JEE Main 2019 Chemistry April Attempt Shift - 2 (08th April, 2019)
JEE Main 2019 Chemistry April Attempt Shift - 2 (08th April, 2019)
JEE Main 2019 Chemistry April Attempt Shift - 2 (08th April, 2019)
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PART : CHEMISTRY
Straight Objective Type (lh/ks oLrqfu"B izkj)
This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 30 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. The Mond process is used for the :
(1) purification of Zr and Ti (2) extraction of Mo
(3) extraction of Zn (4) purification of Ni
ekWUM izØe iz;qDr gksrk gS%
(1) Zr rFkk Ti ds 'kks/ku ds fy, (2) Mo ds fu"d"kZ.k ds fy,
(3) Zn ds fu"d"kZ.k ds fy, (4) Ni ds 'kks/ku ds fy,
Ans. (4)
50C
Sol. Ni(s) + 4CO(g) [Ni(CO)4]
Impure (v'kq))
200 250 C
[Ni(CO)4] Ni(s) + 4CO(g)
Pure ('kq))
2. The statement that is INCORRECT about the interstitial compounds is :
(1) they are chemically reactive. (2) they have metallic conductivity
(3) they are very hard. (4) they have high melting points
varjkyh ;kSfxdks ds ckjs esa tks dFku vlR; gksxk] og gS%
(1) os jklk;fud :i ls vfHkfØ;k'khy gks rs gS A (2) muesa /kkfRod pkydrk gksrh gSA
(3) os cgq r dBksj gks rs gSa A (4) muds xyukad mPp gks rs gSaA
Ans. (1)
Sol. Interstitial compound are almost inert so (A) is wrong statement
vUrjdk'kh ;kSfxd yxHkx vfØ; gksrs gSA blfy, (A) xyr dFku gSA
3. The covalent alkaline earth metal halide (X = Cl, Br, I) is :
lgla;ksth {kkjh; e`nk /kkrq gSykbM (X = Cl, Br, I) gS%
(1) CaX2 (2) SrX2 (3) BeX2 (4) MgX2
Ans. (3)
Sol. According to Fajan’s rule when size of cation decrease, then covalent character increase.
So BeX2 is covalent in nature.
Qktku fu;e ds vuqlkj tc /kuk;u dk vkdkj ?kVrk gS] rks lgla;kstd xq.k c<+rk gSA
vr% BeX2 lgla;kstd izd`fr dk gSA
4. The correct statement about ICl 5 and ICl –4 is :
(1) ICl 5 is trigonal bipyramidal and ICl 4– is tetrahedral.
(2) ICl 5 is square pyramidal and ICl –4 is square planar.
(3) both are isostructural.
(4) ICl 5 is square pyramidal and ICl –4 is tetrahedral.
ICl 5 rFkk ICl 4– ds fy, lR; dFku gS%
(1) ICl 5 f=kelurk{k f}fijkfeMh rFkk ICl 4– prq"Qydh; gSA
(2) ICl 5 oxZ fijkfeMh rFkk ICl 4– oxZ leryh; gS A
(3) nksuks gh lelajpukRed gSaA
(4) ICl 5 oxZ fijkfeMh ICl –4 prq"Qydh; gSA
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Ans. (2)
– Cl Cl
Cl Cl Cl
Sol.
Cl Cl Cl Cl
Square planar Square pyramidal
– Cl Cl
Cl Cl Cl
Sol.
Cl Cl Cl Cl
oxZ leryh; oxZ fijkfeMh;
5. The major product of the following reaction is :
fuEu vfHkfØ;k dk eq[; mRikn gS%
O
(1) t-BuOK
(2) Conc. H2SO4/
Cl
O O
(1) (2)
O O
(3) (4)
Ans. (1)
O O
(1) t-BuOK
Sol.
E2 elimination
Cl reaction
O
(2) Conc. H2SO4/
Electrophilic
subsitution
6. If p is the momentum of the fastest electron ejected from a metal surface after the irradiation of light
having wavelength , then for 1.5 p momentum of the photoelectron, the wavelength of the light should
be :
(Assume kinetic energy of ejected photoelectron to be very high in comparison to work function) :
;fn rjaxnS/;Z ds izdk'k ls fdjf.kr gksus ij,d /kkrq dh lrg ls fudys gq, rhozre bysDVªkWu dk laosx p gS rks
izdkf'kd bysDVªkWu ds 1.5 p laosx ds fy, izdk'k dk rjaxnS/;Z gksxk%
¼eku yhft;s fd fu"dkflr izdkf'kd bysDVªkWu dh K.E. ¼xfrt ÅtkZ½ mlds dk;ZQyu dh rqy uk esa cgqr mPp gSa½
3 1 4 2
(1) (2) (3) (4)
4 2 9 3
Ans. (3)
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Sol. As kinetic energy is much higher than work function so
E = E0 + KE KE
hc P2
As E = & kE =
2m
2
2 P 1
2
So = 1 2
1 P2 1 .5
4
2 =
9
CN O
H H
NCH3 NCH3
(1) (2)
H2N OH CN O
H H
NCHCl2 NCH3
(3) (4)
CN OH CN OH
Ans. (1)
NH2 NC NH–CH3
1 CHCl .KOH 2 H2 , Pd, C
Sol. 3
CN O CN O OH
CH2NH2
(Carbyalmine reaction) (Reduction)
¼dkfcZy ,ehu vfHkfØ;k½ ¼vip;u½
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9. The major product obtained in the following reaction is :
fuEu vfHkfØ;k esa izkIr gksus okyk eq[; mRikn gS%
CH3 O
NaOH
OHC
CH3
(1) (2)
O
CH3
H3C
(3) (4) H
O
O CH2
Ans. (1)
Sol. It is an example of intramolecular aldol condensation.
;g vUr% v.kqd ,YMksy la?kuu vfHkfØ;k dk mnkgj.k gSA
O O O
O
–
OH
– CH=O
CH=O
OH
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10 – 8
B.O 1(Diamagnetic) (izfrpqEcdh;)
2
O 2 1s 2 , * 1s 2 , 2s 2 , * 2s 2 , 2Pz2 [2Px2 2Py2 ] [ * 2Px1 * 2Py1 ]
10 – 6
B.O 2 (Paramagnetic)
2
10 – 6
cU/k Øe 2 (vuqpqEcdh;)
2
1
B.O
B.L.
1
cU/k Øe
cU/k yEckbZ
12. For the solution of the gases w, x, y and z in water at 298 K, the Henrys law constants (KH) are 0.5, 2, 35
and 40 k bar, respectively. The correct plot for the given data is :
partial y
(1) (2) pressure x
w
(0,0) mole fraction
of water
z
partial z partial
(3) pressure (4) pressure y
y x
x
w w
(0,0) mole fraction (0,0) mole fraction
of water of water
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298 K ij ty esa xSl w, x, y rFkk z ds foy;u ds fy, gsujh fu;e fLFkjkad (KH) Øe'k% 0.5, 2, 35 rFkk 40 k bar,
gSaA fn;s vk¡dM+ksa ds fy;s lgh IykV gS %
partial y
(1) (2) pressure x
w
(0,0) mole fraction
of water
z
partial z partial
(3) pressure (4) pressure y
y x
x
w w
(0,0) mole fraction (0,0) mole fraction
of water of water
Ans. (3)
Sol. Pgas = KH. xgas
Pgas = KH. 1 – x H2O
Pgas = KH – KH. x H2O
y = c + mx
(1) Cl2/h
(2) H2O,
Cl
CHCl2 CO2H CHO CH2OH
Cl Cl Cl Cl
Ans. (3)
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CH3 CH=O
CHCl2
1 Cl2 / h 2 H O,
Sol. 2
Cl Cl
Cl
(Free radical
(SN1)
Substitution)
¼eqDr ewy d izfrLFkkiu½
15. 0.27 g of a long chain fatty acid was dissolved in 100 cm3 of hexane. 10 mL of this solution was added
dropwise to the surface of water in a round watch glass. Hexane evaporates and a monolayer is
formed. The distance from edge to cenre of the watch glass is 10 cm. What is the height of the
monolayer?
[Density of fatty acid = 0.9 g cm–3, = 3]
nh?kZ Ja`[kyk okys QSVh ,flM ds 0.27 g dks 100 cm3 gsDlsu esa ?kksyk x;kA bl foy;u ds 10 mL dks ,d xksykdkj
okp X;kl esa j[ks ty dh lrg ij cw¡n&cw¡n djds fxjk;k x;kA gsDlsu ok"ihÑr gks xbZ vkSj ,d ,dy irZ cu xbZA
okp Xykl ds fdjkus ls muds dsUnz rd dh nwjh 10 cm gSA ml ,dy ijr dh Å¡pkbZ D;k gksxh\
[QSVh ,flM dk ?kuRo = 0.9 g cm–3, = 3]
(1) 10–2 m (2) 10–6 m (3) 10–8 m (4) 10–4 m
Ans. (2)
0.27 0.1
Sol. Mass of fatty acid which is added over watch glass = = 2.7 × 10–2
100
2.7 10 2
Volume of fatty acid = = 3 × 10–2
0 .9
Total Area of glass plate = r2 = 3 × [10]2 = 300 cm2
Volume = Area × hight
3×10–2 = 300 × hight
Hight of the layer = 10–4 cm = 10–6 m
16. The ion that has sp3d2 hybridization for the central atom, is :
fuEu esa ls fdl vk;u es dsfUnz; ijek.kq dk ladj.k sp3d2 gS\
(1) [ICl2]– (2) [IF6]– (3) [BrF2]– (4) [ICl 4]–
Ans. (4)
–
Cl Cl
Sol. Sp3d2
Cl Cl
[BrF2]– sp3d
[ICl 2]– sp3d
[IF6]– sp3d3
17. Which one of the following alkenes when treated with HCl yields majorly an anti Markovnikov product?
fuEufyf[kr ,sYdhuksa esa ls dkSu&lk ,d HCl ds lkFk vfHkfØ;k djds eq[;r% ,d izfr ekdksZuhdkWQ mRikn nsrk gS\
(1) CH3O–CH=CH2 (2) Cl–CH=CH2 (3) H2N–CH=CH2 (4) F3C–CH=CH2
Ans. (4)
Sol. CF3 is very strong -I group hence it will favour anti-Markownikov's product.
CF3–CH=CH2
CF3–CH2–CH2+ CF3–CH2–CH2X (anti-Markownikov's product)
HX
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Sol. CF3 izcyre -I lewg gS] vr% ;g ,UVh&ekjdksuhdkW o mRikn cuk;sxkA
HX
CF3–CH=CH2
CF3–CH2–CH2+ CF3–CH2–CH2X (,UVh&ekjdksuhdkW o mRikn)
18. 5 moles of an ideal gas at 100 K are allowed to undergo reversible compression till its temperature
becomes 200 K. If CV = 28 JK–1 mol–1 , calculate U and pV for this process, (R = 8.0 JK–1 mol –1)
100 K ij] ,d vkn'kZ xsl ds 5 eksy dk mRØe.kh; laihMu rc rd fd;k tkrk gS tc rd dh mldk rki 200 K
ugha gks tkrkA ;fn CV = 28 JK–1 mol–1 , rks bl izØe ds fy, U rFkk pV dh x.kuk dhft, (R = 8.0 JK–1 mol–
1)
19. Consider the bcc unit cells of the solid 1 and 2 with the position of atoms as shown below. The radius of
atoms as shown below. The radius of atom B is twice that of atom A. The unit cell edge length is 50%
more in solid 2 than in 1. What is the approximate packing efficiency in solid 2?
Bksl 1 rFkk 2 ijek.kqvks dh fLFkfr ds lkFk] tSlk fd uhps n'kkZ;k x;k gS] dh ch-lh-lh ¼dk-da-?k-½ ,dd dksf"Bdk ij
fopkj dhft,A ijek.kq B dh f=kT;k ijek.kq A dh f=kT;k dh nwuh gSA Bksl 1 dh ,dd dksf"Bdk dh dksj yEckbZ ls
Bksl 2 dh ,dd dksf"Bdk dh dksj yEckbZ 50% T;knk gSA Bksl 2 ls esa yxHkx lqladqyu n{krk D;k gS\
A A
A A
A A A A
A B
A A A A
A A A A
Solid 1 Solid 2
(1) 65% (2) 45% (3) 90% (4) 75%
Ans. (3)
Sol. 3a 2r 2(2r ) 6r
6r
a= 2 3 r
3
4 3 4
r (2r )3
P.F. = 3 3
a3
4 3
(r 8r 3 )
3 4 9r 3
=
( 2 3r )3
3 8 3 3r 3
= 0.906
2 3
% of packing efficiency = 0.906 × 100 = 90.6%
ladqyu n{krk dk % = 0.906 × 100 = 90.6%
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20. The strength of 11.2 volume solution of H2O2 is : [Given that molar mass of H = 1 g mol –1 and O = 16 g
mol –1]
H2O2 ds 11.2 vk;ru foy;u dh lkeF;Z gS] ¼fn;k x;k gS% eksyj nzO;eku H = 1 g mol–1 rFkk O = 16 g mol–1½
(1) 3.4% (2) 34% (4) 13.6% (4) 1.7%
Ans. (1)
Volume strength vk;ru lkeF; Z
Sol. M=
11.2 11.2
%( w / v ) 10
M=
GMM
%( w / v ) 10
1=
34
w
So % = 3.4 %
v
Cl NH3
22. Calculate the standard cell potential (in V) of the cell in which following reaction takes place :
ml lsy ds ekud lsy foHko (V esa) dh x.kuk dhft, ftlesa fuEu vfHkfØ;k gksrh gS%
Fe2+ (aq) + Ag+ (aq) Fe3+ (aq) + Ag(s)
Given that ¼fn;k x;k gS%½
E0Ag / Ag xV
0
EFe 2
/ Fe
yV
0
EFe 3
/ Fe
zV
(1) x – z (2) x – y (3) x + y – z (4) x + 2y – .3z
Ans. (4)
Sol. Fe2+ Fe G1 –2Fy
Fe3+ Fe G 2 –3Fz
Fe3+ Fe2+ Eº = 3z – 2y
E°cell = E 0Ag |Ag EFe
0
3
| Fe2
= x – [3z – 2y) = x + 2y – 3z
For given cell reaction
fn xbZ lSy vfHkfØ;k ds fy,
Ecell = x + 2y – 3z
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23. The calculated spin-only magnetic moments (BM) of the anionic and cationic species of [Fe(H2O)6]2 and
[Fe(CN)6],
(1) 0 and 5.92 (2) 4.9 and 0 (3) 0 and 4.9 (4) 2.84 and 5.92
[Fe(H2O)6]2 rFkk [Fe(CN)6] ds _.kk;fud rFkk /kuk;fud Lih'kht ds ifjdfyr izpØ.k&ek=k pqEcdh; vk?kw.kZ (BM
esa) Øe'k% gSa%
(1) 0 rFkk 5.92 (2) 4.9 rFkk 0 (3) 0 rFkk 4.9 (4) 2.84 rFkk 5.92
Ans. (3)
Sol. [Fe(CN)6]–4
Fe+2 3d6
CN– S.F.L.
t2g2,2,2 eg0,0
No. of unpaired e– = 0
v;qfXer bysDVªkWuksa dh la[;k = 0
B.M. = 0
[Fe(H2O)6]+2
Fe+2 3d6
H2O W.F.L.
t2g2,1,1 eg1,1
No. of unpaired e– = 4
v;qfXer bysDVªkWuksa dh la[;k = 4
= 46 = 24 B.M. = 4.9BM
k1 k2
24. For a reaction scheme A B C, if the rate of formation of B is set to be zero then the
concentration of B is given by :
k1 k2
vfHkfØ;k ;kstuk A B C ds fy,] ;fn B ds cuus dh nj 'kwU; dh nh tk; rks B dh lkUnz rk fuEu ds
}kjk nh tk;sxh%
k
(1) (k1–k2) [A] (2) (k1 + k2) [A] (3) 1 [A] (4) k1k2 [A]
k2
Ans. (3)
d[B ]
Sol. K 1 [ A ] – K 2 [B ]
dt
d[B ]
0
dt
K
[B] = 1 [ A ]
K2
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26. The major product in the following reaction is :
fuEu vfHkfØ;k esa eq[; mRikn gS%
NH2
N
N
base
+ CH3I
N N
H
NH2 NH2
N +
NCH3 N
N
(1) (2)
N N +
N N
H H
CH3
NHCH3
NH2
N
N N
N
(3) (4)
N N N
N H
CH3
Ans. (3)
(e)
(a) NH2
N N(d)
Sol. (Adenine)
NH N
(b) (c)
Adenine is the purine base present in RNA and DNA. It reacts from nitrogen b with ribose sugar hence
according to this correct product is (3).
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[SO 3 ] 2
K2 = = 10129 …(2)
[O 2 ] 3
[SO 2 ] 2
K12 = = 10104 …(3)
[O 2 ]2
K2 10 129
Keq = = = 1025
(K 1 ) 2 10 104
28. Which of the following compounds will show the maximum 'enol' content?
fuEu ;kSfxdksa es ls dkSu&lk ^bZukWy* dh vf/kdre ek=kk iznf'kZr djsxk\
(1) CH3COCH2CONH2 (2) CH3COCH2COOC2H5
(3) CH3COCH2COCH3 (4) CH3COCH3
Ans. (3)
O O
Sol. Enol content is maximum in CH3–C–CH2–C–CH3
O O
CH3–C–CH2–C–CH3 bZukWy ?kVd vf/kdre gS A
30. The IUPAC symbol for the element with atomic number 119 would be :
119 ijek.kq Øeka d okys rRo ds fy, vkbZ-;w-ih-,-lh izrhd gksxk%
(1) une (2) unh (3) uun (4) uue
Ans. (4)
Sol. 119 Ununenium (uue)
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