


1 Hawes Street
Towanda, PA 18848
USA
Phone: +1 (570) 268-5000
Fax: +1 (570) 268-5323
[email protected]

History of Global Tungsten & Powders:


For over 60 years, GTP in Towanda has been producing tungsten, molybdenum, cobalt, and tantalum powder prod-
ucts. GTP produces a wide range of materials, which are used in the manufacture of numerous products. These
products include metal working tools for cutting, rolling, and stamping; high temperature jet engine components
and protective coatings; circuit manufacturing chemicals for microelectronics; catalysts for petrochemical processing.

The information and recommendations contained in this publication are based upon data collected by Global Tungsten & Powders Corp. and believed to be correct. However,
no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein, and Global Tungsten & Powders Corp. assumes no
responsibility for the results of the use of products and processes described herein. No statements or recommendations made herein are to be construed as inducements to
infringe any relevant patent, now or hereafter in existence. 2008 GTP

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