An Introduction To Ion Exchange Resins
An Introduction To Ion Exchange Resins
An Introduction To Ion Exchange Resins
An Introduction to
TABLE OF CONTENTS
Conclusion
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Chapter One
WHAT ARE ION
EXCHANGE RESINS AND
HOW DO THEY WORK?
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present in the regenerant solution. The contaminant ions will exit the
IX system as part of the regenerant effluent stream and will need to
be properly discharged. In most cases, the resin is rinsed to remove
any residual regenerant prior to the next active IX cycle.
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Chapter Two
Specialty resins
What they are
As their name implies, specialty resins are used for a variety of
specific applications. Chelating resins are the most common type
of specialty resin, and are used for selective removal of certain
metals, brine softening and other substances. Specialty resin
functional groups vary widely depending upon the application at
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Chapter Three
COMMON PROBLEMS WITH ION
EXCHANGE RESINS AND HOW
TO AVOID THEM
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Ion exchange resins can be highly efficient with relatively low cost
and energy requirements. If they are properly maintained, resin beds
can last years before requiring replacement, and for highly selective
removal needs in process streams, ion exchange resins can prove
ideal.
Despite the many benefits of using ion exchange resins in the
appropriate separation processes, challenging issues can arise. This
chapter discusses some “common problems with ion exchange resins
and how to avoid them,” ensuring your facility can keep one step
ahead and remain as productive as possible.
Resin fouling
When your ion exchange treatment system begins to require more
rinsing, becomes more sensitive to temperature and flow rate
variations, or exhibits a decrease in effluent quality and operating
capacity at a quicker-than-anticipated rate, fouled resins could be to
blame.
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Oxidation
When oxidizing agents—such as chlorine, chlorine dioxide,
chloramine, and ozone—come into contact with both cation and
anion resins under certain conditions, they can damage the resins,
leading to capacity loss and inhibited performance. When present in
a feed stream, oxidants degrade IX resin polymers, causing them to
deform and compact over time. This compaction obstructs the flow
of liquids through the resin bed, which can compromise the overall
effectiveness of the IX unit, and lead to inconsistent effluent quality
due to channeling in the resin bed.
While oxidation damage to IX resins cannot be reversed, it can be
prevented through various pretreatment measures. Common
preventative measures for oxidation degradation include application
of activated carbon filtration, ultraviolet irradiation, or chemical
pretreatment through the application of a reducing agent.
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Inadequate regeneration
Suboptimal IX system function can result when regenerant solutions
are administered incorrectly. Sometimes regeneration methods yield
varying results, even when they are implemented with the same
procedure. Resin regeneration is a complex calculation, and the
outcome often depends on the overall resin condition, regeneration
process water quality, regenerant chemical concentration, flow rate,
temperature, and contact time, to name a few. Both cation and anion
resin can be scaled from improper regeneration. For example,
regenerating with a too-high concentration of sulfuric acid can cause
calcium sulfate scale on the resin. With some anion resins, silica can
precipitate with improper caustic concentrations.
With all the possible scenarios, following the resin manufacturer’s
guidelines for regenerant concentration, application time, and flow
control can help prevent issues and is advisable.
Channeling
Channeling occurs when liquids pass through the resin unevenly,
carving pathways that result in the uneven exhaustion of the resin,
and breakthrough of untreated solution into the effluent stream.
Channeling can be caused by incorrect flow rates, failure of the
distributor mechanism, inadequate backwashing, and blockages by
dissolved solids or damaged resin beads.
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Chapter Four
WHAT ARE THE BEST (AND
CHEAPEST) WAYS TO DISPOSE
OF ION EXCHANGE RESINS?
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DISPOSING OF ION
EXCHANGE RESINS
The best and most cost-effective ways
the hydraulic load of the resin, and whether any extreme process
conditions exist. IX resins degrade gradually with use, making it
difficult to tell exactly when they must be replaced. For most
facilities, resins should only be discarded when the output quality or
loss in capacity justifies the re-bedding costs, which can be
substantial, as they include removal and disposal of old resin, and
purchase and installation of new resin.
There are a few key indicators that it might be time for IX resin
replacement. These include the amount of resin lost during
backwash cycles, IX capacity loss of 10-20% or more, and inadequate
quality in the treated stream. Still, the decision to re-bed should be
made with careful cost analysis in mind. Certain changes in system
performance, such as a drop in effluent quality, shorter service runs
or higher chemical dosages, can be good indicators that the resin
should be evaluated. Some companies provide analysis services to
evaluate the salt splitting ability and physical condition of the resin
and can provide you with a report to compare resin performance
against new.
Chapter Five
HOW MUCH DOES IT COST TO
BUY, MAINTAIN, AND DISPOSE
OF ION EXCHANGE RESINS?
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One of the main things you should plan for when regenerating on-site
is a chemical-handling system to store the chemicals and feed them
to the ion exchange system. For a robust industrial chemical handling
system with storage tanks, metering pumps, and forwarding pumps,
cost can be around $100,000 to $300,000 depending on the size.
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