s2 Puma Petro Brochure Doc-b80-Exs019 en High
s2 Puma Petro Brochure Doc-b80-Exs019 en High
s2 Puma Petro Brochure Doc-b80-Exs019 en High
EDXRF
Innovation with Integrity
Get all Information you need for Fuels and
Oils – Elemental Analysis with the S2 PUMA
or Fe measurements
2
S2 PUMA for best data quality –
Optimum precision, best accuracy
and norm compliant
Detection
Concentration Correlation
Element limit (300 s,
range [ppm] (R2)
3s) [ppm]
Sulfur 0-1000 0.6 0.99998
3
Additives in lubricants – there is simply no better
way than the S2 PUMA
Sulfur isn't the only element that plays a central role in
lubricants and fuels. That is why the S2 PUMA is also
capable of determining the quality and quantity of addi-
tives used in the refinement of lubricants. These addi-
tives, such as abrasion minimizers or pitting protection
additives, are added to lubricating oils in small quantities
in order to achieve or improve certain properties. Due to
their complex formulations, these special chemicals can
sometimes be very expensive, so the quantities added
are decisive for the quality, efficiency, but also the envi-
ronmental friendliness of the product.
S2 PUMA – Norm compliance for Mg, P, S, Cl, Ca,
Zn, and Mo
In addition to the norm ASTM D6481 now also
ASTM D7751 is applied for these measurements. This
Fig. 3: Repeatability of duplicate measurements of 25
ppm sulfur standards in accordance with ASTM norm takes into account the important additive elements
D4294. The horizontal red lines denote the allowed magnesium, phosphorus, sulfur, chlorine, calcium, zinc,
limits for reproducibility according to the norm. The and molybdenum in concentration ranges typical for
high requirements placed on the determination their use in lubricants.
of sulfur in fuels, such as those contained in the
ASTM D4294 norm, but also the requirements of Using the example of zinc as abrasion-reducing additive,
EN ISO 20847 (DIN) and EN ISO 8754 (DIN), are Figure 4 depicts the calibration line on the S2 PUMA.
met by the S2 PUMA.
Table 2 shows the calibration results for zinc in lubri-
cants on the S2 PUMA, and Table 3 gives typical repeat-
abilities of ten measurements of additive elements in
lubricants.
The S2 PUMA meets all requirements of ASTM D7751
and D6481 on the analysis of additives. Calibration over
a wide range of concentrations, the low detection limit,
the small standard deviation, and very good accuracy
make the S2 PUMA the ideal partner when it comes to
the analysis of oil additives. The S2 PUMA can also be
used to examine used oils. Here the amounts of heavy
metals, halogens, etc. contained determine the type of
recycling or disposal.
No matter which lubricating oil you need to specify:
The S2 PUMA delivers spot-on ASTM compliance for
D6481, D7751 and other.
Fig. 4: Calibration line for zinc in a lubricating oil matrix
Detection Standard
Concentration Correlation
Element limit (100 s, deviation
range [ppm] (R2)
3s) [ppm] [ppm]
Zinc 0 - 0.4 0.3 8 0. 99997
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Table 3: Repeatability data for 10 measurements of a QC sample for additives in lubricants according to ASTM D7751
Abs. standard
0.0030 0.0004 0.0018 0.0005 0.0009 0.0005 0.0001
deviation
Rel. standard
3.4 % 0.5 % 0.4 % 2.1 % 0.5 % 0.5 % 0.7 %
deviation
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Technological innovations as key to best
results and reliable evaluation
volatile samples
S2 PUMA XY Autochanger with failsafe recognition
of liquid cups
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S2 PUMA – Analytical performance
comes in handy with ease of use
and lowest cost of ownership
With the analysis of light elements in particular, their
low-energy radiation is absorbed by the surrounding
air. Consequently, such measurements are carried out
in a helium atmosphere or under vacuum. Since such
vacuum analyses may not be conducted with highly
volatile samples, such as fuels, it pays off that the
S2 PUMA XY Autochanger automatically detects these
samples when loaded and prevents the formation of
a vacuum. A sample-chamber that is reduced to the
smallest possible dimensions translates into minimal
consumption of helium, which means very low operat-
ing costs but high analytical capability.
EDXRF together with the S2 PUMA provides you with
everything you need for monitoring and optimizing lubri-
cants and fuels:
The highest in analytical accuracy and precision
S2 PUMA with SampleCareTM: Unique protection
in compliance with international standards
HighSense technology for excellent detection
against contamination of important system com-
ponents ensures the best in device availability
limits, with high spectral resolution
Outstanding results for light elements such as
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Technical Data
S2 PUMA Single S2 PUMA XY Autochanger
Element range Sodium to americium (Na – Am) with standard XFlash®
Carbon to americium (C – Am) with XFlash® Light Element (LE)
Concentration range From ppm to 100 %
X-ray tube Pd or Ag anode; max. power 50 W; max. voltage 50 kV (low kV version: 30 kV max.)
Primary beam filters 10-position automatic filter changer; for wide range elemental analysis
pre-installed filters: 5 μm Ag, 20 and 500 μm Al, 100 and 250 μm Cu
Detector XFlash® Silicon Drift Detector: Peltier cooled (no need for liquid nitrogen)
Collimator masks For small spot analysis: 1, 3, 8, 12, 18, 23 and 28 mm (optional)
Sample observation Integrated HD video camera, for exact sample positioning and documenting the
measurement position of a sample (optional)
Mode Air mode
Gas flushing (optional): Helium for liquids and loose powders
Vacuum pump (optional): Enhanced light element performance for hot-pressed disks,
low cost of operation
TouchControl™ Integrated 12.1” TFT touchscreen, multilingual user interface
Connectivity Built-in Ethernet port RJ45, 4x USB ports for mouse, keyboard, printer
Power requirements 100-240 V, 50/60 Hz, max. power consumption 600 VA
Bruker AXS is continually improving its products and reserves the right to change specifications without notice.
Sample types Loose powders, granules, solids, pressed pellets, fused beads and liquids up to
20 mL
Sample rotation (optional)
S2 PUMA Single S2 PUMA XY Autochanger
Sample sizes Up to 51.5 mm Ø samples. Liquids, Up to 40 mm Ø and 38 mm height in
loose powders and smaller samples in sample holders, max. weight 200 g or
liquid cups: up to 20 mL 51.5 mm Ø as sample ring.
Sample loader Single position, EasyLoad XYTM sample tray, 20-position,
manual removable. Grabber with automatic sam-
ple detection
Dimensions 67 x 71 x 37 cm; 87 kg 67 x 71 x 61 cm; 108 kg
width x depth x height; weight 26.2 x 27.8 x 14.6“; 192 lbs 26.2 x 27.8 x 23.8“; 238 lbs
Quality & safety DIN EN ISO 9001:2008; CE-certified Machinery directive 2006/42/EC; Electrical
equipment 2006/95/EC; Electromagnetic Compatibility 2004/108/EC; Fully radia-
tion-protected system; radiation < 1 μSv/h (H*); German type approval (BfS) for
X-ray safety; Conform to ICRP, IAEA, EURATOM
Order No. DOC-B80-EXS019. © 2016 Bruker AXS.
TouchControl™, SampleCare™, EasyLoad™, DynaMatch™,
HighSense™ and DustShield™ are trademarks of Bruker AXS Inc.;
XFlash® is a registered trademark of Bruker Nano Analytics
DuraBeryllium® is a trademark of Moxtek® Inc.
www.bruker.com