Chemistry 12 - Unit 3 - Solubility (M.C.)
Chemistry 12 - Unit 3 - Solubility (M.C.)
Chemistry 12 - Unit 3 - Solubility (M.C.)
August 1998
[Na+] [CrO42-]
A 0.40M 0.20M
B 0.20M 0.20M
C 0.20M 0.40M
D 0.40M 0.80M
A. H2S
B. KNO3
C. ZnSO4
D. Ca(OH)2
15) Which of the following 0.20M solutions will not form a precipitate when mixed with
an equal volume of 0.20M Sr(OH)2?
A. CaS
B. NH4Cl
C. Na2SO4
D. Ba(NO3)2
A. H2O (l)
B. SrF2 (s)
C. SrCl2 (s)
D. NaNO3 (s)
17) Two ions found in hard water are Ca2+ and Mg2+. Which of the following will
precipitate only one of these ions?
A. I-
B. S2-
C. SO42-
D. CO32-
18) At 25, the solubility of AgBr is
A. 2.9 10-25 M
B. 5.4 10-13 M
C. 2.7 10-13 M
D. 7.3 10-7 M
19) Which of the following saturated solutions has the greatest [CO32-]?
A. SrCO3
B. CaCO3
C. BaCO3
D. MgCO3
January 1999
When 10.0mL of 0.20M Pb(NO3) 2 are added to each of the above, precipitates form in:
A. I and II only.
B. I and III only.
C. II and III only.
D. I, II and III.
16. When equal volumes of 0.20M CuSO4 and 0.20M Li2S are combined, the complete
ionic equation is:
A. Ksp = [Ag2+][CO32-]
C. Ksp = [2g+][CO3-2]
D. Ksp = [2g+]2[CO3-2]
A. 5.9 107
B. 2.4 106
C. 7.1105
D. 8. 4 103
19. If the Trial Ion Product for AgBrO3 is calculated to be 1.0 107, then
A. CaS
B. CaSO4
C. CaC2O4
D. Ca(NO3)2
April 1999
14. Which of the following produces a molecular solution when dissolved in water?
A. RbClO
B. CH3OH
C. NH4SCN
D. NaCH3COO
15. Consider the solubility equilibrium:
A. PbI2
B. PbCl2
C. PbBr2
D. Pb(IO3)2
17. When equal volumes of 0.20M ZnSO4 and 0.20M Sr(OH)2 are combined,
A. no precipitate forms.
B. a precipitate of only SrSO4 forms.
C. a precipitate of only Zn(OH)2 forms.
D. precipitates of both SrSO4 and Zn(OH)2 form.
A. 1. 0 105
B. 3.2 103
C. 6.4 103
D. 5.7 102
A. 1.0M HCl
B. 1.0M NaNO3
C. 1.0M ZnCl2
D. 1.0M AgNO3
20. The solubility of SrF2 is
A. 4.3 109 M
B. 6.6 105 M
C. 1.0 103 M
D. 1.6 103 M
June 1999
A. CaS
B. Fe (OH)3
C. KMnO4
D. NH4HC2O4
16. A solution contains two cations, each having a concentration of 0.20M. When an
equal volume of 0.20M OH is added, these cations are removed from the solution by
A. Ba2+ and K+
B. Sr2+ and Na+
C. Mg2+ and Sr2+
D. Mg2+ and Ca2+
17. The solubility of Mn(IO3)2 is 4.8 103 M. What is the value of Ksp ?
A. 1.1107
B. 4.4 107
C. 7.1106
D. 1.1101
18. The maximum [SO42-] that can exist in 1.0 103 M Ca(NO3)2 without a precipitate
forming is:
A. 7.1105 M
B. 1. 0 103 M
C. 8. 4 103 M
D. 7.1102 M
August 1999
A. I and II
B. II and III
C. II, III and IV
D. I, II, III and IV
15. At a certain temperature, 7.0 104 mol MgSO4 is present in 100.0mL of solution.
The concentration of the Mg2+ in this solution is
A. 7.0 105 M
B. 7.0 104 M
C. 7.0 103 M
D. 7.0 106 M
16. When equal volumes of 0.20M SrBr2 and 0.20M AgNO3 are combined,
A. no precipitate forms.
B. a precipitate of only AgBr forms.
C. a precipitate of only Sr(NO3)2 forms.
D. precipitates of both AgBr and Sr(NO3)2 form.
17. Consider the following solubility equilibrium:
PbCl2 (s) Pb2+ (aq) + 2Cl- (aq)
18. Solid Ag2CrO4 is added to water to form a saturated solution. The Ksp value can be
calculated by:
A. Ksp = [CrO42-]2
B. Ksp = [CrO42-]3
C. Ksp = [CrO42-]3
2
D. Ksp = 4 [CrO42-]3
A. adding water
B. adding BaS (s)
C. adding BaSO3 (s)
D. adding Na2SO3 (s)
20. When equal volumes of 0.20M Ca(NO3)2 and 0.20M Na2SO4 are combined,
A. 2.8 109 M
B. 5.3 107 M
C. 5.3 103 M
D. 1. 0 102 M
January 2000
16. Which of the following will not produce a precipitate when equal volumes of 0.20 M
solutions are combined?
A. the pH increases
B. the [Ca2+]increases
C. bubbles of H2 are given off
D. additional CaSO4 precipitates
18. The solubility of CdS = 2.8 x 10 -14 . The value of Ksp is
A. 7.8 x 10 -28
B. 2.8 x 10 -14
C. 5.6 x 10 -14
D. 1.7 x 10 -7
19. How many moles of solute are dissolved in 200.0 mL of a saturated solution of FeS?
A. 1.2 x 10 -19
B. 6.0 x 10 -19
C. 1.5 x 10 -10
D. 7.7 x 10 -10
Equal moles of AgNO3 are added to each solution. It is observed that a precipitate forms
in all but one solution. Which solution does not form a precipitate?
A. Cl-
B. Br -
C. IO3-
D. BrO3-
21. Which of the following could dissolve a precipitate of CaC2O4 in a saturated solution
of CaC2O4 ?
A. NaOH
B. CaC2O4
C. H2C2O4
D. Ca(NO3)2
April 2000
14. Which of the following will dissolve in water to produce a molecular solution?
A. CaCl2
B. NaOH
C. CH3OH
D. Sr(OH)2
18. The complete ionic equation for the reaction between MgS and Sr(OH)2 is
Which of the following will cause the equilibrium to shift to the right?
A. adding KOH
B. adding Na2S
C. adding Fe(OH)2
D. adding Fe(NO3)2
20. Consider the following experiment:
A. 0.20 M OH-
B. 0.20 M NO3-
C. 0.20 M PO4-3
D. 0.20 M SO4-2
21. A compound has a solubility of 7.1 x 10-5 M at 25 C. The compound is
A. CuS
B. AgBr
C. CaCO3
D. CaSO4
June 2000
A. 0.062 M
B. 1.60 M
C. 3.65 M
D. 6.24 M
A. 0.30 M
B. 0.60 M
C. 1.5 M
D. 3.0 M
16. When equal volumes of 0.20 M RbCl and 0.20 M and M SrS are combined,
A. no precipitate forms.
B. a precipitate of Rb2S only forms.
C. a precipitate of SrCl2 only forms.
D. precipitates of both Rb2S and SrCl2 form.
17. A solution contains both Ag+ and Mg2+ ions. During selective precipitation, these
ions are removed one at a time by adding
A. I- followed by OH-
B. OH- followed by S2-
C. SO42- followed by Cl-
D. NO3- followed by PO43-
20. When 1.0 x10-3 moles of CuCl2 (s) are added to 1.0 L of 1.0 x10-3 M IO3-, the
A. SrSO4
B. Na3PO4
C. C6 H12O6
D. NH4CH3COO
A. excess solute
B. an ionic solute
C. solute of low solubility
D. trial ion product is less than Ksp
16. The net ionic equation that describes a saturated solution of Ag2CrO4 is
D. 2Ag+ (aq) + CrO42 (aq) + 2H2O (l) 2AgOH (s) + H2CrO4 (aq)
A. SrS
B. CaCl2
C. Rb2CO3
D. Zn(OH)2
18. Which of the following will form a precipitate when equal volumes
of 0 2. M solutions are combined?
A. HI and Na2CO3
B. SrS and NH4OH
C. BaCl2 and CuSO4
D. Mg(NO3)2 and KCl
19. The solute AgBr is least soluble in
A. H2O
B. 1.0 M FeBr3
C. 1.0 M CaBr2
D. 1.0 M AgNO3
20. The magnesium and calcium ions in hard water can be removed by the addition of
A. NaI
B. NaNO3
C. Na2CO3
D. Na2SO4
21. The solubility of an AB2 type salt is 2.3 x 106 M. The salt is
A. PbBr2
B. Fe(OH)2
C. Cu(IO3) 2
D. Mg(OH)2
22. Which of the following saturated solutions will have the lowest [Pb2+]?
A. PbI2
B. PbCl2
C. Pb(IO3)2
D. Pb(NO3) 2
January 2001
14. A saturated solution forms when a 0.10 mol of salt is added to 1.0L of water.
The salt is
A. Li2S
B. CuBr2
C. Zn(OH)2
D(. (NH4))2CO3
A. H2O (l)
B. HCl (aq))
C. KOH (s))
D. Ca((OH))2 ((s))
16. Consider the following solubility equilibrium:
AgCl (s)) Ag+(+ (aq) + Cl (aq)
Which of the following graphs represents the [Ag+]+ after equilibrium has been
established?
17. The concentrations of the cation and anion in 0.40 M (NH4)2Cr2O7 (aq) are
18. Which of the following will produce a solution with the highest [OH-]?
A. AgOH
B. Sr(OH)2
C. Fe(OH)3
D. Mg(OH)2
19. When equal volumes of 0.20 M ZnSO4 and 0.20 M SrS are combined
A. 9.0 x 10-5 M
B. 5.7 x 10-5 M
C. 4.5 x 10-5 M
D. 1.1 x 10-4 M
April 2001
A. KCl
B. Na2O
C. NH4Br
D. C2H5OH
15. A saturated solution is formed by adding 10.0g PbI2 (s) to 10.0 mL of water in a
beaker. Describe the situation which exists in the beaker.
A. [Pb2+] = [I-]
B. moles PbI2 (s) = moles Pb+2 (aq)
C. mass of PbI2 (s) = mass of PbI2 (aq)
D. rate of crystallization = rate of dissociation
A. 1.00 x 10-2 M
B. 1.21 x 10-2 M
C. 2.00 x 10-2 M
D. 2.08 M
A. MgS
B. ZnCl2
C. SrSO4
D. AgNO3
18. Consider the following solubility equilibrium:
A. Na+
B. Ca2+
C. Pb2+
D. Zn2+
A. Ksp = [Ni+2]3[PO4-3]2
B. Ksp = [Ni+2]2[PO4-3]3
C. Ksp = [3Ni+2][2PO4-3]
D. Ksp = [3Ni+2]3[2PO4-3]2
June 2001
15. Consider the following equilibrium:
Adding which of the following will cause more solid BaSO4 to form?
A. CaCl2 (s)
B. K2CO3 (s)
C. Na2SO4 (s)
D. Mg(NO3)2 (s)
A. g/mL
B. mL/L
C. mol/L
D. g/min
What is the relationship for the [Pb2+] in the solution in the three beakers?
A. I = II = III
B. I > II > III
C. II > III > I
D. III > II > I
A. NaCl
B. Na2S
C. Na2SO4
D. Na2CO3
A. 3.2 x 10-28
B. 1.8 x 10-14
C. 3.6 x 10-14
D. 1.3 x 10-7
August 2001
13. At 25C, which of the following compounds has a low solubility when
added to water?
A. FeS
B. CuCl2
C. ZnSO4
D. NH4CH3COO
A. KCl
B. NaOH
C. CH3OH
D. NH4CH3COO
15. List the compounds AgI, KBr and MgCO3 in order of solubility
from lowest to highest.
Ksp = [Cu+2][IO3-]2
17. The solubility of NiCO3 is 3.8 x 10-4 mol/L. The Ksp value is
A. 1.4 x 10-7
B. 3.8 x 10-4
C. 7.6 x 10-4
D. 1.9 x 10-2
A. 2.8 x 10-9 M
B. 2.6 x 10-5 M
C. 5.3 x 10-5 M
D. 7.3 x 10-3 M
19. When solutions of AgNO3 and NaCl are combined, the Trial Ksp for AgCl is
5.6 x 10-11. Predict what will be observed.
A. 1.4 x 10-6 M
B. 3.4 x 10-5 M
C. 2.6 x 10-3 M
D. 5.8 x 10-3 M
January 2002
17) When equal volumes of 0.2M solutions are mixed, which of the following
combinations forms a precipitate?
18) A solution contains 0.2 M Zn2+ and 0.2M Sr2+. An equal volume of a second solution
was added, forming a precipitate with Sr2+ but not with Zn2+. What is present in the
second solution?
A. 0.2M Cl-
B. 0.2M OH-
C. 0.2M SO42-
D. 0.2M PO43-
19) The Ksp expression for a saturated solution of Ba3(AsO4)2 is
A. Ksp = [Ba2+][AsO43-]
B. Ksp = [Ba2+]3[AsO43-]2
C. Ksp = [3Ba2+][2AsO43-]
D. Ksp = [3Ba2+]3[2AsO43-]2
20) The solubility of NiCo3 is 4.4 10-2g/L. Determine the Ksp value of NiCO3.
A. 1.4 10-7
B. 3.7 10-4
C. 1.9 10-3
D. 2.1 10-1
A. 3.2 10-16 M
B. 1.8 10-8 M
C. 3.6 10-8 M
D. 1.3 10-4 M
22) When a solution containing Ag+ is mixed with a solution containing BrO3-, the trial
ion product is determined to be 2.5 10-7. What would be observed?
April 2002
15) Which of the following will dissolve in water to form an ionic solution?
A. O2
B. CH4
C. NH4Cl
D. CH3OH
16) The solubility of SrCO3 is 2.4 10-5 M. How many moles of dissolved solute are
present in 100.0 mL of saturated SrCO3 solution?
[Cu2+] [Cl-]
A. 0.10 M 0.20 M
B. 0.20 M 0.10 M
C. 0.30 M 0.30 M
D. 0.30 M 0.60 M
18) What is the net ionic equation for the reaction that occurs when equal volumes of
0.20M Ba(NO3)2 and 0.20 M Na2SO4 are mixed together?
[Ag+] [IO3-]
A. Decreased Decreased
B. Decreased Increased
C. Increased Decreased
D. Increased Increased
A. Ksp = [Zn2+][OH-]2
B. Ksp = [Zn2+]2[OH-]
C. Ksp = [Zn2+][2OH-]
D. Ksp = [Zn2+][2OH-]2
21) The solubility of CdCO3 is 2.5 10-6 M. Calculate the Ksp value for CdCO3.
A. 6.3 10-12
B. 2.5 10-6
C. 5.0 10-6
D. 1.6 10-3
June 2002
A. equal to zero.
B. equal to the rate of crystallization
C. less than the rate of crystallization
D. greater than the rate of crystallization
A. CaS
B. CuS
C. FeS
D. MgS
18) What is the formula equation for the reaction that occurs when equal volumes of
0.20M K3PO4 and 0.20M ZnCl2 are mixed together?
19) Which of the following could be added to a sample of hard water to remove both
0.2M Ca2+ and 0.2M Mg2+?
A. 0.2 M S2-
B. 0.2 M Cl-
C. 0.2 M OH-
D. 0.2M So42-
20) The Ksp expression for a saturated solution of Ag2SO3 is
A. Ksp = [2Ag+][SO32-]
B. Ksp = [Ag+]2[SO32-]
C. Ksp = [Ag22+][SO32-]
D. Ksp = [2Ag+]2[SO32-]
21) The solubility of CaF2 is 3.3 10-4 M. Determine the Ksp value of CaF2.
A. 3.6 10-11
B. 1.4 10-10
C. 1.1 10-7
D. 3.3 10-4
22) What is the maximum [Ag+] that can exist in a solution of 0.010M NaIO3?
A. 3.2 10-10 M
B. 3.2 10-8 M
C. 3.2 10-6 M
D. 1.8 10-4 M
August 2002
16) When 100.0mL of a saturated solution of BaF2 is heated and all the water is
evaporated, 3.6 10-4 mol of solute remains. The solubility of BaF2 is
A. 1.9 10-10 M
B. 1.3 10-5 M
C. 3.6 10-4 M
D. 3.6 10-3 M
17) A solution contains both 0.2M Mg2+(aq) and 0.2M Sr2+(aq). These ions can be removed
separately through precipitation by adding equal volumes of 0.2M solutions of
A. OH-, and then S2-
B. Cl-, and then OH-
C. CO32-, and then SO32-
D. SO42-, and then PO43-
18) Consider the following equilibrium:
CaSO4(s) Ca2+(aq) + SO42-(aq)
Which of the following would shift the above equilibrium to the left?
A. adding CaSO4(s)
B. adding MgSO4(s)
C. removing some Ca2+(aq)
D. removing some SO42-(aq)
21) What happens when equal volumes of 0.2M AgNO3 and 0.2M NaCl are combined?
A. A precipitate forms because the trial ion product > Ksp
B. A precipitate forms because the trial ion product < Ksp
C. No precipitate forms because the trial ion product > Ksp
D. No precipitate forms because the trial ion product < Ksp
22) Determine the maximum [Na2CO3] that can exist in 1.0L of 0.0010M Ba(NO3)2
without forming a precipitate.
A. 2.6 10-12 M
B. 2.6 10-9 M
C. 2.6 10-6 M
D. 5.1 10-5 M
January 2003
17) Which of the following would be true when equal volumes of 0.2M NaBr and
0.2M AgNO3 are combined?
A. No precipitate forms.
B. A precipitate of AgBr forms.
C. A precipitate of NaNO3 forms.
D. Precipitates of both NaNO3 and AgBr form.
18) Using the solubility table, determine which of the following ions could not be used to
separate S2- from SO42- by precipitation?
A. Be2+
B. Ca2+
C. Ba2+
D. Sr2+
19) Which of the following is true when solid Na2S is added to a saturated solution of
CuS and equilibrium is reestablished?
A. [S2-] increases.
B. [Cu2+] increases.
C. [S2-] does not change.
D. [Cu2+] does not change.
20) Which of the following describes the relationship between the solubility product
constant (Ksp) and the solubility (s) of PbI2?
A. Ksp = S2
B. Ksp = 4S3
21) Which of the following saturated solutions will have the lowest [S2-]?
A. BaS
B. CaS
C. CuS
D. ZnS
A. 3.2 10-25 M
B. 1.8 10-17 M
C. 4.3 10-9 M
D. 1.0 10-3 M
April 2003
A. grams
B. moles
C. molarity
D. milliliters per second
16) A saturated solution is prepared by dissolving a salt in water. Which of the following
graphs cold represent the ion concentrations as the temperature is changed?
17) What is the concentration of OH- ions in 250mL of 0.20 M Sr(OH)2?
A. 0.050 M
B. 0.10 M
C. 0.20 M
D. 0.40 M
18) What happens when 10.0mL of 0.2 M KOH is added to 10.0mL of 0.2M CuSO4?
A. No precipitate forms.
B. A precipitate of K2SO4 forms
C. A precipitate of Cu(OH)2 forms.
D. Precipitates of K2SO4 and Cu(OH)2 form.
19) Solid NaCl is added to a saturated AgCl solution. How have the [Ag+] and [Cl-]
changed when equilibrium has been reestablished?
[Ag+] [Cl-]
A. increased increase
B. decreased increased
C. increased decreased
D. decreased decreased
20) Which of the following expressions represents [Fe2+] in a saturated Fe(OH)3 solution?
21) What is the value of Ksp for Zn(OH)2 if the solubility of Zn(OH)2 is equal to
4.2 10-6 M?
A. 1.0 10-2
B. 4.0 10-3
C. 1.8 10-11
D. 3.0 10-16
22) What is the maximum number of moles of Cl- that can exist in 500.0mL
of 2.0M AgNO3?
A. 4.5 10-11
B. 9.0 10-11
C. 1.8 10-10
D. 1.8 10-9
June 2003
[Al3+] [SO42-]
A 0.33 M 0.50 M
B 1.0 M 1.5 M
C 1.5 M 1.5 M
D 3.0 M 4.5 M
17) Which of the following compounds could be used to prepare a solution with a
[S2-] greater than 0.1 M?
A. ZnS
B. PbS
C. Ag2S
D. Rb2S
18) Which of the following will not form a precipitate when mixed with an equal
volume of 0.2 M AgNO3?
A. 0.2 M NaBr
B. 0.2 M NaIO3
C. 0.2 M NaNO3
D. 0.2 M NaBrO3
19) A solution is prepared containing both 0.2 M OH- and 0.2 M PO43- ions. An
equal volume of a second solution is added in order to precipitate only one of these
two anions. The second solution must contain which of the following?
A. 0.2 M Cs+
B. 0.2 M Zn2+
C. 0.2 M Pb2+
D. 0.2 M Sr2+
21) How many moles of Pb2+ are there in 500.0mL of a saturated solution of PbSO4?
A. 3.2 10-16
B. 9.0 10-9
C. 6.7 10-5
D. 1.3 10-4
A. CuI
B. BeS
C. CsOH
D. AgBrO3
August 2003
A. H2SO4
B. AgNO3
C. Ca(OH)2
D. C6H12O6
16) Consider the following equilibrium:
A. heat
B. HCl
C. AgNO3
D. a catalyst
17) What is the [Cl-] when 15.0g of NaCl is dissolved in enough water to make
100.0mL of solution?
A. 0.150 M
B. 0.390 M
C. 2.56 M
D. 3.90 M
18) An equal number of moles of Na2CO3 is added to four different 10.0mL samples.
A precipitate forms in only one of the samples. Identify the cation which is
present in the precipitate.
A. Ba2+
B. Ca2+
C. Mg2+
D. Sr2+
19) What is the net ionic equation of the reaction between BaS(aq) and Sr(OH)2(aq)?
A. 1 M HCl
B. 1 M BaCl2
C. 1 M K2SO4
D. 1 M Pb(No3)2
21) The solubility of ZnCO3 is 6.4 10-9 M. What is the value of Ksp for ZnCO3?
A. 4.1 10-17
B. 6.4 10-9
C. 1.3 10-8
D. 8.0 10-5
22) When equal volumes of 0.20 M NaOH and 0.20 M CaS are mixed together,
A. a precipitate forms and the Trial Ksp would be less than Ksp.
B. no precipitate forms and the Trial Ksp would be less than Ksp.
C. a precipitate forms and the Trial Ksp would be greater than Ksp.
D. no precipitate forms and the Trial Ksp would be greater than Ksp.
Solutions
August 1998
13 A
14 D
15 B
16 C
17 C
18 D
19 D