SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

(amended by Regulation (EU) 2015/830)
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Silica gel
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1. Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier

CAS-No. 7631-86-9
EC-No. 231-545-4
REACH No. 01-2119379499-16-0036

Product code None.

Synonyms Silicagel x, C-Gel C-x, ZEObeads x, ZEOprep x, ZEOsphere x:

x = amendment of the product designation by up to three numerals,
optionally amended by up to three characters.

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture Adsorbent

Chromatography
Desiccant

1.3. Details of the supplier of the safety data sheet

Company/Undertaking Zeochem AG, www.zeochem.ch

Identification Seestrasse 108, CH-8707 Uetikon, Schweiz
Tel. +41 44 922 93 93
[email protected]

Only representative according to Art. 8 Regulation (EC) No 1907/2006:

Dr. Knoell Consult GmbH, www.knoell.com

Dynamostr. 19, 68165 Mannheim, Deutschland
Tel. +49 621 718 85 80
[email protected]

1.4. Emergency telephone Tox-Zentrum Zrich : 145 / +41 44 251 51 51 [24h/7d]

number

Issuing date 10.08.2016

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Version KOR 1, this safety data sheet replaces the following ones:
ZEOCHEM Silicagel version GHS 2
C-Gel version GHS 2
ZEObeads 720 version GHS 4
ZEOprep version GHS 3
ZEOprep 60 Y version GHS 1
ZEOsphere version GHS 3

2. Hazards identification
2.1. Classification of the substance or mixture

Classification according to The substance or mixture is not classified.

Regulation (EC) No. 1272/2008

In accordance with Regulation (EC) No. 1272/2008, the product does not need to be classified nor
labelled.

Additional information For the full text of the phrases mentioned in this Section, see
Section 16.

2.2. Label elements

Signal Word None.

Hazard Statements None.

Precautionary statements None.

Supplemental information None.

Product identifier Amorphous silica, CAS-No. 7631-86-9, EC-No. 231-545-4,

REACH No. 01-2119379499-16-0036

2.3. Other hazards No information available.

3. Composition/information on ingredients
Chemical characterization Synthetic amorphous silica

Components CLP Classification Product identifier

CAS-No.: 7631-86-9
Amorphous silica > 90 % EC-No.: 231-545-4
REACH No.: 01-2119379499-16-0036
CAS-No.: 7732-18-5
Water < 10 %
EC-No.: 231-791-2

For the full text of the phrases mentioned in this Section, see Section 16.
Hazardous impurities None known.

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4. First aid measures
4.1. Description of first aid measures

Inhalation No special measures required.

Skin contact Wash with water and soap as a precaution.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids. If eye
irritation persists, consult a specialist.

Ingestion Clean mouth with water and drink afterwards plenty of water.

4.2. Most important symptoms The product contains no substances known to be hazardous to
and effects, both acute and health in concentrations which need to be taken into account.
delayed

4.3. Indication of any immediate None known.

medical attention and special
treatment needed

5. Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media Use dry chemical, CO2, water spray or alcohol foam.

Extinguishing media which must High volume water jet.

not be used for safety reasons

5.2. Special hazards arising from The product is not flammable.

the substance or mixture

5.3. Advice for firefighters

Special protective equipment for Standard procedure for chemical fires.

firefighters

Specific methods No special measures required.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Advice for non-emergency No special measures required.

personnel

Advice for emergency Handle in accordance with good industrial hygiene and safety
responders practice.

6.2. Environmental precautions No special environmental precautions required.

6.3. Methods and material for Use mechanical handling equipment. After cleaning, flush away
containment and cleaning up traces with water.
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7. Handling and storage
7.1. Precautions for safe No special technical protective measures required.
handling

7.2. Conditions for safe storage, Store at room temperature in the original container. Take
including any incompatibilities precautionary measures against static discharges.

7.3. Specific end use(s) No information available.

8. Exposure controls/personal protection

8.1. Control parameters

Exposure limit(s) Exposure limit(s): 4 mg/m.

8.2. Exposure controls

Occupational exposure controls General industrial hygiene practice.

Personal protection equipment

Respiratory protection No special protective equipment required. Breathing apparatus only

if aerosol or dust is formed.

Hand protection PVC disposable gloves

Eye protection Avoid contact with eyes.

Skin and body protection No special measures required.

Thermal hazards No special measures required.

Environmental exposure controls No special measures required.

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9. Physical and chemical properties
9.1. Information on basic physical and chemical properties

Form Solid.
Colour White.
Odour Odorless
Odour Threshold No information available.
pH: 5-8 (5% in H2O)
Melting point/range: >1000C
Boiling point/range: n.a.
Flash point: does not flash
Evaporation Rate: n.a.
Flammability: No information available.
Explosion limits: No information available.
Vapour pressure: n.a.
Vapor density: n.a.
Relative density: 400-800 g/L
Water solubility: practically insoluble
Partition coefficient (n- n.a.
octanol/water):
Autoignition temperature: No information available.
Decomposition temperature: No information available.
Viscosity: n.a.
Combustion/explosion hazards: not hazardous
Oxidizing properties: None

9.2. Other information

General Product Characteristics No information available.

10. Stability and reactivity

10.1. Reactivity No information available.

10.2. Chemical stability No decomposition if used as directed.

10.3. Possibility of hazardous No information available.

reactions

10.4. Conditions to avoid Not required.

10.5. Incompatible materials None.

10.6. Hazardous decomposition None under normal use.

products

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11. Toxicological information
11.1. Information on toxicological effects

Acute toxicity Amorphous silica (CAS 7631-86-9)

LD50/oral/rat = 10000 mg/kg.
LCLO/inhalation/4h/rat = 139 mg/m.
LD50/dermal/rabbit > 5000 mg/kg.

Skin corrosion/irritation No skin irritation.

Serious eye damage/eye No eye irritation.

irritation

Respiratory / Skin Sensitisation None.

Carcinogenicity Animal testing did not show any carcinogenic effects.

Germ cell mutagenicity Animal testing did not show any mutagenic effects.

Reproductive toxicity Animal testing did not show any hazardous effects.

Specific target organ toxicity no data available

(single exposure)

Specific target organ toxicity no data available

(repeated exposure)

Aspiration hazard No data available.

Human experience This product has no known adverse effect on human health.

12. Ecological information

12.1. Toxicity Amorphous silica (CAS 7631-86-9)
LC50/96h/fish > 10000 mg/l.
EC50/24h/daphnia = 10000 mg/l.
EC50/72h/algae > 10000 mg/l.

12.2. Persistence and No data available.

degradability

12.3. Bioaccumulative potential Does not bioaccumulate. Accumulation in aquatic organisms is

unlikely. Accumulation in terrestrial organisms is unlikely.

12.4. Mobility in soil No data available.

12.5. Results of PBT and vPvB This information is not available.

assessment

12.6. Other adverse effects This information is not available.

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13. Disposal considerations
13.1. Waste treatment methods

Waste from residues / unused Dispose of in accordance with local regulations.

products

Contaminated packaging Offer rinsed packaging material to local recycling facilities.

14. Transport information

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

Further Information Not classified as dangerous in the meaning of transport regulations.

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulatory Information In accordance with Regulation (EC) No. 1272/2008, the product
does not need to be classified nor labelled.

15.2. Chemical safety Not required.

assessment

16. Other information

Key or legend to abbreviations CLP: Classification according to Regulation (EC) No. 1272/2008
and acronyms (GHS)

Full text of phrases referred to None.

under sections 2 and 3

Further information Not relevant.

Disclaimer The information provided in this Safety Data Sheet is correct to the
best of our knowledge, information and belief at the date of its pub-
liccation. The information given is designed only as a guidance for
safe handling, use, processing, storage, transportation, disposal and
release. It is not to be considered a warranty or quality specification.

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