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INORGANIC CHEMISTRY 2

[[ Number of Pages:

4 including coverpage

Annexure(s): 1

FACULTY OF APPLIED SCIENCES

CHEMISTRY DEPARTMENT

COURSE:

SUBJECT:

CODE(S):

DATE:

DURATION:

MARKS:

EXAMINER:

INTERNAL EXTERNAL
MODERATOR: MODERATOR:

INSTRUCTIONS TO CANDIDATES:

REQUIREMENTS:

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INORGANIC CHEMISTRY 2

SECTION A

1. 1.1 Give the noble-gas-core abbreviated notations for the electron


configuration of

(a) chromium 2
(b) nickel 2

1.2 Make use of the electron configuration of nickel to explain what


ferromagnetism is. 2
(6)
2. Associate, giving the main forces between particles, each of the solids

K2CrO7 , Hg , SiO2 , CHI3

with one of the following sets of properties:

(a) a very hard substance that melts at about 3000 C.


(b) an orange non-conducting solid that melts at 800 C to give an
electrically conducting liquid.
(c) a yellow solid with a characteristic odour having a melting point of
120 C.
(d) a gray lustrous electrically conducting liquid. (6)

3. Choose, with reasons, which substance in each of the following pairs has
the higher boiling point:

3.1 HCl or HI 3
3.2 CaO or KBr 4
3.3 NO or N2 3
3.4
O 3
or CH3CH2OH
3.5

or 3
(16)

4. Use reaction equations to briefly discuss energy changes involved in the


formation of solid magnesium chloride from solid magnesium and chlorine
gas. (5)

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INORGANIC CHEMISTRY 2

5. Study the structure below and answer the following questions:

(a) Is the structure body-centered cubic (bcc) or face-centered cubic


(fcc)? Explain your answer. 3

(b) What is the coordination number of the ion in the shaded unit cell? 1
(4)

6. An isolated ion had no definite size, but in a crystal, it is possible to assign


a “radius” to ions.

Briefly discuss the two (2) main factors that will influence the magnitude of
ionic radii. (4)

7. The approximate radii of the Na + and Cl- ions are 99 pm and 181 pm
respectively.

(a) Calculate the radius ratio of NaCl. 1

(b) What can be predicted (determined) from the radius ratio? 2


(3)

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