AITS 1819 OT JEEA PAPER 2 Sol
AITS 1819 OT JEEA PAPER 2 Sol
AITS 1819 OT JEEA PAPER 2 Sol
JEE (Advanced)-2019
PAPER – 2
SECTION – A
1. B, D
Sol. Distance of image of fish as seen by bird only after refraction is Bird
2
(x h) (h y) 2
1
z
1 x image
(x h) (h y) 1 h
4/3
Fish
Differentiate w.r.t. time y
d 3 17
( 6 2) ( 2 4) cm/sec
dt 4 2
Similarly we can calculate for 2nd case.
2. C, D
Sol. Collision takes place in ideal gases are elastic hence total kinetic energy will be conserved.
3. A, C, D
2u sin
Sol. T 2 sin15
g
Horizontal component of velocity will reverse in each collision.
u2 sin2
R 5 m
g
4. A, C
1 2
Sol. In time interval (0 to 3) sec, S ut at = 30 m
2
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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2
30
v average 10 m/s
3
In time interval (0 to 6) sec
v u at 40 m/s
v f vi (5 40) 5 5 20 2
aaverage m/s
t 6 3
5. A, C
Sol. Deviation Normal
1
1 2 (Clockwise)
50°
2 2 50 (Anti-clockwise)
40°
1 2
40°
50°
2
6. A
Sol. Ball moves very slowly hence it is in equilibrium at each instant.
7. D
hC
N x
Sol. Intensity is given by I , where
(A cos )t y
N total number of photons and
wavelength of photons 90
8. C
Sol. Circuit can be solved by using Phasor diagram.
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3 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19
9. A
Sol. By using concept of motional emf induced in the circuit.
10. A
y
Sol. v 0 2gh 5 m/s …(i) Jy
Jy = Py = 2 80 5 = 800 N-s …(ii)
Jx = Px
Jy = mv x Jx x
v0
v x = 1 m/s …(iii) f
MvC = Jx
Jx f
vC = 0.4 m/s …(iv)
25 Cart
t0 1 sec …(v)
10
Lmin = 2(1 + 0.4) 1 = 2.8 m …(vi)
At the time of second collision
R 1 = 0.4
= 7 rad/s …(vii)
J L
JxR I( 0 )
0 19.5 rad/sec …(viii)
1
WmM Mv C2 16J …(ix)
2
1 1 1
WMm I()2 mv 2x I02 172 J
2 2 2
SECTION – D
11. 00006.92
x normal
Sol. tan 60 Y
2
x2 3m
60
Hence total length = 4 3 m. M2 3030 M1
O
man x x-axis
12. 00035.20
Sol. To reach at ‘B’ it should crosses the point ‘A’. Now from work energy theorem
W = K
W g + W f = K f Ki
mg(4H) (0.4)mgH = 0 ki
Ki = 44 mH = 35.20
13. 00002.40
Sol. L Icm (r pcm )
m(2R)2
L 0 R(2m)(R0 )
2
L 4mR2 0 = 2.40
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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 4
14. 00016.64
Sol. dsin ( 1)t x
3 3
d x
2d 2
x = 3
Hence maximum intensity will occur at ‘O’.
I = 4I0 = 16.64 W/m2
15. 00002.67
2E0
Sol. (Mg) 1 = 2
tc
2 20 2 8
M 3 8
= 103 kg
10 0.01 10 3 10 3
16. 00000.74
Sol. pitch = 0.2 mm
Total division = 200
Least count = 0.001 mm
ve zero error = 40 L.C. = 0.04 mm
Reading = 0.6 mm + 100 L.C. = 0.7 mm
Thickness = 0.7 mm + 0.04 mm = 0.74 mm
17. 00002.25
Sol. In time dt shift in centre of mass of system (ball + liquid)
m ds m2 ds2 b V vdt V vdt
d SCM 1 1 …(i)
M M
dS
Momentum of system = M. cm …(ii)
dt
= (bV) v – (V ) v
Therefore momentum of liquid = (V )v
= 2.25 gm/cm 3.
18. 00002.33
2GM
Sol. Speed of projection v 0 ...(1)
R
1 GMm 1 GMm
mv 2 mv 2 …(2)
2 R 2 r
2GM
v
r
4R t
rdr 2GM dt
R 0
3
7 2R
t .
3 GM
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5 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19
Chemistry PART – II
SECTION – A
19. A, C
Sol. Main hexagonal unit cell (figure A) consists of three identical smaller unit cells (B).
20. A, C, D
Sol. H3C H3C
Cl Cl
CH3 CH3
Cl Cl
H3C
Cl B
A
21. B, C, D
22. B, C
Sol. Weight of pay load = 80 × 103 g
Let, the number of balloons required be x.
nRT
80 103 0 100x x 1.25
P
x = 26.8
23. A, B, D
Sol. O
O O
O3
CH3 CH CH CH2 CH3
H3C CH CH CH2 CH3
O O
H3 C CH CH CH2 CH3
O
Zn / H2O
24. A, B, D
Sol. Cl Cl
Br
Mg 1 eqvt int ramolecular nucleophilic substitution
ether
N
N N
H MgBr
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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 6
O O O OH
H
Br
H
Br Br
Tautomerism
25. A
26. C
Sol. NaCl type solid CsCl type solid
a 3a
1st nearest distance
2 2
a
2nd nearest distance a
2
3a
3rd nearest distance 2a
2
11a
4th nearest distance a
2
5a
5th nearest distance 3a
2
3a
6th nearest distance 2a
2
27. C
Sol. General property trends.
28. A
Sol. O O
OH
i MCPBA
OH
ii dil. H2SO4
O
O
H
dil. OH
O
O
O
+ 3
C OH
NK
i CH Cl
CH3NH2
ii Dil. H
C OH
O O
Na/C2H5 OH
CH3NC CH3 NH CH3
SECTION – D
29. 00002.50
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7 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19
n2a
Sol. P 2 V nb nRT
V
n=1
a
P V 2 V b RT
If ‘b’ is negligible, then
a RT a
P V 2 V RT , P V V 2
The equation is quadratic in ‘V’, thus
RT R2 T 2 4aP
V
2P
‘V’ has one value at a given P and T, thus numerical value of discriminant = 0
So, R2 T 2 4aP
2 2
R2 T 2 0.08 300
P 40
4a 4 3.6
30. 00000.50
2x
Sol. x A sin
d x 2 2x
A cos
dx
d2 x 2
2
2x
2
A sin So, n = 2, m = -4, p = 2, q = 2
dx
d2 x 4 2 x
dx 2 2
31. 00015.05
Sol. Complex Magnetic moment
2
Cu NH3 4 3 1.73 B.M.
3
Fe CN6 3 1.73 B.M.
2
NiCl4 2 2 2.82 B.M.
3
CoF6 24 4.90 B.M.
32. 00054.50
Sol. x = 22.5; y = 30; z = 2
In parallel reactions the activation energy of the overall path is given by
k1Ea1 k 2Ea2
Ea net
k1 k 2
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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 8
33. 00007.50
2
Sol. 2 Au CN2 Zn 2Au Zn CN4
Eo 0.60 1.26 0.66 V
o + +
Since E value for the reduction of complexed Ag ion to Ag is higher than that of complexed Au
+
ion into Au. So, Ag ion will be reduced first.
78
Moles of Zn added 1.2
65
–
Moles of [Ag(CN)2] = 0.003 × 500 = 1.5
Moles of [Au(CN)2]– = 0.002 × 500 = 1.0
–
Moles of Zn used to reduce 1.5 moles of [Ag(CN)2] = 0.75
–
Moles of [Au(CN)2] reduced by remaining 0.45 moles of Zn = 0.90
Moles of [Au(CN)2]– left in the solution = 0.10
– 0.10
Concentration of [Au(CN)2] left in the solution 2 10 4 M x
500
–
Au CN2 , K f 4 10
Also, Au 2CN
28
–
Au CN2 90 Au
Kf 4 10 28
2 2
Au CN 10 Au CN
CN 1.5 1014 M y
y 1.5 10 14
So, 7.50 10 11
x 2 10 4
So, A = 7. 50
34. 00367.50
Sol. Let, the moles of KClO3 required to be ‘x’. Assuming 50% yield in each step.
x
Moles of O2 formed in step (i) .
2
x
Moles of each of K2MnO4 and Cl2 formed in (i)
4
x
Moles of O2 formed in step (ii) =
8
x x 5x
Total moles of O2 formed
2 8 8
5x 60
8 32
x=3
35. 00000.80
Sol. Tf i K f m
0.00558 = i × 1.86 × 0.001 i 3
i 1 y 1 1 3 y 3
So, formula of the complex Pt NH3 4 Cl2 Cl2
36. 00004.50
Sol. x = 3, y = 15, z = 10
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9 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19
SECTION – A
37. A, B, C, D
Sol. A + B = ABAB = A2 + A
2
B=A
BAB = A5 = A + I A(A4 – I) = I
B5 – A5 = (A5)2 – A5 = (A + I)2 – (A + I) = A2 + A = A + B
38. A, D
x
Sol. Let f(a) = 0 and F x f t dt
0
F(x) = –f(x) 0 x < a, F(x) = f(x) a x 1
2 2
1
x F 1 F a 2 = S1 S2 S 2 7
f x f t dt dx
2
2
2
0 0
39. B, C
b b b
tan
tan 1 1
Sol. tan a = a a ab
b b
1 tan2 cot tan 2 b 2 ab
a a a
A(a cos , a sin )
b b 2b
tan cot
a a 2ab
tan 2
a 2 2 2
b b a b
1 2 1 2
a a
40. A, C
393 n 5
Sol. n2 5 2n 5 n2 25
5
73.6 n 83.6, n = 80 is only possible value
41. B, C
x x
1 x 2 tan 2
2 1 x sin 3x
2
1 x 1 x2
Sol. lim
x 0 xp
Using expansion
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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 10
x x3 2 x5
1 x2 3
5
.....
1 x 2 15
3 1 x2 2
1 x2 2
2x x3 x5
2 1 x 3
5
..... 3x
1 x 2
lim
3! 1 x 2 2
5! 1 x 2 2
x 0 xp
2 2 1
2 x5
3 15 2 2
lim
1 x2
5! 1 x 2
x 0 xp
2 2 2 31
p = 5 and limit =
3 15 5! 60
42. A, B, D
Sol. All the values of |A| = 4, 0 and determinant is 0 when two rows/columns are proportional
43. B
Sol. (P) d2 3
(Q) These lines are skew and O lies on shortest distance
(R) Lines are parallel and O lies mid way between them (1, 1, –1) (A, B)
(S) Lines are coplanar and perpendicular
O
44. D
Sol. We can consider 9 cells as 9 different boxes and we have to fill these boxes by 3 identical balls
(2 written on them), 4 identical balls (3 written on them) and 7 identical balls (5 written on them)
as per given conditions
45. A
Sol. (P) x2 – a = x
x2 – x – a = 0
D<0
1 + 4a < 0
1
a
4
(Q) a a
a a
a > a2
2
a –a<0
a(a – 1) < 0
0<a<1 (–a, 0)
One real
a,0 a,0
1
a (0, –a) One real
4
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11 AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19
(R) x2 – x – a = 0
1 + 4a > 0, –a > 0
1
a ,a<0
4
1
a0
a, 0
4 (–a, 0) Two real
a a One real
a a , a2 > a (–a, 0)
a(a – 1) > 0, a 1
46. A
Sol. For regular quadrilateral n must be multiple of 4. Perpendiculars dropped from a plane
5
C 8C
circumcentre to side is always collinear. For one of the side to be diameter P E 101 1 and
C3
9
C1 4 C2 5
orthocentre is inside for acute angled triangle P E 1 9
C3 14
SECTION – D
47. 00021.00
a d 1 a d 1
Sol. b e 1 5 b e 2 3
c f 1 c f 3
a d 1 a d 1
2 b e 2 3 b e 1 21
c f 3 c f 1
a d 1
b e 1 21
c f 3
48. 00009.00
1 a1
Sol. Take an n
, on solving, we get an ,
2 tn 2 2 n n 1
a1 2
6
2 2 n
for periodicity a1 2 n1 1 ,
6
n
2 2
for undefined a1 2 n 1 0 ,
6
lim an 0
n
49. 01600.00
6 3
Sol. x – 2x – 8 = (x – 1)(x – 2) .....(x – 6)
6 3
(2) – 2(2) – 8 = (2 – 1)(2 – 1) ..... (2 – 6)
((2 ) – 2(22)3 – 8) = (22 – 1) ..... (2 – 6)
2 6
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AITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/19 12
50. 00062.00
2014 r 2014
k
Sol. 1 k 1k 2 2019 Cr k 2 2016 Cr 22017 4034
r 0 k 0 r 0
51. 00061.25
dx x 1 x 1
Sol. e e 3
dy y y
d x 1 1
dy
e y 2 , e x y c
y y
52. 00018.00
Sol. Area PRST = PQR – QST
1 1 1
P 3, 2 3
= 8 2 3 4 4 sin150º
2 2 2 T
= 8 3 2 3 6 3
30º
Q S R
53. 00009.00
y y
2 y3
Sol.
x 4 y 3 y dx x 2 y 3 y dx
3
y2 3 y
0 0
3
y
f y y2 3 y
3
f(y) = y2 + 6y – 3y2 = 2y(3 – y) > 0 for 0 y 3 so maximum occurs at y = 3
54. 00056.25
Sol. Given expression is r1r2 + r2r3 + r1r3 = s2 = (7.5)2
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