JEE Main 2020 Chemistry Answer Key 9 Jan Shift 2 by Resonance
JEE Main 2020 Chemistry Answer Key 9 Jan Shift 2 by Resonance
JEE Main 2020 Chemistry Answer Key 9 Jan Shift 2 by Resonance
com
PART : CHEMISTRY
SECTION – 1 : (Maximum Marks : 80)
Straight Objective Type (lh/ks oLrqfu"B izdkj )
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. 5 g of Zn reacts with
(I) Excess of NaOH (II) Dilute HCl, then volume ratio of H2 gas evolved in (I) and (II) is
(1) 2 : 1 (2) 1 : 2 (3) 1 : 1 (4) 3 : 1
5 xzke Zn fuEu ds lkFk fØ;k djrk gSA
(I) NaOH dk vkf/kD; (II) ruq HCl, rc (I) rFkk (II) es mRlftZr H2 xSl dk vk;ru vuqikr gS&
(1) 2 : 1 (2) 1 : 2 (3) 1 : 1 (4) 3 : 1
Ans. (3)
Sol. Zn + 2NaOH Na2ZnO2 + H2
Zn + 2HCl ZnCl2 + H2
According to stoichiometry in both the reactions, equal number of moles of H2 are evolved.
nksuks vfHkfØ;kvksa es jllehdj.kfefr ds vuqlkj H2 ds eksyks dh leku la[;k mRlftZr gksrh gSA
2. Given Ksp for Cr(OH)3 is 6 × 10–31 then determine [OH–].
(Neglect the contribution of OH– ions from H2O)
fn;k gS Cr(OH)3 ds fy;s Ksp, 6 × 10–31 gS rc [OH–] dk fu/kkZj.k dhft;sA
(H2O ls OH– vk;uksa dk ;ksxnku ux.; ekusaA)
1/ 4
6
(1) (18 × 10–31)1/4 M (2) (18 × 10–31)1/2 M (3) (6 × 10–31)1/4 M (4) 10– 31 M
27
Ans. (1)
Sol. Cr(OH)3 Cr+3 + 3OH–
s 3s
Ksp = s . (3s)3
6 × 10–31 = 27.s4
1/ 4
6
s= 10– 31
27
–
[OH ] = 3s
1/ 4
6
=3× 10– 31 = (18 × 10–31)1/4 M
27
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kJ kJ
4. Given an element having following ionisation enthalpies IE1 = 496 and IE2 = 4562 one mole
mol mol
hydroxide of this element is treated separated with HCl and H2SO4 respectively. Moles of HCl and
H2SO4 reacted respectively is
kJ kJ
fuEu vk;uu ,UFkSYih j[kus okyk ,d rRo fn;k x;k gS IE1 = 496 rFkk IE2 = 4562 bl rRo ds ,d
mol mol
eksy gkbMªkWDlkbM dks i`Fkd :i ls Øe'k% HCl rFkk H2SO4 ds lkFk mipkfjr fd;k tkrk gSA vfHkÑr HCl rFkk
H2SO4 ds eksy Øe'k% gS&
(1) 1, 0.5 (2) 0.5, 1 (3) 2, 0.5 (4) 0.5, 2
Ans. (1)
Sol. According to the given data of I.E, This element must belong to group 1 and thus is monovalent & form
hydroxide of the type M(OH).
MOH + HCl MCl + H2O
1 mole 1 mole
2MOH + H2SO4 M2SO4 + H2O
1 mole 1/2 mole
Sol. I.E. ds fn;s x;s vkadM+ks ds vuqlkj ;g rRo oxZ 1 ls lEcfU/kr gksuk pkfg;s blfy;s ;g ,dy la;ksth gSS rFkk
M(OH) izdkj dk gkbMªkWDlkbM cukrk gSA
MOH + HCl MCl + H2O
1 mole 1 mole
2MOH + H2SO4 M2SO4 + H2O
1 mole 1/2 mole
5. Reactant A represented by square is in equilibrium with product B represented by circles. Then value of
equilibrium constant is
oxZ }kjk iznf'kZr vfHkdkjd A o`Ùkksa }kjk iznf'kZr mRikn B ds lkFk lkE; esa gSA rc lkE; fu;rkad dk eku gSA
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8. A compound (A ; B3N3H3Cl3) reacts with LiBH4 to form inorganic benzene (B). (A) reacts with (C) to
form B3N3H3(CH3)3. (B) and (C) are respectively.
(1) Boron nitride, MeMgBr (2) Boron nitride, MeBr
(3) Borazine, MeBr (4) Borazine, MeMgBr
,d ;kSfxd (A ; B3N3H3Cl3) LiBH4 ds lkFk fØ;k djds vdkcZfud cSathu (B) cukrk gSA (A), (C) ds lkFk fØ;k
djds B3N3H3(CH3)3 cukrk gSA (B) rFkk (C) Øe'k% gSA
(1) cksjksu ukbVªkbM, MeMgBr (2) cksjksu ukbVªkbM, MeBr
(3) cksjksthu, MeBr (4) cksjksthup, MeMgBr
Ans. (4)
Sol. B3N3H3Cl3 + LiBH4 B3N3H6 + LiCl + BCl3
(A) (B)
B3N3H3Cl3 + 3MeMgBr B3N3H3 (CH3)3 + 3MgBrCl
(A) (C)
9. In a box a mixture containing H2, O2 and CO along with charcoal is present then variation of pressure
with the time will be as follows :
,d ckWDl es pkjdksy ds lkFk H2, O2 rFkk CO ;qDr ,d feJ.k mifLFkr gS rks le; ds lkFk nkc dk vUrj fuEu
izdkj gksxk&
P
P
(1) (2)
Time Time
P
(3) (4)
P
Time Time
Ans. (3)
Sol. Theory based. ¼lS}kfUrd½
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HCl HBr
(3) (4) CH3CH2–CH=CH2
Ans. (2)
Sol. (CH3)2CH–CH=CH2
HCl
(CH3 )2 CH CH CH3
Hydride shift
CH3–C–CH2–CH3
CH3
Cl
CH3–C–CH2–CH3
CH3
In this reaction, major product is not chiral.
mijksDr vfHkfØ;k eas eq[; mRikn fdjSy ugh gSA
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17.
Lab tests
Compound Molisch's test Barfoed test Biuret test
A
B
C
Which of the following options is correct ?
A B C
(1) Lactose Glucose Albumin
(2) Lactose Glucose Alanine
(3) Lactose Fructose Alanine
(4) Glucose Sucrose Albumin
iz;ksxkRed ifj{k.k
;kSfxd ekWfy'k ifj{k.k cksjQkWM ifj{k.k ckb;wjsV ifj{k.k
A
B
C
fuEu esa ls dkSulk fodYi lgh gS\
A B C
(1) ysDVksl Xyqdksl ,YC;qfeu
(2) ysDVksl Xyqdksl ,ykuhu
(3) ysDVksl ÝDVksl ,ykuhu
(4) Xyqdksl lqØksl ,YC;qfeu
Ans. (1)
Sol.
iz;ksxkRed ifj{k.k ekWfy'k ifj{k.k cksjQkWM ifj{k.k ckb;wjsV ifj{k.k
ifj{k.k nsrk gS ysDVksl, Xyqdksl, ÝDVksl Xyqdksl ,YC;qfeu
ifj{k.k ugha nsrk gS lqØksl ,ykuhu
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CH3
Br
B (C7H6NBr3)
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CH=O CH=O
(1) Br2, h
20. Compound X ;kSfxd X (1) Br2, h
(2) alc.KOH (2) ,Ydks.KOH
(3) O3 (3) O3
(4) Me2S (4) Me2S
(5) dil. NaOH, (5) ruqNaOH,
Compound X will be :
;kSfxd X gksxk%
Ans. (4)
Br CH=O
O
Sol.
Br,h
alc.KOH
O3
H H
OH
Me2S
O
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21. Total number of Cr–O bonds in Chromate ion and dichromate ion is.
ØksesV vk;u rFkk MkbØksesV vk;u es Cr–O cU/kksa dh dqy la[;k gS&
Ans. 12.00
O O O
22. Lacto bacillus has generation time 60 min. at 300 K and 40 min. at 400 K. Determine activation energy
kJ 2
in . (R = 8.3 J K–1mol–1) ln –0.4 (given wrong in paper)
mol
3
kJ
ysDVkscsflyl 300 K ij ih<+h le; 60 min. rFkk 400 K ij 40 min j[krk gSA es lfØ;.k ÅtkZ dk fu/kkZj.k
mol
2
dhft;sA (R = 8.3 J K–1mol–1) ln –0.4 (iz'ui=k es xyr fn;k x;k gSA)
3
Ans. 03.98
K Ea 1 1
Sol. ln 2 = –
K1 R T1 T2
60 E 100
ln = a ×
40 8 .3 400 300
ln(3/2) × 8.3 × 1200 = Ea
Ea = 0.4 × 8.3 × 1200
Ea = 3984 J/mol.
Ea = 3.984 kJ/mol.
23. One litre sea water (d = 1.03g/cm 3) contains 10.3 mg O2 gas. Determine concentration of O2 in ppm.
,d yhVj leqnzh ty (d = 1.03g/cm3) es 10.3 mg O2 xSl mifLFkr gSA O2 dh lkUnzrk dk fu/kkZj.k ppm es dhft;s
Ans. 10.00
10.3 10–3
Sol. ppm = ×106 = 10
1030
24. 0.1 mole of an ideal gas has volume 1 dm 3 in a locked box with friction less piston. The gas is in thermal
equilibrium with excess of 0.5 m aqueous ethylene glycol at its freezing point. If piston is released all of
a sudden at 1 atm then determine the final volume of gas in dm 3 (R = 0.08 atm L mol–1 K–1 Kf = 2.0 K
molal–1).
0.1eksy ,d vkn'kZ xSl ?k"kZ.k jfgr fiLVu ;qDr ,d cUn ckWDl es 1 dm3 vk;ru j[krh gSA ;g xSl blds fgekad
ij 0.5 m tyh; ,FkkbZfyu Xykbdksy ds vkf/kD; ds lkFk rkih; lkE; es gSA ;fn fiLVu dks vpkud 1 atm ij
NksM+ fn;k tkrk gS rks xSl ds vfUre vk;ru dk fu/kkZj.k dm3 es dhft;sA (R = 0.08 atm L mol–1 K–1 Kf = 2.0 K
molal–1).
Ans. (02.18)
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Ideal gas
Sol.
CH3MgBr Cu
25. Compound A B CH3–C=CH–CH3
H3O+ 573 K
CH3
Percentage carbon in compound A is:
CH3MgBr Cu
;kSfxd A B CH3–C=CH–CH3
H3O+ 573 K
CH3
;kSfxd A esa fdrus izfr'kr dkcZu mifLFkr gS%
Ans. 66.67
O O– OH
H3O
Cu
Sol. CH3–C–CH2–CH3
CH3–C–CH2–CH3 CH3–C–CH2–CH3
CH3MgBr CH3–C=CH–CH3
573 K
CH3 CH3 CH3
O
Compound A is CH3–C–CH2–CH3 (C4H8O)
12 4
Percentage carbon in compound A = 100 = 66.67
48 16 8
O
;kSfxd A is CH3–C–CH2–CH3 (C4H8O)
12 4
;kSfxd A dkcZu dh izfr'krrk =
100 = 66.67
48 16 8
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