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Safety data sheet according to regulation (EC) No. 1907/2006, Annex II
Revision: 19.11.2009. Replaces version of 19.11.2009. PDF date: 2016/01/01
Microcide SQ

Safety data sheet

according to Regulation (EC) No 1907/2006, Annex II
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING

Identification of the substance or preparation

Microcide SQ®
Use of the substance/preparation
Disinfectant cleaner

Company/undertaking identification

Global Biotechnologies, Inc 19 Rigby Road Scarborough, ME 04074

Tel +1 207-799-8420 Fax +1 207-883-0308

E-mail address of the competent person:

[email protected]

Emergency telephone
Advisory office in case of poisoning:
Tel.:
Tel +1 207-799-8420

r 2. HAZARDS IDENTIFICATION

To people
See point 11 and 15.
Preparation is classified as hazardous in the sense of directive 1999/45/EC.
Irritation of the eyes
To the environment
See point 12.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name 1
content % Symbol R-phrases EINECS, ELINCS
Registration number (ECHA)

Sodium carbonate
1-5 Xi 36 207-838-8

Alkyl dimethyl ethylbenzyl ammonium chloride

1 -< 5 Xn/C/N 21/22-34-50 287-090-7

Alkyldimethylbenzylammonium chloride
1 -< 5 Xn/C/N 21/22-34-50 269-919-4

Tetrasodium ethylene diamine tetraacetate

1 -< 5 Xn/Xi 22-41 200-573-9

For complete wording of the R-phrases, refer to point 16.

4. FIRST AID MEASURES

4.1 Inhalation
Remove person from danger area.
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Safety data sheet according to regulation (EC) No. 1907/2006, Annex II Revision: 19.11.2009.
Replaces version of 19.11.2009. PDF date: 2016/01/01
Microcide SQ

Supply person with fresh air and consult doctor according to symptoms. Keep Data
Sheet available.
4.2 Eye contact
Wash thoroughly for several minutes using copious water - call doctor immediately, have Data Sheet available.
4.3 Skin contact
Wash thoroughly using copious water - remove contaminated clothing immediately. If skin irritation occurs (redness etc.), consult doctor.
4.4 Ingestion
Rinse the mouth thoroughly with water.
Do not induce vomiting - give copious water to drink. Consult doctor immediately.
4.5 Special resources necessary for first aid
n.c.

5. FIRE-FIGHTING MEASURES

5.1 Suitable extinguishing media

Product is not combustible.
Adapt to the nature and extent of fire. Water jet
spray/foam/CO2/dry extinguisher
5.2 Extinguishing media which shall not be used for safety reasons
n.c.
5.3 Special exposure hazards arising from the substance or preparation itself, combustion
products, resulting gases
In case of fire the following can develop:
Oxides of carbon Oxides of
nitrogen Hydrogen chloride
Toxic pyrolysis products.
5.4 Special protective equipment for fire-fighters
Protective respirator with independent air supply. According to
size of fire
Full protection, if necessary
5.5 Further information
Dispose of contaminated extinction water according to official regulations.

6. ACCIDENTAL RELEASE MEASURES

Refer to point 13. and for personal protection refer to point 8.

6.1 Personal precautions
Ensure sufficient supply of air. Avoid contact
with eyes or skin.
If applicable, caution - risk of slipping
6.2 Environmental precautions
If leakage occurs, dam up.
Prevent from entering drainage system.
Prevent surface and ground-water infiltration, as well as ground penetration.
If accidental entry into drainage system occurs, inform responsible authorities.
6.3 Methods for cleaning up
Collect using absorbant material (e.g. Universal binding medium), and dispose of according to point 13.

7. HANDLING AND STORAGE

7.1 Handling
Tips for safe handling:
See point 6.1
Avoid aerosol formation.
Eating, drinking, smoking, as well as food-storage, is prohibited in work-room. Wash hands
before breaks and at end of work.
Observe directions on label and instructions for use.
Use working methods according to operating instructions.
7.2. Storage
Requirements for storage rooms and containers:
Not to be stored in gangways or stair wells.
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Safety data sheet according to regulation (EC) No. 1907/2006, Annex II Revision: Replaces version
of 19.11.2009. PDF date: 2016/01/01
Microcide SQ

Store product closed and only in original packing.

Special storage conditions:
See point 10
Protect from frost.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Exposure limit values

8.2 Exposure controls

8.2.1 Occupational exposure controls
Ensure good ventilation. This can be achieved by local suction or general air extraction.
If this is insufficient to maintain the concentration under the WEL or AGW values, suitable breathing protection should be worn. Applies only if
maximum permissible exposure values are listed here.
General hygiene measures for the handling of chemicals are applicable. Wash hands before
breaks and at end of work.
Keep away from food, drink and animal feedingstuffs.
Respiratory protection: Normally not necessary.
Hand protection: Chemical resistant protective gloves (EN 374). Protective hand
cream recommended.
If applicable
Rubber gloves (EN 374).
Protective hand cream recommended.
Eye protection: Tight fitting protective goggles with side protection (EN 166). Skin protection:
Protective working garments (e.g. safety shoes EN ISO 20345,
long-sleeved protective working garments)

Additional information on hand protection - No tests have been performed.

Selection made for preparations according to the best available knowledge and information on the ingredients. Selection of materials
derived from glove manufacturer's indications.
Final selection of glove material must be made taking the breakthrough times, permeation rates
and degradation into account.
Selection of a suitable glove depends not only on the material but also on other quality characteristics and varies from
manufacturer to manufacturer.
In the case of preparations the resistance of glove materials cannot be calculated in advance so it has to be tested
before use. The exact breakthrough time of the glove material can be requested from the protective glove
manufacturer and must be observed.

8.2.2 Environmental exposure controls

n.ay.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid Colour: Colourless Odour:

Odourless pH-value undiluted:
— 10
Boiling point/boiling range (°C): > 100
Melting point/melting range (°C): <0
Flash point (°C): n.c. Vapour pressure:
n.c. Density (g/ml):
1,007
Water solubility: Soluble

10. STABILITY AND REACTIVITY

Conditions to avoid
Stable when handled and stored correctly.
Materials to avoid
See point 7
Avoid contact with other chemicals. Hazardous
decomposition products See point 5.3
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Safety data sheet according to regulation (EC) No. 1907/2006,
Annex II Revision: 19.11.2009. Replaces version of 19.11.2009.
PDF date: 2016/01/01
Microcide SQ

11. TOXICOLOGICAL INFORMATION

Acute toxicity and

immediate effects
Ingestion, LD50 rat oral (mg/kg):
n.ay. Inhalation, LC50 rat inhal.(mg/I/4h):
n.ay. Skin contact, LD50 rat dermal (mg/kg):
n.ay.
Eye contact:
See point 15.

Delayed and
Chronic effects
Sensitization:
May cause sensitization by
skin contact. * "
Benzalkonium chloride
Carcinogenicity:
n.c.
Mutagenicity:
n.c. Reproductive toxicity:
n.c. Narcosis:
n.c.

Further
informati
on
Classification according to
calculation procedure. The
following may occur:
Irritation of the
skin. Ingestion of
large quantities:
Product is
dangerous to
health. Risk of
serious damage
to eyes. "
Benzalkonium
chloride

12. ECOLOGICAL INFORMATION

Water hazard class (Germany):

3
Self classification: Yes (VwVwS) Persistence and degradability:
Readily
biodegradable
(86%) *
79,9%
/28d US-
EPA **
Behaviour in sewage plants:
n.ay. Aquatic toxicity:
n.ay. Ecological toxicity:
n.ay.
*
POLYS
ORBA
TE 80
""
Alkyldimethylbenzylammoni
um chloride

13. DISPOSAL CONSIDERATIONS

13.1. for the material / preparation / residue

EC disposal code no.:
The waste codes are recommendations based on the scheduled use of
this product. Owing to the user's specific conditions for use and disposal,
other waste codes may be allocated under certain circumstances.
(2001/118/EC, 2001/119/EC, 2001/573/EC)
07 06 01 aqueous washing liquids and mother liquors
20 01 29 detergents containing dangerous substances
Recommendation:
Pay attention to local and national official regulations
E.g. suitable incineration plant.
E.g. dispose at suitable refuse site.
13.2 for contaminated packing material
See point 13.1
Pay attention to local and national official regulations
Empty container completely.
Uncontaminated packaging can be recycled.
Dispose of packaging that cannot be cleaned in the same manner as the substance.
14. TRANSPORT INFORMATION
5/5 Safety data sheet according to regulation (EC) No. 1907/2006, Annex II Revision: 19.11.2009. Replaces version of 19.11.2009. PDF date: 2016/01/01
Microcide SQ

LQ: n.a. Tunnel restriction code:

Additional information:
Non-dangerous material according to Transport Regulations.

15. REGULATORY INFORMATION

Classification according to Dangerous Product Regulations incl. EC Directives (67/548/EEC and

1999/45/EC)

Symbols: Xi
Indications of danger: Irritant
R-phrases:
36 Irritating to eyes. S-phrases:
(2) Keep out of the reach of children.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
35 This material and its container must be disposed of in a safe way.
(46) If swallowed, seek medical advice immediately and show this container or label.

Additions: n.a.
Observe restrictions: Yes
Observe youth employment law (German regulation).
Observe restrictive guidelines 76/769/EEC, 1999/51/EC, 1999/77/EC

16. OTHER INFORMATION

These details refer to the product as it is delivered.

Storage class VCI (Germany): 12
Revised points: n.a.
The following phrases represent the prescribed R-phrases / H-phrases (GHS) for the ingredients (designated in point 3).
36 Irritating to eyes.
21/22 Harmful in contact with skin and if swallowed.
34 Causes burns
50 Very toxic to aquatic organisms.
22 Harmful if swallowed.
41 Risk of serious damage to eyes.

Legend:

n.a. = not applicable / n.v., k.D.v. = n.ay. = not available / n.g. = n.c. = not checked
WEL = Workplace Exposure Limit EH40, TWA = Long-term exposure limit (8-hour TWA (= time weighted average) reference period), STEL = Short-terme exposure
limit (15-minute reference period) / BMGV = Biological monitoring guidance value EH40
AGW = "Arbeitsplatzgrenzwert" (workplace limit value, Germany) / BGW = "Biologischer Grenzwert" (biological limit value, Germany) VbF = Regulations for flammable
liquids (Austria)
WGK = water hazard class (Germany) - WGK 3 = very hazardous, WGK 2 = hazardous, WGK 1 = slightly hazardous to water
VOC = Volatile organic compounds / AOX = Adsorbable organic halogen compounds
VwVwS = Administrative Order relating to substances hazardous to water (Germany)
The statements made here should describe the product with regard to the necessary safety precautions - they are not meant to guarantee definite
characteristics - but they are based on our present up-to-date knowledge.
No responsibility.
These statements were made by: GLOBAL BIOTECHNOLOGIES, INC